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| ???org.dspace.app.webui.jsptag.ItemTag.dcfield??? | Value | Language |
|---|---|---|
| dc.contributor.advisor | 陳力騏(Richie L. C. Chen) | |
| dc.contributor.author | Wei-Cheng Chen | en |
| dc.contributor.author | 陳韋成 | zh_TW |
| dc.date.accessioned | 2021-06-16T05:10:34Z | - |
| dc.date.available | 2014-08-22 | |
| dc.date.copyright | 2014-08-22 | |
| dc.date.issued | 2014 | |
| dc.date.submitted | 2014-08-18 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/55907 | - |
| dc.description.abstract | 本研究採用具有高輸入阻抗、低輸入偏壓電流與低輸入補償電壓等特性之運算放法器（OPA2336P，Texas Instruments），搭配USB供電的DAQ（NI 6008/6009，National Instruments）與LabVIEWTM撰寫的圖形化使用者介面，組裝一台平行輸入自動換檔並且便於攜帶之小型恆電位儀，可應用於實驗室外的現場檢測並且與商用實驗室泛用型儀器（AutolabTM，Eco Chemie）相比所得到之檢測結果幾乎相同。本研究所提出之恆電位儀操作電位的範圍約從-1.3 V到1.1 V，最佳量測的解析度可到100 pA。以本研究所提出之恆電位儀搭配流動式注射系統，對鄰苯二甲醛濃度做初步的的濃度檢測，所量測到的氧化電流大小在0.2%-0.65%（w/v）範圍內呈線性相關（R2 = 0.9911），且變異係數小於5%，靈敏度為0.18 μA/cm2 mM，可應用於評估消毒內視鏡常用之鄰苯二甲醛最低有效濃度（Minimum effective concentration, MEC）。 | zh_TW |
| dc.description.abstract | An auto ranging mini-potentiostat was constructed by parallel reading architecture and using operational amplifiers (OPA2336P, Texas Instruments) with high input impedance, low input bias current and low input offset voltage. After implementing with a USB-powered DAQ (NI 6008/6009, National Instruments) and LabVIEWTM based graphical user interface, the portable electrochemical device can be used for on-site analysis with a performance comparable to a commercialized laboratory machine (AutolabTM, Eco Chemie). The operating voltage ranges from -1.3 V to 1.1 V and the resolution can reach 100 pA level. The mini-potentiostat was served as the amperometric detector of a conventional flow injection analysis system for measuring o-phthalaldehyde concentration. The current outputs (the peak heights of FIAgram) are reproducible (CV < 5%) and showed good linearity (R2 = 0.9911) in the range of 0.2%-0.5% (w/v), which can be used to evaluate the antiseptic efficiency (minimum effective concentration of o-phthalaldehyde) of the disinfectant used for cleaning endoscope. The sensitivity is 0.18 μA/cm2 mM. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T05:10:34Z (GMT). No. of bitstreams: 1 ntu-103-R01631016-1.pdf: 4825191 bytes, checksum: 10835953c3455b7dc37812b2035fee34 (MD5) Previous issue date: 2014 | en |
| dc.description.tableofcontents | 摘要 i
目錄 iii 圖目錄 vi 表目錄 viii 第一章 研究目的 1 第二章 文獻探討 2 2.1 電化學分析 2 2.1.1 二極與三極式電極架構 2 2.1.2 電位測定法（Potentiometry） 4 2.1.3 庫倫量測法（Coulometry） 5 2.1.4 伏安法（Voltammetry） 6 2.1.5 電流測定法（Amperometry） 9 2.2 恆電位儀（Potentiostat） 11 2.2.1 電位控制組態 13 2.2.1.1 工作電極接地 13 2.2.1.2 輔助電極接地 14 2.2.2 電流量測組態 15 2.3.2.1 轉阻放大器量測 (Transimpedance amplifier measurement) 15 2.2.2.2 電流經純電阻跨壓差動量測 17 2.2.2.3 電流傳輸器量測 (Current conveyor measurement) 19 2.3 內視鏡消毒劑 20 2.3.1 鄰苯二甲醛 (o-phthalaldehyde, OPA) 20 2.3.2 鄰苯二甲醛現行檢測方法與棄置 23 第三章 研究方法 23 3.1 實驗藥品與製備 25 3.2 實驗儀器與器材 26 3.3 恆電位儀電路元件建置與選擇 27 3.3.1 分段電阻檔位 27 3.3.2 檔位合併無段量測 29 3.3.3 元件選擇 33 3.4 恆電位儀基本性能校正與測試 34 3.4.1 Dummy cell 測試 34 3.4.2 Electrochemical cell測試 35 3.4.3 樣品循環伏安法測試 36 3.4.4 定電位電流測定法(Amperometry) 37 3.5 以電化學法檢測消毒劑鄰苯二甲醛（o-phthalaldehyde, OPA） 38 3.5.1 鄰苯二甲醛與甘胺酸反應後之氧化電位檢測 38 3.5.2 流動注射式系統架設 39 3.5.3 鄰苯二甲醛定電位電流測定 41 第四章 結果與討論 42 4.1 恆電位儀基本性能分析 42 4.1.1 Dummy cell 測試結果與限制 42 4.1.2 Electrochemical cell測試結果與限制 44 4.1.3 樣品循環伏安圖之比較與分析 46 4.1.4 定電位電流測定圖之比較與分析 48 4.2 OPA濃度檢測分析) 51 第五章 結論 54 第六章 參考文獻 55 第七章 附錄 63 | |
| dc.language.iso | zh-TW | |
| dc.title | USB驅動型迷你恆電位儀之開發與鄰苯二甲醛消毒劑之檢測 | zh_TW |
| dc.title | Development of a USB-powered Mini-potentiostat and the Detection of o-phthalaldehyde Disinfectant | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 102-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.coadvisor | 陳仲瑄(Chung-Hsuan Chen) | |
| dc.contributor.oralexamcommittee | 鄭宗記(Tzong-Jih Cheng),陳林祈(Lin-Chi Chen) | |
| dc.subject.keyword | 恆電位儀,鄰苯二甲醛,消毒劑, | zh_TW |
| dc.subject.keyword | potentiostat,o-phthalaldehyde,disinfectant, | en |
| dc.relation.page | 67 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2014-08-19 | |
| dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
| dc.contributor.author-dept | 生物產業機電工程學研究所 | zh_TW |
| Appears in Collections: | 生物機電工程學系 | |
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