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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 鄭淑芬(Soofin Cheng) | |
dc.contributor.author | Chung-Ming Huang | en |
dc.contributor.author | 黃崇銘 | zh_TW |
dc.date.accessioned | 2021-06-16T04:16:47Z | - |
dc.date.available | 2014-08-25 | |
dc.date.copyright | 2014-08-25 | |
dc.date.issued | 2014 | |
dc.date.submitted | 2014-08-20 | |
dc.identifier.citation | [1] Larminie. A.; Dieks, J. Fuel cell system explained 2nd, John Wiely, 2003.
[2] O’Hayre, R.; Cha, S. W.; Colella, W.; Prinz. F.B., Fuel cell fundamentals, Wiely, 2005. [3] 黃鎮江, 燃料電池, 全華科技圖書股份有限公司, 2003 [4] 清華大學材料科學與工程學系王丞浩博士論文, 2007. [5] Service, R. F. Science 2006, 312, 35. [6] Petrii, O. A. Journal of Solid State Electrochemistry 2008, 12, 609. [7] Sakthivel, M.; Schlange, A.; Kunz, U.; Turek, T. Journal of Power Sources 2010, 195, 7083. [8] Kim, J. H.; Fang, B.; Yoon, S. B.; Yu, J.-S. Applied Catalysis B: Environmental 2009, 88, 368. [9] Liu, Y.; Zheng, N.; Chao, W.; Liu, H.; Wang, Y. Electrochimica Acta 2010, 55, 5617. [10] Hwan Jung, D.; Hyeong Lee, C.; Soo Kim, C.; Ryul Shin, D. Journal of Power Sources 1998, 71, 169. [11] Seo, S. H.; Lee, C. S. J. Mechanical Engineering Sci. 2010, 224, 2211. [12] Hickner, M. A.; Ghassemi, H.; Kim, Y. S.; Einsla, B. R.; McGrath, J. E. Chemical Reviews 2004, 104, 4587. [13] Kreuer, K. D. Journal of Membrane Science 2001, 185, 29. [14] 中央大學化學系吳千舜碩士論文, 2004. [15] Ahmad, H.; Kamarudin, S. K.; Hasran, U. A.; Daud, W. R. W. Int J Hydrogen Energ 2010, 35, 2160. [16] Smitha, B.; Sridhar, S.; Khan, A. A. Journal of Membrane Science 2005, 259, 10. [17] Gebel, G. Polymer 2000, 41, 5829. [18] Kerres, J. A. Journal of Membrane Science 2001, 185, 3. [19] Deluca, N.W.; ELABD, Y. A. Journal of polymer science Part B: Polymer Physics 2006, 44, 2201. [20] Choi, P.; Jalani, N. H.; Datta, R. Journal of The Electrochemical Society 2005, 152, E123. [21] Haubold, H. G.; Vad, T.; Jungbluth, H.; Hiller, P. Electrochimica Acta 2001, 46, 1559. [22] Li, Q.; He, R.; Jensen, J. O.; Bjerrum, N. J. Chemistry of Materials 2003, 15, 4896. [23] Watanabe, M.; Uchida, H.; Seki, Y.; Emori, M.; Stonehart, P. Journal of The Electrochemical Society 1996, 143, 3847. [24] Antonucci, P. L.; Arico, A. S.; Cretı̀, P.; Ramunni, E.; Antonucci, V. Solid State Ionics 1999, 125, 431. [25] Kim, J. H.; Kim, S. K.; Nam, K.; Kim, D. W. Journal of Membrane Science 2012, 415-416, 700. [26] Asgari, M. S.; Nikazar, M.; Molla-abbasi, P.; Hasani-Sadrabadi, M. M. International Journal of Hydrogen Energy 2013, 38, 5894-5902. [27] Jiang, Z.; Zhao, X.; Manthiram, A. International Journal of Hydrogen Energy 2013, 38, 5875-5884. [28] Rhee, C. H.; Kim, H. K.; Chang, H.; Lee, J. S. Chemistry of Materials 2005, 17, 1691. [29] Eguizabal, A.; Lemus, J.; Urbiztondo, M.; Garrido, O.; Soler, J.; Blazquez, J. A.; Pina, M. P. Journal of Power Sources 2011, 196, 8994-9007. [30] Jiang, R.; Kunz, H. R.; Fenton, J. M. Journal of Membrane Science 2006, 272, 116. [31] Mauritz, K. A.; Stefanithis, D.; Davis, S. V.; Scheetz, R. W.; Pope, R. K.; Wilkes, G.; Huang, H. H. J. Appl. Poly. Sci. 1995, 55, 181. [32] Yoonoo, C.; Dawson, C. P.; Roberts, E. P. L.; Holmes, S. M. Journal of Membrane Science 2011, 369, 367-374. [33] Yang, H. N.; Lee, J. Y.; Jeong, J. Y.; Na, Y.; Kim, W. J. Microporous and Mesoporous Materials 2011, 143, 215-220. [34] Cozzi, D.; Bonis. C.; D’Epifanio, A.; Mecheri, B.; Tavares, A.; Licoccia, S. Journal of Power Sources 2014, 248, 1127-1132. [35] Kim, J.; Jeon, J. D.; Kwak, S. Y. Microporous and Mesoporous Materials 2013, 168, 148-154. [36] Ye, Y. S.; Liang, G. W.; Chen, B. H.; Shen, W. C.; Tseng, C. Y.; Cheng, M. Y.; Rick, J.; Huang, Y. J.; Chang, F. C.; Hwang, B. J. Journal of Power Sources 2011, 196, 5408-5415. [37] Luu, D. X.; Cho, E. B.; Han, O. H.; Kim, D. The Journal of Physical Chemistry B 2009, 113, 10072-10076. [38] Ladewig, B. P.; Knott, R. B.; Martin, D. J.; Diniz da Costa, J. C.; Lu, G. Q. Electrochemistry Communications 2007, 9, 781. [39] Jiang, R.; Kunz, H. R.; Fenton, J. M. Journal of Membrane Science 2006, 272, 116. [40] Lin, Y.; Li, H.; Liu, C.; Xing, W.; Ji, X. Journal of Power Sources 2008, 185, 904. [41] Lin, H.-L.; Wang, S.-H.; Chiu, C.-K.; Yu, T. L.; Chen, L.-C.; Huang, C.-C.; Cheng, T.-H.; Lin, J.-M. Journal of Membrane Science 2010, 365, 114. [42] Li, H.; Ai, M.; Jiang, F.; Yu, L.; Tu, H.; Yu, Q.; Wang, H. Journal of Power Sources 2011, 196, 4583. [43] Yang, T. Journal of Membrane Science 2009, 342, 221. [44] Chu, P.; Rubin, M. K. USP: 4954325 1990 [45] Leonowicz, M. E.; Lawton, S. L. Science 1994, 264, 1910-1913. [46] Corma, A.; Fornes, V.; Guil, J. M.; Pergher, S.; Maesen, Th. L. M.; Buglass, J. G. Microporous and Mesoporous Materials 2000, 38, 301-309. [47] Wu, T.; Xu, N.; 化學通報 2004, 67, 1-21. [48] 台灣大學化學系鄭茹方碩士論文, 2011. [49] 台灣大學化學系周瑋仁碩士論文, 2012. [50] Wieslaw, J. R.; Douglas, L. D. Microporous and Mesoporous Materials 2011, 142, 32-36. [51] Yang, S. T.; Kim, J. Y.; Kim, J.; Ahn, W. S. Fuel 2012, 97, 435-442. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/55678 | - |
dc.description.abstract | 燃料電池具有高發電效率以及低噪音等優點,因此在近年來越來越受到重視,其中在低溫下運作的直接甲醇燃料電池能被應用在攜帶式電子產品上,加上其具有低汙染以及比以氫氣為燃料的質子交換膜燃料電池來的安全,因此成為近年來熱門的開發目標。然而,甲醇燃料易經由質子交換膜由陽極穿透到陰極,造成使用效率下降。
本研究嘗試在Nafion溶液中加入MCM-22沸石,製備Nafion/MCM-22複合膜,希望能降低甲醇穿透度並提升質子傳導度。本研究第一部分為合成出MCM-22(P),接著利用反微胞的方式使其層間分散,並嘗試萃取和嫁接等後處理方式來應用在經過分散的材料上,以及藉由煆燒移除MCM-22(P)的模板得到MCM-22。第二部分為複合膜的製備,複合膜是以溶劑揮發法製成,最後實際應用在直接甲醇燃料電池上,並比較不同材料和添加量對膜的影響。 MCM-22等材料以X光繞射儀、氮氣吸脫附、掃描式電子顯微鏡、熱重分析儀、傅立葉轉換紅外線光譜儀進行分析。複合膜以甲醇擴散實驗和交流阻抗儀分析甲醇穿透度和質子傳導度,剖面型態則由掃描式電子顯微鏡來觀察,並實際做成膜電極組測試複合膜在甲醇燃料電池上的效果。 | zh_TW |
dc.description.abstract | Direct methanol fuel cell (DMFC) is considered as a highly efficient power source for portable devices. One of the main drawbacks of DMFC in practical application is methanol permeability through proton exchange membrane, which lowers down the cell performance.
In this study, layered zeolite MCM-22 was incorporated into Nafion solution to make composite membranes. The first part of my research is synthesis of MCM-22(P) and MCM-22. We also used inverse-micelle method to dispersive the layered structure of MCM-22(P) to make dis-MCM-22 then modified it by grafting and extraction. The second part of my research is preparation of composite membranes by solvent recasting technique. The influence of different treatments and amounts of MCM-22(P) was examined on the performances of resultant membranes in methanol permeability, proton conductivity and the test of DMFC. The characterization of zeolite is by XRD, BET, SEM, TGA and FT-IR. The performance of membranes is tested by methanol diffusion, proton conductivity, SEM and DMFC experiments. | en |
dc.description.provenance | Made available in DSpace on 2021-06-16T04:16:47Z (GMT). No. of bitstreams: 1 ntu-103-R01223134-1.pdf: 9367375 bytes, checksum: b2610e876d16b57e4c30a0989ec86dfb (MD5) Previous issue date: 2014 | en |
dc.description.tableofcontents | 謝誌……………………………………………………………………………………i
中文摘要………………………………………………………………………………ii ABSTRACT…………………………………………………………………………iii 目錄…………………………………………………………………………………iv List of Figures………………………………………………………………………vii List of Tables………………………………………………………………………xii 第一章 文獻回顧……………………………………………………………………1 1.1 燃料電池…………………………………………………………………………1 1.1.1 燃料電池發展史…………1 1.1.2 燃料電池構造……………3 1.1.3 燃料電池分類…………4 1.2 直接甲醇燃料電池……………………10 1.2.1 直接甲醇燃料電池構造……………………………10 1.2.2 影響直接甲醇燃料電池的因素………………………………13 1.3 質子交換膜………………………………16 1.3.1 質子交換膜…………………………16 1.3.2 全氟磺酸質子交換膜………………………17 1.3.3 質子交換膜發展現況…………………21 1.4 沸石……………………………………………………………………………26 1.4.1 MCM-22簡介………………………………………………………………26 1.5 研究目的………………………………………………………………………29 第二章 實驗方法……………………………………………………………………30 2.1 化學藥品………………………………………………………………30 2.2 無機孔洞材料之製備………………………………………………………32 2.2.1 合成MCM-22(P)及衍生物……………………………………………32 2.3 Nafion複合膜之製備……………………………………………………………34 2.3.1 乾式負載法………………………………………………………………34 2.3.2 溶劑摻入法……………………………………………………………34 2.4 複合膜之清洗……………………………………………………………………35 2.4.1 複合膜之清洗步驟………………………………………………………35 第三章 鑑定方法……………………………………………………………………36 3.1 MCM-22材料鑑定………………………………………………………………36 3.1.1 X光粉末繞射 (Powder X-ray diffraction, XRD)………………………36 3.1.2 氮氣吸附-脫附恆溫曲線 (N2 adsorption-desorption isotherm)…………36 3.1.3 掃描式電子顯微鏡 (Scanning electron microscopy, SEM)………………40 3.1.4 傅立葉紅外線光譜 (FT-IR)……………………………………………….40 3.1.5 熱重分析 (Thermal Gravimetric Analysis, TGA)…………………………40 3.1.6 元素分析 (Elemental Analyzer, EA)………………………………………41 3.2 複合膜之鑑定……………………………………………………………………42 3.2.1 掃描式電子顯微鏡 (Scanning electron microscopy, SEM) ……42 3.2.2 甲醇穿透率 (Methanol permeability) ……………………………………42 3.2.3 質子傳導度 (Proton Conductivity) ………………………………………43 3.2.4 直接甲醇燃料電池電性測量……………………………………………48 第四章 結果與討論…………………………………………………………………50 4.1 MCM-22(P)及其衍生材料鑑定………………………………………………50 4.1.1 MCM-22(P)系列材料之鑑定…………………………………………50 4.2 NafionR及複合膜之鑑定…………………………………………………59 4.2.1 Nafion117及recasting之鑑定……………………………………59 4.2.2 Nafion/MCM-22(P)複合膜之鑑定與比較………………………62 4.2.3 Nafion/dis-MCM-22複合膜之鑑定與比較………………69 4.2.4 Nafion/MCM-22複合膜之鑑定與比較……………………………78 4.2.5 Nafion/SO3H-dis-MCM-22複合膜之鑑定與比較……………………85 4.2.6 Nafion/ex-dis-MCM-22複合膜之鑑定與比較…………………………93 4.2.7 綜合性比較……………………………………102 4.2.8 預處理方式對電池之影響………………………………………………105 4.2.9 膜厚對膜的影響………………………………………………………106 第五章 結論………107 參考文獻……… ………… ………108 | |
dc.language.iso | zh-TW | |
dc.title | Nafion/MCM-22複合材料於直接甲醇燃料電池質子交換膜之應用 | zh_TW |
dc.title | Nafion/MCM-22 Hybrid Material as Proton Exchange Membranes for DMFC Application | en |
dc.type | Thesis | |
dc.date.schoolyear | 102-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 劉如熹(Ru-Shi Liu),陳貴賢(Kuei-Hsien Chen),王丞浩(Chen-Hao Wang) | |
dc.subject.keyword | 直接甲醇燃料電池,質子交換膜,MCM-22,NafionR, | zh_TW |
dc.subject.keyword | Direct methanol fuel cell (DMFC),Proton exchange membrane (PEM),MCM-22,NafionR, | en |
dc.relation.page | 112 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2014-08-20 | |
dc.contributor.author-college | 理學院 | zh_TW |
dc.contributor.author-dept | 化學研究所 | zh_TW |
顯示於系所單位: | 化學系 |
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