請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/55350
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 楊志忠(Chih-Chung Yang) | |
dc.contributor.author | Chien-Yu Chen | en |
dc.contributor.author | 陳建瑜 | zh_TW |
dc.date.accessioned | 2021-06-16T03:57:56Z | - |
dc.date.available | 2020-09-02 | |
dc.date.copyright | 2020-09-02 | |
dc.date.issued | 2020 | |
dc.date.submitted | 2020-07-30 | |
dc.identifier.citation | [1] M. Achermann et al., “Energy-transfer pumping of semiconductor nanocrystals using an epitaxial quantum well,” Nature 429(10), 642–646 (2004).
[2] J. Yu et al., “Improving the internal quantum efficiency of green InGaN quantum dots through coupled InGaN/GaN quantum well and quantum dot structure,” Appl. Phys. Express, 8(9), 094001 (2015). [3] U. Kaiser et al., “Determining the exact number of dye molecules attached to colloidal CdSe/ZnS quantum dots in Förster resonant energy transfer assemblies,” J. Appl. Phys. 117(2), 024701 (2015). [4] A. C. Kuriakose et al., “Energy transfer kinetics in basic fuchsin dye sensitized CdS quantum dots,” Mater. Chem. Phys. 242(12), 122560 (2020). [5] K. Boeneman et al., “Self-assembled quantum dot-sensitized multivalent DNA photonic wires,” J. Am. Chem. Soc. 132(51), 18177-18190 (2010). [6] S. Mandal et al., “Photoinduced energy transfer in ZnCdSeS quantum dot phthalocyanines hybrids,” ACS Omega 3(8), 10048-10057 (2018). [7] Y. C. Lu et al., “Improving emission enhancement in surface plasmon coupling with an InGaN/GaN quantum well by inserting a dielectric layer of low refractive index between metal and semiconductor,” Appl. Phys. Lett. 94(23), 233113 (2009). [8] C. H. Lin et al., “Further reduction of efficiency droop effect by adding a lower-index dielectric interlayer in a surface plasmon coupled blue light-emitting diode with surface metal nanoparticles,” Appl. Phys. Lett. 105(10), 101106 (2014). [9] C. H. Lin et al., “Modulation behaviors of surface plasmon coupled light-emitting diode,” Opt. Express 23(6), 8150-8161 (2015). [10] C. Y. Su et al., “Dependencies of surface plasmon coupling effects on the p-GaN thickness of a thin-p-type light-emitting diode,” Opt. Express 25(18), 21526-21536 (2017). [11] Y. Kuo et al., “Surface plasmon coupling with radiating dipole for enhancing the emission efficiency of a light-emitting diode,” Opt. Express 19(14), A914-A929 (2011). [12] A. Neogi et al., “Enhancement of spontaneous recombination rate in a quantum well by resonant surface plasmon coupling,” Phys. Rev. B. 66(15), 153305 (2002). [13] K. Okamoto et al., “Surface-plasmon-enhanced light emitters based on InGaN quantum wells,” Nat. Mater. 3, 601-605 (2004). [14] G. Sun et al., “Practicable enhancement of spontaneous emission using surface plasmons,” Appl. Phys. Lett. 90(11), 111107 (2007). [15] G. Sun and J. B. Khurgin, “Plasmon enhancement of luminescence by metal nanoparticles,” IEEE J. Select. Topics in Quantum Electron. 17(1), 110-118 (2011). [16] K. Tateishi et al., “Highly enhanced green emission from InGaN quantum wells due to surface plasmon resonance on aluminum films,” Appl. Phys. Lett. 106(12), 121112 (2015). [17] D. M. Yeh et al., “Surface plasmon coupling effect in an InGaN/GaN single-quantum-well light-emitting diode,” Appl. Phys. Lett. 91(17), 171103 (2007). [18] D. M. Yeh et al., “Localized surface plasmon-induced emission enhancement of a green light-emitting diode,” Nanotechnology 19(34), 345201 (2008). [19] C. Y. Cho et al., “Surface plasmon-enhanced light-emitting diodes with silver nanoparticles and SiO2 nano-disks embedded in p-GaN,” Appl. Phys. Lett. 99(4), 041107 (2011). [20] C. F. Lu et al., “Reduction of the efficiency droop effect of a light-emitting diode through surface plasmon coupling,” Appl. Phys. Lett. 96(26), 261104 (2010). [21] K. C. Shen et al., “Polarization dependent coupling of surface plasmon on a one-dimensional Ag grating with an InGaN/GaN dual-quantum-well structure,” Appl. Phys. Lett. 92(1), 013108 (2008). [22] K. C. Shen et al., “Enhanced and partially polarized output of a light-emitting diode with its InGaN/GaN quantum well coupled with surface plasmons on a metal grating,” Appl. Phys. Lett. 93(23), 231111 (2008). [23] M. K. Kwon et al., “Surface-plasmon-enhanced light-emitting diodes,” Adv. Mater. 20, 1253-1257 (2008). [24] C. Y. Cho et al., “Enhanced optical output power of green light-emitting diodes by surface plasmon of gold nanoparticles,” Appl. Phys. Lett. 98(5), 051106 (2011). [25] Y. Kuo et al., “Surface plasmon coupling with a radiating dipole near an Ag nanoparticle embedded in GaN,” Appl. Phys. Lett. 102(16), 161103 (2013). [26] H. S. Chen et al., “Surface plasmon coupled light-emitting diode with metal protrusions into p-GaN,” Appl. Phys. Lett. 102(4), 041108 (2013). [27] C. H. Lin et al., “Efficiency improvement of a vertical light-emitting diode through surface plasmon coupling and grating scattering,” Opt. Express 22(S3), A842-A856 (2014). [28] Y. Kuo et al., “Surface plasmon coupled light-emitting diode - experimental and numerical studies,” Jap. J. Appl. Phys. 54, 02BD01 (2015). [29] C. H. Lin et al., “High modulation bandwidth of a light-emitting diode with surface plasmon coupling,” IEEE Trans. Electron Dev. 63(10), 3989-3995 (2016). [30] M. Chekini et al., “Fluorescence enhancement in large-scale self-assembled gold nanoparticle double arrays,” J. Appl. Phys. 118(23), 233107 (2015). [31] C. Seo et al., “Plasmon-enhanced phosphorescence of hybrid thin films of metal-free purely organic phosphor and silver nanoparticles,” Chemical Physics Letters 676, 134-139, (2017). [32] F. J. Tsai et al., “Absorption enhancement of an amorphous Si solar cell through surface plasmon-induced scattering with metal nanoparticles,” Opt. Express 18(S2), A207-A220 (2010). [33] H. Y. Lin et al., “Surface plasmon effects in the absorption enhancements of amorphous silicon solar cells with periodical metal nanowall and nanopillar structures,” Opt. Express 20(S1), A104-A118 (2012). [34] S. Pillai et al., “Surface plasmon enhanced silicon solar cells,” J. Appl. Phys. 101(9), 093105 (2007). [35] H. A. Atwater and A. Polman, “Plasmonics for improved photovoltaic devices,” Nature Mater. 9, 205-213 (2010). [36] S. Nootchanat et al., “Grating-coupled surface plasmon resonance enhanced organic photovoltaic devices induced by blu-ray disc recordable and blu-ray disc grating structures,” Nanoscale 9(15), 4963-4971 (2017). [37] J. Zhu et al., “Nanodome solar cells with efficient light management and self-cleaning,” Nano Lett. 10(6), 1979-1984 (2010). [38] S. Nie and S. R. Emory, “Probing single molecules and single nanoparticles by surface-enhanced Raman scattering,” Science 275(5303), 1102-1106 (1997). [39] R. Gillibert et al., “Directional surface enhanced Raman scattering on gold nano-gratings,” Nanotechnology 27(11), 115202 (2016). [40] W. Yue et al., “Amplification of surface-enhanced Raman scattering due to substrate-mediated localized surface plasmons in gold nanodimers,” J. Mater. Chem. C. 5(16), 4075-4084 (2017). [41] Y. He et al., “Exocytosis of gold nanoparticle and photosensitizer from cancer cells and their effects on photodynamic and photothermal processes,” Nanotechnology 29(23), 235101 (2018). [42] C. K. Chu et al., “Combination of photothermal and photodynamic inactivation of cancer cell through surface plasmon resonance of gold nanoring,” Nanotechnology 27(11), 115102 (2016). [43] C. K. Chu et al., “Cancer cell uptake behavior of Au nanoring and its localized surface plasmon resonance induced cell inactivation,” Nanotechnology 26(7), 075102 (2015). [44] N. Yin et al., “Ag nanobox/silica/CdTeS quantum dot nanoprobe with photoluminescence emission enhancement for labeling cancer cells,” J. Alloys and Compounds 741, 141-147 (2018). [45] T. Jiang et al., “An Au nanoflower@SiO2@CdTe/CdS/ZnS quantum dot multi-functional nanoprobe for photothermal treatment and cellular imaging,” RSC Adv. 4(45), 23630-23636 (2014). [46] A. K. Tobias and M. Jones, “Metal-enhanced fluorescence from quantum dot-coupled gold nanoparticles,” J. Phys. Chem. C 123, 1389-1397 (2019). [47] K. S. Kim et al., “Metal-enhanced fluorescence in polymer composite films with Au@Ag@SiO2 nanoparticles and InP@ZnS quantum dots,” RSC Adv. 9(1), 224-233 (2019). [48] F. Shan et al., “Hot spots based gold nanostar@SiO2@CdSe/ZnS quantum dots complex with strong fluorescence enhancement,” AIP Adv. 8, 025219 (2018). [49] S. Hu et al., “Surface plasmon resonance enhancement of photoluminescence intensity and bioimaging application of gold nanorod@CdSe/ZnS quantum dots,” Beilstein J. Nanotechnol. 10, 22-31 (2019). [50] Q. Huang et al., “Enhanced photoluminescence property for quantum dot-gold nanoparticle hybrid,” Nanoscale Res. Lett. 10, 400 (2015). [51] Y. Wang et al., “Emission enhancement from CdSe/ZnS quantum dots induced by strong localized surface plasmonic resonances without damping,” J. Phys. Chem. Lett. 10, 2113-2120 (2019). [52] P. Ghenuche et al., “Matching Nanoantenna Field Confinement to FRET Distances Enhances Förster Energy Transfer Rates,” Nano Lett. 15(9), 6193-6201 (2015). [53] T. Ozel et al., “Observation of Selective Plasmon-Exciton Coupling in Nonradiative Energy Transfer: Donor-Selective versus Acceptor-Selective Plexcitons,” Nano Lett. 13(7), 3065-3072 (2013). [54] H. P. P. Richard et al., “Metal-enhanced fluorescence and FRET on nanohole arrays excited at angled incidence,” Analyst 140(14), 4792 (2015). [55] L. J. Higgins et al., “ Enhancing Förster nonradiative energy transfer via plasmon interaction,” Proc. SPIE 9884, 98840 (2016). [56] M. Lunz et al., “Surface Plasmon Enhanced Energy Transfer between Donor and Acceptor CdTe Nanocrystal Quantum Dot Monolayers,” Nano Lett. 11(8), 3341-3345 (2011). [57] X. Zhang et al., “Experimental and Theoretical Investigation of the Distance Dependence of Localized Surface Plasmon Coupled Förster Resonance Energy Transfer,” ACS Nano 8(2), 1273-1283 (2014). [58] Y. J. Jang et al., “Enhancing the organic solar cell efficiency by combining plasmonic and Forster Resonance Energy Transfer (FRET) effects,” J. Power Sources 438(22), 227031 (2019). [59] H. Deng and H. Yu, “Self-assembly of rhodamine 6G on silver nanoparticles,” Chem. Phys. Lett. 692, 75-80 (2018). | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/55350 | - |
dc.description.abstract | 在本論文中,我們將羅丹明6G吸附至硒化鎘鋅/硫化鋅的核殼綠光量子點上,並將此羅丹明6G、綠光量子點的複合體利用靜電自組裝的方式使與銀奈米顆粒接合成一體,以研究侷域表面電漿子耦合效應對於量子點與羅丹明6G間福斯特共振能量轉換的影響。表面電漿子可以透過近場與發光體耦合以提高量子點的發光效率,因此能量透過福斯特共振能量轉換至羅丹明6G的過程必須與量子點的自發光競爭,我們觀測到在表面電漿子耦合效應下福斯特共振能量轉換的效率降低。另外雖然當羅丹明6G直接接合至銀奈米顆粒上時,表面電漿子耦合效應可以提升羅丹明6G的發光效率,但是當羅丹明6G先吸附在量子點上再接合至銀奈米顆粒上時,表面電漿子耦合提升發光效率的效果會降低,甚至當量子點吸附較多羅丹明6G分子時,表面電漿子耦合效應可降低羅丹明6G的發光效率。本研究中我們也建立一個速率方程式模型,嘗試與量測所得的光致發光衰減數據比對,並合理解釋我們所得到的實驗結果。 | zh_TW |
dc.description.abstract | Rhodamine 6G (R6G) molecules linked CdZnSeS/ZnS green-emitting quantum dots (QDs) are self-assembled onto Ag nanoparticles (NPs) for studying the surface plasmon (SP) coupling effect on the Förster resonance energy transfer (FRET) process between QD and R6G. SP coupling can enhance the emission efficiency of QD such that FRET has to compete with QD emission for transferring energy into R6G. It is found that FRET efficiency is reduced under the SP coupling condition. Although R6G emission efficiency can also be enhanced through SP coupling when it is directly linked onto Ag NP, the enhancement decreases when R6G is linked onto QD and then the QD-R6G complexes are self-assembled onto Ag NP. In particular, R6G emission efficiency can be reduced through SP coupling when the number of R6G molecules linked onto a QD is high. A rate-equation model is built for resembling the measured photoluminescence decay profiles and providing detailed explanations for the observed FRET and SP coupling behaviors. | en |
dc.description.provenance | Made available in DSpace on 2021-06-16T03:57:56Z (GMT). No. of bitstreams: 1 U0001-3007202012085600.pdf: 3993994 bytes, checksum: d7b144040c5c1d0180ec6cadf9ed2c2b (MD5) Previous issue date: 2020 | en |
dc.description.tableofcontents | 誌謝 III 摘要 IV Abstract V Content VI Chapter 1 Introduction 1 1.1 Förster resonance energy transfer 1 1.2 Surface plasmon coupling 1 1.3 Fourier-domain optical coherence tomography 2 1.4 Research motivations 4 1.5 Thesis structure 5 Chapter 2 Sample Preparation 6 2.1 Sample structures under study and their fabrication procedures 6 2.2 Silver nanoparticles for surface plasmon coupling 9 2.3 Concerned spectra 10 Chapter 3 Fluorescence Resonance Energy Transfer between Quantum Dot and Rhodamine 6G 20 3.1 Fluorescence behavior of quantum dot 20 3.2 Fluorescence behavior of rhodamine 6G 21 3.3 FRET efficiency 23 Chapter 4 Surface Plasmon Coupling Effects with Low Rhodamine 6G Concentration 32 4.1 Fluorescence behavior of quantum dot 32 4.2 Fluorescence decay behaviors of Rhodamine 6G 33 Chapter 5 Surface Plasmon Coupling Effects with High Rhodamine 6G Concentration 43 5.1 Fluorescence decay behaviors of quantum dot 43 5.2 Fluorescence decay behaviors of Rhodamine 6G 44 Chapter 6 Numerical Study with Rate Equations – A Simple Model 54 6.1 Derivations of the rate equations 54 6.2 Numerical results and discussions 56 Chapter 7 Conclusions 75 References 76 | |
dc.language.iso | en | |
dc.title | 表面電漿子耦合對量子點與羅丹明6G間福斯特共振能量轉換的影響 | zh_TW |
dc.title | Surface Plasmon Coupling Effects on the Förster Resonance Energy Transfer Process between Quantum Dot and Rhodamine 6G | en |
dc.type | Thesis | |
dc.date.schoolyear | 108-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 江衍偉(Yean-Woei Kiang),黃建璋(Jian-Jang Huang),郭仰(Yang Kuo),吳育任(Yuh-Renn Wu) | |
dc.subject.keyword | 福斯特共振能量轉換,局域表面電漿子共振,量子點, | zh_TW |
dc.subject.keyword | FRET,LSPR,quantum dot,Rhodamine 6G, | en |
dc.relation.page | 81 | |
dc.identifier.doi | 10.6342/NTU202002092 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2020-07-30 | |
dc.contributor.author-college | 電機資訊學院 | zh_TW |
dc.contributor.author-dept | 光電工程學研究所 | zh_TW |
顯示於系所單位: | 光電工程學研究所 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
U0001-3007202012085600.pdf 目前未授權公開取用 | 3.9 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。