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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 鄭如忠 | |
| dc.contributor.author | I-Chun Tang | en |
| dc.contributor.author | 唐儀君 | zh_TW |
| dc.date.accessioned | 2021-06-16T03:42:16Z | - |
| dc.date.available | 2020-03-16 | |
| dc.date.copyright | 2015-03-16 | |
| dc.date.issued | 2015 | |
| dc.date.submitted | 2015-02-12 | |
| dc.identifier.citation | 1. H. Schnell and H. Krimm Angew. Chem., Int. Ed.. 1963, 2, 373.
2. S. Fukahori, H. Ichiura , T. Kitaoka and H. Tanaka Appl. Catal., B: Environmental 2003, 46, 453. 3. H. Ito, C. G. Willson, J. M. J. Frechet, M. J. Farrall and E. Eichler Macromolecules 1983, 16, 510. 4. W. F. Chen, H. Y. Lin and S. A. Dai Org. Lett. 2004, 6, 2341. 5. A. J. Caruso and J. L. Lee J. Org. Chem. 1997, 62, 1058. 6. C. Harbordt. Ann. Chem. Pharm. 1862, 123, 287. 7. S. Gabriel and T. A. Maas Ber. Dtsch. Chem. Ges. 1899, 32, 1266. 8. C. P. Yang and W. T. Chen Makromol. Chem. 1993, 194, 1959. 9. N. Yamazaki and F. Higashi J. Polym. Sci. Polym. Chem. Ed. 1947, 12, 2149. 10. N. Yamazaki, M. Matsumoto and F. Higashi J. Polym. Sci. Polym. Chem. Ed. 1975, 13, 1373. 11. E. L. Wittbecker and P. W. Morgan J. Polym. Sci. 1959, 40, 289. 12. P. W. Morgan and S. L. Kwolek J.Polym. Sci. 1959, 40, 299. 13. R. G. Beaman, P. W. Morgan, C. R. Kroller, E. L. Wittbeaker and E. E. Magat J. Polym. Sci. 1959, 40, 329. 14. J. R. Schaetgen, F. H. Koonntz and R. F. Tietz J. Polym. Sci. 1959, 40, 377. 15. D. J. Lyman and S. L. Jung J. Polym. Sci. 1959, 40, 407. 16. N. V. Mikhailov, V. I. Maiboroda and S. S. Nikolaeva Vysokomol. Soedin. 1960, 2, 989. 17. T. M. Frunze, V. V. Korshak, V. V. Kurashev and P. A. Alievskii Vysokomol. Soedin. 1959, 1, 1795. 18. P. W. Morgan and S. L. Kwolek J. Polym. Sci. 1962, 62, 33. 19. W. Michler and A. Zimmermann Ber. Dtsch. Chem. Gesel. 1881, 14, 2177. 20. M. Frankel, Y. Liwschitzy and A. Zilkha Experientia 1953, 9, 179. 21. P. J. Perry, B. D. Wilson Macromolecules 1993, 26, 1503. 22. T. M. Bogert, and R. R. Renshaw J. Am. Chem. Soc. 1908, 30, 1140. 23. P. M. Heigenisher and N. J. Johnstin, in C. A. May (ed.): Resins for Aerospace, ACS Symp. Ser. 132, Washington, DC, 1980. 24. D. Wilson, H. D. Stenzenberger and P. M. Hergenrother Polyimides Blackie & Son,London 1 1990. 25. N. A. Adrova, M. I. Bessonov, L. A. Laius and A. P. Rudakov Polyimide：A new class of thermally stable polymers(in Russian), Nauka, Leningrad1 1968. 26. 李伯毅. 正型鹼性水溶液顯影感光性聚亞醯胺材料之研究 國立成功大學化工研究所碩士論文 2002. 27. Kirk-Othmer. Encyclopedia of Chemical Technology, New York : Wiley 1991, 19, 812. 28. M. K. Ghosh and K. L. Mittal Polyimides: Fundamentals and Applications, New York: Dekker 1996. 29. V. L. Rao Polym. Rev. 1999, 39, 655. 30. H. R. Kricheldorf, L. Vakhtangishvili, D. Fritsch. J. Polym. Sci. Part A: Polym. Chem. 2002 40, 2967. 31. N. B. McKeown, P. M. Budd, K. J. Msayib, B. S. Ghanem, H. J. Kingston, C. E. Tattershall, S. Makhseed, K. J. Reynolds and D. Fritsch Chem. Eur. J. 2005, 11, 2610. 32. P. M. Budd, B. S. Ghanem, S. Makhseed, N. B. McKeown, K. J. Msayib and C. E. Tattershall Chem. Commun. 2004, 230-231. 33. J. Weber, Q. Su, M. Antonietti and A. Thomas Macromol. Rapid. Comm. 2007, 28, 1871. 34. H.-J. Yen, J.-H. Wu, Y.-H. Huang, W.-C. Wang, K.-R. Lee and G.-S. Liou Polym. Chem. 2014, 5, 4219. 35. X. Ma, R. Swaidan, Y. Belmabkhout, Y. Zhu, E. Litwiller, M. Jouiad, I. Pinnau and Y. Han Macromolecules 2012, 45, 3841. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/54944 | - |
| dc.description.abstract | 本論文探討雙酚A於酸性條件下分別和m-cresol與3,4-dimethylphenol之反應情形。實驗預期該反應可分別獲得階梯狀(Ladder)單體X-1、X-2與螺環狀(Spiro)單體SC-1、SC-2，結果顯示，溫度、反應物比例、觸媒量與時間之調控皆是決定是否可獲得螺環單體SC-1及SC-2之重要影響因素。
所得之單體經由官能化後將運用於高性能高分子材料製備，由階梯狀單體衍生物XA-1製備出之聚醯胺材料將表現出優異的熱性質，且SCA-1之單體反應性將進一步於本論文中探討。單體反應過程之副產物SI，藉由純化後可用以製備聚醚碸高分子，並在本論文中將與一般雙酚A型聚醚碸進行性質比較。 | zh_TW |
| dc.description.abstract | In this thesis we investigated the reaction phenomenon of bisphenol A with m-cresol and 3,4-dimethylphenol, respectively. We expected to get ladder monomers X-1, X-2 and spiro monomers SC-1, SC-2, respectively by the reaction. The result suggested that temperature, ratio of reactants, amount of catalyst and control of time were the important factors that determined the accessibility to the spiro monomers.
The obtained monomer would be applied in the preparation of high performance polymer after functionalization. Polyamide made by ladder monomer XA-1 exhibit excellent thermal properties, while the reactivity of SCA-1 monomer would be investigated in the thesis. SI monomer, the by product of the monomer's reaction, could be made into polyether sulfone, and its properties would be compared to that made of bisphenol A in the thesis. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T03:42:16Z (GMT). No. of bitstreams: 1 ntu-104-R02549005-1.pdf: 4635608 bytes, checksum: 414f29cc62e79bb2b7ae4a74c470dd0a (MD5) Previous issue date: 2015 | en |
| dc.description.tableofcontents | 中文摘要 i
Abstract ii 目錄 iii Scheme目錄 vi 表目錄 viii 圖目錄 ix 代號說明 xi 第一章 緒論 1 第二章 原理與文獻回顧 2 2.1 BPA酸裂解文獻回顧 2 2.2 高分子材料文獻回顧 11 2.2.1 聚醯胺(Polyamide, PA)簡介 11 2.2.2聚醯胺(Polyamide, PA)製備 11 2.2.3 聚醯胺(Polyamide, PA)之特性 14 2.2.4 聚醯亞胺(Polyimide, PI) 簡介 15 2.2.5聚醯亞胺(Polyimide, PI)合成特性 17 2.2.6 聚醚碸(Polyether sulfone, PES) 簡介 20 2.2.7聚醚碸(Polyether sulfone, PES)合成特性 20 2.3 氣體分離-固有微孔聚合物(Polymers of intrinsic microporosity, PIMs) 22 第三章 實驗內容 25 3.1 實驗藥品與溶劑 25 3.2 實驗儀器 35 3.3 實驗規劃 40 3.4 實驗步驟 41 3.4.1 單體合成 41 3.4.2 高分子製備 50 3.4.2.1 聚醯胺(PA)製備 50 3.4.2.2 聚醚碸(PES)製備 51 3.4.2.3 聚醯亞胺(PI)製備 52 3.4.3 高分子薄膜製備 53 3.4.3.1聚醯胺(PA)薄膜製備 53 3.4.3.2 聚醚碸(PES)薄膜製備 53 3.4.3.3聚醯亞胺(PI)薄膜製備 53 第四章 化合物結構鑑定與分析 54 4.1 X-1單體結構鑑定與分析 54 4.1.1 1H-NMR鑑定 54 4.2 XA-1單體結構鑑定 57 4.2.1 1H-NMR鑑定 57 4.3 SC-1單體結構鑑定 60 4.3.1 1H-NMR鑑定 60 4.3.2 X光單晶繞射鑑定 62 4.4 SCA-1單體結構鑑定 63 4.4.1 1H-NMR鑑定 63 4.5 SI單體結構鑑定 66 4.5.1 1H-NMR鑑定 66 4.6 X-2單體結構鑑定 68 4.6.1 1H-NMR鑑定 68 4.7 XA-2單體結構鑑定 70 4.7.1 傅立葉轉換紅外線光譜(FTIR)鑑定 70 4.7.2 質譜儀(Mass)鑑定 71 4.8 SC-2單體結構鑑定 72 4.8.1 1H-NMR鑑定 72 4.9 SCA-2單體結構鑑定 74 4.9.1 1H-NMR鑑定 74 4.9.2 FTIR光譜鑑定 76 4.9.3 質譜儀(Mass)鑑定 78 4.10 高分子結構鑑定 79 4.10.1 X-1-d-PA聚醯胺1H-NMR光譜鑑定 79 4.10.2 X-1-o-PA聚醯胺1H-NMR光譜鑑定 80 4.10.3 SC-1-PA聚醯胺1H-NMR光譜鑑定 81 4.10.4 SI-PES聚醚碸1H-NMR光譜鑑定 82 4.10.5 SC-2-PI聚醯亞胺1H-NMR光譜鑑定 83 第五章 結果與討論 84 5.1 單體合成探討 84 5.1.1 X-1與SC-1合成探討 84 5.1.2 X-2與SC-2合成探討 90 5.1.3 單體氧化之探討 95 5.2 高分子合成探討與分子量鑑定 96 5.3熱性質分析 98 第六章 結論 104 第七章 未來展望 105 第八章 參考文獻 106 附錄 108 | |
| dc.language.iso | zh-TW | |
| dc.subject | 階梯狀 | zh_TW |
| dc.subject | 聚醯胺 | zh_TW |
| dc.subject | 聚醯亞胺 | zh_TW |
| dc.subject | 螺環狀 | zh_TW |
| dc.subject | 聚醚? | zh_TW |
| dc.subject | 酸裂解 | zh_TW |
| dc.subject | polyether sulfone | en |
| dc.subject | acid-fragmentation | en |
| dc.subject | spiro | en |
| dc.subject | ladder | en |
| dc.subject | polyamide | en |
| dc.subject | polyimide | en |
| dc.title | 由雙酚A酸裂解合成階梯狀及螺環狀單體與其高分子之製備 | zh_TW |
| dc.title | Ladder and Spiro-based Monomers from Acid-fragmentation of Bisphenol A and Preparation of Their Polymer Derivatives | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 103-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.coadvisor | 戴憲弘 | |
| dc.contributor.oralexamcommittee | 蔣見超,劉英麟,鄭智嘉 | |
| dc.subject.keyword | 酸裂解,螺環狀,階梯狀,聚醯胺,聚醯亞胺,聚醚?, | zh_TW |
| dc.subject.keyword | acid-fragmentation,spiro,ladder,polyamide,polyimide,polyether sulfone, | en |
| dc.relation.page | 134 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2015-02-12 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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