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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 鄭淑芬(Soofin Cheng) | |
dc.contributor.author | Cheng-Hsiu Li | en |
dc.contributor.author | 李政修 | zh_TW |
dc.date.accessioned | 2021-06-16T03:40:53Z | - |
dc.date.available | 2020-03-16 | |
dc.date.copyright | 2015-03-16 | |
dc.date.issued | 2015 | |
dc.date.submitted | 2015-02-13 | |
dc.identifier.citation | (1)(IEA), I. E. A. Key World Energy Statistics 2013, 2013.
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/54893 | - |
dc.description.abstract | 利用鎂鋁層狀雙氫氧化物、氫氧化鋯以及商用的矽膠作為基材,嫁接有機胺官能基、胍官能基和咪唑官能基,並使用這些固體有機鹼作為觸媒,檢視其催化轉酯化反應的效果。利用沉澱法合成層間陰離子為十二烷基硫酸根之鎂鋁層狀雙氫氧化物,探討含碳酸根與十二烷基硫酸根的層狀雙氫氧化物對嫁接胺官能基的影響。而合成的鹼觸媒會利用X光粉末繞射鑑定層狀雙氫氧化物結構,使用元素分析搭配熱重分析計算鎂鋁層狀雙氫氧化物、氫氧化鋯以及矽膠嫁接量,並利用氮氣吸附-脫附測量表面積以及孔體積,並使用掃描式電子顯微鏡鑑定觸媒形貌。
在固定醇油比例(6:1),觸媒量(3wt%),用嫁接胍官能基的氫氧化鋯催化三酸甘油酯進行轉酯化反應,在40分鐘便可以達到83.9%的conversion,yield可以達到58.2%。 | zh_TW |
dc.description.abstract | The Mg-Al layered double hydroxides (LDHs), silica gel and zirconium hydroxide grafted with aminopropyl-groups, 3-guanidinylpropyl-groups and 2-formylimidazolylpropyl-groups were prepared and used as the base catalysts for transesterification. LDHs intercalated with carbonate and DS (dodecyl sulfate) were prepared by co-precipitation method, and the effect of interlayer anions on the grafting of amino-groups was examined. The amine-grafted materials were characterized by X-ray diffraction (XRD), nitrogen sorption isotherms, Element Analysis (EA) and thermo-gravimetric analysis (TGA). The catalytic activities of amine-grafted materials were compared with the pristine materials in base-catalyzed transesterification. Transesterification was performed at reflux temperature, using a fixed methanol to triacetin mole ratio of 6:1 and catalyst of 3 wt% (based on the quantity of triacetin used). One-pot transformation of triacetin with methanol using guanidine-grafted Zirconium hydroxide gave a 58.2% FAME yield after 40 min, with 83.9% conversion for transesterification. | en |
dc.description.provenance | Made available in DSpace on 2021-06-16T03:40:53Z (GMT). No. of bitstreams: 1 ntu-104-R01223131-1.pdf: 4072591 bytes, checksum: 1b347a03321bdc04198f9e50d22c95ec (MD5) Previous issue date: 2015 | en |
dc.description.tableofcontents | 目錄
摘要 I Abstract II 表目錄 VI 圖目錄 VII 第1章 緒論 1 1-1生質柴油簡介 2 1-2轉酯化反應 5 1-3催化劑的簡介 8 1-3-1勻相觸媒(Homogeneous catalyst) 8 1-3-2異相觸媒(Heterogeneous catalyst) 8 1-3-3酵素(Enzyme) 8 1-4催化劑在轉酯化反應上的演進 8 1-5層狀雙氫氧化物 15 1-5-1層狀雙氫氧化物的背景介紹 15 1-5-2層狀雙氫氧化物的化學組成及結構性質 15 1-5-3層狀雙氫氧化物的合成方式 16 1-5-4層狀雙氫氧化物的應用 17 1-6 氫氧化鋯(zirconium hydroxide, Zr(OH)4•nH2O) 19 1-7 矽膠(silica gel, SiO2) 21 1-8 研究動機與目標 22 第2章 實驗部分 25 2-1 化學藥品 25 2-2. 材料製備 26 2-2-1含十二烷基硫酸根的LDH(乾式法) 26 2-2-2 嫁接amine至含十二烷基硫酸根的LDH(乾式) 26 2-2-3含十二烷基硫酸根的LDH(濕式法) LDH-DS-wet 26 2-2-4 嫁接amine至含十二烷基硫酸根的LDH(溼式) LDH-DS-NH3 27 2-2-5 合成guanidinetrimethoxysilane(Cl)60 27 2-2-6 合成guanidinetrimethoxysilane(OMe) 27 2-2-7 合成imidazoletrimethoxysilane60 27 2-2-8 合成 LDH-GuCl 27 2-2-9 合成 LDH-GuOMe 28 2-2-10 合成 LDH-GuOMe-NaCl 28 2-2-11合成LDH-Im 2 steps 28 2-2-12 合成Zr(OH)4 28 2-2-13 合成Zr(OH)4-NH3 28 2-2-12 合成Zr(OH)4-Gu 28 2-2-13 合成Zr(OH)4-Im 1step 28 2-2-14 合成Zr(OH)4-Im 2 steps 29 2-2-15 合成Zr(OH)4-GuIm 1 step 29 2-2-16 合成SiO2-NH3 29 2-2-17 合成SiO2-Gu 1 step 29 2-2-18 合成SiO2-Gu 2 steps 29 2-2-19 合成SiO2-Im 1 step 29 2-2-20 合成SiO2-Im 2 steps 29 2-2-21 合成SiO2-Im 2 steps-half 30 2-2-22 合成SiO2-GuIm 1 step 30 2-2-22 合成SiO2-GuIm 3 steps 30 2-2-23 活化觸媒 30 2-2-24 催化轉酯化 30 2-2-25 酸鹼滴定 30 3. 鑑定材料之儀器與方法 36 2-3-1 X光粉末繞射 ( Powder X-ray Diffraction, XRD ) 36 2-3-2熱重分析 ( Thermal Gravimetric Analysis,TGA) 36 2-3-3 氮氣吸附-脫附等溫曲線 ( N2 Adsorption-desorption Isotherm) 36 2-3-3 元素分析儀 (Elemental Analyzer,EA) 39 2-3-4 掃描式電子顯微鏡(Scanning electron microscopy, SEM) 39 第3章 結果與討論 40 3-1 合成含有機鹼的SiO2 40 3-2 合成含有機鹼的Zr(OH)4 47 3-3 合成含有機鹼的Layered double hydroxides 55 3-3-1 LDH含十二烷基硫酸根與碳酸基比較 55 3-3-2 含十二烷基硫酸根的LDH濕式法與乾式法比較 56 3-3-3 嫁接有機鹼至含十二烷基硫酸根的LDH(溼式) 58 3-4 催化反應測試 67 3-4-1 利用SiO2-Gu催化轉酯化反應(triacetin)條件最佳化 67 3-4-2 利用SiO2系列有機鹼觸媒催化轉酯化反應(triacetin) 69 3-4-3利用Zr(OH)4系列有機鹼觸媒催化轉酯化反應(triacetin) 70 3-4-4利用LDH系列有機鹼觸媒催化轉酯化反應(triacetin) 71 3-4-5 重複使用測試 72 第4章 結論 75 第5章 參考文獻 76 | |
dc.language.iso | zh-TW | |
dc.title | 利用不同基材合成固體有機鹼觸媒以及其在轉酯化的應用 | zh_TW |
dc.title | Preparation of Solid Organic Base Catalysts Using Different Supports and Their Applications in Transesterification | en |
dc.type | Thesis | |
dc.date.schoolyear | 103-1 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 蔡蘊明(Yeun-Min Tsai),萬本儒(Ben-Zu Wan),邱靜雯(Ching-Wen Chiu) | |
dc.subject.keyword | 非勻相觸媒,轉酯化反應,固體有機鹼觸媒, | zh_TW |
dc.subject.keyword | heterogeneous catalysts,transesterification,solid organic base catalysts, | en |
dc.relation.page | 79 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2015-02-13 | |
dc.contributor.author-college | 理學院 | zh_TW |
dc.contributor.author-dept | 化學研究所 | zh_TW |
顯示於系所單位: | 化學系 |
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