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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱勝賢(Sheng-Hsien Chiu) | |
| dc.contributor.author | Cheng-Fu Fan | en |
| dc.contributor.author | 范承甫 | zh_TW |
| dc.date.accessioned | 2021-06-16T02:58:27Z | - |
| dc.date.available | 2025-07-06 | |
| dc.date.copyright | 2015-07-20 | |
| dc.date.issued | 2015 | |
| dc.date.submitted | 2015-07-06 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/54464 | - |
| dc.description.abstract | 本實驗室先前發現，利用鈉離子作為模板，可引導大環分子對單一寡聚乙二醇或尿素單元進行辨識，並以穿透後封鎖或夾鎖法合成相對應的[2]交環烷與[2]車輪烷作為證明，成功地在內鎖分子領域加入新的辨識系統與合成內鎖分子的方法。
在本研究中，我們延伸、結合前人的工作，希望藉由鈉離子模板來引導[4]車輪交環烷的自組裝合成。 | zh_TW |
| dc.description.abstract | Recently, we demonstrated that the threading of oligo(ethylene glyco) and urea units into bis-para-xylyl[26]crown-6 (BPX26C6) via Na+ ion template is possible.
Herein, we reported a single urea functionality in a dumbbell-shaped guest can be “clipped” by macrocycle generated from a diamine and two dialdehydes through the templating effect of a Na+ ion to self-assembly of a [4]rotacatenane. The resulting imine-containing rotacatenane can be reduced to allow isolation of stable amine-based rotacatenane. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T02:58:27Z (GMT). No. of bitstreams: 1 ntu-104-R02223137-1.pdf: 7008998 bytes, checksum: 722f7183de0d3341d09f1bcb8e750436 (MD5) Previous issue date: 2015 | en |
| dc.description.tableofcontents | 中文摘要 i
英文摘要 ii 目錄 iii 圖目錄 iv 第一章 1 1.1研究動機 2 1.2 結果與討論 8 1.2.1 設計新型26員環誘導異[2]交環烷之合成 8 1.2.2 [4]車輪交環烷的合成設計與修改 11 1.2.3 [4]車輪交環烷的自組裝反應測試 15 1.3 結論 20 第二章、實驗部分 21 第三章、參考文獻 29 附錄 32 | |
| dc.language.iso | zh-TW | |
| dc.subject | 車輪烷 | zh_TW |
| dc.subject | 分子辨識 | zh_TW |
| dc.subject | 交環烷 | zh_TW |
| dc.subject | 車輪烷 | zh_TW |
| dc.subject | 自組裝 | zh_TW |
| dc.subject | 分子辨識 | zh_TW |
| dc.subject | 交環烷 | zh_TW |
| dc.subject | 自組裝 | zh_TW |
| dc.subject | self-assembly | en |
| dc.subject | catenane | en |
| dc.subject | molecular recognition | en |
| dc.subject | molecular recognition | en |
| dc.subject | self-assembly | en |
| dc.subject | rotaxane | en |
| dc.subject | rotaxane | en |
| dc.subject | catenane | en |
| dc.title | [4]車輪交環烷的自組裝合成研究 | zh_TW |
| dc.title | Self-Assembly Synthesis of a [4]Rotacatenane | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 103-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳平(Richard P. Cheng),徐秀福(Hsiu-Fu Hsu) | |
| dc.subject.keyword | 自組裝,車輪烷,交環烷,分子辨識, | zh_TW |
| dc.subject.keyword | self-assembly,rotaxane,catenane,molecular recognition, | en |
| dc.relation.page | 51 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2015-07-06 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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| ntu-104-1.pdf 未授權公開取用 | 6.84 MB | Adobe PDF |
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