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  1. NTU Theses and Dissertations Repository
  2. 理學院
  3. 化學系
Please use this identifier to cite or link to this item: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/53722
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???org.dspace.app.webui.jsptag.ItemTag.dcfield???ValueLanguage
dc.contributor.advisor邱靜雯(Ching-Wen Chiu)
dc.contributor.authorChing-Jung Chiangen
dc.contributor.author江青容zh_TW
dc.date.accessioned2021-06-16T02:28:18Z-
dc.date.available2020-08-05
dc.date.copyright2015-08-05
dc.date.issued2015
dc.date.submitted2015-08-03
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dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/53722-
dc.description.abstractDye-sensitized solar cells (DSSCs) have attracted much attention in recent year as they offer the possibility of low-cost conversion of photovoltaic energy. Remarkable progress has been made in the field of metal-free organic dyes having high extinction coefficient, which can be achieved from rational design based on the structure-property relationship. Due to its large extinction coefficient, great electrochemical stability, and tunable absorption wavelength BODIPY has been one of the most widely used organic chromophores in various fields, such as sensing, imaging, and solar cell applications. However, the performance of BODIPY-based DSSC is only moderate. For the purpose of understanding the relationship between the electronic structure of BODIPY molecule and its ability to harvest solar energy, we synthesized a series of BODIPY derivatives and examined their potential for DSSC application.en
dc.description.provenanceMade available in DSpace on 2021-06-16T02:28:18Z (GMT). No. of bitstreams: 1
ntu-104-R02223180-1.pdf: 3910057 bytes, checksum: d22825b866bacb24c198114f99e2f428 (MD5)
Previous issue date: 2015
en
dc.description.tableofcontentsCONTENTS
Chapter 1 Introduction 1
1.1 General Introduction 1
1.1.1 Mechanism for the generation of photocurrent 3
1.1.2 Parameters of power conversion efficiency 5
1.2 BODIPY 6
1.3 BODIPY derivatives for DSSCs 7
1.4 Panchromatic engineering 11
Chapter 2 Result and Discussion 14
2.1 Molecular Modification Strategy and Theoretical Calculation 14
2.1.1 Synthesis of starting materials 18
2.1.2 Syntheses of sensitizers 21
2.2 UV-vis absorption spectrum and CV 22
2.3 Device Performance 24
Chapter 3 Conclusion 27
Chapter 4 Experimental section 28
Chapter 5 References 40
Chapter 6 Appendix 44





List of Figures
Figure 1. Molecular structure of SM315 and N3 2
Figure 2. Schematic configuration of a dye sensitized solar cell 3
Figure 3. Mechanism of photo-current generation 4
Figure 4. Energy levels of TiO2 conduction band and electrolyte 5
Figure 5. BODIPY structure 6
Figure 6. BODIPY-wortmannin 7
Figure 7. The first BODIPY sensitizer in DSSC 8
Figure 8. Type I, II and III donor (D) /acceptor (A) motifs in BODIPY dye 8
Figure 9. BODIPY sensitizer in DSSC and representive diagram 9
Figure 10. Sensitizer PS-1 10
Figure 11. Sensitizer PS-4 11
Figure 12. Molecular structure of YD2-o-C8 and Y123 12
Figure 13. Absorption spectra of YD2-oC8 and SM315 13
Figure 14. Absorption spectra of Aza-BODIPYs and normal BODIPY 15
Figure 15. Concept diagram for strategy a and b 16
Figure 16. Theoretical calculation for BODIPY derivatives (B3LYP, S: 6-31g) 17
Figure 17. Dilution spectra of the fused-BODIPY 20
Figure 18. Absorption spectrum of reference sensitizers 22
Figure 19. Cyclic voltammograms of dyes in DCM 23
Figure 20. IPCE spectra of DSSCs 24
Figure 21. J–V curves of DSSCs based on the dyes 25
Figure 22. EIS (Nyquist plot) of DSSCs measured in the dark under -0.45 V bias. 26

List of Schemes
Scheme 1. Synthesis of phenyl substituted BODIPY 18
Scheme 2. Synthesis of fused BODIPY 19
Scheme 3. Synthesis route adopted for the preparation of anchors on BODIPYs 21
Scheme 4. Synthesis of phenyl substituted BODIPY 31
Scheme 5. Synthesis route adopted for the preparation of Fused BODIPY 32
Scheme 6. Synthesis route adopted for the preparation of anchors on BODIPYs 37
List of Tables
Table 1. Energy levels from calculation 17
Table 2. Energy levels estimated from CV and absorption 23
Table 3. Device performance 25
dc.language.isoen
dc.subject染敏料電池zh_TW
dc.subject氟硼二?啶zh_TW
dc.subjectdye sensitized solar cellen
dc.subjectBODIPYen
dc.title氟硼二吡啶衍生物於染敏料電池之應用zh_TW
dc.titleBODIPY-Derivatives for DSSCen
dc.typeThesis
dc.date.schoolyear103-2
dc.description.degree碩士
dc.contributor.oralexamcommittee詹益慈(Yi-Tsu Chan),周必泰(Pi-Tai Chou)
dc.subject.keyword氟硼二?啶,染敏料電池,zh_TW
dc.subject.keywordBODIPY,dye sensitized solar cell,en
dc.relation.page65
dc.rights.note有償授權
dc.date.accepted2015-08-03
dc.contributor.author-college理學院zh_TW
dc.contributor.author-dept化學研究所zh_TW
Appears in Collections:化學系

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