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| ???org.dspace.app.webui.jsptag.ItemTag.dcfield??? | Value | Language |
|---|---|---|
| dc.contributor.advisor | 邱靜雯(Ching-Wen Chiu) | |
| dc.contributor.author | Ching-Jung Chiang | en |
| dc.contributor.author | 江青容 | zh_TW |
| dc.date.accessioned | 2021-06-16T02:28:18Z | - |
| dc.date.available | 2020-08-05 | |
| dc.date.copyright | 2015-08-05 | |
| dc.date.issued | 2015 | |
| dc.date.submitted | 2015-08-03 | |
| dc.identifier.citation | 1. B. Oregan, M. Gratzel, Nature 1991, 353, 73
2. Simon Mathew, Aswani Yella, Peng Gao, Robin Humphry-Baker, Basile F. E. Curchod, Negar Ashari-Astani, Ivano Tavernelli, Ursula Rothlisberger, Md. Khaja Nazeeruddin, and Michael Gratzel, Nature Chemistry, 2014, 6, 242 3. M. K. Nazeeruddin, A. Kay, 1. Rodicio, R. Humpbry-Baker, E. Miiller, P. Liska, N. Vlachopoulos, and M. Gratzel J. Am. Chem. Soc. 1993,115, 6382 4. Pramod Kumar Singh, R. K. Nagarale, S. P. Pandey, H. W. Rhee and Bhaskar Bhattacharya, Adv. Nat. Sci.: Nanosci. Nanotechnol, 2011, 2, 23002 5. Claudia Longo and Marco-A. De Paoli, J. Braz. Chem. Soc., 2003, 14, 889 6. Amaresh Mishra, Markus K. R. Fischer, and Peter Bauerle, Angew. Chem. Int. Ed. 2009, 48, 2474 7. In Chung, Byunghong Lee, Jiaqing He, Robert P. H. Chang and Mercouri G. Kanatzidis, Nature 2012, 24, 485 8. M. K. Nazeeruddin, A. Kay, Rodicio, R Humpbry-Baker, E. Miiller, P. Liska, N. Vlachopoulos, and M. Gratzel, J. Am. Chem. Soc. 1993,115, 6382 9. Yasuo Chiba, Ashraful Islam, Yuki Watanabe, Ryoichi Komiya, Naoki Koide and Liyuan Han, Jpn. J. Appl. Phys., 2006, 45, 25 10. Treibs, A.; Kreuzer, F.-H., Liebigs Ann. Chem. 1968, 718, 208 11. Loudet, A and Burgess, K, Chem Rev, 2007, 107, 4891 12. Muh-ching Yee, Stefanie C. Fas, Michelle M. Stohlmeyer, Thomas J. Wandless, and Karlene A. Cimprich, J. Biol. Chem. 2005, 280, 29053 13. Shigeki Hattori, Kei Ohkubo, Yasuteru Urano, Hisato Sunahara, Tetsuo Nagano, Yuji Wada, Nikolai V. Tkachenko, Helge Lemmetyinen, and Shunichi Fukuzumi, J. Phys. Chem. B 2005, 109, 15368 14. Catherine Bonnier, Devin D. Machin, Omar Abdi and Bryan D. Koivisto, Org. Biomol. Chem., 2013, 11, 3756 15. Sule Erten-Ela, M. Deniz Yilmaz, Burcak Icli, Yavuz Dede, Siddik Icli, and Engin U. Akkaya, Org. Lett., 2008, 10, 15 16. Safacan Kolemen, O. Altan Bozdemir, Yusuf Cakmak, Gokhan Barin, Sule Erten-Ela, Magdalena Marszalek, Jun-Ho Yum, Shaik M. Zakeeruddin, Mohammad K. Nazeeruddin, Michael Gr?atzel and Engin U. Akkaya, Chem. Sci., 2011, 2, 949 17. Mao Mao, Jian-Bo Wang, Zu-Feng Xiao, Song-Yuan Dai, Qin-Hua Song, Dyes and Pigments 2012, 94, 224 18. Jun-Ho Yum, Etienne Baranoff, Sophie Wenger, Md. K. Nazeeruddin and Michael Gratzel, Energy Environ. Sci., 2011, 4, 842 19. Aswani Yella, Hsuan-Wei Lee, Hoi Nok Tsao, Chenyi Yi, Aravind Kumar Chandiran, Md.Khaja Nazeeruddin, Eric Wei-Guang Diau, Chen-Yu Yeh, Shaik M Zakeeruddin, Michael Grätzel, Science 2011, 334, 629 20. Lintao Zeng, Chongjun Jiao, Xiaobo Huang, Kuo-Wei Huang, Wee-Shong Chin, and Jishan Wu, Org. Lett. 2011, 13, 6026 21. Yuanzhao Wu, Xiao Ma, Jiemin Jiao, Yixiang Cheng, Chengjian Zhu, SYNLETT 2012, 23, 778 22. Mukulesh Baruah, Wenwu Qin, Nikola Basaric, Wim M. De Borggraeve, and Noel Boens, J. Org. Chem. 2005, 70, 415223 23. Lijuan Jiao, Changjiang Yu, Jilong Li, Zhaoyun Wang, Min Wu, and Erhong Hao, J. Org. Chem. 2009 , 74 , 7525 24. Qing Wang, Jacques-E. Moser, and Michael Gratzel, J. Phys. Chem. B, 2005, 109, 14945 25. Koji Naoda, Hirotaka Mori, Naoki Aratani, Byung Sun Lee, Dongho Kim, and Atsuhiro Osuka, Angew. Chem. Int. Ed. 2012, 51, 9856 26. Chuandong Dou, Shohei Saito, Kyohei Matsuo, Ichiro Hisaki, and Shigehiro Yamaguchi, Angew. Chem. Int. Ed. 2012, 51, 1 27. Xinfu Zhang, Haibo Yu, and Yi Xiao, J. Org. Chem. 2012, 77, 66 | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/53722 | - |
| dc.description.abstract | Dye-sensitized solar cells (DSSCs) have attracted much attention in recent year as they offer the possibility of low-cost conversion of photovoltaic energy. Remarkable progress has been made in the field of metal-free organic dyes having high extinction coefficient, which can be achieved from rational design based on the structure-property relationship. Due to its large extinction coefficient, great electrochemical stability, and tunable absorption wavelength BODIPY has been one of the most widely used organic chromophores in various fields, such as sensing, imaging, and solar cell applications. However, the performance of BODIPY-based DSSC is only moderate. For the purpose of understanding the relationship between the electronic structure of BODIPY molecule and its ability to harvest solar energy, we synthesized a series of BODIPY derivatives and examined their potential for DSSC application. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T02:28:18Z (GMT). No. of bitstreams: 1 ntu-104-R02223180-1.pdf: 3910057 bytes, checksum: d22825b866bacb24c198114f99e2f428 (MD5) Previous issue date: 2015 | en |
| dc.description.tableofcontents | CONTENTS
Chapter 1 Introduction 1 1.1 General Introduction 1 1.1.1 Mechanism for the generation of photocurrent 3 1.1.2 Parameters of power conversion efficiency 5 1.2 BODIPY 6 1.3 BODIPY derivatives for DSSCs 7 1.4 Panchromatic engineering 11 Chapter 2 Result and Discussion 14 2.1 Molecular Modification Strategy and Theoretical Calculation 14 2.1.1 Synthesis of starting materials 18 2.1.2 Syntheses of sensitizers 21 2.2 UV-vis absorption spectrum and CV 22 2.3 Device Performance 24 Chapter 3 Conclusion 27 Chapter 4 Experimental section 28 Chapter 5 References 40 Chapter 6 Appendix 44 List of Figures Figure 1. Molecular structure of SM315 and N3 2 Figure 2. Schematic configuration of a dye sensitized solar cell 3 Figure 3. Mechanism of photo-current generation 4 Figure 4. Energy levels of TiO2 conduction band and electrolyte 5 Figure 5. BODIPY structure 6 Figure 6. BODIPY-wortmannin 7 Figure 7. The first BODIPY sensitizer in DSSC 8 Figure 8. Type I, II and III donor (D) /acceptor (A) motifs in BODIPY dye 8 Figure 9. BODIPY sensitizer in DSSC and representive diagram 9 Figure 10. Sensitizer PS-1 10 Figure 11. Sensitizer PS-4 11 Figure 12. Molecular structure of YD2-o-C8 and Y123 12 Figure 13. Absorption spectra of YD2-oC8 and SM315 13 Figure 14. Absorption spectra of Aza-BODIPYs and normal BODIPY 15 Figure 15. Concept diagram for strategy a and b 16 Figure 16. Theoretical calculation for BODIPY derivatives (B3LYP, S: 6-31g) 17 Figure 17. Dilution spectra of the fused-BODIPY 20 Figure 18. Absorption spectrum of reference sensitizers 22 Figure 19. Cyclic voltammograms of dyes in DCM 23 Figure 20. IPCE spectra of DSSCs 24 Figure 21. J–V curves of DSSCs based on the dyes 25 Figure 22. EIS (Nyquist plot) of DSSCs measured in the dark under -0.45 V bias. 26 List of Schemes Scheme 1. Synthesis of phenyl substituted BODIPY 18 Scheme 2. Synthesis of fused BODIPY 19 Scheme 3. Synthesis route adopted for the preparation of anchors on BODIPYs 21 Scheme 4. Synthesis of phenyl substituted BODIPY 31 Scheme 5. Synthesis route adopted for the preparation of Fused BODIPY 32 Scheme 6. Synthesis route adopted for the preparation of anchors on BODIPYs 37 List of Tables Table 1. Energy levels from calculation 17 Table 2. Energy levels estimated from CV and absorption 23 Table 3. Device performance 25 | |
| dc.language.iso | en | |
| dc.subject | 染敏料電池 | zh_TW |
| dc.subject | 氟硼二?啶 | zh_TW |
| dc.subject | dye sensitized solar cell | en |
| dc.subject | BODIPY | en |
| dc.title | 氟硼二吡啶衍生物於染敏料電池之應用 | zh_TW |
| dc.title | BODIPY-Derivatives for DSSC | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 103-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 詹益慈(Yi-Tsu Chan),周必泰(Pi-Tai Chou) | |
| dc.subject.keyword | 氟硼二?啶,染敏料電池, | zh_TW |
| dc.subject.keyword | BODIPY,dye sensitized solar cell, | en |
| dc.relation.page | 65 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2015-08-03 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| Appears in Collections: | 化學系 | |
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| ntu-104-1.pdf Restricted Access | 3.82 MB | Adobe PDF |
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