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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 邱靜雯(Ching-Wen Chiu) | |
| dc.contributor.author | Ching-Jung Chiang | en |
| dc.contributor.author | 江青容 | zh_TW |
| dc.date.accessioned | 2021-06-16T02:28:18Z | - |
| dc.date.available | 2020-08-05 | |
| dc.date.copyright | 2015-08-05 | |
| dc.date.issued | 2015 | |
| dc.date.submitted | 2015-08-03 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/53722 | - |
| dc.description.abstract | Dye-sensitized solar cells (DSSCs) have attracted much attention in recent year as they offer the possibility of low-cost conversion of photovoltaic energy. Remarkable progress has been made in the field of metal-free organic dyes having high extinction coefficient, which can be achieved from rational design based on the structure-property relationship. Due to its large extinction coefficient, great electrochemical stability, and tunable absorption wavelength BODIPY has been one of the most widely used organic chromophores in various fields, such as sensing, imaging, and solar cell applications. However, the performance of BODIPY-based DSSC is only moderate. For the purpose of understanding the relationship between the electronic structure of BODIPY molecule and its ability to harvest solar energy, we synthesized a series of BODIPY derivatives and examined their potential for DSSC application. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-16T02:28:18Z (GMT). No. of bitstreams: 1 ntu-104-R02223180-1.pdf: 3910057 bytes, checksum: d22825b866bacb24c198114f99e2f428 (MD5) Previous issue date: 2015 | en |
| dc.description.tableofcontents | CONTENTS
Chapter 1 Introduction 1 1.1 General Introduction 1 1.1.1 Mechanism for the generation of photocurrent 3 1.1.2 Parameters of power conversion efficiency 5 1.2 BODIPY 6 1.3 BODIPY derivatives for DSSCs 7 1.4 Panchromatic engineering 11 Chapter 2 Result and Discussion 14 2.1 Molecular Modification Strategy and Theoretical Calculation 14 2.1.1 Synthesis of starting materials 18 2.1.2 Syntheses of sensitizers 21 2.2 UV-vis absorption spectrum and CV 22 2.3 Device Performance 24 Chapter 3 Conclusion 27 Chapter 4 Experimental section 28 Chapter 5 References 40 Chapter 6 Appendix 44 List of Figures Figure 1. Molecular structure of SM315 and N3 2 Figure 2. Schematic configuration of a dye sensitized solar cell 3 Figure 3. Mechanism of photo-current generation 4 Figure 4. Energy levels of TiO2 conduction band and electrolyte 5 Figure 5. BODIPY structure 6 Figure 6. BODIPY-wortmannin 7 Figure 7. The first BODIPY sensitizer in DSSC 8 Figure 8. Type I, II and III donor (D) /acceptor (A) motifs in BODIPY dye 8 Figure 9. BODIPY sensitizer in DSSC and representive diagram 9 Figure 10. Sensitizer PS-1 10 Figure 11. Sensitizer PS-4 11 Figure 12. Molecular structure of YD2-o-C8 and Y123 12 Figure 13. Absorption spectra of YD2-oC8 and SM315 13 Figure 14. Absorption spectra of Aza-BODIPYs and normal BODIPY 15 Figure 15. Concept diagram for strategy a and b 16 Figure 16. Theoretical calculation for BODIPY derivatives (B3LYP, S: 6-31g) 17 Figure 17. Dilution spectra of the fused-BODIPY 20 Figure 18. Absorption spectrum of reference sensitizers 22 Figure 19. Cyclic voltammograms of dyes in DCM 23 Figure 20. IPCE spectra of DSSCs 24 Figure 21. J–V curves of DSSCs based on the dyes 25 Figure 22. EIS (Nyquist plot) of DSSCs measured in the dark under -0.45 V bias. 26 List of Schemes Scheme 1. Synthesis of phenyl substituted BODIPY 18 Scheme 2. Synthesis of fused BODIPY 19 Scheme 3. Synthesis route adopted for the preparation of anchors on BODIPYs 21 Scheme 4. Synthesis of phenyl substituted BODIPY 31 Scheme 5. Synthesis route adopted for the preparation of Fused BODIPY 32 Scheme 6. Synthesis route adopted for the preparation of anchors on BODIPYs 37 List of Tables Table 1. Energy levels from calculation 17 Table 2. Energy levels estimated from CV and absorption 23 Table 3. Device performance 25 | |
| dc.language.iso | en | |
| dc.subject | 染敏料電池 | zh_TW |
| dc.subject | 氟硼二?啶 | zh_TW |
| dc.subject | dye sensitized solar cell | en |
| dc.subject | BODIPY | en |
| dc.title | 氟硼二吡啶衍生物於染敏料電池之應用 | zh_TW |
| dc.title | BODIPY-Derivatives for DSSC | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 103-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 詹益慈(Yi-Tsu Chan),周必泰(Pi-Tai Chou) | |
| dc.subject.keyword | 氟硼二?啶,染敏料電池, | zh_TW |
| dc.subject.keyword | BODIPY,dye sensitized solar cell, | en |
| dc.relation.page | 65 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2015-08-03 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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