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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/51654完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 王大銘(Da-Ming Wang) | |
| dc.contributor.author | I-Wei Chang | en |
| dc.contributor.author | 張逸惟 | zh_TW |
| dc.date.accessioned | 2021-06-15T13:43:04Z | - |
| dc.date.available | 2016-02-16 | |
| dc.date.copyright | 2016-02-16 | |
| dc.date.issued | 2015 | |
| dc.date.submitted | 2015-12-23 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/51654 | - |
| dc.description.abstract | 近年，因其低耗能以及操作簡便性，支撐式液膜廣泛被使用於分離回收金屬離子，同時也有許多用於描述物質於支撐式液膜輸送的理論模型被提出。本研究提出一較為簡化的理論模型對具分散反萃取相支撐式液膜分離回收釹、鏑金屬離子進行預測，並由單一金屬離子的實驗求出參數。實驗得出鏑離子的平衡常數為35841.3、水相質傳係數為7.016×10-6m/s，錯合物於膜相質傳係數為4.301×10-7m/s；釹金屬離子的平衡常數為16.7、水相質傳係數為9.665×10-6m/s，錯合物於膜相質傳係數為3.430×10-7 m/s。理論模型在雙成份系統對於pH值改變及萃取劑濃度改變有好的預測，此較為簡化的模型將利於預測系統放大。 | zh_TW |
| dc.description.abstract | The use of supported liquid membrane to separate metal ions has been widely reported for its efficiency and simple process. Mathematical models for this technique have been proposed to describe the transport behavior. In this work, a simplified model for the separation of Dy3+ and Nd3+ through supported liquid membrane with strip dispersion (SLMSD) is established and the situation of excess amount of metal ions is considered. Parameters were calculated based on single-ion experiment. For Dy3+, the equilibrium constant was found to be 35841.3, the hydraulic mass transfer coefficient 7.016×10-6m/s, and the mass transfer coefficient of the complex in the membrane phase 4.301×10-7m/s. For Nd3+, the values were 16.7, 9.665×10-6m/s, 3.430×10-7m/s respectively. The model showed good agreements in Dy3+/Nd3+ separation experiments in various pH value and extractant concentration. The simplicity of the model gives an advantage on scale-up process. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T13:43:04Z (GMT). No. of bitstreams: 1 ntu-104-R02524058-1.pdf: 2296511 bytes, checksum: c643222599ca3b21bbf97c120c918114 (MD5) Previous issue date: 2015 | en |
| dc.description.tableofcontents | 第一章 緒論 1
第二章 文獻回顧 3 2-1溶劑萃取 3 2-1-1溶劑萃取的原理 3 2-1-2物理萃取 5 2-1-3化學萃取 5 2-1-3-1萃取劑 5 2-1-3-2稀釋劑 10 2-1-3-3修飾劑 12 2-2液膜分離技術 12 2-2-1液膜的輸送機制與原理 13 2-2-1-1簡單擴散傳送（simple transport） 13 2-2-1-2載體輔助傳送（facilitated or carrier-mediated transport） 14 2-2-1-3偶聯輔助傳送（coupled transport） 14 2-2-2液膜的型式 16 2-2-2-1乳化式液膜 17 2-2-2-2支撐式液膜 19 2-2-3支撐式液膜的不穩定性與改善 22 2-2-4影響支撐式液膜效率的參數 26 2-2-5支撐式液膜理論模型 28 第三章 實驗理論 33 3-1萃取平衡 33 3-2支撐式液膜之效能參數 34 3-3支撐式液膜透膜速率之理論模型 35 第四章 實驗方法 39 4-1設備與儀器 39 4-2實驗藥品 42 4-3實驗步驟 44 4-3-1搖瓶式萃取平衡實驗 44 4-3-2具分散反萃取相支撐式液膜 45 4-3-3樣品濃度量測 47 第五章 結果與討論 49 5-1釹、鏑離子透過係數的模型建立 49 5-1-1萃取反應機制與平衡常數 49 5-1-2質傳係數計算 53 5-1-3理論模型對雙成分系統的分離回收之預測 64 第六章 結論 69 參考文獻 71 | |
| dc.language.iso | zh-TW | |
| dc.subject | 萃取 | zh_TW |
| dc.subject | 二(2-乙基己基)磷酸 | zh_TW |
| dc.subject | 支撐式液膜 | zh_TW |
| dc.subject | 理論模型 | zh_TW |
| dc.subject | model | en |
| dc.subject | di-(2-ethylhexyl) phosphoric acid | en |
| dc.subject | extraction | en |
| dc.subject | supported liquid membrane | en |
| dc.title | pH值對具分散反萃取相支撐式液膜分離之影響及其數學模式分析 | zh_TW |
| dc.title | pH Effects on Separation Using Supported Liquid Membrane with Strip Dispersion and Mathematical Modeling Analysis | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 104-1 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 謝學真,劉培毅,彭震 | |
| dc.subject.keyword | 支撐式液膜,理論模型,萃取,二(2-乙基己基)磷酸, | zh_TW |
| dc.subject.keyword | supported liquid membrane,model,extraction,di-(2-ethylhexyl) phosphoric acid, | en |
| dc.relation.page | 79 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2015-12-24 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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