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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 彭旭明 | |
dc.contributor.author | Shih-Hong Li | en |
dc.contributor.author | 李士弘 | zh_TW |
dc.date.accessioned | 2021-06-15T13:01:26Z | - |
dc.date.available | 2017-07-26 | |
dc.date.copyright | 2016-07-26 | |
dc.date.issued | 2016 | |
dc.date.submitted | 2016-07-11 | |
dc.identifier.citation | 參考文獻
1. Werner, A. A. Neuere Anschauungen auf dem Gbiete der anorganischen Chemie, 1905. 2. Kauffman, G.B. Coord. Chem. Rev. 1973, 9 , 339. 3. Kauffman, G.B. Coord. Chem. Rev. 1973, 11 , 161. 4. Cotton, F.A. ; Curtis, N.F. ; Harris, C.B. ; Johnson, B.F.G. ; Lippard, S.J. ; Mague, J.T. ; Robinson, B.F.G. ; Robinson, W.R. Inorg. Chem. 1965, 4 , 326. Gatteschi, D. ; Mealli, C. ; Sacconi, L.J. Am. Chem. Soc. 1973, 95 , 2736. 5. Wibaut, J.P. ; Dingemasse, E. Rec. Trav. Chim. Pays-Bas 1923, 42, 243 6. Gibson, C.S. ; Colles, W. Mm J. Chem. Soc. 1931, 2407. 7. Chen, I.-W.P. ; Fu, M.-D. ; Tseng, W.-H. ; Yu, J.-Y. ; Wu, S.-H. ; Ku, C.-J. ; Chen,C.-H. ; Peng, S.-M. Angew. Chem. Int. Ed. 2006, 45, 5814. 8. Berry, J.F. ;Cotton, F.A. ; Lu, T.-B. ; Murillo, C.A. ; Wang, X.P. Inorg. Chem. 2003, 42, 3959. 9. Stephenson, T.A. ; Wilkinson, G.J. Inorg. Nucl. Chem. 1996, 28, 2285. 10. Gatteschi, D. ; Mealli, C. ; Sacconi, L. J. Am. Chem. Soc. 1973, 95, 2736.Cotton, F.A. ; Curtis, N.F. ; Robinson, W.R. Inorg. Chem. 1965, 4, 1696. 11. Stephenson, T.A. ; Bannister, C. ; Wilkinson G. J. Chem. Soc. 1964, 2538. 12. Huang, G.-C. ; Benard, M. ; Rohmer, M.-M. ; Li, L.-A. ;Chiu, M.-J. ; Yeh C.-Y. ; Lee, G.H. ; Peng, S.-M. Eur. J. Inorg. Chem. 2008, 1767. 13. Rempel, G.A. ; Legzdins, P. ; Smith, H. ; Wilkinson, G. Inorg. Synth. 1972, 13 , 90. 14. Nippe, M., Timmer, G.H. ; Berry, J.F. Chem. Commun. 2009, 4357. 15. Hua, S.-A., Doctoral Dissertation in Department of Chemistry in NTU, 2012. 16. Rohmer, M.-M. ; Liu, I. P.-C. ; Lin, J.-C. ; Chiu, M.-J. ; Lee, C.-H. ; Lee, G.H. ; Benard, M. ; Lopez, X. ; Peng, S.-M. Angew. Chem. 2007, 119 , 3603. 17. Kuo, C.-K. Doctoral Dissertation in Department of Chemistry in NTU, 2006. 18. Cheng, M.-C. ; Mai, C.-L. ; Yeh, C.-Y. ; Lee, G.-H. ; Peng, S.-M. Chem. Commun. 2013 , 49 , 7938 19. Ho, P.-H. , Doctoral Dissertation in Department of Chemistry in NTU, 2013. 20. Zall, C.M. ; Clouston, L.J. ; Young, V.G. ; Ding, K. ; Kim, H.J. ; Zherebetskyy, D. ; Chen, Y.S. ; Bill, E. ; Gagliardi, L. ; Lu, C.C. Inorg. Chem. 2013, 52 , 9216. 21. Hua, S.-A. Doctoral Dissertation in Department of Chemistry in NTU, 2012. 22. Huang, G.-C. , Doctoral Dissertation in Department of Chemistry in NTU, 2007. 23. Huang, K.S. ; Kurth, M.J. J. Org. Chem. 2003, 67, 2382. 24. (a)Newkome, G.R. ; Garbis, S.J. ; Majestic, V.K. ; Fronczek, F.R. ; Chiari, G. J. Org. Chem. 1981, 46 , 833.(b) Huang, G.-C. , Doctoral Dissertation in Department of Chemistry in NTU, 2007. 25. Chao, C.-H. , Doctoral Dissertation in Department of Chemitry in NTU, 2012. 26. Kazushi Mashima, Atsushi Fukumoto, Hiroshi Nakano, Yutaka Kaneda, Kazuhide Tani, and Akira Nakamura J. Am. Chem. Soc. 1998, 120, 12151-12152 27. Cotton F.A. Angrew. Chem. Int. Ed. Engl. 1979, 18 | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/50838 | - |
dc.description.abstract | 本論文中以N2,N7-bis(4-methoxyphemyl)-1,8-naphthyridine-2,7-diamine
(H2DAniDANy)對稱型四氮配基,合成以鉬為主要金屬的系列異金屬錯合物,分別為[Mo2(HDAniDANy)4]BF4 (A)、Mo2Ni2(DAniDANy)4(B),並對這兩個金屬串錯合物進行其結構、磁性及電化學進行探討。 由X-Ray單晶繞射可得知,錯合物A是以四片HDAniDANy1-配基以螺旋式纏繞在兩個鉬金屬外圍,中間的鉬金屬以接近square planar的配位模式與氮原子鍵結。而錯合物B是以四片DAniDANy2-配基以螺旋式纏繞在四個金屬離子外圍形成金屬串,雙核鉬金屬以square planar的配位模式與氮原子配位於金屬串的一側,另一側的鎳金屬也以square planar的配位模式與氮原子配位,形成Mo-Mo-Ni-Ni的形式。 藉由晶體結構和磁性上的鑑定,藉由晶體結構與磁性行為上的鑑定,可得知錯和物A在300K時的μeff為1.68 B.M.,推測其電子自旋為Mo25+(S=1/2),接近純自旋理論的μeff = 1.73 B.M. , 推測錯合物A 的鉬鉬金屬為二三混價,其鍵長為2.1428(7)Å。 | zh_TW |
dc.description.abstract | With the use of N2,N7-bis(4-methoxyphenyl)-1,8-naphthyridine- 2,7-diamine(H2DAniDANy), a symmetric tetradentate ligand, new series of HMSCs based on Molybdenum, [Mo2(HDAniDANy)4]BF4 (A)、Mo2Ni2(DAniDANy)4(B) were synthesized. The X-Ray structural studies showed that complex A are two Molybdenum wrapped by four HDAniDANy-1 ligands with 2,2-trans conformation, and metal ions with square planar geometry chelated by naphthyridine N atom and amido N atom of each HDAniDANy-1 . Complex B has two Molybdenum and two Nickel wrapped helically by four DAniDANy2- ligands, and the di-Molybdenum and di-Nickel with square planar geometry chelated by naphthyridine N atom and amido N atom of each DAniDANy2-, like Mo-Mo-Ni-Ni.
The magnetic susceptibility showed that the μeff values of A at 300 K is 1.68 B.M. . The spin state of A with Mo25+(S=1/2) configuration, which is close to the spin-only value 1.73 B.M. . The complex A is an mixed-valence di-Molybdenum with Mo(II)/Mo(III), which bond length is 2.1428(7) Å. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T13:01:26Z (GMT). No. of bitstreams: 1 ntu-105-R03223164-1.pdf: 4452589 bytes, checksum: 7206c642431c3f9b4d18c8b5cec88029 (MD5) Previous issue date: 2016 | en |
dc.description.tableofcontents | 中文摘要.............................................................................................I
ABSTRACT II 第一章 序論 1 1-1 金屬金屬鍵結理論 1 1-2 配基的設計與介紹 5 1-3 金屬串錯合物與分子導線 8 1-4 研究方向 15 第二章 實驗部分 17 2-1 試藥與儀器 17 2-2 實驗合成 20 2-2-1 前驅物及配基的合成 20 2-2-2 金屬錯合物的合成 24 第三章 結果與討論 26 3-1 合成 26 3-2 晶體結構分析 28 3-3 磁性量測與分析 34 3-4 電化學分析 38 3-5電子吸收光譜 39 3-6 反應機構分析 41 3-7 結論 43 四、未來展望 44 參考文獻 45 附錄 47 附錄A MASS、IR、1H NMR spectra 48 | |
dc.language.iso | zh-TW | |
dc.title | 對稱型 萘啶二胺配基異金屬串鉬 /鎳錯合 物之成與研究 | zh_TW |
dc.title | Syntheses and Studies of the Hetero-polynuclear Mo/Ni Metal String Complexes Coordinated by Symmetric Naphthyridinyldiamine Tetradentate Ligand | en |
dc.type | Thesis | |
dc.date.schoolyear | 104-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 金必耀,葉鎮宇,王志傑 | |
dc.subject.keyword | 異金屬串錯合物、鉬鎳異金屬串錯合物、四核異金屬串錯合物、?啶二胺配基, | zh_TW |
dc.subject.keyword | Heterometallic metal string complex、hetero-polynuclear Mo/Ni complex、symmetric tetradentate ligand、naphthyridinyldiamin, | en |
dc.relation.page | 74 | |
dc.identifier.doi | 10.6342/NTU201600814 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2016-07-11 | |
dc.contributor.author-college | 理學院 | zh_TW |
dc.contributor.author-dept | 化學研究所 | zh_TW |
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