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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/50740完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 張煥宗(Huan-Tsung Chang) | |
| dc.contributor.author | Yu-Chi Li | en |
| dc.contributor.author | 李昱錡 | zh_TW |
| dc.date.accessioned | 2021-06-15T12:55:37Z | - |
| dc.date.available | 2026-12-31 | |
| dc.date.copyright | 2016-07-26 | |
| dc.date.issued | 2016 | |
| dc.date.submitted | 2016-07-15 | |
| dc.identifier.citation | 第一章參考文獻
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/50740 | - |
| dc.description.abstract | 本篇論文主要在開發一步合成法，利用加入不同濃度的聚苯乙烯磺酸鈉（polystyrene sulfonate）控制青黴胺（penicillamine）－銅奈米團簇聚集大小。相較於沒有加入聚苯乙烯磺酸鈉的銅奈米團簇，經由聚電解質調控聚集體大小的銅奈米團簇具有很好的分散性、光穩定性以及對於硫化氫有很好的選擇性與靈敏性，對於硫化氫的偵測極限為650 nM，因此可應用於偵測溫泉水樣品中之硫化氫。此外，更將此發光銅奈米團簇與可攜式紙質分析裝置（microfluidic paper-based analytical device）結合，直接使用肉眼判定溫泉水中硫化氫之有無以及微量盤式螢光儀定量硫化氫濃度。有別於傳統的硫化氫檢測方法只能於溶液相進行檢測，我們利用加熱溫泉水後會釋放出硫化氫氣體，可與紙質平臺上的銅奈米團簇反應後使其螢光消光，可直接使用肉眼進行快速判定，此方法亦可避免樣品中一些金屬離子的干擾；而使用微量盤式螢光儀直接定量硫化氫濃度於紙質裝置上，此方法相較於傳統公告方法只需非常小的樣品體積（5 μL）以及較短的分析時間（30分鐘），對於硫化氫的偵測極限為1 μM。由於此發光銅奈米團簇/紙質裝置具有製備簡單、成本低、可拋棄、快速偵測且精準等優點，因此具有很大的發展潛力於監控氣相與液相硫化氫之含量。 | zh_TW |
| dc.description.abstract | An one-pot approach has been developed to control the size of penicillamine-copper nanocluster (PA-Cu NC) aggregates through the addition of different concentrations of polystyrene sulfonate (PSS). The PSS-PA-Cu NC aggregates are photoluminescent and have excellent water dispersity, better photostability under UV irradiation, and remarkable sensitivity towards H2S (limit of detection: 650 nM) compared to PA-Cu NC aggregates without PSS dispersion. The practicability of this probe was verified by determination of the H2S concentration in hot spring-water samples. The PSS-PA-Cu NCs were integrated into a portable microfluidic paper-based analytical device (μPAD) for the on/off determination of H2S in hot spring-water samples. This platform targets released H2S gas to avoid interference from other ions in water samples in contrast with conventional H2S detection methods which can only determine H2S directly from solution. The PSS-PA-Cu NC/μPADs use ultra-low sample volumes (5 μL) and feature shorter analysis times (~30 min) compared to conventional solution-based methods. The quantitative results not only can be seen by the naked-eye, as well as facilely recorded and transmitted using a smartphone but also can determined by microplate reader. The LOD of the PSS-PA-Cu NC/μPAD device was 1 μM. In conclusion the PSS-PA-Cu NC/μPADs have great potential to monitor H2S levels in gaseous and liquid samples. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T12:55:37Z (GMT). No. of bitstreams: 1 ntu-105-R03223140-1.pdf: 2724146 bytes, checksum: 9203da9c73b40a8ef250332c8929d9e9 (MD5) Previous issue date: 2016 | en |
| dc.description.tableofcontents | 論文口試委員審定書..............................i
謝誌 .........................................ii 中文摘要.......................................v 英文摘要.......................................vi 目錄 ........................................ vii 圖目錄 ........................................ix 表目錄 ........................................xi 第一章 緒論 ....................................1 1.1 螢光貴金屬奈米團 ............................1 1.2 螢光銅奈米團簇 ..............................4 1.3 螢光銅奈米團簇之製備方法 .....................5 1.3.1 以聚合物穩定之銅奈米團簇 ...................7 1.3.2 以 DNA 分子穩定之銅奈米團簇.................8 1.3.3 以蛋白質穩定之銅奈米團簇 ...................9 1.3.4 以胜肽穩定之銅奈米團簇.....................10 1.3.5 以巰基分子穩定之銅奈米團簇 .................12 1.4 螢光奈米團簇之應用...........................13 1.5 研究動機動..................................14 1.6 圖表 ......................................15 1.7 參考文獻 ..................................25 第二章 控制銅奈米團簇聚集體大小並應用於紙質平臺偵測硫化氫....34 2.1 前言 .....................................34 2.2 實驗方法 ..................................35 2.2.1 實驗藥品 ................................35 2.2.2 實驗儀器 ................................36 2.2.3 銅奈米團簇的合成 .........................36 2.2.4 紙質裝置的製備 ...........................37 2.2.5 利用銅奈米團簇聚集體偵測硫化氫 .............37 2.2.6 偵測溫泉水樣品中的硫化氫含量................37 2.2.7 利用銅奈米團簇/紙質裝置偵測硫化氫............38 2.2.8 銅奈米團簇/紙質裝置上偵測溫泉水樣品中的硫化氫..38 2.3 實驗結果與討論 ...............................38 2.3.1 聚電解質對銅奈米團簇聚集體形成之影響 .........38 2.3.2 銅奈米團簇聚集體的光學性質與特性 .............41 2.3.3 銅奈米團簇聚集體偵測硫化氫之機制與溫泉水樣品中之檢測...43 2.3.4 於銅奈米團簇/紙質裝置上偵測硫化與溫泉水樣品中之檢測...45 2.4 結論 ........................................47 2.5 圖表 ........................................49 2.6 參考文獻 ....................................65 | |
| dc.language.iso | zh-TW | |
| dc.subject | 銅奈米團簇聚集體 | zh_TW |
| dc.subject | 硫化氫 | zh_TW |
| dc.subject | 銅奈米團簇聚集體 | zh_TW |
| dc.subject | 紙質裝置 | zh_TW |
| dc.subject | 硫化氫 | zh_TW |
| dc.subject | 聚電解質 | zh_TW |
| dc.subject | 聚電解質 | zh_TW |
| dc.subject | 紙質裝置 | zh_TW |
| dc.subject | paper-based devices | en |
| dc.subject | copper nanoclusters aggregates | en |
| dc.subject | polyelectrolyte | en |
| dc.subject | hydrogen sulfide | en |
| dc.subject | hydrogen sulfide | en |
| dc.subject | copper nanoclusters aggregates | en |
| dc.subject | paper-based devices | en |
| dc.subject | polyelectrolyte | en |
| dc.title | 調控銅奈米團簇聚集體大小並應用於紙質平臺偵測硫化氫 | zh_TW |
| dc.title | Size-tunable copper nanocluster aggregates and their application in hydrogen sulfide sensing on paper-based devices | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 104-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 胡焯淳(Cho-Chun Hu),吳秀梅(Shou-Mei Wu),陳明娟(Min-Jane Chen),陳建甫(Chien-Fu Chen) | |
| dc.subject.keyword | 銅奈米團簇聚集體,硫化氫,紙質裝置,聚電解質, | zh_TW |
| dc.subject.keyword | copper nanoclusters aggregates,hydrogen sulfide,paper-based devices,polyelectrolyte, | en |
| dc.relation.page | 69 | |
| dc.identifier.doi | 10.6342/NTU201600868 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2016-07-15 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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