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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 楊志忠 | |
| dc.contributor.author | Chi-Ming Weng | en |
| dc.contributor.author | 翁啟銘 | zh_TW |
| dc.date.accessioned | 2021-06-15T12:49:49Z | - |
| dc.date.available | 2019-07-26 | |
| dc.date.copyright | 2016-07-26 | |
| dc.date.issued | 2016 | |
| dc.date.submitted | 2016-07-21 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/50633 | - |
| dc.description.abstract | The controlling mechanism for determining the growth direction of a Ga-doped ZnO (GaZnO) nanoneedle (NN) by using an Ag nanoparticle (NP) as vapor-liquid-solid (VLS) growth catalyst in molecular beam epitaxy (MBE) is disclosed. It is found that the local Ag (111) orientation of the catalytic Ag portion in an Ag NP determines the ZnO (002) orientation of the grown GaZnO and hence the NN growth direction. The ZnO (002) plane of the grown GaZnO is always parallel with the Ag (111) planes of the Ag portions involved in VLS growth in either the top or bottom Ag NP of an NN. When GaN is used as NN growth template, at a sufficiently high temperature (350-450 oC), a small Ag NP can become a quasi-single crystal with its Ag (111) plane consistent with the GaN (002) plane and hence results in the growth of a vertical GaZnO NN. However, tilted NNs can be grown from a large Ag NP or a cluster of Ag NP on GaN due to its non-uniform Ag (111) orientation distribution. At the early stage of GaZnO growth, GaZnO precipitation can be observed between Ag layers within an Ag NP, indicating the growth of a semiconductor on Ag. On other templates, like Si, sapphire, or SiO2, single-crystal Ag NP cannot be formed such that GaZnO NNs of random orientations are grown. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T12:49:49Z (GMT). No. of bitstreams: 1 ntu-105-R02941107-1.pdf: 3984847 bytes, checksum: 17af3298bb7b4c7cbbb175bf7dd231aa (MD5) Previous issue date: 2016 | en |
| dc.description.tableofcontents | 誌謝-------------------------------------- i
摘要-------------------------------------- ii Abstract--------------------------------- iii Content---------------------------------- iv Chapter 1 Introduction------------------- 1 1.1 Transparent Conducting Oxide---------- 1 1.2 The Electrical Properties of TCO---- 2 1.3 General Reviews on ZnO as a Light-emitting Material 2 1.3.1 Crystal Structures----------------- 4 1.4 Doping of ZnO------------------------- 5 1.4.1 n-type doping--------------------- 5 1.4.2 p-type doping---------------------- 6 1.5 ZnO nanowire growth------------------ 7 1.6 Research Motivations and Thesis Organization8 Chapter 2 Analysis Methods---------------- 16 2.1 Specimen Preparation for Cross-section Transmission Electron Microscopy----------------------- 16 2.2 High-Resolution Transmission Electron Microscopy -------------------------------------------------17 2.3 Energy Dispersive X-ray Spectroscopy (EDX)- 22 2.4 Scanning Electron Microscopy (SEM)---- 23 2.5 Geometric Phase Analysis (GPA)------- 24 Chapter 3 Analysis results of Growth Orientations and Crystal Structures of Ga-doped ZnO Nanoneedles 33 3.1 Sample growth conditions------------- 33 3.2 GaZnO nanoneedles growth on GaN templates-- 34 3.3 GaZnO precipitation within an Ag NP-------- 40 3.4 GaZnO NNs grown on Si, sapphire, and SiO2 templates -------------------------------------------------41 3.5 Discussions------------------------- 46 Chapter 4 Conclusions-------------------- 71 References-------------------------------- 72 | |
| dc.language.iso | en | |
| dc.subject | 穿透式電子顯微鏡 | zh_TW |
| dc.subject | 氧化鋅 | zh_TW |
| dc.subject | 奈米針 | zh_TW |
| dc.subject | 穿透式電子顯微鏡 | zh_TW |
| dc.subject | 氧化鋅 | zh_TW |
| dc.subject | 奈米針 | zh_TW |
| dc.subject | Transmission Electron Microscopy | en |
| dc.subject | Transmission Electron Microscopy | en |
| dc.subject | ZnO | en |
| dc.subject | Nanoneedle | en |
| dc.subject | ZnO | en |
| dc.subject | Nanoneedle | en |
| dc.title | 利用銀奈米顆粒為催化劑經由氣液固相生長模式所製作摻鎵氧化鋅奈米針的生長方向與晶格結構研究 | zh_TW |
| dc.title | Growth Orientations and Crystal Structures of
Ga-doped ZnO Nanoneedles Using Ag Nanoparticles as Catalyst in Vapor-liquid-solid Growth | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 104-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 黃建璋,吳肇欣,吳育任,江衍偉 | |
| dc.subject.keyword | 穿透式電子顯微鏡,氧化鋅,奈米針, | zh_TW |
| dc.subject.keyword | Transmission Electron Microscopy,ZnO,Nanoneedle, | en |
| dc.relation.page | 86 | |
| dc.identifier.doi | 10.6342/NTU201601176 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2016-07-21 | |
| dc.contributor.author-college | 電機資訊學院 | zh_TW |
| dc.contributor.author-dept | 光電工程學研究所 | zh_TW |
| 顯示於系所單位： | 光電工程學研究所 | |
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