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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 蔣本基 | |
dc.contributor.author | Si-Lu Pei | en |
dc.contributor.author | 裴思魯 | zh_TW |
dc.date.accessioned | 2021-06-15T12:38:49Z | - |
dc.date.available | 2016-08-03 | |
dc.date.copyright | 2016-08-03 | |
dc.date.issued | 2016 | |
dc.date.submitted | 2016-07-28 | |
dc.identifier.citation | (1) Abo-El-Enein, S. A., et al. (2013). 'Reactivity of dealuminated kaolin and burnt kaolin using cement kiln dust or hydrated lime as activators.' Construction and Building Materials 47: 1451-1460.
(2) Al Shamaa, M., et al. (2015). 'Influence of relative humidity on delayed ettringite formation.' Cement and Concrete Composites 58: 14-22. (3) American Society for Testing and Materials, A. (2015). 'C150/C150M, Standard Specification for Portland Cement.' (4) Association, C. C. S. and T. U. Congress (2014). 'The economic benefits of carbon capture and storage in the UK.' (5) Azdarpour, A., et al. (2015). 'A review on carbon dioxide mineral carbonation through pH-swing process.' Chemical Engineering Journal 279: 615-630. (6) Baciocchi, R., et al. (2010). 'Carbonation of Stainless Steel Slag as a Process for CO2 Storage and Slag Valorization.' Waste and Biomass Valorization 1(4): 467-477. (7) Baciocchi, R., et al. (2011). 'Wet versus slurry carbonation of EAF steel slag.' Greenhouse Gases: Science and Technology 1(4): 312-319. (8) Baciocchi, R., et al. (2011). 'Wet versus slurry carbonation of EAF steel slag.' Greenhouse Gases-Science and Technology 1(4): 312-319. (9) Baciocchi, R., et al. (2015). 'Thin-film versus slurry-phase carbonation of steel slag: CO2 uptake and effects on mineralogy.' Journal of Hazardous Materials 283: 302-313. (10) Baciocchi, R., et al. (2015). 'Effects of thin-film accelerated carbonation on steel slag leaching.' J Hazard Mater 286: 369-378. (11) Bai., S., et al. (2015). 'SO2 Removal in a Pilot Scale Rotating Packed Bed.' Environmental Engineering Science 32(9): 806-815. (12) Bobicki, E. R., et al. (2012). 'Carbon capture and storage using alkaline industrial wastes.' Progress in Energy and Combustion Science 38(2): 302-320. (13) Chang, E. E., et al. (2013). 'Kinetic modeling on CO(2) capture using basic oxygen furnace slag coupled with cold-rolling wastewater in a rotating packed bed.' J Hazard Mater 260: 937-946. (14) Chang, E. E., et al. (2012). 'Accelerated carbonation of steelmaking slags in a high-gravity rotating packed bed.' Journal of Hazardous Materials 227–228: 97-106. (15) Chi, J. M., et al. (2002). 'Effects of carbonation on mechanical properties and durability of concrete using accelerated testing method.' Journal of marine science and technology 10(1): 14-20. (16) Choudhary, H., et al. (2015). 'Observation of phase transformations in cement during hydration.' Construction and Building Materials 101: 122-129. (17) Cox, L. (1999). Nitrogen Oxides (NOx), Why and How They Are Controlled. U. S. E. P. Agency. Research Triangle Park, North Carolina 27711, Clean Air Technology Center (MD-12). (18) Datta, S., et al. (2013). 'Electrochemical CO2 Capture Using Resin-Wafer Electrodeionization.' Industrial & Engineering Chemistry Research 52(43): 15177-15186. (19) Dave, N. (2013). 'Effect of Sulphate Attack on Properties of Concrete -A Review.' International Journal of Emerging Trends in Engineering and Development 1: 304-310. (20) Dri, M., et al. (2013). 'Dissolution of steel slag and recycled concrete aggregate in ammonium bisulphate for CO2 mineral carbonation.' Fuel Processing Technology 113: 114-122. (21) Dri, M., et al. (2014). 'Mineral carbonation from metal wastes: Effect of solid to liquid ratio on the efficiency and characterization of carbonated products.' Applied Energy 113: 515-523. (22) Duan, P., et al. (2016). 'Influence of partial replacement of fly ash by metakaolin on mechanical properties and microstructure of fly ash geopolymer paste exposed to sulfate attack.' Ceramics International 42(2, Part B): 3504-3517. (23) El-Naas, M. H., et al. (2015). 'CO2 sequestration using accelerated gas-solid carbonation of pre-treated EAF steel-making bag house dust.' Journal of environmental management 156: 218-224. (24) Ernst Worrell, et al. (2001). 'CARBON DIOXIDE EMISSIONS FROM THE GLOBAL CEMENT INDUSTRY.' Annual Review of Energy and the Environment 26(1): 303-329. (25) Fällman, A. M. (2000). 'Leaching of chromium and barium from steel slag in laboratory and field tests — a solubility controlled process?' Waste Management 20(2–3): 149-154. (26) Farmer, V. C. (1973). The Infrared Spectra of Minerals, Mineralogical Society of Great Britain and Ireland. (27) Fernández Bertos, M., et al. (2004). 'A review of accelerated carbonation technology in the treatment of cement-based materials and sequestration of CO2.' Journal of Hazardous Materials 112(3): 193-205. (28) Fu Jia, et al. (2015). 'Research on Removal of Fine Particles by Cross-flow Rotating Packed Bed.' Chemical Industry and Enginerring Progress 34(3). (29) Gerald, P. (1948). 'Effect of Gypsum Content and other Factors on Shrinkage of Concrete Prism.' Journal Proceedings 44(10). (30) Ghosh, S. N. and S. K. Handoo (1980). 'Infrared and Raman spectral studies in cement and concrete (review).' Cement and Concrete Research 10(6): 771-782. (31) GHOSH, S. N., et al. (1979). 'Review The Chemistry of Dicalcium Silicate Mineral.' JOURNAL OF MATERIALS SCIENCE. (32) Ghouleh, Z., et al. (2015). 'High-strength KOBM steel slag binder activated by carbonation.' Construction and Building Materials 99: 175-183. (33) Głowiński, J., et al. (2009). 'Absorption of nitrogen oxides at the final stage of ammonium nitrite production.' Chemical and Process Engineering Vol. 30, z. 2: 217-229. (34) Gunning, P. J., et al. (2010). 'Accelerated carbonation treatment of industrial wastes.' Waste Management 30(6): 1081-1090. (35) Guo, F., et al. (1997). 'Hydrodynamics and mass transfer in cross-flow rotating packed bed.' Chemical Engineering Science 52(21–22): 3853-3859. (36) Haecker, C.-J., et al. (2005). 'Modeling the linear elastic properties of Portland cement paste.' Cement and Concrete Research 35(10): 1948-1960. (37) Han, X. L., et al. (2015). 'Characterization and synthesis of ZTA nanopowders and ceramics by rotating packed bed (RPB).' Ceramics International 41(3): 3568-3573. (38) He, L., et al. (2013). 'A Novel Method for CO2Sequestration via Indirect Carbonation of Coal Fly Ash.' Industrial & Engineering Chemistry Research 52(43): 15138-15145. (39) Hekal, E. E., et al. (2013). 'Hydration characteristics of Portland cement – Electric arc furnace slag blends.' HBRC Journal 9(2): 118-124. (40) Helmuth, R. A. (1967). The reversible and irreversible drying shrinkage of hardened portland cement and tricalcium silicate pastes. Skokie, Ill., Portland Cement Association. Research and Development Laboratories. (41) Hughes, T. L., et al. (1995). 'Determining cement composition by Fourier transform infrared spectroscopy.' Advanced Cement Based Materials 2(3): 91-104. (42) Huijgen, W. J. J. and R. N. J. Comans (2006). 'Carbonation of Steel Slag for CO2 Sequestration: Leaching of Products and Reaction Mechanisms.' Environmental Science & Technology 40(8): 2790-2796. (43) IEA (2010). Coal-Fired Power. I. E. Agency, Energy Technology System Analysis Programme. (44) International Symposium on the Chemistry of, C. and K. Semento Proceedings of the Fifth International Symposium on the Chemistry of Cement : Tokyo, 1968 : symposium held October 7-11, 1968 at the Tokyo Metoropolitan Festival Hall, Tokyo, [Tokyo], [publisher not identified]. (45) IPCC (2015). Climate Change 2014 Mitigation of Climate Change. Working Group III Contribution to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change, Cambridge University Press. (46) Jassim, M. S., et al. (2007). 'Carbon Dioxide Absorption and Desorption in Aqueous Monoethanolamine Solutions in a Rotating Packed Bed.' Industrial & Engineering Chemistry Research 46(9): 2823-2833. (47) Jo, H., et al. (2014). 'Metal extraction and indirect mineral carbonation of waste cement material using ammonium salt solutions.' Chemical Engineering Journal 254: 313-323. (48) Jung, C. H. and K. W. Lee (1998). 'Filtration of Fine Particles by Multiple Liquid Droplet and Gas Bubble Systems.' Aerosol Science and Technology 29(5): 389-401. (49) Kang, J.-L., et al. (2014). 'Modeling studies on absorption of CO2 by monoethanolamine in rotating packed bed.' International Journal of Greenhouse Gas Control 25: 141-150. (50) Kim, H. T., et al. (2001). 'Particle removal efficiency of gravitational wet scrubber considering diffusion, interception, and impaction.' Environmental Engineering Science 18(2): 125-136. (51) Kloprogge, J. T., et al. (2002). 'Vibrational spectroscopic study of syngenite formed during the treatment of liquid manure with sulphuric acid.' Vibrational Spectroscopy 28(2): 209-221. (52) Kodama, S., et al. (2008). 'Development of a new pH-swing CO2 mineralization process with a recyclable reaction solution.' Energy 33(5): 776-784. (53) Lackner, K. S., et al. (1995). 'Carbon dioxide disposal in carbonate minerals.' Energy 20(11): 1153-1170. (54) Lange, L. C., et al. (1996). 'The effect of accelerated carbonation on the properties of cement- solidified waste forms.' Waste Management 16(8): 757-763. (55) Li, M., et al. (2015). 'Treatment of amoxicillin by O-3/Fenton process in a rotating packed bed.' Journal of Environmental Management 150: 404-411. (56) Licht, W. (1988). Air Pollution Control Engineering Basic Calculations for Particulate Collection -2nd Edition. (57) Lin, C.-C., et al. (2002). 'Distillation in a Rotating Packed Bed.' JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 35(12): 1298-1304. (58) Lin, C.-C. and G.-S. Jian (2007). 'Characteristics of a rotating packed bed equipped with blade packings.' Separation and Purification Technology 54(1): 51-60. (59) Lin., C.-C. and C.-R. Chu. (2015). 'Mass transfer performance of rotating packed beds with blade packings in carbon dioxide absorption into sodium hydroxide solution.' Separation and Purification Technology 150: 196-203. (60) Liu, L., et al. (2016). 'Post-combustion carbon dioxide capture via 6FDA/BPDA-DAM hollow fiber membranes at sub-ambient temperatures.' Journal of Membrane Science 510: 447-454. (61) Liu, Y. Z., et al. (2015). 'Mass transfer characteristics in a rotating packed bed with split packing.' Chinese Journal of Chemical Engineering 23(5): 868-872. (62) Mahoutian, M., et al. (2014). 'Carbonation and hydration behavior of EAF and BOF steel slag binders.' Materials and Structures 48(9): 3075-3085. (63) Market, E. (2016). 'ERU Market for Carbon Trade.' from http://www.carbonplace.eu/info-commodities-ERU. (64) Martinez-Ramirez, S. (1999). 'Influence of SO2 deposition on cement mortar hydration.' Cement and Concrete Research 29(1): 107-111. (65) Mollah, M. Y. A., et al. (2004). 'An X-ray diffraction (XRD) and Fourier transform infrared spectroscopic (FT-IR) investigation of the long-term effect on the solidification/stabilization (S/S) of arsenic(V) in Portland cement type-V.' Science of The Total Environment 325(1–3): 255-262. (66) Mollah, M. Y. A., et al. (2000). 'A Fourier transform infrared spectroscopic investigation of the early hydration of Portland cement and the influence of sodium lignosulfonate.' Cement and Concrete Research 30(2): 267-273. (67) Muriithi, G. N., et al. (2013). 'Comparison of CO2 capture by ex-situ accelerated carbonation and in in-situ naturally weathered coal fly ash.' J Environ Manage 127: 212-220. (68) Olajire, A. A. (2013). 'A review of mineral carbonation technology in sequestration of CO2.' Journal of Petroleum Science and Engineering 109: 364-392. (69) Pan, S.-Y., et al. (2015). 'An Innovative Approach to Integrated Carbon Mineralization and Waste Utilization: A Review.' Aerosol and Air Quality Research 15: 1072-1091. (70) Pan, S.-Y., et al. (2014). 'Process Intensification of Steel Slag Carbonation via a Rotating Packed Bed: Reaction Kinetics and Mass Transfer.' Energy Procedia 63: 2255-2260. (71) Pan, S.-Y., et al. (2014). 'Kinetics of carbonation reaction of basic oxygen furnace slags in a rotating packed bed using the surface coverage model: Maximization of carbonation conversion.' Applied Energy 113: 267-276. (72) Pan, S.-Y., et al. (2015). 'Systematic approach to determination of optimum gas-phase mass transfer rate for high-gravity carbonation process of steelmaking slags in a rotating packed bed.' Applied Energy 148: 23-31. (73) Pan, S.-Y., et al. (2016). 'Engineering, environmental and economic performance evaluation of high-gravity carbonation process for carbon capture and utilization.' Applied Energy 170: 269-277. (74) Pan, S. Y., et al. (2013). 'Systematic approach to determination of maximum achievable capture capacity via leaching and carbonation processes for alkaline steelmaking wastes in a rotating packed bed.' Environ Sci Technol 47(23): 13677-13685. (75) Pan, S. Y., et al. (2013). 'Ex Situ CO2 capture by carbonation of steelmaking slag coupled with metalworking wastewater in a rotating packed bed.' Environ Sci Technol 47(7): 3308-3315. (76) Pang, B., et al. (2015). 'Utilization of carbonated and granulated steel slag aggregate in concrete.' Construction and Building Materials 84: 454-467. (77) Pang, B., et al. (2015). 'Utilization of carbonated and granulated steel slag aggregate in concrete.' Construction and Building Materials 84: 454-467. (78) Pérez-Moreno, S. M., et al. (2015). 'CO2 sequestration by indirect carbonation of artificial gypsum generated in the manufacture of titanium dioxide pigments.' Chemical Engineering Journal 262: 737-746. (79) Reddy, K. J., et al. (2010). 'Instantaneous Capture and Mineralization of Flue Gas Carbon Dioxide: Pilot Scale Study.' Nature Precedings. (80) Reynolds, B., et al. (2014). 'Field Application of Accelerated Mineral Carbonation.' Minerals 4(2): 191-207. (81) Said, A., et al. (2013). 'Production of precipitated calcium carbonate (PCC) from steelmaking slag for fixation of CO2.' Applied Energy 112: 765-771. (82) Salman, M., et al. (2014). 'Effect of accelerated carbonation on AOD stainless steel slag for its valorisation as a CO2-sequestering construction material.' Chemical Engineering Journal 246: 39-52. (83) Sanna, A., et al. (2012). 'Waste materials for carbon capture and storage by mineralisation (CCSM) – A UK perspective.' Applied Energy 99: 545-554. (84) Santos, R. M., et al. (2014). 'Distinguishing between carbonate and non-carbonate precipitates from the carbonation of calcium-containing organic acid leachates.' Hydrometallurgy 147–148: 90-94. (85) Santos, R. M., et al. (2013). 'Accelerated mineral carbonation of stainless steel slags for CO2 storage and waste valorization: Effect of process parameters on geochemical properties.' International Journal of Greenhouse Gas Control 17: 32-45. (86) Santos, R. M., et al. (2013). 'Integrated Mineral Carbonation Reactor Technology for Sustainable Carbon Dioxide Sequestration: ‘CO2 Energy Reactor’.' Energy Procedia 37: 5884-5891. (87) Shen, W., et al. (2015). 'Quantifying CO2 emissions from China’s cement industry.' Renewable and Sustainable Energy Reviews 50: 1004-1012. (88) Shi, C. and R. Day (1999). 'Early strength development and hydration of alkali-activated blast furnace slag/fly ash blends.' Advances in Cement Research 11(4): 189-196. (89) Shih, S.-M., et al. (1999). 'Kinetics of the Reaction of Ca(OH)2 with CO2 at Low Temperature.' Industrial & Engineering Chemistry Research 38(4): 1316-1322. (90) Shivhare, M. K., et al. (2013). 'Mass transfer studies on split-packing and single-block packing rotating packed beds.' Chemical Engineering and Processing: Process Intensification 71: 115-124. (91) Silva, D. A., et al. (2002). 'Evidences of chemical interaction between EVA and hydrating Portland cement.' Cement and Concrete Research 32(9): 1383-1390. (92) Steinour, H. H. (1959). 'Some effects of carbon dioxide on mortars and concrete - Discussion.' J. Am. Concr. Inst. 30: 905-907. (93) Streeter, H. W. and E. B. Phelps (1925). A Study of the Pollution and Natural Purification of the Ohio River, United States Public Health Service. (94) Styring, P. and D. Jansen (2011). 'Carbon Capture and Utilization in the Green Economy.' (95) Sudhoff, D., et al. (2015). 'Modelling, design and flexibility analysis of rotating packed beds for distillation.' Chemical Engineering Research and Design 94: 72-89. (96) Sun, Y., et al. (2012). 'Sequestration of carbon dioxide by indirect mineralization using Victorian brown coal fly ash.' J Hazard Mater 209-210: 458-466. (97) Sundberg, R. E. (1974). 'The Prediction of Overall Collection Efficiency of Air Pollution Control Devices from Fractional Efficiency Curves.' Journal of the Air Pollution Control Association 24(8): 758-764. (98) Tanaka, A., et al. (2014). 'Schematic Feasibility Study of Bio-CCS Technology.' Energy Procedia 63: 8062-8068. (99) Taylor, H. F. (1997). Cement chemistry, Thomas Telford. (100) Taylor, H. F. W. (1989). 'Modification of the Bogue calculation.' Advances in Cement Research 2(6): 73-77. (101) Teir, S., et al. (2007). 'Dissolution of steelmaking slags in acetic acid for precipitated calcium carbonate production.' Energy 32(4): 528-539. (102) Uibu, M., et al. (2011). 'The CO2 -binding by Ca-Mg-silicates in direct aqueous carbonation of oil shale ash and steel slag.' Energy Procedia 4: 925-932. (103) Ukwattage, N. L., et al. (2014). 'A laboratory-scale study of the aqueous mineral carbonation of coal fly ash for CO2 sequestration.' Journal of Cleaner Production. (104) van Zomeren, A., et al. (2011). 'Changes in mineralogical and leaching properties of converter steel slag resulting from accelerated carbonation at low CO 2 pressure.' Waste Management 31(11): 2236-2244. (105) Wang, H., et al. (2016). 'Numerical evaluation of the effectiveness of NO2 and N2O5 generation during the NO ozonation process.' J Environ Sci (China) 41: 51-58. (106) Wei, X., et al. (2016). 'Comparison study of electromagnetic wave propagation in high and low pressure Ar inductively coupled plasma.' Vacuum 127: 65-72. (107) Whitby, K. T. (1978). 'Proceedings of the International SymposiumThe physical characteristics of sulfur aerosols.' Atmospheric Environment (1967) 12(1): 135-159. (108) Xiao., L.-S., et al. (2014). 'Comparative Life Cycle Assessment (LCA) of Accelerated Carbonation Process Using Steelmaking Slag for CO2 Fixation.' Aerosol and Air Quality Research. (109) Ylmén, E. R. (2013). Early Hydration of Portland Cement. Department of Chemical and Biological Engineering CHALMERS UNIVERSITY OF TECHNOLOGY. Ph.D. (110) Yu, H., et al. (2013). 'Development of the advanced aqueous ammonia based post combustion capture technology: progress report.' CSIRO. (111) Zhang, T., et al. (2011). 'Preparation of high performance blended cements and reclamation of iron concentrate from basic oxygen furnace steel slag.' Resources, Conservation and Recycling 56(1): 48-55. (112) Zhao, B., et al. (2014). 'Mass transfer performance of CO2 capture in rotating packed bed: Dimensionless modeling and intelligent prediction.' Applied Energy 136: 132-142. (113) 汪翊鐙 (2009). 'CFB副產石灰掺配爐石粉製作混凝土成效研究.' 硕士论文. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/50390 | - |
dc.description.abstract | 本研究重點在於開發整合式的超重力技術,以同時應對二氧化碳減量、空氣污染防治和鹼性廢棄物處置再利用。副產石灰因其富含大量氧化鈣,因此可以當作二氧化碳捕捉的理想材料。本研究目的包括:(1)探究超重力旋轉填充床內碳酸化反應進程;(2)研究不同操作條件對於碳酸化反應之影響;(3)驗證超重力技術對於煙道氣淨化之效果;(4)驗證副產石灰用作輔助性凝膠材料之可行性;(5)從環境、經濟和工程三個面向評估超重力技術之效能。
• 探究超重力旋轉填充床內碳酸化反應進程 借助於電感耦合等離子體分管光度計和熱重分析手段,可以瞭解溶液中鈣離子濃度和固體中氧化鈣之轉化率。隨著反應進行,固體中氧化峰的轉化率逐漸上升,並達到最大值。該現象通過表面覆蓋模式(surface coverage model, SCM)予以描述。此外,通過合理的假設,描述水中溶氧濃度隨BOD分解的Streeter-Phelps方程式被用於描述和預測溶液中鈣離子濃度變化,並得到不錯的相關性。借助於數學模式,研究發現冷卻廢水會抑制碳酸鈣沉澱。 • 研究不同操作條件對於碳酸化反應之影響 研究研究反應溫度、轉速和液固比對於碳酸化反應的影響。研究發現溫度和轉速對於碳酸化有顯著的影響。另外,液固比在冷卻廢水中對碳酸化的影響更為顯著。 • 驗證超重力技術對於煙道氣淨化之效果 通過建立模廠設備,超重力設備被證明可有效去煙道氣中污染物。其中,二氧化碳最高去除率可達95.59%,每日最大捕捉量接近600公斤。通過注入臭氧,超重力技術可有效去除氮氧化物。超重力設備建立後,每年可避免超過8000元美金的費用。 • 驗證副產石灰用作輔助性凝膠材料之可行性 本研究中,副產石灰被用作輔助性凝膠材料。根據測試結果,隨著取代率上升,水泥熟料中的矽酸鹽含量逐漸下降。然而,碳酸鈣可提高水化速率,進而改善水泥性質。最終5%的取代率有利於提高經濟效益和水泥性能。 • 從環境、經濟和工程三個面向評估超重力技術之效能 通過3E分析,超重力技術可有效降低環境衝擊,特別是溫室效應和環境毒性。隨著氣量的提高,二氧化碳捕捉量得到提高,因而其能效亦有提升。借助於圖解法,超重力系統每日二氧化碳捕捉量可達600公斤。捕捉每噸二氧化碳耗能約15度。此外,處理每噸副產石灰可獲得約40元美金。證明超重力設備之較高的經濟效益。 | zh_TW |
dc.description.abstract | This study was focused on the development of an innovative integrated high gravity (HiGee) system to deal with carbon capture, air pollution control coupled with alkaline waste treatment. Byproduct lime originated from burnt petroleum coke of circular fluidized bed was used as the reacting agent for carbonation. The research objectives included (1) to investigate the carbonation behavior in rotating packed bed (RPB); (2).to examine the effect of operating conditions on carbonation behavior in RPB; (3) to study the conjunction effect of RPB on air pollution control; (4) to inspect the alteration of properties of cement induced by the introduction of byproduct lime; (5) to comprehensively evaluate the process from the perspective of environmental, economic and engineering aspects.
• To investigate the carbonation behavior in RPB The concentration of calcium in slurry and carbonation conversion of byproduct lime was examined by Inductively Coupled Plasma (ICP-OES) and thermal gravimetric analysis (TGA) respectively. The correlation between carbon conversion and time was interpreted and predicted by surface coverage model (SCM). On the hand, a Streeter-Phelps equation liked formula was developed and introduced to describe the variation of calcium concentration in slurry, which has achieved good agreement. From the results of modeling, it was found blowdown wastewater was not favorable for carbonation because the precipitation may be inhibited so that the captured carbon dioxide could not be attached into solid matrix permanently. • To examine the effect of operating conditions on carbonation behavior in RPB Rotating speed, solid-liquid ratio and temperature were chosen to examine the influence on carbonation performance. The results indicated that temperature and rotating speed could exert significant influence on carbonation in tap water. In addition, the effect of solid to liquid ratio was more remarkable for carbonation in blowdown wastewater. • To study the conjunction effect of RPB on air pollution control According to the results of on-site operation in real plant, it was proved that the HiGCarb process is effective and efficient for carbon capture and air pollutant removal. Specifically, the highest removal efficiency could reach up to 95.59%, while the maximum daily capture capacity was nearly 600 kg-CO2/day. With the help of ozone, nitric oxide was successfully oxidized as well as absorbed successfully by slurry. In addition, due to the congenital complex packing structure, the particulate matter in flue gas could be efficiently filtrated and collected. After the installation of HiGCarb system, more than 8000 USD of air pollution penalty could be conserved each year. • To inspect the alteration of properties of cement induced by the introduction of byproduct lime Carbonation is able to transform calcium oxide into calcium carbonate. During this research, both fresh and carbonated byproduct lime was introduced into clinker for substitution. According to the results, with substitution ratio going up, the content of silica decreased which is not favorable for cement deployment. However, calcium carbonate was found to be able to accelerate hydration reaction, resulting in more remarkable strength compared with other specimens at the same curing age. Finally, the substitution ratio at 5% was favorable for both economic benefit and engineering performance. • To comprehensively evaluate the process from the perspective of environmental, economic and engineering aspects In order to evaluate the positive effects and negative impacts from HiGCarb process, 3E analysis was performed. It was found that the introduction of HiGCarb process could drastically reduce negative impact to environment, especially global warming potential and toxicity to ecosystem. With gas flow rate going up, the capture capacity increased, and the process would become more energy efficient. Such phenomenon would be beneficial to economic and environmental aspects. Because at higher gas flow rates, less energy would be consumed for capturing one unit of carbon dioxide, which means less pollutant would be generated. According to the results of graphical solution, the highest achievable amount of daily capture capacity is nearly 600 kg-CO2/day. That could be reached at the acceleration of 63 m/s2, corresponding to the energy consumption of 15 kWh/t-CO2. In addition, the economic benefit is also incredible. It is estimated that around 40 USD could be earned by treating one ton of byproduct lime. Finally, the best scenario is determined where the gas flow rate is 1.84 m3/min and rotating speed is 550 rpm. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T12:38:49Z (GMT). No. of bitstreams: 1 ntu-105-R03541135-1.pdf: 4958515 bytes, checksum: bf2938f9522c0408d498633ab290f8ec (MD5) Previous issue date: 2016 | en |
dc.description.tableofcontents | Chapter 1 Introduction 1-1
Chapter 2 Objectives 2-1 Chapter 3 Literature Review 3-1 3-1 Carbonation Mechanism 3-1 3-1-1 Innovative Carbonation Technologies 3-6 3-1-2 Feedstock Selection for Carbonation 3-8 3-1-3 Effects of Properties of Feedstock and Operating Conditions 3-9 3-2 Product Utilization as Supplementary Cementitious Materials 3-10 3-2-1 Composition of Portland Cement Clinker 3-10 3-2-1-1 Principal Compositions 3-11 3-2-1-2 Minor Compositions 3-16 3-2-2 Properties of Portland Cement 3-17 3-2-2-1 Strength 3-17 3-2-2-2 Workability 3-19 3-2-2-3 Durability 3-20 3-2-3 Effect of Utilization on the Properties of Cement 3-23 3-2-3-1 Performance on Workability, Mechanical Strength and Durability 3-24 3-2-3-2 Stabilization of Heavy Metals and Active Species in Wastes 3-25 3-3 Rotating Packed Bed (RPB) 3-26 3-3-1 Features 3-26 3-3-2 Mass Transfer Models 3-27 3-3-3 Applications 3-30 3-4 Air pollution Control 3-33 3-4-1 Collection of Particulate Matter 3-33 3-4-2 Nitrogen Oxides Abatement 3-34 3-5 Comprehensive Performance Evaluation 3-36 3-5-1 Energy Consumption and Capture Capacity (Engineering Aspect) 3-36 3-5-1 Life Cycle Assessment (Environmental Aspect) 3-39 3-5-2 Cost Benefit Analysis (Economic Aspect) 3-40 Chapter 4 Materials and Methods 4-42 4-1 Research Framework 4-42 4-2 Source of Materials 4-43 4-2-1 Source of Feedstock 4-43 4-2-2 Rotating Packed Bed (RPB) 4-44 4-3 Carbonation Performance of Byproduct Lime in RPB 4-45 4-4 Utilization of Carbonated Byproduct Lime as Supplementary Cementitious Material 4-48 4-4-1 Standard Consistency 4-49 4-4-2 Setting Time 4-50 4-4-3 Flow Test 4-51 4-4-4 Autoclave Expansion 4-52 4-4-5 Drying Shrinkage 4-52 4-4-6 Compressive Strength 4-53 4-5 Analytical Techniques 4-54 4-5-1 Thermal Gravimetric Analysis (TGA) 4-54 4-5-2 Inductively Coupled Plasma (ICP) 4-55 4-5-3 Fourier Transform Infrared Spectroscopy (FTIR) 4-57 4-5-4 Aerosol Analyzer 4-63 Chapter 5 Results and Discussion 5-1 5-1 Carbonation of Byproduct lime in a RPB 5-1 5-1-1 Carbonation Behavior of Byproduct Lime in RPB 5-1 5-1-2 Effect of Carbonation on Characteristics of Feedstock 5-7 5-1-3 Effect of Operating Conditions on Carbonation of Byproduct Lime 5-12 5-1-4 Summary 5-22 5-2 Technology Demonstration via On-site Operation 5-23 5-2-1 Carbon Capture Performance 5-24 5-2-2 Collection of Aerosol Particles 5-30 5-2-3 DeNOx 5-35 5-2-4 Summary 5-38 5-3 Evaluation of Feasibility of Cement Substitution by Byproduct Lime 5-39 5-3-1 Effect of Substitution on the Composition of Clinker 5-39 5-3-2 Effect of Substitution on Workability of Cement 5-44 5-3-3 Effect of Substitution on Durability of Cement 5-45 5-3-4 Effect of Substitution on Strength of Cement 5-46 5-3-5 Summary 5-49 5-4 Comprehensive 3E Analysis 5-50 5-4-1 Analysis on Engineering Aspect 5-52 5-4-2 Life Cycle Analysis 5-53 5-4-3 Cost and Benefit Estimation 5-56 5-4-4 Determination of the Best Operating Condition 5-58 5-4-5 Summary 5-60 Chapter 6 Conclusions and Recommendations 6-1 6-1 Conclusions 6-1 6-2 Recommendations 6-2 Chapter 7 References 7-1 | |
dc.language.iso | en | |
dc.title | 整合式超重力程序於煙氣淨化與副產石灰再利用 | zh_TW |
dc.title | Development of High Gravity Process for Integrating Carbon Capture and Utilization with Flue Gas Purification | en |
dc.type | Thesis | |
dc.date.schoolyear | 104-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 顧洋,談駿嵩,張怡怡,陳奕宏 | |
dc.subject.keyword | 超重力技術,二氧化碳捕捉,空氣污染防治,輔助性凝膠材料,3E分析, | zh_TW |
dc.subject.keyword | HiGee,Carbon Capture,Air pollution Control,Supplementary Cementitious Material,3E Analysis, | en |
dc.relation.page | 130 | |
dc.identifier.doi | 10.6342/NTU201601229 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2016-07-29 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 環境工程學研究所 | zh_TW |
顯示於系所單位: | 環境工程學研究所 |
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