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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 林致廷(Chih-Ting Lin) | |
| dc.contributor.author | Yu-Cheng Su | en |
| dc.contributor.author | 蘇育程 | zh_TW |
| dc.date.accessioned | 2021-06-15T12:27:09Z | - |
| dc.date.available | 2018-10-14 | |
| dc.date.copyright | 2016-10-14 | |
| dc.date.issued | 2016 | |
| dc.date.submitted | 2016-08-09 | |
| dc.identifier.citation | [1] https://en.wikipedia.org/wiki/Carbon_dioxide retrieved at 2016/07/14
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'Cooperative doping in polyaniline-poly(ethylene-3,4-dioxythiophene): poly(styrenesulfonic acid) composite system.' Journal of Polymer Research 18(6): 2435-2440. [38] Stegmeier, S., et al. (2011). 'Sensing mechanism of room temperature CO2 sensors based on primary amino groups.' Sensors and Actuators B: Chemical 154(2): 270-276. [39] Crowley, K., et al. (2010). 'Fabrication of Polyaniline-Based Gas Sensors Using Piezoelectric Inkjet and Screen Printing for the Detection of Hydrogen Sulfide.' IEEE Sensors Journal 10(9): 1419-1426. [40] Skorenko, K. H., et al. (2015). 'Vapor phase polymerization and mechanical testing of highly electrically conductive poly(3,4-ethylenedioxythiophene) for flexible devices.' Synthetic Metals 209: 297-303. [41] L.M. Malard, M.A. Pimenta, G. Dresselhaus, M.S. Dresselhaus (2009), “Raman spectroscopy in grapheme”, Physics Reports, vol. 473, Issues 5–6, 51–87. [42] Raman: Theory, Retrieved July 8, 2016, from http://chemwiki.ucdavis.edu/Physical_Chemistry/Spectroscopy/Vibrational_Spectroscopy/Raman_Spectroscopy/Raman%3A_Theory. [43] Da Silva, J. P., et al. (1999). 'Raman characterization of polyaniline induced conformational changes.' Synthetic Metals 101(1): 834-835. [44] Sheng Hsiung, C., et al. (2014). 'Unraveling the Enhanced Electrical Conductivity of PEDOT:PSS Thin Films for ITO-Free Organic Photovoltaics.' IEEE Photonics Journal 6(4): 1-7. [45] http://www.cwb.gov.tw/V7/climate/climate_info/statistics/pdf/other.pdf retrieved at 2016/07/08 [46] 行政院環境保護署環署空字第 1010106229 號令，2012年11月23日 [47] Occupational Safety and Health Administration(OSHA)，”OSHA Fact Sheer: Carbon monoxide poisoning”，2002 苗栗縣政府消防局，http://www.mlfd.gov.tw/goods/dg02.aspx?inf=4 retrieved at 2016/07/08 | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/49980 | - |
| dc.description.abstract | 為了解決現有的二氧化碳感測器所面對的問題，包含金屬氧化物的高功耗問題、以及高分子材料的複雜製程和濕度敏感問題，我們使用聚苯胺（Emeraldine base –polyaniline）以及聚二氧乙基噻吩聚苯乙烯磺酸（poly(3,4-ethylenedioxythiophene) polystyrene sulfonate）混和而成的材料製作可室溫操作的二氧化碳感測器元件。此元件可以在二氧化碳濃度為1000-20000ppm之間有著線性的電阻變化，變化量約在0.98%~3.83%之間。這樣的感測範圍適合用在一般室內的空氣品質檢測，以警示二氧化碳濃度過高的狀況。除此之外，此元件在相對濕度為50~85%之間時，對濕度有著相當低的敏感度，使得在一般檢測環境下不會受到濕度變化的影響，在室內空氣品質檢測的應用上，是相當大的優勢。 | zh_TW |
| dc.description.abstract | To resolve the high power consumption and complex polymerization process of most CO2 sensors, a room temperature operation CO2 sensor based on Emeraldine base –polyaniline (EB-PANI) blended with poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) was developed. In this work, the sensor performed linear response to CO2 in working range of 1000-20000 ppm with the response from 0.98% to 3.83%. This detection range is low enough for environmental detection. On the other hand, compared to the response to CO2, this sensor has extremely lower response to humidity from 50 % to 85 % RH. Hence, in ambient environment, this CO2 sensor can ignore humidity effect to detect CO2 concentration. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T12:27:09Z (GMT). No. of bitstreams: 1 ntu-105-R03943066-1.pdf: 4910168 bytes, checksum: 5acf7c8b72077aed7855b10adf1dc24d (MD5) Previous issue date: 2016 | en |
| dc.description.tableofcontents | 口試委員會審定書 #
誌謝 i 中文摘要 ii ABSTRACT iii CONTENTS iv LIST OF FIGURES vii LIST OF TABLES xi Chapter 1 緒論 1 1.1 二氧化碳氣體檢測在生活中的重要性 1 1.2 物聯網(Internet of Things)簡介 3 1.3 論文架構 5 Chapter 2 元件特性與材料介紹 6 2.1 感測器特性 6 2.2 各種類二氧化碳氣體感測器優缺點分析 7 2.3 感測材料文獻探討 8 2.3.1 各種類聚合物材料 9 2.3.2 奈米碳管 (Carbon Nanotube, CNT)及石墨烯 (Graphene) 12 2.3.3 EB-PANI 使用及改質 15 2.3.4 PEDOT混合EB-PANI之討論與使用 21 Chapter 3 二氧化碳感測器製備 23 3.1 電極製備過程 23 3.1.1 清洗晶圓 23 3.1.2 曝光顯影 24 3.1.3 蒸鍍電極 25 3.1.4 Lift-off 26 3.1.5 切割晶圓 26 3.2 感測材料薄膜製備 27 3.3 量測系統介紹 29 3.3.1 量測系統架設 29 3.3.2 氣體感測器量測流程 34 Chapter 4 量測結果 36 4.1 感測機制推測與探討 36 4.2 材料分析 38 4.2.1 光學顯微鏡表面分析 38 4.2.2 紫外線分光光譜儀（UV-vis） 39 4.2.3 拉曼光譜儀（Raman） 42 4.3 乾空氣下感測效果 46 4.4 濕空氣下感測效果 48 4.4.1 純濕度量測 48 4.4.2 同濕度重複量測 53 4.5 二氧化碳感測效果 54 4.5.1 各二氧化碳感測結果 55 4.5.2 二氧化碳感測結果圖表 58 4.6 環境濕度影響 59 4.6.1 不同濕度下二氧化碳感測結果 59 4.7 二氧化碳感測器生命週期探討 61 4.7.1 首次濕空氣下量測 61 4.7.2 電阻隨時間增大之效應 63 4.7.3 反應量隨時間減少之效應 64 4.8 對其他氣體之選擇性 65 4.8.1 對一氧化碳（CO）之選擇性 65 4.8.2 對二氧化氮（NO2）之選擇性 67 4.9 改變EB-PANI/PEDOT:PSS比例之嘗試 68 4.10 二氧化碳感測元件對比整理 70 Chapter 5 結論 72 REFERENCE 73 | |
| dc.language.iso | zh-TW | |
| dc.subject | 有機氣體感測元件 | zh_TW |
| dc.subject | 二氧化碳 | zh_TW |
| dc.subject | 聚苯胺 | zh_TW |
| dc.subject | 聚二氧乙基?吩聚苯乙烯磺酸 | zh_TW |
| dc.subject | PEDOT:PSS. | en |
| dc.subject | CO2 sensor | en |
| dc.subject | polyaniline | en |
| dc.title | 低功耗有機二氧化碳感測器 | zh_TW |
| dc.title | A Low Power Consumption Organic Carbon Dioxide Sensor | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 104-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.coadvisor | 吳文中(Wen-Jong Wu) | |
| dc.contributor.oralexamcommittee | 李世光(Chih-Kung Lee),許聿翔(Yu-Hsiang Hsu) | |
| dc.subject.keyword | 二氧化碳,有機氣體感測元件,聚苯胺,聚二氧乙基?吩聚苯乙烯磺酸, | zh_TW |
| dc.subject.keyword | CO2 sensor,polyaniline,PEDOT:PSS., | en |
| dc.relation.page | 77 | |
| dc.identifier.doi | 10.6342/NTU201602120 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2016-08-09 | |
| dc.contributor.author-college | 電機資訊學院 | zh_TW |
| dc.contributor.author-dept | 電子工程學研究所 | zh_TW |
| 顯示於系所單位： | 電子工程學研究所 | |
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