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| ???org.dspace.app.webui.jsptag.ItemTag.dcfield??? | Value | Language |
|---|---|---|
| dc.contributor.advisor | 賴喜美(Hsi-Mei Lai) | |
| dc.contributor.author | Po-Jung Chiou | en |
| dc.contributor.author | 邱博嶸 | zh_TW |
| dc.date.accessioned | 2021-06-15T11:18:56Z | - |
| dc.date.available | 2018-08-23 | |
| dc.date.copyright | 2016-11-01 | |
| dc.date.issued | 2016 | |
| dc.date.submitted | 2016-08-18 | |
| dc.identifier.citation | 洪偉峰。2012。以逐層自主裝多層膜奈米塗布技術開發含活性物質之高功能性澱粉膜。國立台灣大學生物資源暨農學院農業化學系碩士論文。
叢可蘭。2013。不同直鏈澱粉含量米澱粉製備多孔性微米球之研究。國立台灣大學生物資源暨農學院農業化學系碩士論文。 Abdorreza, M. N., Cheng, L. H., and Karim, A. A. 2011. Effect of plasticizers on thermal properties and heat sealability of sago starch films. Food Hydrocolloids, 25, 56-60. Acosta, S., Jimenez, A., Chafer, M., Gonzalez-Martínez, C., and Chiralt, A. 2015. Physical properties and stability of starch-gelatin based films as affected by the addition of esters of fatty acids. Food Hydrocolloids, 49, 135-143. Alberto, J., María, J. F., Pau, T., and Amparo, C. 2012. Effect of re-crystallization on tensile, optical and water vapour barrier properties of corn starch films containing fatty acids. Food Hydrocolloids, 26, 302-310. Alexandre, M., and Dubois, P. 2000. Polymer-layered silicate nanocomposites: preparation, properties and uses of a new class of materials. Materials and Engineering R: Reports, 28, 1-63. Angellier, H., Molina-Boisseau, S., Belgacem, M. N., and Dufresne, A. 2005. 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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/49195 | - |
| dc.description.abstract | 本研究之目的為開發一種以澱粉為基質之生物可分解且具抗氧化能力之活性包材。首先以5% Pluronic® F108 (PL F108)及19% | zh_TW |
| dc.description.abstract | This study is aimed to develop a biodegradable active packaging material with antioxidative capability. A polypseudorotaxane (PPR) nanocrystal was first self-assembled with 5% Pluronic® F108 (PL F108) and 19% | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T11:18:56Z (GMT). No. of bitstreams: 1 ntu-105-R03623028-1.pdf: 4870383 bytes, checksum: 9b20ef9fda62aad991f34a6cd43f38fa (MD5) Previous issue date: 2016 | en |
| dc.description.tableofcontents | 中文摘要 I
ABSTRACT III 目錄 V 表目錄 VII 圖目錄 VIII 第一章 前言 1 實驗架構 3 第二章 文獻整理 4 (一) 澱粉 4 1. 澱粉基本性質簡介 4 2. 修飾澱粉 7 (二) 澱粉—生物可分解(BIODEGRADABLE)材料 8 1. 澱粉材料之應用趨勢 8 2. 澱粉膜製作技術 9 2.1 利用小角度X光散射技術觀察澱粉糊液乾燥過程之微細結構變化 11 3. 澱粉奈米複合材料(starch nanocomposite) 12 3.1 奈米複合材料提升機械性質 12 3.2 奈米複合材料提升氣體阻隔性 15 3.3 奈米填充物之種類及應用 18 (三) 生物可分解活性包材(ACTIVE PACKAGE) 20 簡介 20 1. 逐層自主裝(layer-by-layer self-assembly)塗布技術 21 2. 澱粉膜之表面親疏水性及表面張力 23 3. 油脂氧化機制及抗氧化劑(antioxidant) 25 4. 油脂氧化安定性指標(oil stability index, OSI)測定 26 第三章 材料與方法 28 一、材料 28 二、方法 28 (一) 添加PPR澱粉膜之製備及性質分析 28 1. PPR溶液之製備 28 2. 澱粉膜製作流程 29 3. 小角及廣角X光散射(Small- / Wide-angle X-ray scattering, SAXS/WAXS)測定 29 4. 流變(Rehology)性質測定 31 5. 顯微結構測定 31 6. 澱粉膜厚度(Film thickness)測定 31 7. 機械性質(Mechanical properties)測定 32 8. 等溫吸濕曲線(Moisture sorption isotherm) 32 9. 水氣通透性(Water vapor permeability, WVP)測定 33 10. 接觸角(Contact angle)測定 33 (二) 塗布澱粉膜製備及性質分析 34 1. 正電修飾澱粉製備 34 2. 正電澱粉取代度(Degree of substitution, DS)測定 34 3. 負電微乳化系統製備 34 4. 塗布澱粉膜製備 35 5. 澱粉膜塗布效率測定—Vit E塗布量 35 6. 塗布澱粉膜之顯微結構、等溫吸濕曲線及接觸角測定 36 7. 澱粉膜塗布厚度(coating thickness)測定 36 (三) 澱粉膜之應用性測定 36 1. 澱粉膜釋放速率測定 36 2. 油脂儲藏安定性試驗 37 3. Vit E抗氧化活性測試 38 4. 以BHT取代Vit E之油脂氧化安定性試驗 39 (四) 統計分析 40 第四章 結果與討論 41 (一)添加PPR澱粉膜之性質分析 41 1. 小角度X光散射 41 2. 廣角X光散射 46 3. 流變性質 49 4. 顯微結構 50 5. 澱粉膜厚度及機械性質 56 6. 等溫吸濕曲線 58 7. 水氣通透性 58 8. 接觸角測定 61 (二)塗布澱粉膜之性質分析 64 1. 正電澱粉取代度 64 2. 塗布效率測定 64 5. 澱粉膜顯微結構及塗布厚度測定 67 6. 等溫吸濕曲線 72 7. 接觸角測定 74 (三)澱粉膜之應用性測定 77 1. 澱粉膜釋放速率測定 77 2. 油脂儲藏安定性試驗 79 3. 不同濃度之Vit E對大豆油氧化安定性之影響 82 4. 塗布BHT之澱粉膜對油脂儲藏安定性之影響 84 第五章 結論 86 第六章 參考文獻 88 | |
| dc.language.iso | zh-TW | |
| dc.subject | 準聚輪烷 | zh_TW |
| dc.subject | 活性包材 | zh_TW |
| dc.subject | 生物可分解 | zh_TW |
| dc.subject | 澱粉膜 | zh_TW |
| dc.subject | 油脂氧化安定性 | zh_TW |
| dc.subject | 抗氧化 | zh_TW |
| dc.subject | 逐層自主裝 | zh_TW |
| dc.subject | 檸檬酸 | zh_TW |
| dc.subject | 奈米複合材料 | zh_TW |
| dc.subject | nanocomposite | en |
| dc.subject | oil oxidation stability | en |
| dc.subject | antioxidation | en |
| dc.subject | self-assembly | en |
| dc.subject | layer-by-layer | en |
| dc.subject | biodegradable | en |
| dc.subject | starch film | en |
| dc.subject | active package | en |
| dc.subject | polypsuedorotaxane | en |
| dc.subject | citric acid | en |
| dc.title | 以奈米準聚輪烷結晶及多層膜自主裝塗布技術改善澱粉複合材料性質之研究 | zh_TW |
| dc.title | Study of adapting polypseudorotaxane nanocrystal and layer-by-layer self-assembly coating technique to improve the properties of starch composite | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 104-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 張永和(Yung-Ho Chang),邵貽沅(Yi-Yuan Shao) | |
| dc.subject.keyword | 生物可分解,澱粉膜,活性包材,準聚輪烷,奈米複合材料,檸檬酸,逐層自主裝,抗氧化,油脂氧化安定性, | zh_TW |
| dc.subject.keyword | biodegradable,starch film,active package,polypsuedorotaxane,nanocomposite,citric acid,layer-by-layer,self-assembly,antioxidation,oil oxidation stability, | en |
| dc.relation.page | 96 | |
| dc.identifier.doi | 10.6342/NTU201603176 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2016-08-20 | |
| dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
| dc.contributor.author-dept | 農業化學研究所 | zh_TW |
| Appears in Collections: | 農業化學系 | |
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