請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/48748
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 余政靖(Cheng-Ching Yu),吳哲夫(Jeffrey D. Ward) | |
dc.contributor.author | Jian-Kai Cheng | en |
dc.contributor.author | 程建凱 | zh_TW |
dc.date.accessioned | 2021-06-15T07:11:50Z | - |
dc.date.available | 2016-01-17 | |
dc.date.copyright | 2011-01-17 | |
dc.date.issued | 2010 | |
dc.date.submitted | 2010-09-28 | |
dc.identifier.citation | 1. Luyben, W. L.; Yu, C. C. Reactive Distillation Design and Control; Wiley: New Jersey, 2008.
2. Hoffmaster, W. R.; Hauan, S. Using Feasible Regions to Design and Optimize Reactive Distillation Columns with Ideal Vle. AIChE Journal 2006, 52. 3. Taylor, R.; Krishna, R. Modelling Reactive Distillation. Chemical Engineering Science 2000, 55. 4. Kaymak, D. B.; Luyben, W. L.; Smith, O. J. Effect of Relative Volatility on the Quantitative Comparison of Reactive Distillation and Conventional Multi-Unit Systems. Industrial & Engineering Chemistry Research 2004, 43. 5. Kaymak, D. B.; Luyben, W. L. Effect of the Chemical Equilibrium Constant on the Design of Reactive Distillation Columns. Industrial & Engineering Chemistry Research 2004, 43. 6. Kaymak, D. B.; Luyben, W. L. Quantitative Comparison of Reactive Distillation with Conventional Multiunit Reactor/Column/Recycle Systems for Different Chemical Equilibrium Constants. Industrial & Engineering Chemistry Research 2004, 43. 7. Tung, S. T.; Yu, C. C. Effects of Relative Volatility Ranking to the Design of Reactive Distillation. AIChE Journal 2007, 53. 8. Tang, Y. T.; Chen, Y. W.; Huang, H. P.; Yu, C. C.; Hung, S. B.; Lee, M. J. Design of Reactive Distillations for Acetic Acid Esterification. AIChE Journal 2005, 51. 9. Lin, Y. D.; Chen, J. H.; Cheng, J. K.; Huang, H. P.; Yu, C. C. Process Alternatives for Methyl Acetate Conversion Using Reactive Distillation. 1. Hydrolysis. Chemical Engineering Science 2008, 63. 10. Mohl, K. D.; Kienle, A.; Gilles, E. D.; Rapmund, P.; Sundmacher, K.; Hoffmann, U. Steady-State Multiplicities in Reactive Distillation Columns for the Production of Fuel Ethers Mtbe and Tame: Theoretical Analysis and Experimental Verification. Chemical Engineering Science 1999, 54. 11. Ciric, A. R.; Gu, D. Y. Synthesis of Nonequilibrium Reactive Distillation Processes by Minlp Optimization. AIChE Journal 1994, 40. 12. Jackson, J. R.; Grossmann, I. E. A Disjunctive Programming Approach for the Optimal Design of Reactive Distillation Columns. Computers & Chemical Engineering 2001, 25. 13. Stichlmair, J.; Frey, T. Mixed-Integer Nonlinear Programming Optimization of Reactive Distillation Processes. Industrial & Engineering Chemistry Research 2001, 40. 14. Gangadwala, J.; Kienle, A. Minlp Optimization of Butyl Acetate Synthesis. Chemical Engineering and Processing 2007, 46. 15. Cardoso, M. F.; Salcedo, R. L.; de Azevedo, S. F.; Barbosa, D. Optimization of Reactive Distillation Processes with Simulated Annealing. Chemical Engineering Science 2000, 55. 16. Lima, R. M.; Salcedo, R. L.; Barbosa, D. Simop Efficient Reactive Distillation Optimization Using Stochastic Optimizers. Chemical Engineering Science 2006, 61. 17. Gomez, J. M.; Reneaume, J. M.; Roques, M.; Meyer, M.; Meyer, X. A Mixed Integer Nonlinear Programming Formulation for Optimal Design of a Catalytic Distillation Column Based on a Generic Nonequilibrium Model. Industrial & Engineering Chemistry Research 2006, 45. 18. Barbosa, D.; Doherty, M. F. Design and Minimum-Reflux Calculations for Single-Feed Multicomponent Reactive Distillation-Columns. Chemical Engineering Science 1988, 43. 19. Barbosa, D.; Doherty, M. F. Design and Minimum-Reflux Calculations for Double-Feed Multicomponent Reactive Distillation-Columns. Chemical Engineering Science 1988, 43. 20. Groemping, M.; Dragomir, R. M.; Jobson, M. Conceptual Design of Reactive Distillation Columns Using Stage Composition Lines. Chemical Engineering and Processing 2004, 43. 21. Dragomir, R. M.; Jobson, M. Conceptual Design of Single-Feed Kinetically Controlled Reactive Distillation Columns. Chemical Engineering Science 2005, 60. 22. Bessling, B.; Schembecker, G.; Simmrock, K. H. Design of Processes with Reactive Distillation Line Diagrams. Industrial & Engineering Chemistry Research 1997, 36. 23. Chadda, N.; Malone, M. F.; Doherty, M. F. Effect of Chemical Kinetics on Feasible Splits for Reactive Distillation. AIChE Journal 2001, 47. 24. Chadda, N.; Malone, M. F.; Doherty, M. F. Feasibility and Synthesis of Hybrid Reactive Distillation Systems. AIChE Journal 2002, 48. 25. Gadewar, S. B.; Malone, M. F.; Doherty, M. F. Feasible Region for a Countercurrent Cascade of Vapor-Liquid Cstrs. AIChE Journal 2002, 48, 800. 26. Gadewar, S. B.; Malone, M. F.; Doherty, M. F. Feasible Products for Double-Feed Reactive Distillation Columns. Industrial & Engineering Chemistry Research 2007, 46, 3255. 27. Hauan, S.; Ciric, A. R.; Westerberg, A. W.; Lien, K. M. Difference Points in Extractive and Reactive Cascades. I - Basic Properties and Analysis. Chemical Engineering Science 2000, 55. 28. Lee, J. W.; Hauan, S.; Westerberg, A. W. Graphical Methods for Reaction Distribution in a Reactive Distillation Column. AIChE Journal 2000, 46, 1218. 29. Lee, J. W.; Hauan, S.; Westerberg, A. W. Extreme Conditions in Binary Reactive Distillation. AIChE Journal 2000, 46, 2225. 30. Lee, J. W.; Hauan, S.; Westerberg, A. W. Feasibility of a Reactive Distillation Column with Ternary Mixtures. Industrial & Engineering Chemistry Research 2001, 40. 31. Lee, J. W. Feasibility Studies on Quaternary Reactive Distillation Systems. Industrial & Engineering Chemistry Research 2002, 41. 32. Lee, J. W.; Hauan, S.; Westerberg, A. W. Circumventing an Azeotrope Is Reactive Distillation. Industrial & Engineering Chemistry Research 2000, 39. 33. Guo, Z.; Chin, J.; Lee, J. W. Feasibility of Continuous Reactive Distillation with Azeotropic Mixtures. Industrial & Engineering Chemistry Research 2004, 43. 34. Lee, J. W.; Bruggemann, S.; Marquardt, W. Shortcut Method for Kinetically Controlled Reactive Distillation Systems. AIChE Journal 2003, 49, 1471. 35. Subawalla, H.; Fair, J. R. Design Guidelines for Solid-Catalyzed Reactive Distillation Systems. Industrial & Engineering Chemistry Research 1999, 38, 3696. 36. Hung, S. B.; Lee, M. J.; Tang, Y. T.; Chen, Y. W.; Lai, I. K.; Hung, W. J.; Huang, H. P.; Yu, C. C. Control of Different Reactive Distillation Configurations. AIChE Journal 2006, 52. 37. Lai, I. K.; Hung, S. B.; Hung, W. J.; Yu, C. C.; Lee, M. J.; Huang, H. P. Design and Control of Reactive Distillation for Ethyl and Isopropyl Acetates Production with Azeotropic Feeds. Chemical Engineering Science 2007, 62. 38. Lek, C. M.; Rangaiah, G. P.; Hidajat, K. Distillation: Revisiting Some Rules of Thumb. Chemical Engineering 2004, 111, 50. 39. Grossmann, I. E. Review of Nonlinear Mixed-Integer and Disjunctive Programming Techniques. Optimization and Engineering 2002, 3. 40. Biegler, L. T.; Grossmann, I. E. Retrospective on Optimization. Computers & Chemical Engineering 2004, 28. 41. Linke, P.; Kokossis, A. On the Robust Application of Stochastic Optimisation Technology for the Synthesis of Reaction/Separation Systems. Computers & Chemical Engineering 2003, 27. 42. Metropolis, N.; Rosenbluth, A. W.; Rosenbluth, M. N.; Teller, A. H.; Teller, E. Equation of State Calculations by Fast Computing Machines. Journal of Chemical Physics 1953, 21. 43. Kirkpatrick, S.; Gelatt, C. D.; Vecchi, M. P. Optimization by Simulated Annealing. Science 1983, 220. 44. Dolan, W. B.; Cummings, P. T.; Levan, M. D. Process Optimization Via Simulated Annealing - Application to Network Design. AIChE Journal 1989, 35. 45. Lo, C. H. Process Optimization under Uncertainty-Case Studies. Tunghai University, Taiwan, 2006. 46. Chaudhuri, P. D.; Diwekar, U. M. Process Synthesis under Uncertainty: A Penalty Function Approach. AIChE Journal 1996, 42. 47. Suman, B.; Kumar, P. A Survey of Simulated Annealing as a Tool for Single and Multiobjective Optimization. Journal of the Operational Research Society 2006, 57. 48. Diwekar, U. M.; Grossmann, I. E.; Rubin, E. S. An Minlp Process Synthesizer for a Sequential Modular Simulator. Industrial & Engineering Chemistry Research 1992, 31. 49. Leboreiro, J.; Acevedo, J. Processes Synthesis and Design of Distillation Sequences Using Modular Simulators: A Genetic Algorithm Framework. Computers & Chemical Engineering 2004, 28. 50. Aarts, E. H. L.; Vanlaarhoven, P. J. M. Statistical Cooling - a General-Approach to Combinatorial Optimization Problems. Philips Journal of Research 1985, 40. 51. Patel, A. N.; Mah, R. S. H.; Karimi, I. A. Preliminary Design of Multiproduct Noncontinuous Plants Using Simulated Annealing. Computers & Chemical Engineering 1991, 15. 52. Painton, L. A.; Diwekar, U. M. Synthesizing Optimal-Design Configurations for a Brayton Cycle Power-Plant. Computers & Chemical Engineering 1994, 18. 53. Fogler, H. S. Elements of Chemical Reaction Engineering; Prentice Hall PTR: New Jersey, 1999. 54. Gangadwala, J.; Kienle, A.; Haus, U. U.; Michaels, D.; Weismantel, R. Global Bounds on Optimal Solutions for the Production of 2,3-Dimethylbutene-1. Industrial & Engineering Chemistry Research 2006, 45, 2261. 55. Chirico, R. D.; Steele, W. V. Thermodynamic Equilibria in Xylene Isomerization .5. Xylene Isomerization Equilibria from Thermodynamic Studies and Reconciliation of Calculated and Experimental Product Distributions. Journal of Chemical and Engineering Data 1997, 42, 784. 56. Buzad, G.; Doherty, M. F. New Tools for the Design of Kinetically Controlled Reactive Distillation-Columns for Ternary Mixtures. Computers & Chemical Engineering 1995, 19. 57. Buzad, G.; Doherty, M. F. Design of 3-Component Kinetically Controlled Reactive Distillation-Columns Using Fixed-Point Methods. Chemical Engineering Science 1994, 49. 58. Lin, L. C. Effects of Relative Volatility Ranking to the Design of Reactive Distillation: Excess-Reactant Design. National Taiwan University, Taiwan, 2007. 59. Matsuyama, H.; Nishimura, H. Topological and Thermodynamic Classification of Ternary Vapor-Liquid-Equilibria. Journal of Chemical Engineering of Japan 1977, 10. 60. Chen, C. S. Feasibility of Ternary Reactive Distillation Systems: Decomposition Reaction. National Taiwan University, Taipei, 2008. 61. Douglas, J. M. Conceptual Design of Chemical Processes; McGraw-Hill: New York, 1998. 62. Elliott, T. R.; Luyben, W. L. Quantitative Assessment of Controllability During the Design of a Ternary System with Two Recycle Streams. Industrial & Engineering Chemistry Research 1996, 35. 63. Chiang, S. F.; Kuo, C. L.; Yu, C. C.; Wong, D. S. H. Design Alternatives for the Amyl Acetate Process: Coupled Reactor/Column and Reactive Distillation. Industrial & Engineering Chemistry Research 2002, 41. 64. Underwood, A. J. V. Fractional Distillation of Multicomponent Mixtures. Journal of the Institute of Petroleum 1946, 598. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/48748 | - |
dc.description.abstract | 近年來,反應蒸餾技術的發展已經相當成熟,尤其是在可行性分析,程序設計或者控制架構設計都有相當程度的進展。因此,吾人面對一個反應蒸餾的設計,通常都可以藉由前人已經建立的觀念與知識,來分析其概念設計的可行性。一旦概念設計是可行的話,程序工程師會想更進一步知道該設計是否可以用捷徑式設計的方法做前置設計的分析,或者是否可以利用最適化方法找到最經濟的設計以做為未來詳細設計的基礎。
針對反應蒸餾塔的最適化設計,本研究首先將應用模擬退火演算法進行反應蒸餾程序的最適化設計,並且採用信賴度高的商用模擬軟體(Aspen Plus)來建立反應蒸餾程序的模式,而模擬退火演算法和商用程序模擬軟體(Aspen Plus)之間連結的介面是採用Visual Basic Application (VBA)。雖然利用模擬退火演算法得到設計結果沒辦法保證是全域最佳解,但是與傳統方法相較之下,它可以更有效率且得到的解與最佳的設計相距不遠。 針對反應蒸餾塔的捷徑式設計,最大的困難就是要決定反應區內的觸媒填充量。本研究將先針對兩成份的異構物反應系統,以逆流式串級汽液反應器的概念發展出一套捷徑式設計的流程。研究發現在無限個反應器串連在一起的情況下,會有出現理論最小觸媒的填充量,並且推導一個解析解的公式來描述它。接著,在不需要詳細的程序模式,便可藉由最小觸媒填充量可以用來估算真實的觸媒填充量,以及反應蒸餾塔的其他設計參數,如反應段板數、分離板板數。研究結果顯示此捷徑式設計方法應用於三個兩成份反應的真實系統,其估算結果與最適化設計相較下,年總成本相差不到10%。 最後,將最小觸媒填充量的概念延伸至更複雜的系統,包括兩成份雙聚合、三成份、四成份以及具有共沸物等反應系統,探討在何種反應類型與何種反應蒸餾架構才具有最小觸媒填充量。研究結果顯示只有以下三個條件同時存在下才具有最小觸媒填充量,其一是反應系統內至少要有一反應物的沸點必須沸點是最重或者最輕;其二是反應蒸餾架構的反應段必須在塔的上半段或是下半段;其三是分離段內(汽提段或是精餾段)的狹點(pinch point)必須落在具有正向反應的區域內。 | zh_TW |
dc.description.abstract | The development of reactive distillation (RD) processes has matured significantly in the last decade, especially for the progress in the feasibility analysis, design, and control. However, two questions still often come up: (1) Can a shortcut method be employed for preliminary design? (2) How can a near-optimal design be obtained efficiently for further detailed study? In this work, these two questions are addressed.
To obtain a near-optimal design, a derivative-free optimization approach, simulated annealing (SA), is employed for the optimization of the RD column design and the SA algorithm is implemented in the Visual Basic Application which interfaces with the process simulator, Aspen Plus. This method gives an equally good or better design than the optimal flowsheet obtained from the sequential design approach. More importantly, this is achieved with much more efficient computing. To develop a shortcut method, determination of the catalyst mass is a challenging problem in the conceptual design of reactive distillation systems. We use the concept of countercurrent cascaded vapor-liquid reactors (CCRs) to develop a shortcut method for the design of binary reactive distillation columns. An analytical expression for the theoretical minimum catalyst loading can be derived as the number of CCRs approaches infinity. On the basis of this theoretical catalyst loading, we present a calculation procedure to obtain the catalyst mass and other basic process parameters without a detailed model. Three real binary systems are used to illustrate this shortcut method, and the results show that the estimated shortcut designs are similar to the optimal designs. Furthermore, the concept of the minimum catalyst loading is extended to more complex systems, including ternary and quaternary ideal systems and non-ideal systems with azeotropes. The results show that a minimum catalyst loading exists only if three conditions are met: (1) the RD column has a one-sided reaction zone (top or bottom) and products are withdrawn from the other side, (2) One of the reactants or an azeotrope containing a reactant is the heaviest or the lightest and (3) The pinch point in the separation section of the RD column is located in the zone with positive reaction extent. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T07:11:50Z (GMT). No. of bitstreams: 1 ntu-99-D95524021-1.pdf: 2722412 bytes, checksum: 16d6b2405ed1ff16492dd2fdacd1e3f0 (MD5) Previous issue date: 2010 | en |
dc.description.tableofcontents | 致謝 i
Abstract iii 摘要 v List of figures xi List of tables xxiii 1 Introduction 1 1.1 Literature review 2 1.2 Motivation 5 1.3 Dissertation organization 8 2 Design of Reactive Distillation Using the Simulated Annealing Method 9 2.1 Overview 9 2.2 Simulated Annealing 10 2.2.1 Initial Temperature 13 2.2.2 Final Temperature 14 2.2.3 Temperature Decrement 14 2.2.4 Equilibrium Detection 15 2.2.5 Move Generator 15 2.3 Applications 16 2.3.1 Example 1 – Methyl Acetate System 16 2.3.2 Example 2 – Butyl Acetate System 24 2.4 Conclusion 28 3 Determination of Minimum Catalyst Loading and Shortcut Design for Binary Reactive Distillation 29 3.1 Overview 29 3.2 Process Studied 30 3.2.1 Modeling of Countercurrent Cascaded Reactors (CCRs) 32 3.2.2 Derivation of Analytical Expression for Theoretical Minimum Catalyst Loading (Wmin) 39 3.3 Application of Theoretical Minimum Catalyst Loading 45 3.3.1 Shortcut Design Procedure 46 3.3.2 Determination of the Values of r and w 49 3.3.3 Comparison of Catalyst Loading Calculation Method 59 3.4 Application to Real Systems 62 3.5 Simplification of the analytical equation for Wmin 69 3.6 Conclusion 73 4 Extension of the Concept of Minimum Catalyst Loading to More Complex Systems 75 4.1 Overview 75 4.2 Modeling of RD Column 76 4.2.1 Modeling of RD Column 77 4.3 Binary Systems with Non-Equal Molar Reaction 83 4.3.1 HKó2LK 83 4.3.2 Derivation of Expression of Wmin for HKó2LK 87 4.3.3 2LKóHK 91 4.4 Ternary System 92 4.4.1 Single Reactant 93 4.4.2 Two Reactants 112 4.5 Quaternary System 133 4.5.1 HHK+ HK óLK +LLK 135 4.5.2 LLK +LK óHK+ HHK 140 4.5.3 LLK+HHK óLK +HK 144 4.6 Non-ideal Binary System 150 4.6.1 Non-Ideal Binary System 150 4.6.2 Non-Ideal Ternary System with 2LKóIK+HK 158 4.6.3 Non-Ideal Ternary System with 2IKóLK+HK 161 4.7 Discussion and Summary 165 4.8 Conclusion 167 5 Conclusions and Future Work 169 Nomenclature 173 References 177 Appendix A: TAC Calculation 183 Appendix B: Visual Basic (VBA) Code 185 Appendix C: Process Description of the Case with A(HK)↔B(LK) 189 Appendix D: Calculation of Number of Separation Stages 193 Appendix E: Derivation of the Subawalla and Fair Method 197 Appendix F: Derivation of the Integral Expression for Wmin of Ternary System 201 Appendix G: Derivation of the Integral Expression for Wmin of Quaternary System 205 Autobiography 209 | |
dc.language.iso | en | |
dc.title | 利用最適化演算法與捷徑法進行反應蒸餾塔的設計 | zh_TW |
dc.title | Design of Reactive Distillation Process via Rigorous Optimization and Shortcut Methods | en |
dc.type | Thesis | |
dc.date.schoolyear | 99-1 | |
dc.description.degree | 博士 | |
dc.contributor.oralexamcommittee | 黃孝平(Hsiao-Ping Huang),陳誠亮(Cheng-Liang Chen),錢義隆(I-Lung Chien),李明哲(Ming-Jer Lee),周宜雄(Yi-Shyong Chou),汪上曉(David Shan-Hill Wong),王聖潔(San-Jang Wang) | |
dc.subject.keyword | 反應蒸餾,捷徑式設計,最適化設計, | zh_TW |
dc.subject.keyword | Reactive Distillation,Shortcut Method,Optimization Method, | en |
dc.relation.page | 212 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2010-09-29 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-99-1.pdf 目前未授權公開取用 | 2.66 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。