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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 陳奕君 | |
dc.contributor.author | Yung-Bin Chen | en |
dc.contributor.author | 陳永斌 | zh_TW |
dc.date.accessioned | 2021-06-15T07:10:49Z | - |
dc.date.available | 2011-08-23 | |
dc.date.copyright | 2011-08-23 | |
dc.date.issued | 2011 | |
dc.date.submitted | 2011-08-19 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/48730 | - |
dc.description.abstract | 本研究主要是以不鏽鋼箔作為可撓性基材,分別應用於光轉電-染料敏化太陽能電池(DSSC)-及電轉光-有機發光二極體(OLED)-等兩種元件,探討各樣實驗條件如不鏽鋼箔之表面粗糙度對於元件輸出特性之效應。
第一部份利用不鏽鋼箔搭配商用TiO2漿料、N719染料及液態電解質,及商用之導電塑膠基材ITO-PET濺鍍白金作為對電極,製作成以不鏽鋼為光電極基底之可撓性TiO2染料敏化太陽能電池(DSSCs),並觀察不鏽鋼箔的種類、不鏽鋼箔表面粗糙度、多孔隙TiO2層厚度等條件的差異,對於DSSC輸出特性的影響。藉由濺鍍Ti金屬或蒸鍍TiO2薄膜於不鏽鋼箔表面,其結果顯示均可有效提升元件之效能,表示其有效地抑制了電荷與電解液發生逆向複合的機會,此外SUS 430之熱膨脹係數低於其它不鏽鋼箔(如SUS 316L),故若製程條件相同,以SUS 430作為光電極基板製作成DSSC之光電轉換效率亦較高。在入射光強度100mW/cm2之下,SUS 430光電極基底之DSSC最佳光電轉換效率為1.04%,而SUS 316L基底DSSC則以1.10%為最佳值。此外,對於SUS 316L基底DSSC來說,多孔隙TiO2層於厚度3.5μm以下時光電流隨著基板表面粗糙度增加而提升,超過此厚度則無明顯趨勢。多孔性TiO2層厚度為8~11μm達最佳效能。 第二部份是利用前述之不鏽鋼箔作為基板,先旋塗一層高分子材料benzo- cyclobutene (BCB)作為絕緣性之平坦化層,再將有機發光二極體(OLEDs)製作於其上,結構為ITO/NPB/Alq3/Cs2CO3(或LiF)/Al,並以鍍有SiO2防水氧層之PET塑膠膜將其封裝。結果顯示可撓式OLED於彎曲前後其I-V特性沒有變化;基板的粗糙度使OLED產生暗點,而氣體的滲透更是封裝後OLED劣化的主因。 | zh_TW |
dc.description.abstract | In this study, the stainless steel (StSt) foils were applied as flexible substrates for dye-sensitized solar cells (DSSCs) and organic light-emitting diodes (OLEDs). The relationships between various factors and device performances were investigated.
In the first part, porous TiO2 film was fabricated on a StSt substrate by doctor-blade method. To prevent charge recapture by I3-, a evaporated TiO2 film or sputtered Ti film was deposited on StSt surface prior to the fabrication of porous TiO2 film. Then, the sintering of porous TiO2 was taken place at 450℃. Afterwards, the TiO2 electrodes were immersed in N719 dye solution, and assembled with Pt-coated ITO-PET. At last, liquid electrolyte was injected into the assembled cells. The effects of types of StSt, surface roughness of StSt and thickness of porous TiO2 films on the performances of DSSC were studied. Under 100 mW/cm2 (AM1.5) simulated light, the optimal conversion efficiency was 1.04% for SUS 430-based DSSC, and 1.10% for SUS 316L-based DSSC. For SUS 316L-based DSSC, the photocurrent of cells with porous TiO2 layer thickness less than 3.5 μm increased with surface roughness of the substrate. However, for cells with porous TiO2 layer thicker than 3.5 μm, degraded cell performance was observed, which may attribute to the large mismatch of the coefficients of thermal expansion between the StSt substrate and the TiO2 film. Optimal performance was obtained when the porous TiO2 film was about 8~11 μm. In the second part, A steel-based flexible OLED was fabricated with a configuration of StSt/BCB/ITO/NPB/Alq3/ Cs2CO3(or LiF)/Al. Spin-coated BCB was used as a planarization layer. The OLED was then encapsulated with a SiO2-coated PET film. The device exhibited similar I–V characteristics under bending. | en |
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dc.description.tableofcontents | 中文摘要....................................................I
Abstract..................................................II 致謝.....................................................III 目錄......................................................IV 圖目錄....................................................VII 表目錄.....................................................XI 第一章 緒論................................................1 1.1 前言.................................................1 1.2 論文架構..............................................6 第二章 原理分析與文獻回顧.....................................8 2.1......................................................8 2.1.1 染料敏化太陽能電池(DSSC)之基本原理分析.................8 2.1.2 光電極...........................................11 2.1.2.1 基板........................................11 a. 透明導電氧化物...................................11 b. 金屬基板........................................12 2.1.2.2 非多孔性TiO2鈍化底層...........................13 2.1.2.3 奈米多孔隙TiO2層..............................14 a. TiO2的基本性質..................................14 b. 奈米多孔隙TiO2之晶相對DSSC特性之影響................15 c. 奈米多孔隙TiO2層的製作............................16 2.1.3 染料/電解質/對電極.................................17 2.1.3.1染料敏化劑....................................17 2.1.3.2 I-/I3-液態電解質............................18 2.1.3.3 對電極.......................................18 2.1.4 以金屬為基板之可撓性DSSC...........................19 2.1.4.1 以StSt為光電極基底之DSSC.......................20 2.1.4.2 以Ti為光電極基底之DSSC.........................21 2.1.4.3 以金屬為光電極基底DSSC的穩定性..................22 2.1.5 以塑膠為基板之可撓性DSSC...........................23 2.1.6 太陽能電池的輸出特性...............................24 2.1.6.1 太陽光頻譜照度................................25 2.1.6.2 太陽能電池輸出特性.............................26 2.1.7 影響DSSC各項輸出特性的因素.........................27 2.2.....................................................29 2.2.1 有機發光二極體(OLED)之基本原理......................29 2.2.2 OLED材料.......................................31 2.2.3 可撓式OLED的封裝..................................32 2.2.4 OLED元件的非本質劣化因素..........................35 2.2.4.1 水氣的滲入...................................35 2.2.4.2 基板的粗糙度..................................35 第三章 實驗與研究方法.......................................36 3.1 實驗材料.............................................36 3.2 可撓性DSSC之實驗流程...................................37 3.3 可撓性OLED之實驗流程...................................40 3.4 量測方法.............................................42 3.4.1 表面輪廓儀.......................................43 3.4.2 紫外/可見/近紅外光譜...............................44 3.4.3 X光繞射譜.......................................45 3.4.4 DSSC效率的量測..................................45 第四章 結果與討論...........................................46 I. 可撓性DSSC之實驗結果與討論.................................46 4.1 以FTO玻璃作為光電極基底之DSSC...........................46 4.1.1 Pt的量對於DSSC輸出特性之效應.......................46 4.1.2 TiO2阻擋層厚度對於DSSC輸出特性之效應................47 4.1.3 TiCl4處理對於DSSC輸出特性之效應....................48 4.2 以StSt作為光電極基底之DSSC.............................50 4.2.1 多孔隙TiO2膜於StSt基板上之結晶特性..................50 4.2.2 沉積TiO2阻擋層與Ti於StSt基板對於DSSC輸出特性之比較....50 4.2.3 StSt基板種類對DSSC輸出特性之效應...................51 4.2.4 StSt基板表面粗糙度對DSSC輸出特性之效應..............52 4.2.5 多孔隙TiO2層厚度對DSSC輸出特性之效應.................59 4.2.6 TiCl4處理對StSt光電極基底DSSC輸出特性之效應.........61 II. 可撓性OLED實驗結果與討論.................................62 4.3 平坦化/絕緣層之特性....................................62 4.3.1 BCB與PI各項特性之比較.............................62 4.3.2 不鏽鋼基板表面平坦化之結果..........................65 4.4 可撓性OLED電性之觀察...................................68 4.4.1 標準結構之結果....................................68 4.4.2 以塑膠膜封裝之結構.................................69 4.4.3 撓曲測試.........................................70 4.4.4 持續點亮元件之觀察.................................71 第五章 結論與未來展望.......................................74 參考文獻...................................................76 | |
dc.language.iso | zh-TW | |
dc.title | 製作於不鏽鋼基板之染料敏化太陽能電池與有機發光二極體特性研究 | zh_TW |
dc.title | Fabrication and Characterization of On-Stainless Steel Dye-Sensitized Solar Cells and Organic Light-Emitting Diodes | en |
dc.type | Thesis | |
dc.date.schoolyear | 99-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 陳建彰,吳志毅,吳育任 | |
dc.subject.keyword | 不鏽鋼基板,染料敏化太陽能電池,有機發光二極體, | zh_TW |
dc.subject.keyword | Stainless steel substrate,DSSC,OLED, | en |
dc.relation.page | 83 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2011-08-19 | |
dc.contributor.author-college | 電機資訊學院 | zh_TW |
dc.contributor.author-dept | 光電工程學研究所 | zh_TW |
顯示於系所單位: | 光電工程學研究所 |
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