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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳誠亮(Cheng-Liang Chen) | |
| dc.contributor.author | Jui-Yuan Lee | en |
| dc.contributor.author | 李瑞元 | zh_TW |
| dc.date.accessioned | 2021-06-15T06:59:27Z | - |
| dc.date.available | 2011-03-14 | |
| dc.date.copyright | 2011-02-09 | |
| dc.date.issued | 2011 | |
| dc.date.submitted | 2011-01-25 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/48501 | - |
| dc.description.abstract | This thesis deals with resource conservation in process industries through mass and property integration. For the former, the main focus is given to water network synthesis. A graphical technique is first presented for the design of batch water networks (BWNs). By generalizing some useful concepts and principles that are originally developed for continuous processes, this technique consists of a systematic procedure for stream allocation, while determining fresh water consumption and storage policy. The issue of forbidden matches between given water-using operations and its impact on design is explored. To overcome the common limitation of insight-based techniques that they are limited to single contaminant systems, a mathematical technique for the synthesis of BWN with central storage tank(s) is next presented. By assuming a fixed production schedule, the model formulation is based on a superstructure which includes all possible reuse/recycle options. In addition, the synthesis task involves the minimization of fresh water consumption and storage capacity required. An effective method is proposed to facilitate the elimination of forbidden matches.
For property integration, a generic model is developed for the synthesis of property-based resource conservation networks (PRCNs). By treating continuous processes as a special case of batch processes, this model is applicable to both operating modes. The model formulation is based on a superstructure that includes all possible network connections. Apart from direct material reuse/recycle, interception placement is considered to improve streams properties for further recovery or for discharge. In addition, storage tanks are used when a batch process is considered. The developed model is first extended into palm oil mills, with particular focus on the clay bath system for kernel/shell separation based on flotation principle. Different from previous works where the clay bath separator was simplified as a continuous unit, it is modeled more practically as a semicontinuous unit with a specific operating period. Design objectives for clay bath operation comprise the minimization of fresh resource consumption and operating cost. The second extension is to synthesize concentration-based RCNs for continuous processes, where the interaction between sinks and sources is addressed. This has yet to be considered in most previous works on RCN synthesis. Illustrative examples are solved to demonstrate the application of each technique developed in this thesis. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T06:59:27Z (GMT). No. of bitstreams: 1 ntu-100-F95524063-1.pdf: 1666546 bytes, checksum: 03b40fdf3f90ed38eed3eec6eaea27df (MD5) Previous issue date: 2011 | en |
| dc.description.tableofcontents | 口試委員審定書. . . . . . . . . . . . . . . . . . . . . . i
摘要. . . . . . . . . . . . . . . . . . . . . . . . . . iii Abstract. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . v List of Figures. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xi List of Tables. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xvii Nomenclature. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . xix 1 Introduction 1 1.1 Background Problem . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1.2 Process Integration and Resource Conservation . . . . . . . . . . . . . . . 2 1.2.1 Literature review of water network synthesis . . . . . . . . . . . . 2 1.2.2 Literature review of property integration . . . . . . . . . . . . . . . 8 1.3 Aim of this thesis . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9 1.3.1 Graphical approach for BWN design . . . . . . . . . . . . . . . . 9 1.3.2 Mathematical approach for BWN synthesis . . . . . . . . . . . . . 10 1.3.3 Mathematical approach for PRCN synthesis . . . . . . . . . . . . . 10 1.3.4 Property integration in palm oil mills . . . . . . . . . . . . . . . . 10 1.3.5 RCN synthesis with sink-source interaction . . . . . . . . . . . . . 11 2 A Graphical Technique for the Design of Batch Water Networks 13 2.1 Problem Statement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13 2.2 Stream Allocation and Representation . . . . . . . . . . . . . . . . . . . . 14 2.2.1 Arrangement of fixed load operations in batch processes . . . . . . 15 2.2.2 Arrangement of fixed flow rate operations in batch processes . . . . 17 2.3 Illustrative Example (Example 2.1) . . . . . . . . . . . . . . . . . . . . . 18 2.3.1 Analysis for single batch . . . . . . . . . . . . . . . . . . . . . . . 20 2.3.2 Analysis for repeated batches . . . . . . . . . . . . . . . . . . . . 29 2.3.3 Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 2.4 Discussion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 2.4.1 Verification of optimality . . . . . . . . . . . . . . . . . . . . . . . 40 2.4.2 Practical constraints on water reuse/recycle . . . . . . . . . . . . . 42 3 A Mathematical Technique for the Synthesis of Batch Water Networks 49 3.1 Problem Statement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49 3.2 Superstructure and Model Formulation . . . . . . . . . . . . . . . . . . . 50 3.2.1 Water balances for water-using units . . . . . . . . . . . . . . . . . 51 3.2.2 Contaminant balances for water-using units . . . . . . . . . . . . . 52 3.2.3 Water balances for storage tanks . . . . . . . . . . . . . . . . . . . 53 3.2.4 Contaminant balances for storage tanks . . . . . . . . . . . . . . . 54 3.2.5 Objective functions . . . . . . . . . . . . . . . . . . . . . . . . . . 54 3.3 Illustrative Examples . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 55 3.3.1 Example 3.1: Agrochemical manufacturing facility . . . . . . . . . 56 3.3.2 Example 3.2 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58 3.3.3 Example 3.3: Multiple contaminant case . . . . . . . . . . . . . . 59 3.3.4 For bidden water reuse/recycle . . . . . . . . . . . . . . . . . . . . 60 4 Synthesis of Property-based Resource Conservation Networks for Batch and Continuous Processes 67 4.1 Problem Statement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67 4.2 Mixing Rule and Property Operator . . . . . . . . . . . . . . . . . . . . . 68 4.3 Superstructure and Model Formulation . . . . . . . . . . . . . . . . . . . 68 4.3.1 Mass balances for process sinks . . . . . . . . . . . . . . . . . . . 70 4.3.2 Mass balances for process sources . . . . . . . . . . . . . . . . . . 71 4.3.3 Mass balances for interception devices . . . . . . . . . . . . . . . 72 4.3.4 Mass balances for storage tanks . . . . . . . . . . . . . . . . . . . 74 4.3.5 Mass balances for waste discharge . . . . . . . . . . . . . . . . . . 76 4.3.6 Objective function . . . . . . . . . . . . . . . . . . . . . . . . . . 77 4.4 Illustrative Examples . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 77 4.4.1 Example 4.1:metaldegreasing process . . . . . . . . . . . . . . . 77 4.4.2 Example 4.2: palm oil milling process . . . . . . . . . . . . . . . . 84 4.4.3 Example 4.3: batch chemical process – 1 . . . . . . . . . . . . . . 91 4.4.4 Example 4.4: batch chemical process – 2 . . . . . . . . . . . . . . 96 5 Property Integration for Resource Conservation Network Synthesis in Palm Oil Mills 103 5.1 Problem Statement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103 5.2 Model Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 104 5.2.1 Mass balances for the clay bath system . . . . . . . . . . . . . . . 106 5.2.2 Mass balances for interception devices . . . . . . . . . . . . . . . 108 5.2.3 Mass balances for waste discharge . . . . . . . . . . . . . . . . . . 110 5.2.4 Objective function . . . . . . . . . . . . . . . . . . . . . . . . . . 111 5.3 Illustrative Example (Example 5.1) . . . . . . . . . . . . . . . . . . . . . 111 5.3.1 Case1:Fixed operating period . . . . . . . . . . . . . . . . . . . . 114 5.3.2 Case2:Variable operating period . . . . . . . . . . . . . . . . . . 118 6 Synthesis of Resource Conservation Network with Sink-Source Interaction 125 6.1 Problem Statement . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125 6.2 Superstructure and Model Formulation . . . . . . . . . . . . . . . . . . . 126 6.2.1 Mass balances for process sinks . . . . . . . . . . . . . . . . . . . 126 6.2.2 Mass balances for process sources . . . . . . . . . . . . . . . . . . 127 6.2.3 Mass balances for interception devices . . . . . . . . . . . . . . . 129 6.2.4 Mass balances for waste discharge . . . . . . . . . . . . . . . . . . 130 6.2.5 Objective function . . . . . . . . . . . . . . . . . . . . . . . . . . 131 6.3 Illustrative Examples . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 131 6.3.1 Example 6.1:Tire to fuel process . . . . . . . . . . . . . . . . . . 131 6.3.2 Example 6.2: Tricresyl phosphate process . . . . . . . . . . . . . . 139 7 Conclusions 151 Bibliography. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155 Autobiography. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161 | |
| dc.language.iso | en | |
| dc.title | 批式與連續式製程之資源節約網路合成 | zh_TW |
| dc.title | Synthesis of Resource Conservation Networks for Batch and Continuous Processes | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 99-1 | |
| dc.description.degree | 博士 | |
| dc.contributor.oralexamcommittee | 錢義隆,吳哲夫(Jeffery Ward),鄭西顯,張玨庭,符傳藝(Dominic Chwan Yee Foo),Raymond Tan (菲律賓籍教授) | |
| dc.subject.keyword | 批式製程,數學規劃法,網路合成,程序整合,特性整合,資源節約, | zh_TW |
| dc.subject.keyword | Batch process,Mathematical optimization,Network synthesis,Process integration,Property integration,Resource conservation, | en |
| dc.relation.page | 164 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2011-01-25 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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