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請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/48456
完整後設資料紀錄
DC 欄位值語言
dc.contributor.advisor藍崇文(Chung-Wen Lan)
dc.contributor.authorChien-Cheng Wuen
dc.contributor.author吳建澄zh_TW
dc.date.accessioned2021-06-15T06:57:33Z-
dc.date.available2011-02-20
dc.date.copyright2011-02-20
dc.date.issued2011
dc.date.submitted2011-01-28
dc.identifier.citationReference
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dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/48456-
dc.description.abstractCongruent 0.2 and 0.5 mol% Nd-doped LiTaO3 single crystals were grown by the conventional Czochralski technique. Near-stoichiometric lithium tantalate wafers were also produced from these crystals by the vapor-transport equilibration (VTE) process. The crystals were characterized by the measurements of composition (by inductively coupled plasma atomic emission spectroscopy (ICP-AES), UV absorption edge, Curie temperature and thermal diffusivity. From the ICP-AES study, we found that Li/Ta ratio was increased by the VTE treatment, while Nd/Ta ratio was found to decrease with the crystal length. The blue shift in absorption edge was observed in the VTE treated crystals as compared with the congruent ones. The Curie temperature decreased with the increasing Nd concentration, while thermal conductivity was found to increase after the VTE treatment. FTIR was also conducted to investigate how impurity and Li/Ta affect the OH- vibration mode. And there are two blue shift absorption bands in 0.5mol%Nd:SLT in which we use a Ta vancancy model to explain the phenomenon.en
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en
dc.description.tableofcontents第一章 緒論 4
1.1 簡介 4
1.2 文獻回顧 5
1.2.1 鉭酸鋰晶體 5
1.2.2 晶體組成與雜質摻雜 10
1.3 研究動機 16
第二章 實驗藥品、設備及流程 17
2.1 實驗藥品 17
2.1.1 晶體生長用藥品 17
2.1.2 鉭酸鋰溶液配製用藥品 18
2.1.3 晶片研磨用藥品 19
2.1.4 清洗用藥品 20
2.2 晶體生長實驗之設備及流程 20
2.2.1 原料配置 20
2.2.1.1 原料配置設備 21
2.2.1.2 原料配置步驟 22
2.2.2 原料裝填晶體生長極晶體回火 23
2.2.2.1 晶體生長設備 23
2.2.2.2 原料填裝步驟 29
2.2.2.3 晶體生長及晶體回火步驟 29
2.2.3 晶體定向、切割及研磨 31
2.2.3.1 晶體定向、切割及研磨拋光設備 31
2.2.3.2 晶體定向步驟 35
2.2.3.3 晶體切割步驟 36
2.2.3.4 晶片研磨拋光(lapping & polishing)步驟 36
2.2.4 晶體評價 38
2.2.4.1 量測設備 38
2.2.4.2 晶片穿透度、吸收波長量測步驟 43
2.2.4.3 晶片折射率量測步驟 43
2.2.4.4 晶體居禮溫度量測步驟 44
2.2.4.5 晶體組成量測步驟 44
2.2.4.6 晶體熱擴散係數量測步驟 45
2.3 鉭酸鋰晶片進行VTE 實驗之流程 46
第三章 晶體生長及晶體評價 47
3.1 柴式法摻釹鉭酸鋰單晶生長 47
3.2 晶體評價 55
3.2.1 摻釹鉭酸鋰雜質組成量測 55
3.2.2 摻釹鉭酸鋰之穿透光譜 56
3.3 氣相傳輸平衡法製備摻釹計量比鉭酸鋰(Nd:SLT)之研究 57
3.3.1 摻釹鉭酸鋰之吸收波長 60
3.3.2 摻釹鉭酸鋰之組成量測 62
3.3.3 摻釹鉭酸鋰之居禮溫度量測 62
3.3.4 摻釹鉭酸鋰之折射率量測 64
3.3.5 摻釹鉭酸鋰之熱擴散係數量測 65
3.3.6 摻釹鉭酸鋰之FTIR量測 68
第四章 結論 73
dc.language.isozh-TW
dc.title柴式法摻釹鉭酸鋰單晶生長之研究zh_TW
dc.titleGrowth and Characterizations of Nd-doped Lithium Tantalate Single Crystalsen
dc.typeThesis
dc.date.schoolyear99-1
dc.description.degree碩士
dc.contributor.oralexamcommittee張正陽,高振宏,何國川
dc.subject.keyword柴式法,單晶生長,鉭酸鋰,氣相傳輸平衡,雷射晶體,激光變頻,zh_TW
dc.subject.keywordCzochralsky single crystal growth,Lithium tantalate,Vapor transport equilibration,laser material,Frequency conversion,en
dc.relation.page83
dc.rights.note有償授權
dc.date.accepted2011-01-28
dc.contributor.author-college工學院zh_TW
dc.contributor.author-dept化學工程學研究所zh_TW
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