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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 張惠婷 | |
| dc.contributor.author | Wan-Jen Yang | en |
| dc.contributor.author | 楊菀仁 | zh_TW |
| dc.date.accessioned | 2021-06-15T06:53:36Z | - |
| dc.date.available | 2016-08-22 | |
| dc.date.copyright | 2011-08-22 | |
| dc.date.issued | 2011 | |
| dc.date.submitted | 2011-08-19 | |
| dc.identifier.citation | 夏滄琪（2001）談紙質檔案的微生物危害與防治。檔案季刊1:46-59。
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Chang (2002) Comparisons of chemical characteristic variations for photodegraded softwood and hardwood with/without polyurethane clear coatings. Polymer Degradation and Stability 77:129-135. Colom, X., F. Carrillo, F. Nogues and P. Garriga (2003) Structural analysis of photodegraded wood by means of FTIR spectroscopy. Polymer Degradation and Stability 80:543-549. Florian, M.-L. E. (1996) The Role of the Conidia of Fungi in Fox Spots. Studies in Conservation 41:65-75. Hilder, M. and W. Batchelor (2010) Surface-sensitive method to determine calcium carbonate filler contents in cellulose matrices. Cellulose 17:407-415. Herrera, L. K., A. Justo, A. Duran, M. C. J. de Haro, M. Franquelo and J. L. P. Rodriguez (2010) Identification of cellulose fibres belonging to Spanish cultural heritage using synchrotron high resolution X-ray diffraction. Applied Physics a-Materials Science & Processing 99:391-398. Hon, D. N. -S. and Shiraishi, N. (Eds) (2001) Wood and Cellulosic Chemistry. Mercel Dekker, Inc. New York. 919 pp. Inagaki, T., K. Mitsui and S. Tsuchikawa (2008) Near-Infrared Spectroscopic Investigation of the Hydrothermal Degradation Mechanism of Wood as an Analogue of Archaeological Objects. Part I: Softwood. Applied Spectroscopy 62:1209-1215. Kavkler, K., N. Gunde-Cimerman, P. Zalar and A. Demsar (2011) FTIR spectroscopy of biodegraded historical textiles. Polymer Degradation and Stability 96:574-580. Łojewska, J., A. l. nska, P. mi′skowiec, T. Łojewski and L. M. proniewicz (2006) FTIR in situ transmission studies on the kinetics of paper degradation via hydrolytic and oxidative reaction paths. Applied Physics A 83:597-603. Manso, M., S. Pessanha and M. L. Carvalho (2006) Artificial aging processes in modern papers: X-ray spectrometry studies. Spectrochimica Acta Part B: Atomic Spectroscopy 61:922-928. Margutti, S., G. Conio, P. Calvini and E. Pedemonte (2001) Hydrolytic and oxidative degradation of paper. Restaurator-International Journal for the Preservation of Library and Archival Material 22:67-83. May, E. and M. Jones (2006) Methods in Conservation. pp.33-55. In Charola, A. E. and R. J. Koestler, eds. Conservation science: heritage materials. Royal Society of Chemistry, Cambridge. 390 pp. Mehrotra, R., P. Singh and H. Kandpal (2010) Near infrared spectroscopic investigation of the thermal degradation of wood. Thermochimica Acta 507-508:60-65. Michell, A. J. and G. Scurfield (1967) Composition of extracted fungal cell walls as indicated by infrared spectroscopy. Archives of Biochemistry and Biophysics 120:628-637. Mohacek-Grosev, V., R. Bozac and G. J. Puppels (2001) Vibrational spectroscopic characterization of wild growing mushrooms and toadstools. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 57:2815-2829. Moore-Landecker, Elizabeth (1996) Fundamentals of the fungi. Prentice-Hall, New Jersey. 574 pp. Osborne, B.G., T. Fearn and P.H. Hindle (1993) Practical NIR Spectroscopy with applications in Food and Beverage Analysis. Harlow, Essex, Prentice Hall , England. 227 pp. Park, S., J. O. Baker, M. E. Himmel, P. A. Parilla and D. K. Johnson (2010) Cellulose crystallinity index: measurement techniques and their impact on interpreting cellulase performance. Biotechnology for Biofuels 3:1-10. Prescott, L. M., J. P. Harley and D. A. Klein (2007) The fungi (Eumycota), slime molds, and water molds. pp.537-552. Microbiology. McGraw-Hill, New York. 992 pp. Proniewicz, L. M., C. Paluszkiewicz, A. Wesełucha-Birczyn′ska, A. Baran′ski and D. Dutka (2002) FT-IR and FT-Raman study of hydrothermally degraded groundwood containing paper. Journal of Molecular Structure 614:345-353. Shapaval, V., T. Moretro, H. P. Suso, A. W. Asli, J. Schmitt, D. Lillehaug, H. Martens, U. Bocker and A. Kohler (2010) A high-throughput microcultivation protocol for FTIR spectroscopic characterization and identification of fungi. Journal of Biophotonics 3:512-521. Skoog, D. A., F. J. Holler, S. R. Crouch (2007) Applications of infrared spectrometry. pp. 455-477. Principles of Instrumental Analysis, 6th ed. Brooks/Cole Pub Co, Belmont. 1039 pp. Silverstein, R. M., F. X. Webster and D. J. Kiemle (2005) Infrad Spectrometry. pp.72-126. Spectrometric Identification of Organic Compounds. John Wiley & Sons, Hoboken, NJ. 512 pp. Szczepanowska, H. (1986) Biodeterioration of art objects on paper. The Paper Conservator 10:31-39. Szczepanowska, H. M. and W. R. Moomaw (1994) Laser Stain Removal of Fungus-Induced Stains from Paper. Journal of the American Institute for Conservation 33:25-32. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/48353 | - |
| dc.description.abstract | 本研究探討3種常見紙質文物黴菌Aspergillus niger、Aspergillus terreus與Chaetomium globosum對濾紙與道林紙文化用紙之黴害，並透過數種光譜分析瞭解紙張在遭受不同種黴菌危害時之化學元素、官能基與結構之變化，未來可應用於紙張黴害瞭解與紙質文物黴害機制評估。
表面顏色分析結果顯示，A. terreus及C. globisum各自對紙張之黃色值（b*）、明度與白度影響最劇，整體而言以A. terreus對紙張顏色的影響最顯著，A. niger則較為輕微。由掃描式電子顯微鏡（SEM）可看出紙張在受不同菌種危害時，其表面特徵與菌絲型態也產生不同之差異。由紅外線光譜（FTIR）與近紅外線光譜（NIR）分析得知，道林紙與濾紙受3菌劣化的趨勢相同，3種黴害濾紙之纖維素吸收峰強度皆隨生長時間降低，意即隨黴菌生長時間增長，對纖維素降解越趨嚴重，而不同黴菌對纖維素結構改變方式又各有不同，其中同屬之A. terreus與A. niger對纖維素降解的形式較為相近。配合X光粉末繞射（XRD）結果，更可確知3種黴菌對纖維素結晶度降低皆有一定的影響，其中同屬之A. terrus與A. niger對紙張的劣化主要在生長初期發生，並以A. niger與C. globosum對纖維素結晶區的降解最劇烈，結晶度最低可降至59%。從X光螢光分析（XRF）結果可發現隨著黴菌生長時間增長，黴菌菌絲與孢子所含磷與硫的含量有升高的趨勢。 | zh_TW |
| dc.description.abstract | In this research, three fungi, Aspergillus niger, Aspergillus terreus and Chaetomium globosum, commonly found in mildew-caused paper deterioration are selected to investigate their damaging effects on filter paper and wood-free printed paper. Various methods of spectroscopic analysis are employed to examine the changes of structure and chemical properties of paper in the degradation test. In the future, the research can be applied to the investigation of biodegraded historical paper products.
Results of the study indicate that, among these three types of fungi, A. terreus causes the greatest change of the paper color, while A. niger has the slightest effect on it. The scanning electron microscope (SEM) analysis also shows that different types of fungi create different types of hyphae growth patterns and of different surface damage characteristics on paper. The data of Fourier transform infrared spectroscopy (FTIR) and near infrared spectroscopic (NIR) analysis reveal similar degradation patterns on both filter paper and wood-free printed paper, with signals of mold continuing to rise over the deterioration span. In addition, the changes of the cellulose structure of the specimens caused by Aspergillus species are very similar. The signal of cellulose decreases both in filter paper and wood-free printed paper. The results from X-ray diffraction spectroscopy (XRD) also confirm the role of the three kinds of fungi in the degradation of cellulose crystalline region of paper. Both A. terrus and A. niger destroy the crystallinity of cellulose mainly in their initial growth stage. A. niger and C. globosum cause greatest damage on crystallinity of paper with crystallinity reduced to as low as 59% in some specimens. The X-ray fluorescence (XRF) analysis shows that that with the growth of the fungi, the content of phosphorus and sulfur in the fungi hyphae and spores increases over time. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T06:53:36Z (GMT). No. of bitstreams: 1 ntu-100-R98625045-1.pdf: 12065012 bytes, checksum: a4d341b4a8c3f37720c76a5436ed9f01 (MD5) Previous issue date: 2011 | en |
| dc.description.tableofcontents | 誌謝 ................................................................................................................................. II
摘要 ............................................................................................................................... III Abstract ........................................................................................................................... IV 目錄 ................................................................................................................................. V 圖目錄 .......................................................................................................................... VIII 表目錄 ......................................................................................................................... XIV 壹、前言 .......................................................................................................................... 1 貳、文獻回顧 .................................................................................................................. 2 一、紙質文物之黴害介紹 .......................................................................................... 2 （一）真菌對紙質文物之黴害機制 ..................................................................... 2 1. 紙張黴害之過程 ........................................................................................... 2 2. 真菌對纖維素之酵素降解 ........................................................................... 3 3. 酸性物質對纖維素水解之催化 ................................................................... 4 （二）台灣常見之紙質文物黴害菌種 ................................................................. 6 1. 木霉屬（Trichoderma spp.） ....................................................................... 6 2. 麴菌屬（Aspergillus spp.） ......................................................................... 6 3. 毛殼霉屬（Chaetomium spp.） ................................................................... 6 4. 青黴菌屬（Penicillium spp.） ..................................................................... 7 二、傳統之紙質文物黴害評估 .................................................................................. 7 （一）肉眼黴害評估 ............................................................................................. 7 （二）酸鹼性測定 ................................................................................................. 7 三、光譜儀器對紙張劣化狀況之評估 ...................................................................... 8 （一）傅立葉轉換紅外線光譜 ............................................................................. 8 （二）近紅外光光譜 ........................................................................................... 14 （三）X 光繞射光譜 ........................................................................................... 14 （四）X 光螢光光譜 ........................................................................................... 18 四、紙質文物之黴斑去除 ........................................................................................ 21 （一）物理性清除 ............................................................................................... 21 （二）化學性清除 ............................................................................................... 21 五、紙質文物之保存性修復 .................................................................................... 22 （一）紙質文物之除酸保存 ............................................................................... 22 （二）劣損紙質文物的加固與修補方式 ........................................................... 22 參、材料與方法 ............................................................................................................ 23 一、試驗材料 ............................................................................................................ 23 （一）紙樣 ........................................................................................................... 23 （二）試驗菌種 ................................................................................................... 23 二、紙張黴菌劣化試驗 ............................................................................................ 23 三、紙張表面顏色分析 ............................................................................................ 24 四、紙張之光譜儀器分析 ........................................................................................ 24 （一）掃描式電子顯微鏡分析 ........................................................................... 24 （二）傅立葉轉換紅外線光譜分析 ................................................................... 24 （三）近紅外光光譜分析 ................................................................................... 25 （四）X 光繞射分析 ........................................................................................... 25 （五）X 光螢光光譜儀 ....................................................................................... 25 五、統計分析 ............................................................................................................ 26 肆、結果與討論 ............................................................................................................ 27 一、黴菌對紙張表面顏色之影響 ............................................................................ 27 二、黴害紙張表面之形態分析 ................................................................................ 32 三、黴害紙張之化學官能基變化 ............................................................................ 41 （一）黴害濾紙黴菌FTIR 特性吸收之比較 ......................................................... 41 （二）黴害濾紙纖維素FTIR 特性吸收之比較 ..................................................... 48 （三）黴害道林紙與濾紙FTIR 特性吸收之比較 ................................................. 52 （四）黴害紙張近紅外光光譜分析 ........................................................................ 61 四、黴害紙張之纖維素結晶度變化 ........................................................................ 68 五、黴害紙張表面元素變化 .................................................................................... 70 伍、結論 ........................................................................................................................ 75 陸、參考文獻 ................................................................................................................ 77 | |
| dc.language.iso | zh-TW | |
| dc.subject | 紙張 | zh_TW |
| dc.subject | X 光螢光光譜 | zh_TW |
| dc.subject | 近紅外線光譜 | zh_TW |
| dc.subject | 傅立葉轉換紅外線光譜 | zh_TW |
| dc.subject | 生物劣化 | zh_TW |
| dc.subject | 黴菌 | zh_TW |
| dc.subject | X 光粉末繞射分析 | zh_TW |
| dc.subject | mildew | en |
| dc.subject | X-ray diffraction spectroscopy | en |
| dc.subject | X-ray fluorescence spectroscopy | en |
| dc.subject | Near infrared spectroscopy | en |
| dc.subject | Biodegradation | en |
| dc.subject | paper | en |
| dc.subject | Fourier transform infrared spectroscopy | en |
| dc.title | 以光譜分析評估黴菌劣化後紙張性質之變化 | zh_TW |
| dc.title | Spectroscopic Analyses of the Properties of Mildew-Damaged Paper | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 99-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 張上鎮,蘇裕昌,許富蘭,葉汀峰 | |
| dc.subject.keyword | 紙張,生物劣化,黴菌,傅立葉轉換紅外線光譜,近紅外線光譜,X 光螢光光譜,X 光粉末繞射分析, | zh_TW |
| dc.subject.keyword | Biodegradation,paper,mildew,Fourier transform infrared spectroscopy,Near infrared spectroscopy,X-ray fluorescence spectroscopy,X-ray diffraction spectroscopy, | en |
| dc.relation.page | 80 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2011-08-20 | |
| dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
| dc.contributor.author-dept | 森林環境暨資源學研究所 | zh_TW |
| 顯示於系所單位： | 森林環境暨資源學系 | |
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