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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 何國川(Kuo-Chuan Ho) | |
| dc.contributor.author | Chen-Yu Chou | en |
| dc.contributor.author | 周振宇 | zh_TW |
| dc.date.accessioned | 2021-06-15T06:43:08Z | - |
| dc.date.available | 2013-07-25 | |
| dc.date.copyright | 2011-07-25 | |
| dc.date.issued | 2011 | |
| dc.date.submitted | 2011-07-06 | |
| dc.identifier.citation | [1] M. Gratzel, Solar energy conversion by dye-sensitized photovoltaic cells. Inorganic Chemistry 44 (2005) 6841-6851.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/47932 | - |
| dc.description.abstract | 本論文研究製備二氧化鈦(TiO2)或氧化鋅(ZnO)作為量子點敏化太陽能電池(QDSSC)光電極中半導體奈米結構層之應用，並探討藉由改良光電極增進元件效率之方法與其原因。
本研究第一部分(第二章)是以一定比例參雜單分散聚苯乙烯(PS)乳膠圓球粒子(約300 nm)於二氧化鈦薄膜之中，經過高溫燒結得到含有微奈米複合孔隙，團簇結構的二氧化鈦薄膜(M-TiO2)。之後利用液相之連續離子層吸附反應(SILAR)，將硫化鎘量子點合成並吸附沉積於此改良結構中(M-TiO2/CdS)，並與未經PS球修飾但經同樣製程製備之二氧化鈦薄膜(B-TiO2/CdS)做比較。在本研究探討沉積次數對元件效能之影響中，我們發現若使用B-TiO2結構之薄膜吸附量子點，當SILAR次數達到五層(B-TiO2/CdS5)時，可以得到1.35% 的光電轉化效率；而使用修飾後之薄膜，當SILAR次數達到六層(M-TiO2/CdS6)時，其最高效率表現可提升至1.79%。在本研究中亦首次發現硫氰酸胍(guanidine thiocyanate，GuSCN)可應用於量子點敏化太陽能電池中多硫成分電解液之添加劑，其光電轉化效率可進一步提升至2.01%。此外，本章量測了量子點敏化太陽能電池之元件穩定性。本研究使用掃描式電子顯微鏡(SEM)觀測薄膜表面及側面之型態，能量散佈分析儀用於研究M-TiO2/CdS 與 B-TiO2/CdS之化學元素組成計量比，元件中光電流變化則利用入射光子-電流轉化效率(IPCE)進一步證實。 在本論文的第二部分探討的是如何製備並組裝氧化鋅奈米線及奈米粒子之複合式半導體結構薄膜(CL-ZnO)，並探討其元件效率表現。此氧化鋅奈米線(ZNW)長約6微米，直徑約100奈米，此部分藉由X光繞射儀及掃描式電子顯微鏡，探討氧化鋅奈米粒子(ZNP)，ZNW，和CL-ZnO之表面型態與及晶格結構。此三種薄膜亦利用SILAR的方式沉積CdS量子點，結果在應用CL-ZnO光電極之元件中得到最高效率，其光電流大幅度的提升，為使用ZNW的2.81倍。在此基礎上，使用硒化鎘(CdSe)量子點做為CdS量子點的共敏化吸收劑，其薄膜結構為CL-ZnO/CdS/CdSe。如此得到的光電轉化效率亦超越單純使用CdS量子點之元件。最後應用硫化鋅(ZnS)作為光電極最外層之保護層，可得到此系統中最高效率0.55%。本研究之結果可藉由電化學阻抗頻譜(EIS)，紫外-可見光吸收光譜(UV-vis absorbance spectra)，穿透式電子顯微鏡(TEM)，以及IPCE佐證。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2021-06-15T06:43:08Z (GMT). No. of bitstreams: 1 ntu-100-R98524009-1.pdf: 7107494 bytes, checksum: 18ba740c5d487604b796c5046d184ad8 (MD5) Previous issue date: 2011 | en |
| dc.description.tableofcontents | Acknowledgements……………………………………………………………….................I
摘要(Chinese Abstract)………………………………………………………………….......II Abstract………………………………………………………………………………….......IV Table of contents…………………………………………………………………………….VI List of tables…………………………………………………………………………………IX List of figures………………………………………………………………………………..XI Frequent abbreviations and symbols………………………………………………………..XV Chapter 1 Introduction…………………………………………………………………….1 1.1 Background……………………………………………………………………1 1.2 Dye-sensitized solar cells…………………………………………………......3 1.2.1 Materials development and basic working principles of DSSCs………...3 1.2.2 The factors that determine overall conversion efficiency of DSSCs…….9 1.2.3 Measurements and Instrumentation of DSSCs’ Performance……………13 1.2.4 Recent Advances in Efficiencies of DSSCs……………………………...14 1.3 Quantum Dot-sensitized Solar Cells………………………………………….14 1.3.1 Semiconductor QD……………………………………………………….15 1.3.2 QD synthesis and sensitization…………………………………………...20 1.3.3 Literature review of QDSSCs in power conversion efficiencies and the flow sheet of this research………...............................................................22 Chapter 2 Efficient Quantum Dot-sensitized Solar Cell with Polystyrene-modified TiO2 Photoanode and with GuSCN in Its Polysulfide Electrolyte…………………..30 2.1 Motivation and objectives…………………………………………………….30 2.2 Experimental……………………………………………………………..........31 2.2.1 Materials………………………………………………………………….31 2.2.2 Preparation of photoanodes for QDSSCs and the corresponding SILAR process…………………………………………………………………...32 2.2.3 Assembly of the QDSSCs………………………………………………..33 2.2.4 Instrumentation…………………………………………………………...33 2.3 Results and discussion………………………………………………………...34 2.3.1 SEM analyses of polystyrene particles, bare TiO2 film, and modified TiO2 film………………………………………………………………...34 2.3.2 Photovoltaic parameters of QDSSCs with B-TiO2/CdS1 to B-TiO2/CdS6……………………………………………………………36 2.3.3 SEM analysis of B-TiO2/CdS5, B-TiO2/CdS6, and M-TiO2/CdS6…….40 2.3.4 EDX analysis of B-TiO2/CdS5, B-TiO2/CdS6, and M-TiO2/CdS6…….43 2.3.5 Photovoltaic parameters of QDSSCs with B-TiO2/CdS5, B-TiO2/CdS6, M-TiO2/CdS5, and M-TiO2/CdS6………………………………………46 2.3.6 Correlation of EDX data with the photovoltaic performance………….48 2.3.7 Incident photon-to-current conversion efficiencies of the QDSSCs……48 2.3.8 Photovoltaic parameters of the QDSSC with GuSCN………………….49 2.3.9 Durability of the QDSSC……………………………………………….51 2.4 Summary……………………………………………………………………....53 Chapter 3 ZnO nanowire/nanoparticles composite films for the photoanodes of quantum dot-sensitized solar cells....................................................................................54 3.1 Motivation and objectives…………………………………………………….54 3.2 Experimental…………………………………………………………………..55 3.2.1 Materials………………………………………………………………….55 3.2.2 Preparation of the ZNP film……………………………………………...56 3.2.3 Preparation of the ZNW and CL-ZnO film………………………………56 3.2.4 Deposition of QDs on the ZnO films by SILAR process………………...56 3.2.5 Assembly of the ZnO-based QDSSCs……………………………………57 3.2.6 Instrumentation and measurements………………………………………57 3.3 Results and discussion………………………………………………………...58 3.3.1 SEM analyses of ZNW, CL-ZnO, and ZNP films………………………..58 3.3.2 Characterization of ZNW, ZNP, and CL-ZnO(50) films by XRD analyses…………………………………………………………………...62 3.3.3 Photovoltaic parameters and EIS spectra of QDSSCs with ZNW/CdS, CL-ZnO(25)/CdS, CL-ZnO(50)/CdS, and ZNP/CdS…………………......64 3.3.4 UV-vis absorption spectra and IPCE spectra……………………………….68 3.3.5 The role of ZNWs in the film of CL-ZnO(50)………………………….......71 3.3.6 CdSe QDs as the co-sensitizer………………………………………………72 3.4 Summary…………………………………………………………………………75 Chapter 4 Conclusions and suggestions……………………………………………………..77 References……………………………………………………………………………….......79 Appendix…………………………………………………………………………………….92 Curriculum Vitae………………………………………………………………………….....94 | |
| dc.language.iso | en | |
| dc.title | 量子點敏化太陽能電池：以聚苯乙烯模板之二氧化鈦及氧化鋅奈米線/奈米粒子光電極研究 | zh_TW |
| dc.title | Quantum Dot-sensitized Solar Cells: Investigation on Polystyrene-templated TiO2 and ZnO Nanowire/Nanoparticle Photoanodes | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 99-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 周澤川(Tse-Chuan Chou),吳嘉文(Chia-Wen Wu),楊明長(Ming-Chang Yang),林正嵐(Cheng-Lan Lin) | |
| dc.subject.keyword | 單分散聚苯乙烯,多硫成分電解液,硫化鎘量子點,量子點敏化太陽能電池,連續離子層吸附反應,氧化鋅奈米線,硒化鎘量子點, | zh_TW |
| dc.subject.keyword | Monodispersed polystyrene (PS),Polysulfide electrolyte,Cadmium sulfide quantum dots,Quantum dot-sensitized solar cell (QDSSC),Successive ionic layer adsorption and reaction (SILAR),ZnO nanowires,Cadmium selenide quantum dots, | en |
| dc.relation.page | 96 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2011-07-06 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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