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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 吳紀聖(Chi-Sheng Wu) | |
| dc.contributor.author | Pei-Yin Liou | en |
| dc.contributor.author | 劉珮吟 | zh_TW |
| dc.date.accessioned | 2021-06-15T04:59:05Z | - |
| dc.date.available | 2012-07-29 | |
| dc.date.copyright | 2010-07-29 | |
| dc.date.issued | 2010 | |
| dc.date.submitted | 2010-07-28 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/46230 | - |
| dc.description.abstract | 將二氧化碳與水在光照射之下，經由光觸媒催化為有價值的有機化合物，稱之為「人工光合作用」，有助於解決全球暖化與能源危機。本研究以溶凝膠法製備SiO2與NiO/InTaO4，將SiO2與NiO/InTaO4依序覆膜於蜂巢狀陶瓷載體上，形成多層結構，SiO2層有助於避免觸媒掉進載體孔洞中造成觸媒浪費，觸媒經過1100 oC鍛燒形成銦鉭晶相。蜂巢式反應器中，於載體的每一個通道內置入PMMA側面發光光纖，光可經由光線傳送並照射到觸媒表面，在光纖的側面鑿洞以增加側面發光強度，並於光纖尾端加金屬鍍膜以增加光反射，同時進行氣相光催化還原二氧化碳，以GC/FID層析儀分析主要產物為甲醇與乙醛。由UV-Vis圖譜得知銦鉭觸媒可吸收至可見光波段，能隙為2.7 eV，添加NiO共觸媒後能隙下降為2.2 eV，並經由XRD圖確認無雜相形成，SEM圖可見觸媒均勻附著於載體表面，並可觀察到NiO形成於InTaO4表面；利用光纖設計增加側面發光比率，比較不同光纖的甲醇產率，經過側面鑿洞與Pt尾端沉積的光纖，室溫下使用42.46 mW/cm2的可見光照射下，甲醇最佳產率為0.16 µmole/g•hr，當光源轉換為AM1.5 G模擬太陽光時，產物轉移為乙醛，以不同鎳含量與不同溫度下的活性比較，在反應溫度為70 oC時2.6%NiO/InTaO4獲得最佳產率為0.3 µmole/g•hr。 | zh_TW |
| dc.description.abstract | Global warming and fuel shortage are undeniable enviromental and energy problems nowadays. To solve these two problems, CO2 and water can be converted into organic compounds via photocatalysts under light irradiation, which is also called artificial photosynthesis. In the research, sol-gel prepared SiO2 and NiO/InTaO4 were coated sequentially on monolith to form multilayer structure. The catalyst was calcined to form crystal at 1100 oC. PMMA fibers with caves which can increase the side emission of light were put inside each channel of monolith. Furthermore, the end of the fibers was deposited a mirror to increase the light refletance from the end. The UV−VIS spectra of powder InTaO4 as well as NiO loaded InTaO4 indicated that both photocatalysts could absorb visible light. Pure InTaO4 was observed from XRD pattern. From SEM images, uniform catalyst layer and NiO were formed on monolith surface. The methanol yield achieved 0.16 µmol/g•h with visible light intensity of 42.46 mW/cm2 at 25°C. The product shifted to acetaldehyde under AM1.5G sunlight irradiation which yield obtained was 0.3 µmol/g•h at 70 °C on 2.6%NiO/InTaO4. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T04:59:05Z (GMT). No. of bitstreams: 1 ntu-99-R97524037-1.pdf: 13075092 bytes, checksum: ce205f6c23a94ae8c16d5ebd9c7f5825 (MD5) Previous issue date: 2010 | en |
| dc.description.tableofcontents | 摘要 I
Abstract II 目錄 III 表目錄 XIV 第一章 緒論 1 第二章 文獻回顧 3 2-1 光觸媒反應原理 3 2-2 銦鉭觸媒簡介 4 2-2-1 銦鉭觸媒結構與性質 4 2-2-2 添加NiO共觸媒改質 7 2-3 觸媒製備─溶凝膠法 15 2-4 二氧化碳的簡介 19 2-5 二氧化碳的減量 19 2-5-1 二氧化碳固定 19 2-5-2 二氧化碳的光催化還原 21 2-5-2-1 溫度效應 29 2-6 光纖簡介 30 2-7蜂巢狀反應器 35 2-7-1蜂巢狀載體(Monolithic support)簡介 35 2-7-2 蜂巢狀陶瓷反應器(Honeycomb monolith reactor) 36 第三章 實驗方法 44 3-1 實驗藥品與器材 44 3-1-1 藥品 44 3-1-2 器材 45 3-2 實驗步驟 46 3-2-1 負載不同金屬InTaO4觸媒粉體製備 46 3-2-2 SiO2覆膜液製備 46 3-2-3 觸媒覆膜液製備 47 3-2-3-1 NiO/InTaO4(sg) 47 3-2-3-2 NiO/InTaO4(imp) 47 3-2-4 浸漬覆膜法(Dip-coating method) 47 3-3 觸媒特性分析原理與方法 53 3-3-1 儀器型號與規格 53 3-3-2 紫外光-可見光光譜儀(UV-VIS) 54 3-3-3 X光繞射儀(XRD) 56 3-3-4 掃描式電子顯微鏡(SEM) 60 3-3-5 能量散佈光譜儀(EDS) 61 3-3-6 穿透式電子顯微鏡(TEM) 61 3-3-7 X光光電子能譜儀(XPS) 62 3-3-8 比表面積分析(BET) 63 3-3-9 汞壓法(MIP) 64 3-3-10大氣壓力化學游離/質譜儀 (APCI/MS) 66 3-3-11 原子吸收光譜( AAS) 67 3-3-12 氣相管柱層析儀(GC) 68 3-3-13 X光吸收光譜(XAS) 68 3-4 光催化活性檢測 71 3-4-1 液相反應器 71 3-4-2 內照明蜂巢式反應器 72 3-4-3 太陽光譜介紹 75 3-4-4 二氧化碳光催化還原 78 3-4-5 訊華軟體—SISC色層分析數據處理系統 83 第四章 觸媒特性分析結果與討論 85 4-1 觸媒製備 85 4-1-1 SiO2覆膜液 85 4-1-2 InTaO4覆膜液 86 4-1-3 Atomic Absorption 86 4-2 觸媒檢測與特性分析 89 4-2-1 UV-VIS 89 4-2-2 XRD 91 4-2-3 XPS 92 4-2-4 BET 97 4-2-5 TEM 97 4-2-6 SEM 100 4-2-7 EDS 105 4-2-8 MIP 106 4-2-9 XAS 107 第五章 光催化還原結果與討論 110 5-1 液相反應器 110 5-2 內照明蜂巢式反應器 111 5-2-1 空白實驗 111 5-2-2 光纖效應 112 5-2-3 APCI/MS 114 5-2-4 覆膜條件效應 115 5-2-5 鎳含量適化 116 5-2-6 溫度效應 118 5-2-7 失活測試 120 5-2-8 產率和量子效率比較 121 第六章 結論 124 參考文獻 125 附錄 131 個人小傳 145 | |
| dc.language.iso | zh-TW | |
| dc.subject | 銦鉭光觸媒 | zh_TW |
| dc.subject | 蜂巢狀反應器 | zh_TW |
| dc.subject | InTaO4 photocatalyst | en |
| dc.subject | Monolith reactor | en |
| dc.title | 以內照明蜂巢式反應器進行CO2光催化還原 | zh_TW |
| dc.title | CO2 photoreduction using internally illuminated monolith reactor | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 98-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 萬本儒(Ben-Zu Wan),白曛綾(Hsun-Ling Bai) | |
| dc.subject.keyword | 蜂巢狀反應器,銦鉭光觸媒, | zh_TW |
| dc.subject.keyword | Monolith reactor,InTaO4 photocatalyst, | en |
| dc.relation.page | 145 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2010-07-29 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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| ntu-99-1.pdf 未授權公開取用 | 12.77 MB | Adobe PDF |
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