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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 林清富(Ching-Fuh Lin) | |
| dc.contributor.author | Ding-shin Wang | en |
| dc.contributor.author | 王鼎鑫 | zh_TW |
| dc.date.accessioned | 2021-06-15T04:31:54Z | - |
| dc.date.available | 2019-11-25 | |
| dc.date.copyright | 2009-08-20 | |
| dc.date.issued | 2009 | |
| dc.date.submitted | 2009-08-19 | |
| dc.identifier.citation | [1] European Photovoltaic Industry Association，歐洲太陽光電協會
[2] 王啟川，劉興鑑，黃俊哲，奈米技術在電池上的應用，萬能生活化學學程 [3] K. Colladet, M. Nicolas, L. Goris, L. Lutsen, D. Vanderzande, “Low-band gap polymers for photovoltaic applications”, Thin Solid Films 451-452, P.P. 7-11, (2004). [4] Kenji Okumoto, Kenjiro Wayaku, Tetsuya Noda, Hiroshi Kageyama, Yashuhiko Shirota, ”Amorphous molecular materials: charge transport in the glassy state of N/N’ –di(biphenylyl) –N,N’ –diphenyl-[1,1’ -biphenyl] -4,4’ -diamines ”, Synthetic Metals ,111-112, p.p. 473-476 ,(2000). [5] A. J. Breeze, A. Salomon , D.S. Ginley, and B. A. Gregga ,“polymer-perylene diimide heterojunction solar cells ”, APPLIED PHYSICS LETTERS VOLUME, 81 , NUMBRT , 16 ,p.p. 3085-3087, (2002). [6] H. Neugebauer, C. Brabec, J.C. Hummelen, N.S. Sariciftci, “Stability and photo degradation mechanisms of conjugated polymer/fullerene plastic solar cells”, Solar Energy Materials & Solar Cells ,61,p.p. 35-42,(2000). [7] 韓建中教授，材化特論：Organic Electronics，國立清華大學化學系 [8] K. Kim, J. Liu, M. A. G. Namboothiry, D. L. Carroll, “Roles of donor and acceptor nanodomains in 6% efficient thermally annealed polymer photovoltaics”, Appl, Phys. Lett., 90, (2007) [9] 林彥勝教授，發光二極體 Light Emitting Diode, LED，義守大學電子工程學系 [1] 劉修宏，高效率高分子太陽能電池之研究，國立成功大學光電科學與工程研究所碩士論文 (2006) [2] 施敏教授，半導體元件物理與製作技術，交大出版社 [3] J. J. Dittmer, E. A. Marseglia, and R. H. Friend, “Trapping in dye/ polymer blend photovoltaic Cells,” Adv. Mater. 12(17), 1270-1274 (2000). [4] 韓建中教授，材化特論：Organic Electronics，國立清華大學化學系 [5] 石政言，利用元件後段處理與主動層有機溶劑改善有機太陽能電池之短路電流密度，國立東華大學電機工程學系碩士論文 (2005) [6] H. Kallmans , M. Pope, “Photovoltaic effect in organic crystals”, J. Chem Phys, 30, pp.585-586 (1958). [7] G.A. Chamberlain: Organic solar cells: A review. Solar Cells 8,47 (1983). [8] D. Wo¨hrle and D. Meissner: Organic solar cells. Adv. Mater. 3,129 (1991). [9] A. K. Ghosh, T.Fen, “Merocyanine organic solar cells”, J. Appl, Phys, 49, pp. 5982-5989 (1978). [10] A.K. Gosh, D.L. Morel, T. Feng, R.F. Shaw, and C.A. Rowe, Jr., ”Photovoltaic and rectification properties of Al/Mg phthalocyanine/Ag Schottky-barrier cells. “ J. Appl. Phys. 45, 230 (1974). [11] D. Meissner, S. Siebentritt, and S. Gu¨nster, ”Charge carrier photogeneration in organic solar cells”, presented at the International Symposium on Optical Materials Technology for Energy Efficiency and Solar Energy Conversion XI: Photovoltaics, Photochemistry and Photoelectrochemistry, Toulouse, France, 1992. [12] S. Karg, W. Riess, V. Dyakonov, and M. Schwoerer: Electrical and optical characterization of poly(phenylene-vinylene) light emitting diodes. Synth. Met. 54, 27 (1993). [13] D.L. Morel, A.K. Gosh, T. Feng, E.L. Stogryn, P.E. Purwin, R.F. Shaw, and C. Fishman: High-efficiency organic solar cells. Appl. Phys. Lett. 32, 495 (1978). [14] A.K. Gosh and T. Feng: Merocyanine organic solar cells. J. Appl. Phys. 49, 5982 (1978). [15] C.W. Tang: Two-layer organic photovoltaic cell. Appl. Phys. Lett. 48, 183 (1986). [16] J. Nelson, “Organic photovoltaic films,” Curr. Opin. Solid State Mater. Sci. 6, 87-95 (2002). [17] K. M. Coakley and M. D. McGehee, “Conjugated polymer photovoltaic cells,” Chem. Mater. 16, 4533-4542 (2004). [18] C. Y. Kwong, A. B. Djurisic, P. C. Chui, K. W. Cheng, W. K. Chan, “Influence of solvent on film morphology and device performance of poly(3-hexylthiophene):TiO2 nanocomposite solar cells”, Chem. Phys. Lett., 384, pp.372-375(2004) [19] W.J.E. Beek, Martijn, M. Wienk, A.J. Janssen, ”Hybrid polymer solar cell based on zinc oxide”, J. Mater. Chem., 15, pp.2985-2988(2005) [20] W.U. Huynh, J.J. Dittmer, A.P. Alivisatos, “Hybrid Nanorod-Polymer Solar Cells”, Science, 29, pp. 2425-2427(2002). [21] M. S. White, D. C. Olson, S. E. Shaheen, N. Kopidakis, and D. S. Ginley, “Inverted bulk-heterojunction organic photovoltaic device using a solution-derived ZnO underlayer”, Appl. Phys. Lett. 89, 143517 (2006). [22] V.D. Mihailetchi, P. W. M. Blom, J. C. Hummelenm, M. T. rispens, “Cathode dependence of the open-circuit voltage of polymer: fullerene bulk heterojunction solar cells”, J. Appl, Phys, 94, pp.6849-6854 (2003). [23] C.J. Brabec, A. Cravino, D. Meissner, N. S. Sariciftci, T. Fromherz, M. T. Rispens, L. Sanchez, J. C. Hummelen, ”Origin of the Open Circuit Voltage of Plastic Solar Cells”, Adv. Fun. Mater. ,11, pp.374-380 (2001). [24] 廖婉真，有機串聯太陽能電池之製程研究，國立清華大學電子工程研究所碩士論文 [25] S. R. Forrest, “The limits to organic photovoltaic cell efficiency,” MRS Bull. 30, 28-32 (2005). [26] C. Brabec, V. Dyakonov, J. Parisi, N. S. Sariciftci, “Organic Photovoltaics”, SPRINGER (2003). [27] S.R. Forrest, “The limits to organic photovoltaic cell efficiency”, Mrs Bull., 30, pp.28-32 (2005). [1] Haraguchi, K., Katsuyama, T., Hiruma, K. & Ogawa, K. GaAs p-n junction formed in quantum wire crystals. Appl. Phys. Lett. 60, 745–747 (1992). [2] Noborisaka J, Sato T, Motohisa J, Hara S, Tomioka K and Fukui,” Electrical Characterizations of InGaAs Nanowire-Top-Gate Field-Effect Transistors by Selective-Area Metal Organic Vapor Phase Epitaxy” T 2007 Japan. J. Appl. Phys. 46 7562 [3] Kim H M, Cho Y H, Lee H, Kim S I, Ryu S R, Kim D Y, Kang T W and Chung K S, “High-brightness light emitting diodes using dislocation-free indium gallium nitride/gallium nitride multiquantum-well nanorod arrays “ ,2004 Nano Lett. 4 1059 [4] R. S. Wagner and W. C. Ellis, ” Vapor-liquid-solid mechanism of single crystal growth”, Appl. Phys. Lett. 4(5), 89 (1964). [5] B.M. Kayes, M.A. Filler, M.C. Putnam, M.D. Kelzenberg, N.S. Lewis, H.A. Atwater,” Growth of vertically aligned Si wire arrays over large areas (>1 cm2) with Au and Cu catalysts”, Appl. Phys. Lett. 91 (2007) 103110. [6] Y. Arakawa, ” Fabrication of quantum wires and dots by MOCVD selective growth”, Solid State Electron 37, 523(1994). [7] A.M. Morales, C.M. Lieber , “A laser ablation method for the synthesis of semiconductor crystalline nanowires”, Science 279 (1998) 208 - 211. [8] Soo-Ghang Ihn , Jong-In Song , Young-Hun Kim , Jeong Yong Lee , and Il-Ho Ahn ,” Growth of GaAs Nanowires on Si Substrates Using a Molecular Beam Epitaxy” ,IEEE TRANSACTIONS ON NANOTECHNOLOGY , VOL. 6, NO. 3, 2007. [9] H. Yu and W. E. Buhro, “Solution-liquid-solid growth of soluble GaAs nanowires,” Adv. Mater. 15(5), 416-419 (2003). [10] Eih-Zhe Liang, Chao-Jei Huang, and Ching-Fuh Lin , “Use of SiO2 nanoparticles as etch mask to generate Si nanorods by reactive ion etch”, J. Vac. Sci. Technol. B 24(2),2006. [11] Shinya Maenosono, Tatsuya Okubo and Yukio Yamaguchi ,” Overview of nanoparticle array formation by wet coating” ,Journal of Nanoparticle Research 5: 5–15, 2003. [12] Young-Kyu Hong, Hanchul Kim, Geunseop Lee, and Wondong Kim ,” Controlled two-dimensional distribution of nanoparticles by spin-coating method” , Appl. Phys. Lett. 5, 80 (2002). [13] Fendler J.H.,” Self-assembled nanostructured materials.”, Chem. Mater. 8, 1616–1624(1996). [14] Shipway A.N., E. Katz & I. Willner,” Nanoparticle arrays on surfaces for electronic, optical, and sensor applications.” , ChemPhysChem 1, 18–52(2000). [15] Perez H., R.M.L. de Sousa, J.P. Pradeau & P.A. Albouy,” Elaboration and electrical characterization of Langmuir–Blodgett films of 4-mercaptoaniline functionalized platinum nanoparticles.”, Chem. Mater. 13, 1512–1517(2001). [16] Nakanishi T., B. Ohtani&K. Uosaki, “ Fabrication and characterization of CdS-nanoparticle mono- and multilayers on a self-assembled monolayer of alkanedithiols on gold”, J. Phys. Chem. B 102, 1571–1577 (1998). [17] Bakkers E.P.M.A., A.L. Roest, A.W. Marsman, L.W. Jenneskens, L.I. de Jong-van Steensel, J.J. Kelly & D. Vanmaekelbergh,” Characterization of photoinduced electron tunneling in gold/SAM/Q-CdSe systems by time-resolved photoelectron-chemistry”, J. Phys. Chem. B 104, 7266–7272(2000). [18] Cassagneau T., T.E. Mallouk & J.H. Fendler, “ Layer-bylayer assembly of thin film zener diodes from conducting polymers and CdSe nanoparticles”, J. Am. Chem. Soc. 120, 7848–7859(1998). [19] Shimomura M. & T. Sawadaishi, “ Bottom-up strategy of materials fabrication: A new trend in nanotechnology of soft materials”, Curr. Opin. Colloid Interface Sci. 6, 11–16(2001). [20] Teranishi T., M. Hosoe, T. Tanaka & M. Miyake, “ Size control of monodispersed Pt nanoparticles and their 2D organization by electrophoretic deposition”, J. Phys. Chem. B 103, 3818–3827(1999). [21] Hayward R.C., D.A. Saville & I.A. Aksay, “ Electrophoretic assembly of colloidal crystals with optically tunable micropatterns”, Nature 404, 56–59.(2000). [22] Denkov N.D., O.D. Velev, P.A. Kralchevsky, I.B. Ivanov, H. Yoshimura&K. Nagayama, “ Mechanism of formation of 2-dimensional crystals from latex-particles on substrates”, Langmuir 8, 3183–3190(1992). [23] Motte L., E. Lacaze, M. Maillard & M.P. Pileni, “ Self-assemblies of silver sulfide nanocrystals on various substrates”, Langmuir 16, 3803–3812(2000). [24] L. Tonks and I. Langmuir, “A general theory of the plasma of an arc,” Phys. Rev. 34, 876-922 (1929). [25] 林明哲教授，半導體製程第七章：電漿的基礎原理，義守大學機械與自動化工程學系 [26] M. A. Liberman and A. J. Lichtenberg, “Principles of Plasma Discharges and Materials Processing,” Wiley New York, 1994. [27] M. A. Liberman and A. J. Lichtenberg , “Principles of Plasma Discharges and Materials Processing,” Wiley New York, 1994. [28] Laurent Jalabert *, Pascal Dubreuil, Franck Carcenac, Se’bastien Pinaud, Ludovic Salvagnac, Hugues Granier, and Chantal Fontaine,” High aspect ratio GaAs nanowires made by ICP-RIE etching using Cl2/N2 chemistry” , Microelectronic Engineering 85 (2008) 1173–1178 [29] 黃昭睿，矽奈米結構與矽發光效率之關係研究，國立台灣大學光電工程學研 究所碩士論文，2004. [1] K. Kim, J. Liu, M. A. G. Namboothiry, D. L. Carroll, “Roles of donor and acceptor nanodomains in 6% efficient thermally annealed polymer photovoltaics”, Appl, Phys. Lett., 90, (2007) [2] C. Y. Kwong, A. B. Djurisic, P. C. Chui, K. W. Cheng, W. K. Chan, “Influence of solvent on film morphology and device performance of poly(3-hexylthiophene):TiO2 nanocomposite solar cells”, Chem. Phys. Lett., 384, pp.372-375(2004) [3] W.J.E. Beek, Martijn, M. Wienk, A.J. Janssen, ”Hybrid polymer solar cell based on zinc oxide”, J. Mater. Chem., 15, pp.2985-2988(2005) [4] W.U. Huynh, J.J. Dittmer, A.P. Alivisatos, “Hybrid Nanorod-Polymer Solar Cells”, Science, 29, pp. 2425-2427(2002). [5] K. Peng, Y. Xu, Y. Wu, Y. Yan, S. T. Lee, and J. Zhu, “Aligned single-crystalline Si nanowire arrays for photovoltaic application,” Small 1, 1062-1067 (2005). [6] L. Tsakalakos, J. Balch, J. Fronheiser, B. A. Korevaar, O. Sulima, and J. Rand, “Silicon nanowire solar cells,” Appl. Phys. Lett. 91, 233117 (2007). [7] A. P. Goodey, S. M. Eichfeld, K. K. Lew, J. M. Redwing, and T. E. Mallouk, “Silicon nanowire array photoelectrochemical cells,” J. Am. Chem. Soc. 129, 12344-12345 (2007). [8] Keitaro Ikejiri, Takuya Sato, Hiroatsu Yoshida, Kenji Hiruma, Junichi Motohisa, Shinjiroh Hara and Takashi Fukui,”Growth characteristics of GaAs nanowires obtained by selective area metal-organic vapour-phase epitaxy”, Nanotechnology 19, 265604 (2008) [9] Y. Saito, T. Kitamura, Y. Wada, and S. Yanagida, “Application of poly(3,4-ethylenedioxythiophene) to counter electrode in dye-sensitized solar cells,” Chem. Lett. 31(10), 1060-1061 (2002). [10] G. Li, V. Shrotriya, J. Huang, Y. Yao, T. Moriarty, K. Emery, and Y. Yang, “High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends,” Nat. Mater. 4, 864-868 (2005). [11] C. Kittel, “Introduction to Solid State Physics”, Chapter 11, John Wiley & Sons, New York (1996). [1] H.L. Hartnagel, A.L. Dawar, A.K. Jain, C. Jagadish, “Semiconducting Transparent Thin Films”, Institute of Physics Publishing, Bristol, 1995. [2] Jeong Chul Lee, Viresh Dutta, Jinsu Yoo, Junsin Yi, Jinsoo Song, Kyung Hoon Yoon, Superlattices and Microstructures 42,369-374 (2007). [3] Kenji Nomura, Hiromichi Ohta, Kazushige Ueda, Toshio Kamiya, Masahiro Hirano, Hideo Hosono, Science 300,1296 (2003). [4] T. Wangner, T. Waitz , J. Roggenbuck , M. Fröba , C.-D. Kohl, M. Tiemann, Thin Solid Films 515, 8360-8363 (2007). [5] Shih Min Chou, Lay Gaik Teoh, Wei Hao Lai, Yen Hsun Su and Min Hsiung Hon, Sensors 6, 1420-1427 (2006). [6] Lukas Schmidt-Mende, Judith L. MacMacnus-Driscoll, materialstoday 10, 40-48(2007). [7] Yu-Yun Peng, Tsung-Eong Hsieh and Chia-Hung Hsu, Nanotechnology 17, 174-180 (2006). [8] W. Tang, D. C. Cameron, Thin Solid Films 238,83(1994) [9] S. Muthukumar, C.R. Gorla, N.W. Emanetoglu, S. Liang, T. Lu, J. Cryst. Growth 225, 197(2001) [10] H. S. Randhawa, M.D. Matthews, R.F. Bunshan, Thin Solid Films 83,267 (1981) [11] W. Wenas, A. Yamada, K. Takahashi, “Electrical and optical properties of boron-doped ZnO thin films for solar cells grown by metalorganic chemical vapor deposition”, J. Appl. Phys. 70, pp. 7119(1991) [12] H. Kim, J. S. Horwitz, S. B. Qadri and D. B. Chrisey, ” Epitaxial growth of Al-doped ZnO thin films grown by pulsed laser deposition”, Thin Solid Films 420-421, pp.107-111(2002) [13] P. F. Carcia, R. S. McLean, M. H. Reilly, G. Nunes, Jr., “Transparent ZnO thin-film transistor fabricated by rf magnetron sputtering”, Appl. Phys. Lett. 82, pp.1117(2003) [14] Chen Tao, Shengping Ruan, Xindong Zhang, Guohua Xie, Liang Shen, Xiangzi Kong, Wei Dong, Caixia Liu, and Weiyou Chena, “Performance improvement of inverted polymer solar cells with different top electrodes by introducing a MoO3 buffer layer”, APPLIED PHYSICS LETTERS, 93, 193307 (2008) [15] A. K. K. Kyaw, X. W. Sun, C. Y. Jiang, G. Q. Lo, D. W. Zhao, and D. L. Kwong , “An inverted organic solar cell employing a sol-gel derived ZnO electron selective layer and thermal evaporated MoO3 hole selective layer”, APPLIED PHYSICS LETTERS 93, 221107 2008 [16] Ana M. Peiro´, Punniamoorthy Ravirajan, Kuveshni Govender, David S. Boyle, Paul O’Brien, Donal D. C. Bradley, Jenny Nelson and James R. Durrant , ” Hybrid polymer/metal oxide solar cells based on ZnO columnar structures”, J. Mater. Chem., 16, 2088-2096(2006) [17] Chen Tao, Shengping Ruan, Guohua Xie, Xiangzi Kong, Liang Shen, Fanxu Meng,Caixia Liu, Xindong Zhang, Wei Dong, and Weiyou Chen , “Role of tungsten oxide in inverted polymer solar cells”, APPLIED PHYSICS LETTERS 94, 043311 (2009) [18] Jin Young Kim, Sun Hee Kim, Hyun-Ho Lee, Kwanghee Lee,* Wanli Ma, Xiong Gong, and Alan J. Heeger, “New Architecture for High-Efficiency Polymer Photovoltaic Cells Using Solution-Based Titanium Oxide as an Optical Spacer”, Advanced Materials, 18, 572-576 (2006) [19] Michael D. Irwin, D. Bruce Buchholz, Alexander W. Hains, Robert P. H. hang, and Tobin J. Marks, “P-Type Semiconducting Nickel Oxide as an Efficiency-Enhancing Anode Interfacial Layer in Polymer Bulk-Heterojunction Solar Cells” PNAS , vol. 105 (2008) 2783-2787 [20] G. Li, V. Shrotriya, J. Huang, Y. Yao, T. Moriarty, K. Emery, and Y. Yang, “High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends,” Nat. Mater. 4, 864-868 (2005). [21] Salima Alem, Remi De Bettignies, Michel Cariou, Emmanuel Allard, Stephanie Chopin, Jack Cousseau, Sylvie Dabos-Seignon, Jean-Michel Nunzi, ”Realization and characterization of plastic photovoltaic cells”, Proceedings of SPIE, 5351, 284-290 (2004) [22] J. V. Manca , T. Munters, T. Martens, Z. Beelen , L. Goris, J. D’Haen, M. D’olieslaeger, L. Lutsen, D. Vanderzande, L. De Schepper, K. Haenen, M. Nesladek, W. Geens, J. Poortmans, R. Andriessen,”State-of-the-art MDMO-PPV:PCBM bulk hetero-junction organic solar cells: materials, nano-morphology and electro-optical properties” , Proceedings of SPIE, 4801, 15-20 (2003) [23] Abay Gadisa, Fengling Zhang, Deepak Sharma, Mattias Svensson, Mats R. Andersson and Olle Inganas,”Improvements of fill factor in solar cells based on blends of polyfluorene copolymers as electron donors”, Thin Solid Films, 515, 3126-3131 (2007) | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/45637 | - |
| dc.description.abstract | 本論文的研究主要在於有機無機混成的太陽能電池製備。在本篇論文的第一部分當中，我們以乾式蝕刻的方式來製作砷化鎵奈米線。而砷化鎵奈米線是以感應耦合式電漿蝕刻來製備，並利用二氧化矽奈米粒子鋪在砷化鎵基板上形成單層遮罩以進行蝕刻。為了在砷化鎵基板上均勻地形成單層遮罩，使用的溶液濃度、溫度以及對砷化鎵基板的介面活性劑處理是很重要的。有了在砷化鎵基板上形成的單層遮罩，我們利用感應耦合式電漿蝕刻來製作出高選擇比的砷化鎵奈米線。由於我們利用旋塗的技術取代耗時且昂貴的電子顯影技術來製作蝕刻遮罩，所以我們可以蝕刻出大面積的砷化鎵奈米線。而且砷化鎵奈米線的長度以及直徑，可以藉由蝕刻的時間和二氧化矽奈米粒子的大小來控制。接著藉由特殊的轉移方法，將砷化鎵奈米線轉移到P3HT:PCBM所覆蓋的玻璃基板，製作成排列整齊砷化鎵奈米線混成太陽能電池。
於本篇論文的第二部分，我們利用溶液製程的方式取代熱蒸鍍，將金屬氧化物氧化鎳（稱作電子阻擋層/電動傳輸層）旋轉塗佈在有機層上面，利用其較高的最低分子未佔據軌域，來阻擋電子直接傳輸到陽極，與收集到陽極的電洞進行復合，減少元件的漏電流產生增加元件的填充因子，進而提升反向結構的氧化鋅半導體與有機高分子混成之太陽能電池效率。我們的結果展示利用氧化鎳大大增加了並聯電阻，並聯電阻從502 W-cm2增加到632 W-cm2有效地抑制了漏電流，提升元件的短路電流以及填充因子，填充因子從53 %增加到59 %，使得太陽能電池效率有所提升，光電轉換效率從3.3 %增加到3.8 %。除此之外，在有機層上面旋轉塗佈氧化鎳，元件的光電轉換效率在第六天達到最大值3.8 %，其在大氣下的穩定性相當得不錯，經過60天後的效率仍然有2.91%。 | zh_TW |
| dc.description.abstract | In this study, we focus on fabrications of organic polymer/Inorganic semiconductor hybrid solar cells. In the first part of the work, large-area GaAs nanowires are fabricated using SiO2 nanoparticles monolayer as the etching mask. SiO2 nanoparticles monolayer is spin-coated on the GaAs substrate. To obtain a uniform monolayer of SiO2 nanoparticles across the substrate, raised temperature, adequate solution concentration, and the substrate treated with a solvent for interface activation are required. With the monolayer of SiO2 nanoparticles as the etching mask, the GaAs substrate is etched by Induced-Coupled Plasma Reactive Ion Etcher to form GaAs nanowires with a high aspect ratio. The diameter and length of GaAs nanowires can be controlled by the size of SiO2 nanoparticles and etching time of ICP-RIE. Then, we transferred GaAs nanowires onto the glass substrate with the P3HT:PCBM. We combined GaAs nanowires with P3HT:PCBM to fabricate conjugated polymer-based organic solar cells.
In the second part of the work, we used solution process to replace deposition to spin NiO layer on polymer. NiO layer acts as an interfacial electron-blocking layer/hole-transporting layer (EBL/HTL). Utilizing its higher LUMO (lowest unoccupied molecular orbital) could block electron leakage to anode to recombine with hole. The leakage current is reduced to improve the power conversion efficiency of inverted structure with organic polymer/ZnO semiconductor hybrid solar cells. Our investigations show that utilizing NiO as an interfacial layer increases the shunt resistance from 502 W-cm2 to 632 W-cm2 , the filling factor from 53 % to 59 % , and the power conversion efficiency from 3.3% to 3.8%. Besides, the stability in the air of cells with NiO film has good performance. After 60 days, the power conversion efficiency of the cell reaches constant with 2.91%. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T04:31:54Z (GMT). No. of bitstreams: 1 ntu-98-R96941067-1.pdf: 3799655 bytes, checksum: 7f7ea0e6e7bda6733da6786f99fa7fad (MD5) Previous issue date: 2009 | en |
| dc.description.tableofcontents | 致謝……………………………………………………………………...........III
摘要…………………………………………………………………………...IV Abstract………………………………………………………………………...V 目錄…………………………………………………………………………………VII 圖目錄………………………………………………………………………...IX 表目錄………………………………………………………………………XIII 第一章 緒論………………………………………………………………...1 1-1 前言…………………………………………………………………1 1-2 有機太陽能電池元件的發展……………………………………....4 1-3 研究動機……………………………………………………………6 1-4 論文導覽……………………………………………………………8 1-5 參考資料……………………………………………………………9 第二章 有機太陽能電池的基本原理與結構探討……………………….10 2-1 概述………………………………………………………………..10 2-2 有機太陽能電池之基本原理……………………………………..12 2-3 有機太陽能電池結構探討………………………………………..16 2-3-1 單層結構………………………………………………...16 2-3-2 雙層異質接面結構……………………………………...17 2-3-3 混摻異質接面結構……………………………………...18 2-3-4 有序本體異質結構……………………………………...19 2-3-5 傳統正向結構與反向結構……………………………...20 2-4 有機太陽能電池特性分析………………………………………..22 2-4-1 開路電壓分析…………………………………………...22 2-4-2 短路電流分析…………………………………………...23 2-4-3 填充因子分析…………………………………………...25 2-4-4 光電轉換效率分析……………………………………...27 2-5 參考資料…………………………………………………………..28 第三章 砷化鎵奈米線的製備與研究…………………………………….31 3-1 砷化鎵奈米線之簡介……………………………………………..31 3-2 形成單層奈米粒子陣列之簡介…………………………………..33 3-3 砷化鎵奈米線的製備……………………………………………..34 3-3-1 蝕刻機制介紹……………………………………………34 3-3-2 電漿和感應耦合式電漿介紹……………………………35 3-3-3 感應耦合式電漿蝕刻的機制簡介……………………….36 3-3-4 單層二氧化矽奈米粒子蝕刻遮罩的製備……………….40 3-3-5 砷化鎵奈米線的製備和討論…………………………….48 3-4 結論…………………………………………………………………53 3-5 參考資料……………………………………………………………54 第四章 結合砷化鎵奈米線的正向結構有機太陽能電池……………….58 4-1 簡介………………………………………………………………..58 4-2 實驗過程…………………………………………………………..60 4-3 電壓電流特性曲線分析…………………………………………..66 4-4 結論………………………………………………………………..74 4-5 參考資料…………………………………………………………..76 第五章 利用電子阻擋層提高反向結構之有機太陽能電池的效率…….78 5-1 氧化鋅簡介………………………………………………………..78 5-2 電子阻擋層………………………………………………………..80 5-2-1 電子阻擋層簡介………………………………………...80 5-2-2 文獻回顧………………………………………………...81 5-2-3 研究動機………………………………………………...84 5-3 加入電子阻擋層NiO之反向結構的有機太陽能電池……….....86 5-3-1 實驗步驟………………………………………………...86 5-3-2 實驗結果………………………………………………...88 5-4 加入電子阻擋層NiO之反向結構的PV2000太陽能電池……..97 5-4-1 實驗步驟………………………………………………...97 5-4-2 實驗結果……………………………………………….100 5-5 結論………………………………………………………………108 5-6 參考資料…………………………………………………………109 第六章 總結……………………………………………………………...112 6-1 論文回顧…………………………………………………………112 6-2 未來展望…………………………………………………………114 | |
| dc.language.iso | zh-TW | |
| dc.subject | 高分子 | zh_TW |
| dc.subject | 砷化鎵奈米線 | zh_TW |
| dc.subject | 二氧化矽奈米粒子 | zh_TW |
| dc.subject | 混成太陽能電池 | zh_TW |
| dc.subject | 本體異質結構 | zh_TW |
| dc.subject | 電子阻擋層 | zh_TW |
| dc.subject | electron blocking layer | en |
| dc.subject | SiO2 nanoparticles | en |
| dc.subject | gallium arsenide nanowire | en |
| dc.subject | polymer | en |
| dc.subject | hybrid solar cells | en |
| dc.subject | bulk heterojunction structure | en |
| dc.title | 有機高分子與無機半導體混合式太陽能電池的製備 | zh_TW |
| dc.title | Fabrications of Organic Polymer/Inorganic Semiconductor Hybrid Solar Cells | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 97-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 羅禮強(Lee-Chiang Lo),蘇國棟(Guo-Dung Su),何志浩(Jr-Hau He) | |
| dc.subject.keyword | 砷化鎵奈米線,二氧化矽奈米粒子,高分子,混成太陽能電池,本體異質結構,電子阻擋層, | zh_TW |
| dc.subject.keyword | gallium arsenide nanowire,SiO2 nanoparticles,polymer,hybrid solar cells,bulk heterojunction structure,electron blocking layer, | en |
| dc.relation.page | 115 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2009-08-19 | |
| dc.contributor.author-college | 電機資訊學院 | zh_TW |
| dc.contributor.author-dept | 光電工程學研究所 | zh_TW |
| 顯示於系所單位： | 光電工程學研究所 | |
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