請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/45304
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 王大銘(Da-Ming Wang) | |
dc.contributor.author | Se-Tsung Kao | en |
dc.contributor.author | 高瑟聰 | zh_TW |
dc.date.accessioned | 2021-06-15T04:13:19Z | - |
dc.date.available | 2015-02-04 | |
dc.date.copyright | 2010-02-04 | |
dc.date.issued | 2010 | |
dc.date.submitted | 2010-01-21 | |
dc.identifier.citation | 1. M. H. V. Mulder, Basic Principles of Membrane Technology, Kluwer Academic Publishers, The Netherlands (1996)
2. S. T. Hwang, K. Kammermeyer, Membrane in separation, John Wiley Sons, New York (1975) 3. R. W. Baker, Membrane technology and applications, McGraw Hill companies, Inc. (2004) 4. R. Y. M. Huang, R. Pal, G. Y. Moon, Pervaporation dehydration of aqueous ethanol and isopropanol mixtures through alginate/chitosan two ply composite membranes supported by poly(vinylidene fluoride) porous membrane, J. Membr. Sci. 167 (2000) 275-289 5. M. Y. Teng, K. R. Lee, D. J. Liaw, J. Y. Lai, Preparation and pervaporation performance of poly(3-alkylthiophene) membrane, Polymer 41 (2000) 2047-2052 6. R. W. Baker, Euromembrane 97, Twente, The Netherlands (1997) 7. P. M. Bungy, H. K. Lonsdale, M. N. d. Pinho, Synthetic membranes: science, engineering and applications, D. Reidel, Dordrecht/Boston /Lancaster/Tokyo (1986) 8. 李魁然, 滲透蒸發薄膜硏究 : 成膜與改質, 中原大學博士論文 (1993) 9. C. D. Jones, M. Fidalgo, M. R. Wiesner, A. R. Barron, Alumina ultrafiltration membranes derived from carboxylate-alumoxane nanoparticles, J. Membr. Sci. 193 (2001) 175-184 10. T. V. Gestel, C. Vandecasteele, A. Buekenhoudt, C. Dotremont, J. Luyten, R. Leysen, B. V. d. Bruggen, G. Maes, Salt retention in nanofiltration with multiplayer ceramic TiO2 membranes, J. Membr. Sci. 209 (2002) 379-389 11. H. Strathmann, K. Kock, The formation mechanism of phase inversion membrane, Desalination 21 (1977) 241-255 12. R. E. Kesting, Synthetic polymeric membrane, John Wiley, New York (1985) 13. M. Kurata, Thermodynamics of polymer solutions, Harwood Academic, London (1982) 14. P. Vandeweerdt, H. Berghmans, Temperature-concentration behavior of solution polydisperse, atactic poly(methyl methacrylate) and its influence on the formation of amorphous microporous membranes, Macromolecules 24 (1991) 3547-3552 15. F. J. Hua, T. G. Park, D. S. Lee, A facile preparation of highly interconnected macroporous poly(D,L-lactic acid-co-glycolic acid) (PLGA) scaffolds by liquid-liquid phase separation of a PLGA-Dioxane-Water ternary system, Polymer 44 (2003) 1911-1920 16. L. Zeman, T. Fraser, Formation of air-cast cellulose acetate membranes, part II. kinetic of demixing and macrovoid growth, J. Membr. Sci. 87 (1993) 267-279 17. Y. C. Wang, C. L. Li, J. Huang, C. Lin, K. R. Lee, D. J. Liaw, J. Y. Lai, Pervaporation of benzene/cyclohexane mixtures through aromatic polyamide membranes, J. Membr. Sci. 185 (2001) 193-200 18. H. D. W. Roesink, Ph.D. Thesis, University of Twente (1989) 19. A. F. M. Leenaars, Ph.D. Thesis, University of Twente (1984) 20. D. M. Wang, T. T. Wu, F. C. Lin, J. Y. Hou, J. Y. Lai, A novel method for controlling the surface morphology of polymeric membranes, J. Membr. Sci. 169 (2000) 39-51 21. H. Matsuyama, M. Tachibana, T. Maki, M. Teramoto, Light scattering study on porous membrane formation by dry cast process, J. Appl. Polym. Sci. 86 (2002) 3205-3209 22. R. Zsigmondy, W. Bachmann, Filter and method of producing same, US Patent 1,421,341 (1922) 23. J. Y. Lai, M. J. Liu, K. R. Lee, Polycarbonate membrane prepared via a wet phase inversion method for oxygen enrichment from air, J. Membr. Sci. 86 (1994) 103-118 24. F. C. Lin, D. M. Wang, J. Y. Lai, Asymmetric TPX membranes with high gas flux, J. Membr. Sci. 110 (1996) 25-36 25. S. L. Huang, M. S. Chao, J. Y. Lai, Diffusion of ethanol and water through PU membrane, Eur. Polym. J. 34 (1998) 449-454 26. 蔡惠安, 添加劑對Polysulfone非對稱性薄膜型態與滲透蒸發之影響---平板膜與管狀膜, 中原大學博士論文 (2002) 27. F. W. Altena, C. A. Smolders, Calculation of liquid-liquid phase separation in a ternary system of a polymer in a mixture of a solvent and a nonsolvent, Macromolecules 15 (1982) 1491-1497 28. R. M. Boom, T. V. Boomgaard, C. A. Smolders, Mass transfer and thermodynamics during immersion precipitation for two-polymer system:evaluation with the system PES-PVP-NMP-water, J. Membr. Sci. 90 (1994) 231-249 29. H. Wood, S. Sourirajan, The effect of additives, solvent type, and polymer concentration on macromolecule dimensions, J. Appl. Polym. Sci. 43 (1991) 213-217 30. H. Tompa, Polymer solutions, Butterworths, London (1956) 31. P. J. Flory, Principles of polymer chemistry, Cornell University Press. New York (1953) 32. K. Kamide, Thermodynamics of polymer solutions, Elsevier Science Publishers B. V., Amsterdam, The Netherlands (1990) 33. J. K. Kim, Y. D. Kim, T. Kanamori, H. K. Lee, K. J. Balk, Vitrification phenomena in polysulfone/NMP/water system, J. Appl. Polym. Sci. 71 (1999) 431-438 34. J. Y. Lai, S. F. Lin, F. C. Lin, D. M. Wang, Constructure of ternary phase diagrams in nonsolvent/solvent/PMMA systems, J. Polym. Sci., Part B: Polym. Phys. 36 (1998) 607-615 35. J. Y. Kim, H. K. Lee, K. J. Bank, S. C. Kim, Liquid-liquid phase separation in polysulfone/solvent/water systems, J. Appl. Polym. Sci. 65 (1997) 2643-2653 36. R. J. Ray, W. B. Krantz, R. L. Sani, Linear stability theory model for finger formation in asymmetric membranes, J. Membr. Sci. 23 (1985) 155-182 37. C. A. Smolders, A. J. Reuvers, R. M. Boom, I. M. Wienk, Microstructure in phase-inversion membranes. Part 1:Formation of macrovoids, J. Membr. Sci. 73 (1992) 259-275 38. S. P. Nunes, T. Inoue, Evidence for spinodal decomposition and nucleation and growth mechanisms during membrane formation, J. Membr. Sci. 111 (1996) 93-103 39. A. J. Reuvers, Membrane formation:diffusion induced demixing processes in ternary systems, Ph.D. Thesis, Twente University of Technology, The Netherlands (1987) 40. C. A. Yao, R. P. Bruford, A. G. Fane, C. J. D. Fell, Effect of coagulant conditions on structure and properties of membrane from aliphatic polyamides, J. Membr. Sci. 38 (1988) 113-125 41. Y. S. Kang, H. J. Kim, U. Y. Kim, Asymmetric membrane formation via immersion precipitation method. I. Kinetic effect, J. Membr. Sci. 60 (1991) 219-232 42. D. A. Skoog, J. J. Leary, Principles of instrmnetal analysis, USA (1971) 43. T. Ribar, R. Bhargave, J. L. Koenig, FT-IR image of polymer dissolution by solvent mixtures. 1. solvents, Macromolecules 33 (2000) 8842-8849 44. M. Schleiffelder, C. S. Bickel, Crosslinkable copolyimides for the membrane-based separation of p-/o-xylene mixtures, React. Funct. Polym. 49 (2001) 205-213 45. J. P. G. Villaluenga, A. T. Mohammadi, A review on the separation of benzene/cyclohexane mixtures by pervaporation processes, J. Membr. Sci. 169 (2000) 159-174 46. A. Shepherd, A. C. Habert, C. P. Borges, Hollow fibre modules for orange juice aroma recovery using pervaporation, Desalination 148 (2002) 111-114 47. P. A. Kober, Pervaporation, perstillation and percrystallization, J. Am. Chem. Soc. 39 (1917) 944-948 48. R. C. Binning, F. E. James, Now separate by membrane permeation, Petroleum Refiner 37 (1958) 214-215 49. R. C. Binning, J. F. Jennings, E. C. Martin, Removal of water from organic chemicals, U.S. Patent 3,035,060 (1962) 50. W. F. Strazik, E. Perry, Process for the separation of styrene from ethyl benzene, U.S. Patent 3,776,970 and U.S. Patent 4,067,805;4,218,312 51. J. Kaschemekat, B. Barbknecht, K. W. Böddeker, Concentration of ethanol by pervaporation, Chem. Ing. Tech. 58 (1986) 740-742 52. J. G. Wijmans, R. W. Baker, The Solution-diffusion model: a review, J. Membr. Sci. 107 (1995) 1-21 53. T. Okada, T. Matsuura, A new transport model for pervaporation, J. Membr. Sci. 59 (1991) 133-150 54. T. Okada, T. Matsuura, Predictability of transport-equations for pervaporation on the basis of pore-flow mechanism, J. Membr. Sci. 70 (1992) 163-175 55. T. Okada, M. Yoshikawa, T. Matsuura, A study on the pervaporation of ethanol/water mixtures on the basis of pore flow model, J. Membr. Sci. 59 (1991) 151-168 56. A. Jonquières, R. Clément, P. Lochon, J. Néel, M. Dresch, B. Chrétien, Industrial state-of-the art of pervaporation and vapour permeation in the western countries, J. Membr. Sci. 206 (2002) 87-117 57. A. Mochizuki, Y. Sato, H. Ogawara, S. Yamashita, Pervaporation separation of water/ethanol mixtures through polysaccharide membranes: The permselectivity of chitosan membrane, J. Appl. Polym. Sci. 37 (1989) 3375-3384 58. X. P. Wang, Z. Q. Shen, F. Y. Zhang, Y. F. Zhang, Preferential separation of ethanol from aqueous solution through hydrophilic polymer membranes, J. Appl. Polym. Sci. 73 (1999) 1145-1151 59. X. Chen, W. Li, Z. Shao, W. Zhong, T. Yu, Separation of alcohol-water mixture by pervaporation through a novel natural polymer blend membrane-chitosan/silk fibroin blend membrane, J. Appl. Polym. Sci. 73 (1999) 975-980 60. L. Zhang, J. Guo, J. Zhou, G. Yang, Y. Du, Blend membranes from carboxymethylated chitosan/alginate in aqueous solution, J. Appl. Polym. Sci. 77 (2000) 610-616 61. A. Mochizuki, S. Amyia, Y. Sato, H. Ogawara, S. Yamashita, Pervaporation separation of water/ethanol mixtures through polysaccharide membranes. III. The permselectivity of the neutralized chitosan membrane and the relationships between its permselectivity and solid state structure, J. Appl. Polym. Sci. 37 (1989) 3385-3398 62. J. J. Shieh, R. Y. M. Huang, Pervaporation with chitosan membranes II. blend membranes of chitosan and polyacrylic acid and comparison of homogeneous and composite membrane base on polyelectrolyte complexes of chitosan and polyacrylic acid for the separation ethanol-water mixtures, J. Membr. Sci. 127 (1997) 185-202 63. K. Richau, H. H. Schwarz, R. Apostel, D. Paul, Dehydration of organics by pervaporation with polyelectrolyte complex membranes: some considerations concerning separation mechanism, J. Membr. Sci. 113 (1996) 31-41 64. Y. M. Lee, S. Y. Nam, D. J. Woo, Pervaporation of ionically surface crosslinked chitosan composites membranes for water-alcohol mixtures, J. Membr. Sci. 133 (1997) 103-110 65. A. Chanachai, R. Jiraratananon, D. Uttapap, G. Y. Moon, W. A. Anderson, R. Y. M. Huang, Pervaporation with chitosan/ hydroxyethylcellulose (CS/HEC) blended membranes, J. Membr. Sci. 166 (2000) 271-280 66. T. Hirotsu, K. Ichimura, K. Mizoguchi, E. Nakamura, Water-ethanol permseparation by pervaporation through photocrosslinked poly(vinyl alcohol) composite membranes, J. Appl. Polym. Sci. 36 (1988) 1717-1729 67. A. Yamasaki, K. Mizoguchi, Preparation of PVA membranes containing b-cyclodextrin oligomer (PVA/CD membrane) and their pervaporation characteristics for ethanol/water mixtures, J. Appl. Polym. Sci. 51 (1994) 2057-2062 68. W. Y. Chiang, C. M. Hu, Separation of liquid mixtures by using polymer membranes. I. Water-alcohol separation by pervaporation through PVA-g-MMA/MA membrane, J. Appl. Polym. Sci. 43 (1991) 2005-2012 69. C. K. Yeom, K. H. Lee, Characterization of sodium alginate and poly (vinyl alcohol) blend membranes in pervaporation separation, J. Appl. Polym. Sci. 67 (1998) 949-959 70. C. K. Yeom, K. H. Lee, Characterization of sodium alginate membrane crosslinked with glutaraldehyde in pervaporation separation, J. Appl. Polym. Sci. 67 (1998) 209-219 71. J. W. Rhim, C. K. Yeom, S. W. Kim, Modification of poly( vinyl alcohol) membranes using sulfur-succinic acid and its application to pervaporation separation of water-alcohol mixtures, J. Appl. Polym. Sci. 68 (1998) 1717-1723 72. Y. F. Xu, R. Y. M. Huang, Pervaporation separation of ethanol-water mixtures using ionically crosslinked blended polyacrylic acid (PAA)-nylon 6 membranes, J. Appl. Polym. Sci. 36 (1988) 1121-1128 73. A. Mochizuki, Y. Sato, H. Ogawara, S. Yamashita, Pervaporation separation of water/ethanol mixtures through polysaccharide membranes. I. The effects of salts on the permselectivity of cellulose membrane in pervaporation, J. Appl. Polym. Sci. 37 (1989) 3357-3374 74. K. M. Song, W. H. Hong, Dehydration of ethanol and isopropanol using tubular type cellulose acetate membranes with ceramic support in pervaporation process, J. Membr. Sci. 123 (1997) 27-33 75. C. S. Hsu, R. M. Liou, S. H. Chen, M. Y. Hung, H. A. Tsia, J. Y. Lai, Pervaporation separation of a water-ethanol mixture by PSF-PEG membrane, J. Appl. Polym. Sci. 87 (2003) 2158-2164 76. X. P. Wang, Preparation of crosslinked alginate composite membrane for dehydration of ethanol-water mixtures, J. Appl. Polym. Sci. 77 (2000) 3054-3061 77. M. Yoshikawa, K. Masaki, M. Ishikawa, Pervaporation separation of aqueous organic mixtures through agarose membranes, J. Membr. Sci. 205 (2002) 293-300 78. M. Yoshikawa, T. Yukoshi, K. Sanui, N. Ogata, Selective separation of water from water-ethanol solution through quarternized poly(4-vinylpyridine-co-acrylonitrile) membranes by pervaporation technique, J. Appl. Polym. Sci. 33 (1987) 2369-2392 79. S. H. Chen, K. C. Yu, S. S. Lin, D. J. Chang, R. M. Liou, Pervaporation separation of water/ethanol mixture by sulfonated polysulfone membrane, J. Membr. Sci. 183 (2001) 29-36 80. S. H. Chen, R. M. Liou, C. S. Hsu, D. J. Chang, C. Y. Chang, Pervaporation separation water/ethanol mixture through lithiated polysulfone membrane, J. Membr. Sci. 193 (2001) 59-67 81. F. Lipnizki, R. W. Field, P. K. Ten, Pervaporation-based hybrid process: a review of process design, applications and economics, J. Membr. Sci. 153 (1999) 183-210 82. A. H. Ballweg, H. E. A. Brüschke, W. H. Schneider, G. F. Tüsel, K. W. Böddeker, Pervaporation Membrane, in Proceeding of 5th international alcohol fuel technology symposium, Auckland New Zesland, May (1982) 83. H. E. A. Brüschke, State of Art of pervaporation, in Proceeding of 3th international Conference on pervaporation processes in the Chemical Industry, France, Sep. 1988 84. W. J. WARDIII, W. R. Browall, R. M. Salemme, Ultrathin Silicone Rubber Membranes for Gas Separations, J. Membr. Sci. 1 (1976) 99-108 85. S. Sommer, T. Melin, Design and Optimization of Hybrid Separation Processes for the Dehydration of 2-Propanol and Other Organics, Ind. Eng. Chem. Res. 43 (2004) 5248-5259 86. Y. L. Liu, C. H. Yu, K. R. Lee, J. Y. Lai, Chitosan/poly(tetrafluoroethylene) composite membranes using in pervaporation dehydration processes, J. Membr. Sci. 287 (2007) 230-236 87. Y. L. Liu, Y. H. Su, K. R. Lee, J. Y. Lai, Crosslinked organic–inorganic hybrid chitosan membranes for pervaporation dehydration of isopropanol–water mixtures with a long-term stability, J. Membr. Sci. 251 (2005) 233-238 88. R. Y. M. Huang, R. Pal, G. Y. Moon, Crosslinked chitosan composite membrane for the pervaporation dehydration of alcohol mixtures and enhancement of structural stability of chitosan/polysulfone composite membranes, J. Membr. Sci. 160 (1999) 17-30 89. M. G. M. Nawawi, R. Y. M. Huang, Pervaporation dehydration of isopropanol with chitosan memnbrane, J. Membr. Sci. 124 (1997) 53-62 90. G. Y. Moon, R. Pal, R. Y. M. Huang, Novel two-ply composite membranes of chitosan and sodium alginate for the pervaporation dehydration of isopropanol and ethanol, J. Membr. Sci. 156 (1999) 17-27 91. C. Y. Tu, Y. L. Liu, K. R. Lee, J. Y. Lai, Hydrophilic surface-grafted poly(tetrafluoroethylene) membranes using in pervaporation dehydration processes, J. Membr. Sci. 274 (2006) 47-55 92. Q. Zhao, J. Qian, Q. An, Z. Gui, H. Jin, M. Yin, Pervaporation dehydration of isopropanol using homogeneous polyelectrolyte complex membranes of poly(diallyldimethylammonium chloride)/sodium carboxymethyl cellulose, J. Membr. Sci. 329 (2009) 175-182 93. A. A. Kittur, S. S. Kulkarni, M. I. Aralaguppi, M. Y. Kariduraganavar, Preparation and characterization of novel pervaporation membranes for the separation of water–isopropanol mixtures using chitosan and NaY zeolite, J. Membr. Sci. 247 (2005) 75-86 94. M. C. Burshe, S. A. Netke, S. B. Sawant, J. B. Joshi, V. G. Pangarkar, Pervaporative Dehydration of Organic Solvents, Sep. Sci. Technol. 32 (1997) 1335-1349 95. A. Svang-Ariyaskul, R. Y. M. Huang, P. L. Douglas, R. Pal, X. Feng, P. Chen, L. Liu, Blended chitosan and polyvinyl alcohol membranes for the pervaporation dehydration of isopropanol, J. Membr. Sci. 280 (2006) 815-823 96. X. Qiao, T. S. Chung, W. F. Guo, T. Matsuura, M. M. Teoh, Dehydration of isopropanol and its comparison with dehydration of butanol isomers from thermodynamic and molecular aspects, J. Membr. Sci. 252 (2005) 37-49 97. F. Peng, J. Liu, J. Li, Analysis of the gas transport performance through PDMS/PS composite membranes using the resistances-in-series model, J. Membr. Sci. 222 (2003) 225–234 98. L. P. Cheng, D. J. Lin, C. H. Shih, A. H. Dwan, C. C. Gryte, PVDF Membrane Formation by Diffusion-Induced Phase Separation-Morphology Prediction Based on Phase Behavior and Mass Transfer Modeling, J. Polym. Sci., Part B: Polym. Phys. 37 (1999) 2079–2092 99. T. H. Young, L. P. Cheng, D. J. Lin, L. Fane, W. Y. Chuang, Mechanisms of PVDF membrane formation by immersion-precipitation in soft (1-octanol) and harsh (water) nonsolvents, Polymer 40 (1999) 5315–5323 100. X. Wang, L. Zhang, D. Sun, Q. An, H. Chen, Formation mechanism and crystallization of poly(vinylidene fluoride) membrane via immersion precipitation method, Desalination 236 (2009) 170–178 101. S. Bonyadi, T. S. Chung, Highly porous and macrovoid-free PVDF hollow fiber membranes for membrane distillation by a solvent-dope solution co-extrusion approach, Journal of Membrane Science 331 (2009) 66–74 102. C. Y. Kuo, S. L. Su, H. A. Tsai, Y. S. Su, D. MingWang, J. Y. Lai, Formation and evolution of a bicontinuous structure of PMMA membrane during wet immersion process, Journal of Membrane Science 315 (2008) 187–194 103. 邱昭諭, 醋酸纖維酯複合膜材之支撑層結構設計與滲透蒸發效能硏究, 中原大學化學工程學系碩士學位論文 (2007) 104. C. Y. Kuo, H. N. Lin, H. A. Tsai, D. M. Wang, J. Y. Lai, Fabrication of a high hydrophobic PVDF membrane via nonsolvent induced phase separation, Desalination 233 (2008) 40–47 105. 郭純因, 非溶劑誘導相分離製備具雙連續結構微孔膜及其成膜機制之研究, 中原大學化學工程學系博士學位論文 (2008) 106. H. A. Tsai, W. H. Chen, C. Y. Kuo, K. R. Lee, J. Y. Lai, Study on the pervaporation performance and long-term stability of aqueous iso-propanol solution through chitosan/polyacrylonitrile hollow fiber membrane, Journal of Membrane Science 309 (2008) 146–155 107. H. A. Tsai, H. C. Chen, W. L. Chou, K. R. Lee, M. C. Yang, J. Y. Lai, Pervaporation of Water/Alcohol Mixtures Through Chitosan/Cellulose Acetate Composite Hollow-Fiber Membranes, Journal of Applied Polymer Science 94 (2004) 1562–1568 108. 馬良智, 聚偏二氟乙烯中空纖維膜之結構設計研究, 中原大學化學工程學系碩士學位論文 (2007) 109. M. M. Meier, L. A. Kanis, V. Soldi, Characterization and drug-permeation profiles of microporous and dense cellulose acetate membranes: influence of plasticizer and pore forming agent, International Journal of Pharmaceutics 278 (2004) 99–110 110. K. Y. Wang, T. S. Chung, M. Gryta, Hydrophobic PVDF hollowfiber membranes with narrowpore size distribution and ultra-thin skin for the freshwater production through membrane distillation, Chemical Engineering Science 63 (2008) 2587-2594 111. Y. C. Jean, P. E. Mallon, D. M. Schrader, Principles and Applications of Position and positronium chemistry, World Scientific, Singapore (2003) 112. H. Chen, W. S. Hung, C. H. Lo, S. H. Huang, M. L. Cheng, G. Liu, K. R. Lee, J. Y. Lai, Y. M. Sun, C. C. Hu, et al, Free-Volume Depth Profile of Polymeric Membranes Studied by Positron Annihilation Spectroscopy: Layer Structure from Interfacial Polymerization, Macromolecules 40 (2007) 7542-7557 113. D. M. Schrader, Y. C. Jean, Position and positronium chemistry, Elsevier Sci., Amsterdam (1988) 114. Y. Li, C. Cao, T. S. Chung, K. P. Pramoda, Fabrication of dual-layer polyethersulfone (PES) hollow fiber membranes with an ultrathin dense-selective layer for gas separation, J. Membr. Sci. 245 (2004) 53-60 115. K. Vasarhelyi, J. A. Ronner, M. H. V. Mulder, C. A. Smolders, Development of wet-dry reversible reverse osmosis membranes with high performance from cellulose acetate and cellulose triacetate blends, Desalination 61 (1987) 211-235 116. B. Jung, J. K. Yoon, B. Kim, H. W. Rhee, Effect of molecular weight of polymeric additives on formation, permeation properties and hypochlorite treatment of asymmetric polyacrylonitrile membranes, J. Membr. Sci. 243 (2004) 45-57 117. S. H. Yoo, J. H. Kim, J. Y. Jho, J. Won, Y. S. Kang, Influence of the addition of PVP on the morphology of asymmetric polyimide phase inversion membranes: effect of PVP molecular weight, J. Membr. Sci. 236 (2004) 203-207 118. P. Menut, Y. S. Su, W. Chinpa, C. Pochat-Bohatier, A. Deratani, D. M. Wang, P. Huguet, C. Y. Kuo, J. Y. Lai, C. Dupuy, A top surface liquid layer during membrane formation using vapor-induced phase separation (VIPS)-Evidence and mechanism of formation, J. Membr. Sci. 310 (2008) 278–288 119. J. A. v. t. Hof, A. J. Reuvers, R. M. Boom, H. M. Rolevink, C. A. Smolders, Preparation of asymmetric gas separation membranes with high selectivity by dual-bath coagulation method, J. Membr. Sci. 70 (1992) 17-30 120. A. Yamasaki, R. K. Tyagi, A. E. Fouda, T. Matsuura, K. Jonasson, Effect of gelation conditions on gas separation performance for asymmetric polysulfone membranes, J. Membr. Sci. 123 (1997) 89-94 121. H. J. Kim, A. Tabe-Mohammadi, A. Kumar, A. E. Fouda, Asymmetric membranes by a two-stage gelation technique for gas separation: formation and characterization, J. Membr. Sci. 161 (1999) 229-238 122. P. Radovanovic, S. W. Thiel, S. T. Hwang, Formation of asymmetric polysulfone membranes by immersion precipitation. Part I. Modelling mass transport during gelation, J. Membr. Sci. 65 (1992) 213-229 123. P. Radovanovic, S. W. Thiel, S. T. Hwang, Formation of asymmetric polysulfone membranes by immersion precipitation. Part II. The effects of casting solution and gelation bath compositions on membrane structure and skin formation, J. Membr. Sci. 65 (1992) 231-246 124. J. Eckelt, S. Loske, M. C. Gonçalves, B. A. Wolf, Formation of micro- and nano-spheric particles (filter dust) during the preparation of cellulose acetate membranes, J. Membr. Sci. 212 (2003) 69-74 125. T. H. Young, D. M. Wang, C. C. Hsieh, L. W. Chen, The effect of the second phase inversion on microstructures in phase inversion EVAL membranes, J. Membr. Sci. 146 (1998) 169-178 126. L. P. Cheng, Effect of Temperature on the Formation of Microporous PVDF Membranes by Precipitation from 1-Octanol/DMF/PVDF and Water/DMF/PVDF Systems, Macromolecules 32 (1999) 6668-6674 127. T. H. Young, L. P. Cheng, D. J. Lin, L. Fane, W. Y. Chuang, Mechanisms of PVDF membrane formation by immersion-precipitation in soft (1-octanol) and harsh (water) nonsolvents, Polymer 40 (1999) 5315-5323 128. L. P. Cheng, T. H. Young, W. Y. Chuang, L. Y. Chen, L. W. Chen, The formation mechanism of membranes prepared from the nonsolvent-solvent-crystalline polymer systems, Polymer 42 (2001) 443-451 129. S. C. Fan, Y. C. Wang, C. L. Li, K. R. Lee, D. J. Liaw, H. P. Huang, J. Y. Lai, Effect of coagulation media on membrane formation and vapor permeation performance of novel aromatic polyamide membrane, J. Membr. Sci. 204 (2002) 67-79 130. C. Y. Kuo, S. L. Su, H. A. Tsai, Y. S. Su, D. MingWang, J. Y. Lai, Formation and evolution of a bicontinuous structure of PMMA membrane during wet immersion process, J. Membr. Sci. 315 (2008) 187-194 131. C. C. Pereira, R. Nobrega, C. P. Borges, Membranes obtained by simultaneous casting of two polymer solutions, J. Membr. Sci. 192 (2001) 11-26 132. D. F. Li, T. S. Chung, R. Wang, Y. Liu, Fabrication of fluoropolyimide/polyethersulfone (PES) dual-layer asymmetric hollow fiber membranes for gas separation, J. Membr. Sci. 198 (2002) 211-223 133. L. Jiang, T.-S. Chung, D. F. Li, C. Caoa, S. Kulprathipanja, Fabrication of Matrimid/polyethersulfone dual-layer hollow fiber membranes for gas separation, J. Membr. Sci. 240 (2004) 91-103 134. Y. Li, T.-S. Chung, Z. Huang, S. Kulprathipanja, Dual-layer polyethersulfone (PES)/BTDA-TDI/MDI co-polyimide (P84) hollow fiber membranes with a submicron PES–zeolite beta mixed matrix dense-selective layer for gas separation, J. Membr. Sci. 277 (2006) 28-37 135. R. X. Liu, X. Y. Qiao, T.-S. Chung, Dual-layer P84/polyethersulfone hollow fibers for pervaporation dehydration of isopropanol, J. Membr. Sci. 294 (2007) 103-114 136. K. Y. Wang, T. S. Chung, R. Rajagopalan, Dehydration of tetrafluoropropanol (TFP) by pervaporation via novel PBI/BTDA-TDI/MDI co-polyimide (P84) dual-layer hollow fiber membranes, J. Membr. Sci. 287 (2007) 60-66 137. N. Widjojo, T. S. Chung, W. B. Krantz, A morphological and structural study of Ultem/P84 copolyimide dual-layer hollow fiber membranes with delamination-free morphology, J. Membr. Sci. 294 (2007) 132-146 138. N. Widjojo, S. D. Zhang, T. S. Chung, Y. Liu, Enhanced gas separation performance of dual-layer hollow fiber membranes via substructure resistance reduction using mixed matrix materials, J. Membr. Sci. 306 (2007) 147-158 139. X. Ding, Y. Cao, H. Zhao, LinaWang, Q. Yuan, Fabrication of high performance Matrimid/polysulfone dual-layer hollow fiber membranes for O2/N2 separation, J. Membr. Sci. 323 (2008) 352-361 140. Y. Li, T. S. Chung, Y. Xiao, Superior gas separation performance of dual-layer hollow fiber membranes with an ultrathin dense-selective layer, J. Membr. Sci. 325 (2008) 23-27 141. Y. Wang, S. H. Goh, T. S. Chung, P. Na, Polyamide-imide/polyetherimide dual-layer hollow fiber membranes for pervaporation dehydration of C1–C4 alcohols, J. Membr. Sci. 326 (2009) 222-233 142. L. Yan, Y. S. Li, C. B. Xiang, S. Xiande, Effect of nano-sized Al2O3-particle addition on PVDF ultrafiltration membrane performance, J. Membr. Sci. 276 (2006) 162-167 143. D. J. Lin, C. L. Chang, F. M. Huang, L. P. Cheng, Effect of salt additive on the formation of microporous poly(vinylidene fluoride) membranes by phase inversion from LiClO4/Water/DMF/PVDF system, Polymer 44 (2003) 413-422 144. M. C. Yang, T. Y. Liu, The permeation performance of polyacrylonitrile/polyvinylidine fluoride blend membranes, J. Membr. Sci. 226 (2003) 119-130 145. N. A. Ochoa, M. Masuell, J. Marchese, Effect of hydrophilicity on fouling of an emulsified oil wastewater with PVDF/PMMA membranes, J. Membr. Sci. 226 (2003) 203-211 146. L. Wu, J. Sun, Q. Wang, Poly(vinylidene fluoride)/polyethersulfone blend membrane: Effect of solvent sort, polyethersulfone and polyvinylpyrrolidone concentration on their properties and morphology, J. Membr. Sci. 285 (2006) 290-298 147. D. J. Lin, C. H. Chang, T. C. Chen, L. P. Cheng, Fine structure of poly(vinylidene fluoride) membranes prepared by phase inversion from a Water/N-Methyl-2-pyrollidone/Poly(vinylidene fluoride) system, J. Polym. Sci., Part B: Polym. Phys. 42 (2004) 830-842 148. D. J. Lin, H. H. Chang, T. C. Chen, Y. C. Lee, L. P. Cheng, Formation of porous poly(vinylidene fluoride) membranes with symmetric or asymmetric morphology by immersion [recipitation in the Water/TEP/PVDF system, Eur. Polym. J. 42 (2006) 1581-1594 149. M. Peng, H. Li, L. Wu, Q. Zheng, T. Chen, W. Gu, Porous poly(vinylidene fluoride) membrane with highly hydrophobic surface, J. Appl. Polym. Sci. 98 (2005) 1358-1363 150. A. Bottino, G. Capannelli, A. Comite, Novel porous membranes from chemically modified poly(vinylidene fluoride), J. Membr. Sci. 273 (2006) 20-24 151. T. H. Young, J. H. Huang, W. Y. Chuang, Effect of evaporation temperature on the formation of particulate membranes from crystalline polymers by dry-cast process, Eur. Polym. J. 38 (2002) 63-72 152. A. Akthakul, W. F. McDonald, A. M. Mayes, Noncircular pores on the surface of asymmetric polymer membranes: evidence of pore formation via spinodal demixing, J. Membr. Sci. 208 (2002) 147-155 153. H. Matsuyama, M. Teramoto, R. Nakatani, T. Maki, Membrane formation via phase separation induced by penetration of nonsolvent from vapor phase. II. Membrane morphology, J. Appl. Polym. Sci. 74 (1999) 171-178 154. J. E. Mark, Polymer data handbook, New York : Oxford University Press (1999). | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/45304 | - |
dc.description.abstract | 本論文主要目的是探討無皮層基材膜之製備,包括使用蒸氣誘導式相分離(vapor induced phase inversion, VIPS)與雙凝聚劑溼式相分離結合同步塗佈(in-situ casting process)兩種鑄膜液方法製備無皮層之基材膜,也利用添加無機顆粒的方法製備表面多孔的基材膜,並進一步釐清形成無皮層基材膜的成膜機制。此外,研究中也針對無皮層基材膜所製得之複合膜運用在滲透蒸發分離上加以探討。
在PC/PAN表面多孔複合膜的製備方面,此薄膜利用VIPS結合同步塗佈兩種鑄膜液的方法所製備,可以有效得到多孔的表面結構,與傳統具有皮層之非對稱PAN薄膜相比,蒸氣誘導式相分離結合同步塗佈兩種鑄膜液所製備無皮層之PC/PAN基材膜可以有效抑制表面緻密層的生成,進而提高PC/PAN複合膜高純水透過量。在機械性質方面,隨著上層PC濃度降低而PC/PAN複合膜的機械強度會有下降的趨勢。 利用雙凝聚劑的方法製備無皮層CA (skin-free CA, SF-CA)基材膜方面,隨著CA鑄膜液在第一凝聚劑(乙醇)浸漬時間的增加,表面孔洞有變大的趨勢,且表面顆粒也趨之明顯造成表面粗糙度也隨之上升,進而提高CA基材膜的純水透過量。製備成Chitosan/ SF-CA複合膜時,運用在70oC、70 wt% IPA/H2O的滲透蒸發分離時,在維持相同的透過水濃度的情形下,以單槽成膜法為基準,此一雙凝聚劑成膜方式約可提高約50 %的純水通量。 利用同步塗佈法結合溼式相轉換法製備SF-CA基材膜方面,由於上層低濃度鑄膜液改變下層鑄膜液表面高分子濃度,造成表面高分子濃度下降,進而製得SF-CA基材膜,結果發現隨著上層CA濃度增加,其表面結構由多孔慢慢轉變成緻密的表面結構,因此造成其純水透過量與滲透蒸發透過量都有逐漸下降趨勢。數據顯示運用在滲透蒸發分離70oC 、70 wt% IPA/water時,Chitosan/SF-CA複合膜在維持相同的透過水濃度的情形下,可以提高20 %的滲透蒸發透過量。 在添加silica製備有機/無機混成薄膜(silica/PVDF)方面,結果發現純水透過量、孔洞直徑、表面孔隙度與孔洞密度隨silica添加量上升而增加,在添加7 wt%時有極大值,之後隨silica添加量上升會有下降的趨勢。將Chitosan/(silica/PVDF)複合膜,運用在70oC 、70 wt% IPA/water的滲透蒸發脫水程序,在不損失透過水濃度的情形下,添加silica之Chitosan/(silica/PVDF)複合膜比未添加之Chitosan/PVDF複合膜大約提高1000 g/m2h的滲透蒸發透過量。 | zh_TW |
dc.description.abstract | The main purpose of this dissertation is to study how to prepare skin-free support membranes and to interpret the mechanism of membrane formation by the nonsolvent-induced phase separation method, which involves the absorption of water vapor to induce phase separation, combined in-situ casting process with dual coagulation or precipitation method, and added inorganic particle. Also, the effects of skin-free support membranes on their pervaporation performance were discussed.
In the preparation of skin-free PC/PAN composite membranes, the membrane formation was via the vapor-induced phase separation (VIPS) method combined with in-situ casting process. This method proved effective in obtaining a porous top surface. Compared with the traditional method of preparing asymmetric PAN membrane with a dense skin layer and porous support layer, the VIPS method combined with the in-situ casting process effectively prevented skin layer formation in the ensuing PC/PAN composite membranes, resulting in the water flux increase. The mechanical properties of the PC/PAN composite membranes decreased with decreasing the PC casting layer concentration. Dual coagulation bath was the precipitation method used in forming the skin-free PC/PAN composite membranes. The surface pore size and surface roughness increased with increase in the immersion time in the first coagulation bath (ethanol), resulting in the water flux increase. Chitosan/skin-free CA composite membranes were prepared for the separation of 70 wt% IPA/H2O at 70 | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T04:13:19Z (GMT). No. of bitstreams: 1 ntu-99-D94549002-1.pdf: 14671537 bytes, checksum: be4ca86e28b4e963c8a730736cd06181 (MD5) Previous issue date: 2010 | en |
dc.description.tableofcontents | 口試委員會審定書 I
誌謝 II 中文摘要 III Abstract V 圖目錄 XV 表目錄 XXIII 第一章 緒論 1 1-1前言 1 1-2薄膜的定義 2 1-3薄膜分離程序 3 1-4薄膜製備與型態 4 1-4-1薄膜結構 5 1-4-2薄膜製備方法 6 1-5薄膜成膜理論 9 1-5-1熱力學 10 1-5-2質傳動力學 13 1-6 滲透蒸發 15 1-6-1 滲透蒸發(Pervaporation)之發展 16 1-6-2 何為滲透蒸發 18 1-6-3滲透蒸發於商業化的應用 23 1-7複合膜製備 28 1-7-1基材膜之製備方式 28 1-7-2 緻密層之製備方式 29 1-8研究動機 29 1-9研究目的 35 第二章 實驗 37 2-1實驗藥品 37 2-2實驗儀器 40 2-3實驗方法 41 2-3-1高分子溶液配製 41 2-3-2薄膜製備 41 2-3-3薄膜結構分析 44 2-3-4霧點(Cloud-point)量測 44 2-3-5光穿透實驗 44 2-3-6光學顯微鏡觀察 45 2-3-7接觸角量測 46 2-3-8原子力顯微鏡 (Atomic Force Microscopy, AFM) 47 2-3-9拉力試驗(Instron) 測試 49 2-3-10純水透過測試 49 2-3-11正子湮滅光譜(Positron annihilation spectroscopy, PAS)分析技術 50 2-3-12薄膜氣體透過測試 57 2-3-13滲透蒸發 (Pervaporation) 測試 59 2-4實驗流程 61 第三章 高通量PC/PAN複合膜之製備 62 摘要 62 3-1前言 62 3-2結果與討論 64 3-2-1以不同之相轉換法製備單層PAN之薄膜結構 64 3-2-2不同之相轉換法製備單層PC之薄膜結構 65 3-2-3上層PC/NMP鑄膜液濃度變化對PC/PAN複合膜結構之影響 69 3-2-4上層PC/NMP鑄膜液濃度變化對PC/PAN複合膜純水透過測試之影響 71 3-2-5上層PC/NMP鑄膜液濃度變化對PC/PAN複合膜表面孔徑分佈之影響 72 3-2-6改變PC/NMP濃度對PC/PAN複合膜機械強度之影響 73 3-3結論 74 第四章 雙凝聚劑成膜系統對Chitosan/ SF-CA複合膜滲透蒸發效能之影響 75 摘要 75 4-1前言 75 4-2結果與討論 77 4-2-1鑄膜液濃度對薄膜結構之影響 78 4-2-2不同製膜程序對薄膜結構之影響 80 4-2-3溶劑與非溶劑交換情形之觀察 83 4-2-4第一凝聚劑槽浸漬時間對CA基材膜結構之影響 89 4-2-5第一凝聚劑槽浸漬時間對CA基材膜孔徑之影響 91 4-2-6第一凝聚劑槽浸漬時間變化對CA基材膜表面粗糙度之影響 91 4-2-7第一凝聚劑槽浸漬時間變化對CA基材膜純水透過測試之影響 94 4-2-8 Chitosan/ SF-CA複合膜之滲透蒸發測試 96 4-2-9第一凝聚劑槽浸漬時間變化對Chitosan/SF-CA複合膜截面結構之影響 97 4-2-10第一凝聚劑槽浸漬時間變化對Chitosan/ SF-CA複合膜表面粗糙度之影響 99 4-2-11第一凝聚劑槽浸漬時間變化對Chitosan/SF-CA複合膜孔洞型態之影響 101 4-2-12第一凝聚劑槽浸漬時間變化對Chitosan/SF-CA複合膜氣體透過通量之影響 104 4-2-13進料溫度對Chitosan/ SF-CA複合膜之滲透蒸發分離之影響 106 4-3結論 107 第五章 同步塗佈法對Chitosan/SF-CA複合膜滲透蒸發效能之影響 108 摘要 108 5-1前言 108 5-2結果與討論 111 5-2-1鑄膜液濃度對CA薄膜結構之影響 111 5-2-2同步塗佈法製備無皮層CA (SF-CA) 薄膜 113 5-2-3上層CA/NMP濃度變化對SF-CA薄膜表面粗糙度之影響 116 5-2-4上層CA/NMP濃度變化對SF-CA薄膜純水透過之影響 118 5-2-5 Chitosan/SF-CA複合膜之滲透蒸發分離測試 119 5-3結論 122 第六章 有機/無機混成Chitosan/(silica/PVDF)複合膜之滲透蒸發效能探討 123 摘要 123 6-1前言 123 6-2結果與討論 128 6-2-1基材薄膜結構與性質探討 128 6-2-2 Silica含量變化對PVDF薄膜表面結構與性質之影響 136 6-2-3 Silica含量對相分離速率之影響 140 6-2-4溶劑與非溶劑交換情形之觀察 140 6-2-5 Silica在silica/PVDF混成膜中分散情形之鑑定 143 6-2-6 Chitosan/(silica/PVDF)複合膜之滲透蒸發分離效能測試 146 6-2-7進料溫度對Chitosan/(silica/PVDF)複合膜滲透蒸發分離效能之影響 150 6-3結論 152 第七章 總結與未來展望 153 7-1總結 153 7-2未來展望 156 參考文獻 157 作者簡介 173 著作 174 | |
dc.language.iso | zh-TW | |
dc.title | 基材膜結構對滲透蒸發複合膜效能之影響 | zh_TW |
dc.title | Effect of support layer structure of composite membrane on the pervaporation performance | en |
dc.type | Thesis | |
dc.date.schoolyear | 98-1 | |
dc.description.degree | 博士 | |
dc.contributor.coadvisor | 賴君義(Juin-Yih Lai),李魁然(Kueir-Rarn Lee) | |
dc.contributor.oralexamcommittee | 廖文彬(Wen-Bin Liau),戴子安(Chi-An Dai),呂幸江(Shing-Jiang Lue) | |
dc.subject.keyword | 無皮層基材膜,複合膜,蒸氣誘導式相分離法,雙凝聚劑法,同步塗佈法,有機/無機混成薄膜,滲透蒸發, | zh_TW |
dc.subject.keyword | skin-free support membranes,composite membrane,vapor-induced phase separation (VIPS) method,dual coagulation method,in-situ casting process,organic/inorganic blend membrane,pervaporation, | en |
dc.relation.page | 177 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2010-01-21 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
顯示於系所單位: | 高分子科學與工程學研究所 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-99-1.pdf 目前未授權公開取用 | 14.33 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。