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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 陳文章(Wen-Chang Chen) | |
dc.contributor.author | Yu-Wen Wang | en |
dc.contributor.author | 王育文 | zh_TW |
dc.date.accessioned | 2021-06-15T03:59:17Z | - |
dc.date.available | 2011-04-16 | |
dc.date.copyright | 2010-04-16 | |
dc.date.issued | 2010 | |
dc.date.submitted | 2010-04-14 | |
dc.identifier.citation | Chapter 1
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/44952 | - |
dc.description.abstract | 有機無機混成材料由於具有調控彼此之間的特性來製備出各種創新的用途,所以近年來已被廣泛地討論及應用。這些混成材料在光學應用中相當廣泛,例如高折射率薄膜、光波導元件、非線性光學材料及各種光學保護層等。本論文中探討以高分子聚醯亞胺和無機奈米粒子混摻之後得到不同功能性之奈米複合材料,並探討製備之光學應用及光學特性,其中光波導材料、包含高折射率薄膜及抗反射膜的研究。
感光性的聚醯亞胺-二氧化矽混成材料部分,研究中探討兩個系列的奈米複合材料之合成與鑑定。在第二章中,利用加入耦合劑和無機粒子的方式,將離子型感光聚醯亞胺在熱烘烤過程中所造成的膜厚損失從原先的28.1 %降低到5.9 %,並且同時提高曝光顯影後所得圖形的解析度及降低紅外光之光傳損失 在第三章中,將感光性色淡性聚醯亞胺利用添加較多比例的無機奈米粒子,除了在熱烘烤過程中能有低收縮率的表現之外,還能維持在可見光區良好的透明度。在曝光顯影部分可以製作出多種不同形狀之圖案且具有低光傳損失性質,其光學膜也可以應用在各種光學波導元件上。 利用二氧化矽及二氧化鈦混摻在色淡性聚醯亞胺中,可以得到高低折射率分佈的聚醯亞胺-無機混成材料。在第四章中,將修飾過的二氧化鈦前驅溶液加入色淡性聚醯亞胺中製備奈米複合材料,之後更進一步的使用水熱法促進生成及分散於高分子中,並提高混成材料的折射率。所得之薄膜除了在可見光區呈透明之外,折射率分佈可從1.550至1.847,而其光學膜也可應用在三層抗反射塗層,在可見光範圍其反射率可小於0.5 %. 以上合成出的高分子有機無機混成光學材料均具有比原材料更優異的各種光學性質,因此這些混成光學材料可應用於各種光電元件上,例如抗反射膜與光波導等應用。 | zh_TW |
dc.description.abstract | Organic–inorganic hybrid materials have been extensively studied recently since their molecular tailing properties could produce new functionalities. Such hybrid materials have been widely investigated for advanced optical applications, such as high refractive materials, non-linear optical materials, optical waveguide, and protective layer materials. In this study, the objectives are to synthesize hybrid nanocomposites of polyimide / inorganic hybrid and explore the optical application, including optical waveguides, high refractive index films, and antireflective films.
Two classes of photosensitive-silica hybrid materials are synthesized and characterized. In Chapter 2, the volume shrinkage during imidization is largely reduced by introducing coupling agent and inorganic moiety in the conventional ionic salt photosensitive polyimide. The volume shrinkage during the thermal curing imidization is reduced from 28.1 % to 5.9 %, and this approach also increases the resolution of patterns and reduces the optical loss as well. In Chapter 3, photosensitive colorless polyimide-silica hybrid materials with more inorganic content are not only have lower volume shrinkage during thermal imidization, but also exhibit transparency in the visible region. The hybrid film could be patterned by a direct lithographic process and developed to kinds of patterns and have the application in different optical waveguides. Colorless polyimide-silica and polyimide-titania hybrid thin films are described in Chapter 4. The modified titania precursors are added in the polyimide matrix to form the polyimide-titania hybrid materials. Furthermore, hydrothermal treatment was used to induce condensation and crystallization of amorphous titania at a relative low temperature, thus enhance the refractive indices also. The experimental results suggest that transparent and tunable refractive indices (1.550-1.847 at 633nm) polyimide-silica/titania hybrid thin films were prepared. A three-layer anti-reflective coating based on the prepared hybrid films was designed and processed on glass and polymer film substrates with a reflectance of less than 0.5 % in the visible range. The above polyimide-inorganic hybrid materials exhibit superior optical characteristics than their parent polymers. Such materials would be of interest in various optical and optoelectronic devices, such as antireflective films and optical waveguides…etc. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T03:59:17Z (GMT). No. of bitstreams: 1 ntu-99-F92549010-1.pdf: 7590837 bytes, checksum: bae2a9e64c9a1968c48bf3f80e22cf96 (MD5) Previous issue date: 2010 | en |
dc.description.tableofcontents | 中文摘要 i
Abstract ii Table of Contents iv Table Captions vii Scheme Captions viii Figure Captions ix Chapter 1 Introduction of Functional Organic-Inorganic Hybrid Nanocomposites: Design, Synthesis, and Optical Applications 1 1.1 Introduction of organic-inorganic hybrid nanocomposites. 1 1.2 Design and synthesis of functional hybrid nanocomposites 4 1.2.1 Sol-gel route 4 1.2.2 In situ formation of nanoparticles in polymer matrices 6 1.2.3 Ex situ synthesis method 7 1.3 Polyimide based hybrid nanocomposites 11 1.3.1 Polyimide-Silica hybrid nanocomposites 11 1.3.2 Photosensitive polyimide hybrid materials 13 1.3.3 Polyimide-titania hybrid nanocomposites 15 1.3.4 Colorless polyimide hybrid 17 1.4 Optical application of functional hybrid nanocomposites 19 1.4.1 Optical Waveguide 20 1.4.2 Antireflective coatings 24 1.5 Research objectives 27 1.6 References 29 Chapter 2 Low Volume Shrinkage Photosensitive Polyimide-Silica Hybrid Optical Materials: Synthesis, Properties, and Patterning 55 2.1 Introduction 55 2.2 Experimental Sections 58 2.2.1 Materials 58 2.2.2 Preparation of the photosensitive APrTEOS-Capped poly(amic-acid)-silica precursor (A-PAA) 58 2.2.3 Preparation of the precursor solutions of the hybrid films, P1~P3c 59 2.2.4 Lithographic patterning 59 2.2.5 Characterization 60 2.3 Results and discussions 62 2.4 Conclusions 67 2.5 References 68 Chapter 3 Photosensitive Colorless Polyimide-Silica Hybrid Optical Materials: Synthesis, Properties and Patterning 78 3.1 Introduction 78 3.2 Experimental Section 81 3.2.1 Materials 81 3.2.2 Preparation of 1, 4-Bis (3, 4-dicarboxyphenoxy)-2, 5-di-tert-butylbenzene dianhydride. (DDBBDA) 81 3.2.3 Preparation of photosensitive poly (amic acid)-silica precursors 82 3.2.4 Photolithography 83 3.2.5 Characterization 84 3.3 Result and Discussion 85 3.4 Conclusions 91 3.5 References 92 Chapter 4 Synthesis, Properties, and Antireflective Applications of New Colorless Polyimide-inorganic Hybrid Optical Materials 105 4.1 Introduction 105 4.2 Experimental Sections 107 4.2.1 Materials 107 4.2.2 Preparation of the titania precursor (TiM41) 107 4.2.3 Preparation of APrTEOS end-capped poly(amic acid) and its inorganic hybrid films 108 4.2.4 Characterization 109 4.3 Results and Discussions 111 4.4 Conclusions 116 4.5 References 117 Chapter 5 Conclusions and Future Works 128 5.1 Conclusions 128 5.2 Future works 130 5.3 Reference 134 Publication Lists 139 Appendix A Polyimide-BT Hybrid Materials for High Refractive Index and High Dielectric Constant Thin Films 141 Appendix B Selected Journal Papers 164 | |
dc.language.iso | en | |
dc.title | 新穎性聚醯亞胺及其有機/無機混成材料之設計、合成、性質及其於光學應用 | zh_TW |
dc.title | Design, Synthesis, and Properties of Polyimides and Their Hybrid Materials for Optical Applications | en |
dc.type | Thesis | |
dc.date.schoolyear | 98-2 | |
dc.description.degree | 博士 | |
dc.contributor.oralexamcommittee | 劉貴生(Guey-Sheng Liou),童世煌(Shih-Huang Tung),游洋雁(Yang-Yen Yu),顏誠廷(Cheng-Tyng Yen) | |
dc.subject.keyword | 聚醯亞胺,混成材料,感光性,色淡,光學性質,光波導,抗反射膜, | zh_TW |
dc.subject.keyword | Polyimide,Hybrid materials,Photosensitive,Colorless,Optical properties,Optical waveguide,Antireflective coatings, | en |
dc.relation.page | 163 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2010-04-15 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
顯示於系所單位: | 高分子科學與工程學研究所 |
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