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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 陳希立(Shi-Li Chen) | |
| dc.contributor.author | Hung-Ting Su | en |
| dc.contributor.author | 蘇宏庭 | zh_TW |
| dc.date.accessioned | 2021-06-15T03:55:38Z | - |
| dc.date.available | 2011-07-12 | |
| dc.date.copyright | 2010-07-12 | |
| dc.date.issued | 2010 | |
| dc.date.submitted | 2010-06-24 | |
| dc.identifier.citation | [1]陳仁德譯，太陽能電力公司：新能源新就業機會，新自然主義，2005，15-20。
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Kung, C.-C. Lin, “The effects of the thickness of TiO2 films on the performance of dye-sensitized solar cells”, Thin Solid Films 517 (2009) 5096-5099. [115]Y. Suzuki, S. Ngamsinlapasathian, R. Yoshida and S. Yoshikawa, “Partially nanowire-structured TiO2 electrode for dye-sensitized solar cells”, Cent. Eur. J.Chem. 4 (2006) 476–488. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/44818 | - |
| dc.description.abstract | 本文是研究以三種奈米級氧化鈦材料；放電式奈米流體製程(EDNP)產出二氧化鈦(TiO2)奈米粒子、商用P25(TiO2)粒子以及利用水熱式化學反應改質P25而成的氧化鈦(TiO)奈米管，分別應用於染料敏化太陽能電池的光電極材料。藉由旋轉加熱塗佈平台裝置與電泳沉積技術，將奈米粒子均勻的塗佈沉積在ITO導電玻璃上形成薄膜，再浸泡入N719 染料中12小時以上作為DSSC的光電極元件。EDNP產出的TiO2奈米粒子具有優質的銳鈦礦晶相性質，粒徑尺寸可控制在20~50nm之間。奈米流體的表面電位約為-22 to -28.8mV，所以粒子是穩定懸浮於去離子水內。添加微量的介面活性劑Triton X-100在導電玻璃表面上，可以輔助製成均勻與緻密的TiO2薄膜，然後持續加熱旋轉平台達200℃以上就能去除混入的介面活性劑。ED(TiO2)薄膜也展現較佳的染料吸附成效，甚至不必藉由熱處理程序來提升本質特性。經過DSSC能量轉換分析結果呈現，比較厚的薄膜結構將提升Jsc而導致較高的光電轉換效率(η)5.37%。但是，當薄膜結構太厚(超過20μm)，Voc與FF兩者都會逐漸下降而導致DSSC效率變差。P25(TiO2)搭配異丙醇(IPA)之膠體添加1x10-4的電解質Mg(NO3)2．6H2O可維持膠體的穩定；電泳沉積薄膜的最佳電場強度在40V/cm時之薄膜堆積效率最佳，並且呈現高平整特性的薄膜表面粗糙度(Ra=1005.725Å)。以400℃高溫熱處理持續30分鐘有助於P25(TiO2)薄膜的銳鈦礦晶相轉強並且提高薄膜緻密性，多層電泳沉積不僅可以防止薄膜因內部應力的破壞，並且能夠降低裂縫缺陷的存在，使得TiO2薄膜的粒子增加染料分子吸附量，進而提升DSSC之光電流密度至12.2mA/cm2(η=5.29%)。TiO奈米管(Tnt)是無晶相的鈦酸鹽結構[H2Ti3O7]，雖然奈米管擁有較大的比表面積能吸附較多的染料，但是因為材料性質無法像銳鈦礦或是金紅石一樣具有良好的半導體特性，其能量轉換效率最高也只有3.16% (9μm)。因此，從P25改質後所得到初形成的Tnt不適合直接作為光電極材料的應用。 | zh_TW |
| dc.description.abstract | The investigation is to apply three kind of oxide titanium nanomaterials, TiO2 nanoparticles by electrical-discharge-nanofluids-process (EDNP), commercial P25 nanopowders (TiO2) and TiO nanotube which made by hydrothermal chemistry reaction to be photoelectrode material of dye sensitized solar cell. Through spreading nanoparticles evenly onto the ITO glass by spin-heat platform coats a TiO2 thin film and then soaks it in the dye N719 more than 12 hours to prepare for the photoelectrode device. The TiO2 nanoparticles produced by EDNP has premium anatase crystal property, and its diameter can be controlled within a range between 20-50 nm. The surface energy zeta potential of nanofluid is about -22 to -28.8 mV, it is a stable particles suspension in the DI water. Using a trace of surfactant Triton X-100 upon the surface of ITO glass can helpful produce a uniform and dense TiO2 thin film, heating up the spin platform to over 200℃ is able to eliminate mixed surfactant. The ED(TiO2) film presents excellent dye absorption performance as well and even doesn’t through heat treatment procedure to enhance essential property. Results of energy analysis show the thicker film structure will increase the Jsc generation that causes higher conversion efficiency (η) 5.37%. But, as the film structure is large thick condition (over 20μm), both Voc and FF will decline gradually to lead bad of DSSC efficiency.
The P25(TiO2)/IPA colloid could well suspend when it mixed with electrolyte 10-4M of Mg(NO3)2．6H2O. The optimal electric field intensity of EPD indicates at 40V/cm, which produce well thin film roughness about 1005.725Å. Through 400℃ heat treatment to keep 30 minutes for P25(TiO2) film is able to reinforce helpfully the anatase crystalline property improvement and density consolidation. Multilayers EPD could not only prevent inner stress to breack film structure but also decrease vacancy and crack defect in the film, and absorb more quantity of dye molecule on the P25(TiO2) particle surface to increase photocurrent density of DSSC at 12.2mA/cm2(η=5.29%). TiO nanotube (Tnt) belongs amorphous H2Ti3O7 phase, even though the Tnt has higher specific surface area to absorb huge dye molecule, but its material property is not like anatase or ruitle phase to present great semiconductor feature as well, its best η result is 3.16% at 9μm thickness. Consequently, the initial phase changed of Tnt, which made by chemical reaction from P25, is not best suitable for photoelectrode material application directly. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T03:55:38Z (GMT). No. of bitstreams: 1 ntu-99-D93522022-1.pdf: 14271392 bytes, checksum: 200227b128bb66c5a780e719c4b6524c (MD5) Previous issue date: 2010 | en |
| dc.description.tableofcontents | 摘要.......................................................I
ABSTRACT..................................................II 目錄......................................................IV 圖目錄..................................................VIII 表目錄..................................................XIII 符號說明.................................................XIV 第一章 緒論................ ...............................1 1-1前言.................... ...............................1 1-2 研究背景............... ...............................2 1-3 研究動機............... ...............................3 1-4 論文架構..............................................5 第二章 DSSC科學理論與文獻回顧.............................10 2-1染料敏化太陽能電池.....................................10 2-1-1導電基板.............................................10 2-1-2 染料................................................10 2-1-3 多孔性奈米半導體薄膜電極............................13 2-1-4 氧化還原電解質......................................16 2-1-5 反電極..............................................17 2-2 DSSC的發生理論........................................17 2-2-1 DSSC電化學原理......................................17 2-2-2 電子擴散傳遞理論....................................19 2-2-3 DSSC的耗損機制......................................19 2-3 DSSC的性能分析........................................20 2-3-1 開路電壓(Voc)與短路電流(Isc)........................20 2-3-2 I-V curve的光電轉換效率與充填因子...................21 2-3-3入射光子-電子轉換效率IPCE............................21 2-3-4 開路電壓衰退量測法OCVD..............................22 2-4奈米材料的應用.........................................23 2-4-1 物理法製程技術......................................23 2-4-2 化學法製程技術......................................23 2-4-3 光電極材料- TiO2奈米粒子............................24 2-4-4 光電極材料- TiO奈米管...............................24 2-5膠體分散體系的穩定與聚沉...............................24 2-5-1膠體分散體系三大理論.................................24 2-5-2電雙層理論...........................................27 2-5-3 表面電位............................................27 第三章 實驗裝置與程序.....................................43 3-1實驗材料與分析檢驗設備.................................43 3-1-1實驗材料.............................................43 3-1-2檢驗設備.............................................43 3-1-2-1掃描式電子顯微鏡...................................44 3-1-2-2穿隧式電子顯微鏡...................................44 3-1-2-3 X光繞射分析儀.....................................45 3-1-2-4紫外光/可見光光譜吸收儀............................45 3-1-2-5雷射光散射儀.......................................46 3-1-2-6光學干涉式表面輪廓儀...............................47 3-1-2-7電池性能測試分析系統...............................47 3-1-3 前置準備............................................47 3-1-3-1透明導電基板之清潔.................................47 3-1-3-2反電極製備.........................................48 3-2 物理法-放電式製做奈米粒子.............................48 3-2-1放電製程原理.........................................48 3-2-2放電加工參數控制.....................................49 3-2-3放電式奈米流體製程設備...............................51 3-2-4 EDNP實驗流程........................................52 3-3化學法-水熱反應式製做奈米管............................53 3-3-1水熱反應式原理.......................................53 3-3-2水熱反應式實驗設備與流程.............................53 3-4光電極製做實驗與分析...................................54 3-4-1旋轉加熱塗佈.........................................54 3-4-2電泳沉積.............................................55 3-4-2-1電泳原理...........................................55 3-4-2-2電泳設備與實驗流程.................................58 3-4-3染料N719與電解質的配置...............................58 3-5 DSSC組裝程序與光電轉換效率實驗........................59 3-5-1 DSSC組裝程序........................................59 3-5-2 實驗流程............................................59 第四章 實驗結果與討論.....................................80 4-1 物理法-放電式產出奈米粒子的製備成果...................80 4-1-1 放電製程控制對TiO2 nanoparticles的影響..............80 4-1-2 粒子外形檢測........................................82 4-1-3粒子的成份分析.......................................82 4-1-4粒子晶相檢測.........................................83 4-1-5奈米流體表面電位.....................................83 4-1-6奈米粒子懸浮液光吸收效應.............................84 4-2化學法-水熱式產出奈米管的製備成果......................84 4-2-1奈米管外形檢測.......................................85 4-2-2奈米管的晶相分析.....................................85 4-3薄膜成形與檢測.........................................86 4-3-1旋轉加熱塗佈成形與檢測結果...........................86 4-3-2電泳沉積薄膜成形與檢測結果...........................87 4-3-2-1 P25奈米粒子懸浮液穩定性...........................87 4-3-2-2電泳沉積-電壓控制的影響............................88 4-3-2-3電泳沉積-厚度控制..................................89 4-3-2-4 晶相結構分析......................................90 4-4光電極分析與光電轉換效率量測...........................90 4-4-1薄膜對染料的吸附特徵.................................90 4-4-2薄膜厚度結構對DSSC效率的影響.........................91 4-4-3 (TiO2)/ITO燒結溫度對DSSC效率的影響..................95 4-4-4初形成奈米管作為光電極的DSSC效率.....................96 4-4-5薄膜厚度對充填因子的影響.............................97 第五章 研究結論與展望....................................128 5-1研究結論..............................................128 5-2未來展望與建議........................................131 參考文獻.................................................133 附錄A....................................................145 | |
| dc.language.iso | zh-TW | |
| dc.subject | 光電轉換效率 | zh_TW |
| dc.subject | 銳鈦礦 | zh_TW |
| dc.subject | 二氧化鈦 | zh_TW |
| dc.subject | 光電極 | zh_TW |
| dc.subject | 電泳沉積 | zh_TW |
| dc.subject | 體製程 | zh_TW |
| dc.subject | 米流 | zh_TW |
| dc.subject | 放電式奈 | zh_TW |
| dc.subject | photoelectrode | en |
| dc.subject | energy conversion efficiency | en |
| dc.subject | anatase | en |
| dc.subject | electrical-discharge nanofluid-process(EDNP) | en |
| dc.subject | Electrophoresis deposition(EPD) | en |
| dc.subject | TiO2 film | en |
| dc.title | TiO2奈米粒子應用於染料敏化太陽能電池光電極之研究 | zh_TW |
| dc.title | Investigation of Applying TiO2 Nanoparticles in Photoelectrode of Dye Sensitized Solar Cell | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 98-2 | |
| dc.description.degree | 博士 | |
| dc.contributor.oralexamcommittee | 張合(Ho Chang),卓清松(Ching-song Jwo),張西龍,陳輝俊,吳文方 | |
| dc.subject.keyword | 放電式奈,米流,體製程,電泳沉積,光電極,二氧化鈦,銳鈦礦,光電轉換效率, | zh_TW |
| dc.subject.keyword | electrical-discharge nanofluid-process(EDNP),Electrophoresis deposition(EPD),photoelectrode,TiO2 film,anatase,energy conversion efficiency, | en |
| dc.relation.page | 145 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2010-06-24 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 機械工程學研究所 | zh_TW |
| 顯示於系所單位： | 機械工程學系 | |
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