請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/4474
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 蔡定平(Din Ping Tsai) | |
dc.contributor.author | Wen-Ting Hsieh | en |
dc.contributor.author | 謝文婷 | zh_TW |
dc.date.accessioned | 2021-05-14T17:42:31Z | - |
dc.date.available | 2018-07-11 | |
dc.date.available | 2021-05-14T17:42:31Z | - |
dc.date.copyright | 2015-08-19 | |
dc.date.issued | 2015 | |
dc.date.submitted | 2015-08-17 | |
dc.identifier.citation | 1. Wu, P.C., et al., Vertical split-ring resonator based nanoplasmonic sensor. Applied Physics Letters, 2014. 105(3): p. 033105.
2. Lin, J.Y., et al., Nanopatterned Substrates Increase Surface Sensitivity for Real-Time Biosensing. The Journal of Physical Chemistry C, 2013. 117(10): p. 5286-5292. 3. Lee, K.-L., et al., Enhancing Surface Plasmon Detection Using Template-Stripped Gold Nanoslit Arrays on Plastic Films. ACS Nano, 2012. 6(4): p. 2931-2939. 4. Duyne, K.A.W.a.R.P.V., Localized Surface Plasmon Resonance Spectroscopy and Sensing. Annu. Rev. Phys. Chem, 2007. 58: p. 267-297. 5. Maier, S.A., Plasmonics: Fundamentals and Applications. 2007. 6. Bryant, M.P.a.G.W., Introduction to Metal-nanoparticle Plasmonics. Contemporary Physics, 2014. 55(4): p. 352-353. 7. 邱國斌、蔡定平, 金屬表面電漿簡介. 物理雙月刊, 2006. 28(2): p. 472-485. 8. Dong, B., et al., Substrate-, Wavelength-, and Time-Dependent Plasmon-Assisted Surface Catalysis Reaction of 4-Nitrobenzenethiol Dimerizing to p,p′-Dimercaptoazobenzene on Au, Ag, and Cu Films. Langmuir, 2011. 27(17): p. 10677-10682. 9. Johnson, P.B. and R.W. Christy, Optical Constants of the Noble Metals. Physical Review B, 1972. 6(12): p. 4370-4379. 10. Kittel, C., Introduction to Solid State Physics, 8th Edition. 2005. 11. Mulvaney, P., Surface Plasmon Spectroscopy of Nanosized Metal Particles. Langmuir, 1996. 12(3): p. 788-800. 12. Zeman, E.J. and G.C. Schatz, An accurate electromagnetic theory study of surface enhancement factors for silver, gold, copper, lithium, sodium, aluminum, gallium, indium, zinc, and cadmium. The Journal of Physical Chemistry, 1987. 91(3): p. 634-643. 13. Rycenga, M., et al., Controlling the Synthesis and Assembly of Silver Nanostructures for Plasmonic Applications. Chemical Reviews, 2011. 111(6): p. 3669-3712. 14. Le Ru, E.C. and P.G. Etchegoin, Principles of Surface-Enhanced Raman Spectroscopy, in Principles of Surface-Enhanced Raman Spectroscopy, E.C.L. Ru and P.G. Etchegoin, Editors. 2009, Elsevier: Amsterdam. 15. 雷敏宏、吳紀聖, 觸媒化學概論與應用. 2014. 16. Kale, M.J., et al., Controlling Catalytic Selectivity on Metal Nanoparticles by Direct Photoexcitation of Adsorbate–Metal Bonds. Nano Letters, 2014. 14(9): p. 5405-5412. 17. Davis, M.E.D.R.J., Fundamentals of Chemical Reaction Engineering. McGraw-Hill, Boston, 2003 edition., 2012. 18. Fujishima, A. and K. Honda, Electrochemical Photolysis of Water at a Semiconductor Electrode. Nature, 1972. 238(5358): p. 37-38. 19. Atwater, H.A. and A. Polman, Plasmonics for improved photovoltaic devices. Nat Mater, 2010. 9(3): p. 205-213. 20. Chen, Y.L., et al. Zinc Oxide Nanorod Optical Disk Photocatalytic Reactor for Photodegradation. in Frontiers in Optics 2013. 2013. Orlando, Florida: Optical Society of America. 21. Zhang, X., et al., Plasmonic photocatalysis. Reports on Progress in Physics, 2013. 76(4): p. 046401. 22. Thuillier, G.H., M.; Labs, D.; Foujols, T.; Peetermans, W.; Gillotay, D.; Simon, P. C.; Mandel, H., The Solar Spectral Irradiance from 200 to 2400 nm as Measured by the SOLSPEC Spectrometer from the Atlas and Eureca Missions. Solar Physics, 2003. 214(1): p. 1-22. 23. Anpo, M. and M. Takeuchi, The design and development of highly reactive titanium oxide photocatalysts operating under visible light irradiation. Journal of Catalysis, 2003. 216(1–2): p. 505-516. 24. Awazu, K., et al., A Plasmonic Photocatalyst Consisting of Silver Nanoparticles Embedded in Titanium Dioxide. Journal of the American Chemical Society, 2008. 130(5): p. 1676-1680. 25. Kale, M.J., T. Avanesian, and P. Christopher, Direct Photocatalysis by Plasmonic Nanostructures. ACS Catalysis, 2013. 4(1): p. 116-128. 26. Xiao, M., et al., Plasmon-enhanced chemical reactions. Journal of Materials Chemistry A, 2013. 1(19): p. 5790-5805. 27. Mukherjee, S., et al., Hot Electrons Do the Impossible: Plasmon-Induced Dissociation of H2 on Au. Nano Letters, 2012. 13(1): p. 240-247. 28. Zhang, X., et al., Plasmon-driven sequential chemical reactions in an aqueous environment. Sci. Rep., 2014. 4. 29. Xu, P., et al., Mechanistic understanding of surface plasmon assisted catalysis on a single particle: cyclic redox of 4-aminothiophenol. Sci. Rep., 2013. 3. 30. Wang, J.L., R.A. Ando, and P.H.C. Camargo, Investigating the Plasmon-Mediated Catalytic Activity of AgAu Nanoparticles as a Function of Composition: Are Two Metals Better than One? ACS Catalysis, 2014: p. 3815-3819. 31. van Schrojenstein Lantman, E.M., et al., Catalytic processes monitored at the nanoscale with tip-enhanced Raman spectroscopy. Nat Nano, 2012. 7(9): p. 583-586. 32. Christopher, P., H. Xin, and S. Linic, Visible-light-enhanced catalytic oxidation reactions on plasmonic silver nanostructures. Nat Chem, 2011. 3(6): p. 467-472. 33. Chen, X., et al., Visible-Light-Driven Oxidation of Organic Contaminants in Air with Gold Nanoparticle Catalysts on Oxide Supports. Angewandte Chemie International Edition, 2008. 47(29): p. 5353-5356. 34. Liu, Z., et al., Plasmon Resonant Enhancement of Photocatalytic Water Splitting Under Visible Illumination. Nano Letters, 2011. 11(3): p. 1111-1116. 35. Wang, F., et al., Plasmonic Harvesting of Light Energy for Suzuki Coupling Reactions. Journal of the American Chemical Society, 2013. 135(15): p. 5588-5601. 36. Nishijima, Y., et al., Near-Infrared Plasmon-Assisted Water Oxidation. The Journal of Physical Chemistry Letters, 2012. 3(10): p. 1248-1252. 37. E. de Jongh, P., D. Vanmaekelbergh, and J. J. Kelly, Cu2O: a catalyst for the photochemical decomposition of water? Chemical Communications, 1999(12): p. 1069-1070. 38. Marimuthu, A., J. Zhang, and S. Linic, Tuning Selectivity in Propylene Epoxidation by Plasmon Mediated Photo-Switching of Cu Oxidation State. Science, 2013. 339(6127): p. 1590-1593. 39. Manjavacas, A., et al., Plasmon-Induced Hot Carriers in Metallic Nanoparticles. ACS Nano, 2014. 8(8): p. 7630-7638. 40. Ueba, H. and B. Gumhalter, Theory of two-photon photoemission spectroscopy of surfaces. Progress in Surface Science, 2007. 82(4–6): p. 193-223. 41. Petek, H. and S. Ogawa, Femtosecond time-resolved two-photon photoemission studies of electron dynamics in metals. Progress in Surface Science, 1997. 56(4): p. 239-310. 42. Brongersma, M.L., N.J. Halas, and P. Nordlander, Plasmon-induced hot carrier science and technology. Nat Nano, 2015. 10(1): p. 25-34. 43. Avanesian, T. and P. Christopher, Adsorbate Specificity in Hot Electron Driven Photochemistry on Catalytic Metal Surfaces. The Journal of Physical Chemistry C, 2014. 44. Linic, S., P. Christopher, and D.B. Ingram, Plasmonic-metal nanostructures for efficient conversion of solar to chemical energy. Nat Mater, 2011. 10(12): p. 911-921. 45. Sun, M. and H. Xu, A Novel Application of Plasmonics: Plasmon-Driven Surface-Catalyzed Reactions. Small, 2012. 8(18): p. 2777-2786. 46. Xu, B.-B., et al., Surface-Plasmon-Mediated Programmable Optical Nanofabrication of an Oriented Silver Nanoplate. ACS Nano, 2014. 8(7): p. 6682-6692. 47. Kleinman, S.L., et al., Creating, characterizing, and controlling chemistry with SERS hot spots. Physical Chemistry Chemical Physics, 2013. 15(1): p. 21-36. 48. Adleman, J.R., et al., Heterogenous Catalysis Mediated by Plasmon Heating. Nano Letters, 2009. 9(12): p. 4417-4423. 49. Fang, Z., et al., Evolution of Light-Induced Vapor Generation at a Liquid-Immersed Metallic Nanoparticle. Nano Letters, 2013. 13(4): p. 1736-1742. 50. Hogan, N.J., et al., Nanoparticles Heat through Light Localization. Nano Letters, 2014. 14(8): p. 4640-4645. 51. Neumann, O., et al., Solar Vapor Generation Enabled by Nanoparticles. ACS Nano, 2013. 7(1): p. 42-49. 52. Christopher, P., et al., Singular characteristics and unique chemical bond activation mechanisms of photocatalytic reactions on plasmonic nanostructures. Nat Mater, 2012. 11(12): p. 1044-1050. 53. Huang, Y., et al., Can p,p′-Dimercaptoazobisbenzene Be Produced from p-Aminothiophenol by Surface Photochemistry Reaction in the Junctions of a Ag Nanoparticle−Molecule−Ag (or Au) Film? The Journal of Physical Chemistry C, 2010. 114(42): p. 18263-18269. 54. Kazumasa Uetsuki, P.V., *,‡,§ Taka-aki Yano,‡ Yuika Saito,‡, Taro Ichimura,‡ and Satoshi Kawata‡, Experimental Identification of Chemical Effects in Surface Enhanced Raman Scattering of 4-Aminothiophenol. J. Phys. Chem. C, 2010. 114: p. 7515–7520. 55. CORPORATION, S.M., http://www.shibaura.co.jp/ 56. 高敦科技公司, http://www.kaoduen.com.tw/. 57. Molecular Probes, I., Product Information LI Silver Enhancement Kit L-24919. 58. -, E.C.b.O.P.-O.P.L.u.C.v.W.C., http://commons.wikimedia.org/wiki/File:ExB_Column.jpg#/media/File:ExB_Column.jpg Focused ion beam. 59. 林智仁, 場發射式掃描式電子顯微鏡的簡介. 工業材料雜誌, 1991. 181: p. 94-99. 60. 中研院物理所, http://www.phys.sinica.edu.tw/~nanofacilities/dbfib.htm. 61. Ryan Fuierer, A.R., Procedural Operation ‘Manualette’Version 10.5. 2009. 62. OLYMPUS, http://www.olympus-ims.com/. 63. COMSOL, http://www.comsol.com/. 64. Moxfyre, b.o.w.o.U.P., wiki, Molecular energy levels and Raman effect. 2009. 65. Stiles, P.L., et al., Surface-Enhanced Raman Spectroscopy. Annual Review of Analytical Chemistry, 2008. 1(1): p. 601-626. 66. Scientific, T.F., http://www.thermoscientific.cn/product/. 67. sigmaaldrich, https://www.sigmaaldrich.com/. 68. Xie, W., B. Walkenfort, and S. Schlücker, Label-Free SERS Monitoring of Chemical Reactions Catalyzed by Small Gold Nanoparticles Using 3D Plasmonic Superstructures. Journal of the American Chemical Society, 2013. 135(5): p. 1657-1660. 69. Wang, H., et al., Plasmon-driven surface catalysis in hybridized plasmonic gap modes. Sci. Rep., 2014. 4. 70. Zhao, L.-B., et al., A DFT study on photoinduced surface catalytic coupling reactions on nanostructured silver: selective formation of azobenzene derivatives from para-substituted nitrobenzene and aniline. Physical Chemistry Chemical Physics, 2012. 14(37): p. 12919-12929. 71. Shalaev, V.M., et al., Negative index of refraction in optical metamaterials. Optics Letters, 2005. 30(24): p. 3356-3358. 72. Schott, Optical glass datasheets http://www.schott.com/. 73. Hayashi, S. and T. Konishi, Scanning Near-Field Optical Microscopic Observation of Surface-Enhanced Raman Scattering Mediated by Metallic Particle-Surface Gap Modes. Japanese Journal of Applied Physics, 2005. 44(7R): p. 5313. 74. Li, S.H.a.X., Optimal Size of Gold Nanoparticles for Surface-Enhanced Raman Spectroscopy under Different Conditions. Journal of Nanomaterials, 2013. 2013. 75. Kim, K., et al., Surface-enhanced Raman scattering of 4,4[prime or minute]-dimercaptoazobenzene trapped in Au nanogaps. Physical Chemistry Chemical Physics, 2012. 14(12): p. 4095-4100. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/4474 | - |
dc.description.abstract | 表面電漿共振光觸媒是近幾年崛起並受高度關注的主題,結合異相觸媒特性以及電漿子結構獨特光學響應性質,使之能夠將發散的光能量集中至反應分子,並提供一條嶄新的控制反應速率及化學反應選擇性之途徑,展現了異相觸媒發展的新希望。由於表面電漿共振的特殊熱電子效應,也使得表面電漿共振光觸媒具有能做到過去傳統熱化學催化反應所不能做到的化學反應可能性。
本論文中使用表面增強拉曼散射光譜進行拉曼熱點區域隨時變之反應偵測,表面增強拉曼散射光譜的就地偵測特性能提供立即的反應偵測,使反應過程更為明朗。並藉由聚焦離子束削磨技術,製造精準的奈米等級結構以對化學反應機制有更進一步的了解。 | zh_TW |
dc.description.abstract | Direct plasmonic photocatalyst is a newly emerging top-trending topic, combining the characteristic of heterogeneous catalyst and the unique light response of plasmon structure, makes it a highly promising way to concentrate light energy into reactant molecule and provides a new pathway to control chemical reaction rate and thus, reaction selectivity. Direct plasmonic photocatalyst also lights up the possibility to do what conventional thermal-based catalysis reaction can’t do, showing up with the new reaction path attributed to the plasmon-induced hot electron effect.
In this endeavor, surface-enhanced Raman spectroscopy (SERS) has been employed to detect time-dependent and hot-spot localized reaction process, and its in-situ detection facilitates the immediately observation of reaction procedure. With the help of focused ion beam milling technique, the precisely designed nanostructure can be fabricated and tailored to discover underlying reaction mechanism. | en |
dc.description.provenance | Made available in DSpace on 2021-05-14T17:42:31Z (GMT). No. of bitstreams: 1 ntu-104-R02222058-1.pdf: 6091167 bytes, checksum: 57b95e53c9012e5611e573f1bcc07681 (MD5) Previous issue date: 2015 | en |
dc.description.tableofcontents | 口試委員會審定書 #
誌謝 I 中文摘要 II ABSTRACT III 目錄 IV 圖目錄 VII 表目錄 XV 第1章 緒論 1 1.1 引言 1 1.2 研究動機 1 第2章 表面電漿共振原理與性質 2 2.1 引言 2 2.2 基礎電磁學及體積電漿共振 2 2.3 表面電漿共振 8 第3章 表面電漿共振增強光觸媒機制探討 12 3.1 異相觸媒簡介 12 3.2 表面電漿共振光觸媒機制 17 3.2.1 表面電漿共振光觸媒 17 3.2.2 彈性二次輻射 19 3.2.3 蘭道阻尼 19 3.2.4 化學介面衰減 24 3.2.5 侷域電場效應 26 3.2.6 電漿子加熱 27 第4章 表面電漿共振光觸媒反應實驗步驟與方法 30 4.1 前言 30 4.2 基板製備儀器與方法 31 4.2.1 濺鍍法製備金屬薄膜 31 4.2.2 熱蒸鍍法製備金屬薄膜 32 4.2.3 光化學方法合成金屬結構 33 4.2.4 聚焦離子束削磨技術 33 4.3 樣品分析與量測方法 34 4.3.1 掃描式電子顯微鏡原理與簡介 34 4.3.2 原子力顯微鏡原理與簡介 36 4.3.3 穿透反射光譜儀原理與簡介 38 4.3.4 Comsol模擬軟體簡介 40 4.4 表面增強拉曼光譜原理與量測 41 4.4.1 拉曼光譜原理 41 4.4.2 表面增強拉曼光譜原理介紹 42 4.4.3 表面增強拉曼光譜儀器與量測方法 43 4.5 化學反應原理介紹 44 4.5.1 PNTP、PATP轉化為DMAB之實驗原理與反應理論 44 第5章 實驗結果與討論 48 5.1 樣品製備與表面形貌量測 48 5.1.1 非規則結構樣品製備方法 48 5.1.2 規則結構樣品製備方法 53 5.2 設計模擬概念與結果討論 55 5.2.1 模擬方法 55 5.2.2 單一圓負結構模擬消光光譜及結構設計 56 5.2.3 規則單一週期圓結構樣品模擬消光及場強圖 59 5.2.4 規則多週期圓結構樣品模擬消光及場強圖 60 5.3 穿透反射消光光譜量測 67 5.3.1 非規則結構樣品 67 5.3.2 規則結構樣品 69 5.4 表面增強拉曼光譜偵測化學反應進行 74 5.4.1 非規則結構樣品 75 5.4.2 規則結構樣品 80 5.5 化學反應效率分析 83 5.5.1 分析方法 83 5.5.2 化學反應效率分析 84 5.6 改變波長對反應影響 89 5.7 比較不同反應物在相同基板反應效率差異 92 5.8 比較同反應物在相同基板以不同偏振反應效率差異 94 第6章 結論 97 參考文獻 98 附錄 102 | |
dc.language.iso | zh-TW | |
dc.title | 表面電漿增強拉曼光譜原位觀察表面電漿共振光催化在化學反應上的影響 | zh_TW |
dc.title | In-Situ Observation of Plasmonic Photocatalytic Reaction by Surface-Enhanced Raman Spectroscopy | en |
dc.type | Thesis | |
dc.date.schoolyear | 103-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 張允崇,藍永強 | |
dc.subject.keyword | 表面電漿光觸媒,表面增強拉曼散射,聚焦離子束,拉曼光譜偵測化學反應,表面電漿子, | zh_TW |
dc.subject.keyword | Plamonic photocatalyst,Surface-Enhanced Raman Spectroscopy (SERS),Focused Ion Beam (FIB),Chemical Reaction Detection by Using Raman Spectrum,Surface Plasmon, | en |
dc.relation.page | 102 | |
dc.rights.note | 同意授權(全球公開) | |
dc.date.accepted | 2015-08-17 | |
dc.contributor.author-college | 理學院 | zh_TW |
dc.contributor.author-dept | 物理研究所 | zh_TW |
顯示於系所單位: | 物理學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-104-1.pdf | 5.95 MB | Adobe PDF | 檢視/開啟 |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。