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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 謝國煌 | |
dc.contributor.author | Ling-Wei Huang | en |
dc.contributor.author | 黃凌威 | zh_TW |
dc.date.accessioned | 2021-06-15T02:29:40Z | - |
dc.date.available | 2010-08-19 | |
dc.date.copyright | 2009-08-19 | |
dc.date.issued | 2009 | |
dc.date.submitted | 2009-08-17 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/43822 | - |
dc.description.abstract | 本研究中探討紫外光可硬化聚胺酯丙烯酸樹脂應用於玻璃基材之防護膜,使玻璃基材能於受撞擊破裂時也不會飛散開。經由比較不同二異氰酸酯、聚合多元醇以及不同設計結構了解各項變因如胺酯連結密度與交聯密度對樹脂熱性質、光學性質與機械性質的影響。
為了達到較佳的玻璃防護效果,樹脂必須擁有絕佳的玻璃黏著力與強韌的機械性質。可利用丙烯酸系矽氧烷化合物3-(甲基丙烯酰氧)丙基三甲氧基矽烷 (3-Methacryloxypropyltrimethoxysilane, MSMA )透過溶膠-凝膠法對玻璃進行改質,使其表面帶有具反應性之壓克力官能基,如此即可於光聚合反應中與聚胺酯丙烯酸樹脂進行形成化學鍵結增強黏著力。對於機械性質的補強有兩種方式,其一為利用高韌性聚胺酯混摻聚胺酯丙烯酸樹脂,使其聚合後形成半網狀互穿高分子結構,得到增韌效果。另一種方法為利用改變平均聚合軟鏈段分子量的形式調整交聯密度與胺酯連結密度,進而合成更加強韌的樹脂。IBp051kDUA樹脂在所合成之樹脂中展現出最好防護效果,能以200μm之厚度在耐撞擊測試中達到最佳測試等級,且塗佈於玻璃上之平均可見光穿透度接近90%。 | zh_TW |
dc.description.abstract | In this study, a series of UV-curable urethane acrylate resin, applied as blast resistant film on the glass substrate were developed. This blast resistant film was designed to be able to stick the glass debris when the glass is broken. We could find the influences of structures with different urethane linkage and crosslink density on thermal, optical, and mechanical properties of urethane acrylate.
In order to reach better protective effect, the resin must have outstanding adhesion strength to glass and mechanical property. To improve the interaction between resin and glass, the 3-Methacryloxypropyltrimethoxysilane (MSMA) was used to modify glass surface through sol-gel process to form the chemical bonds with the urethane acrylate resins during the UV-curing process. Tensile property of urethane acrylate resin can be improved by blending high toughness PU to form semi-IPNs structure. In other way, we can design and synthesis the resin which has proper density of urethane linkage and crosslink point by changing average molecular weight of urethane acrylate monomer. IBp051kDUA exhibit the best protective effect in the blast-resistance test, and IBp051kDUA-coated glass has about 90% visible light transmittance. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T02:29:40Z (GMT). No. of bitstreams: 1 ntu-98-R96524067-1.pdf: 2973806 bytes, checksum: 6d2da61f98f45d32e8730fa32edfd496 (MD5) Previous issue date: 2009 | en |
dc.description.tableofcontents | 摘要 I
ABSTRACT II 目錄 III 表目錄 VII 圖目錄 VIII 第一章 緒論 1 1-1 前言 1 1-2 安全玻璃之發展背景 1 1-3 高分子防護塗料 2 1-4 研究目的 3 第二章 文獻回顧 5 2-1 相關高分子樹脂文獻整理 5 2-1-1 聚胺酯 5 2-1-1-1 聚胺酯簡介 5 2-1-1-2 聚胺酯之微觀相分離 6 2-1-1-3 聚胺酯反應製程與催化劑 7 2-1-2 聚丙烯酸酯 10 2-1-3 聚胺酯丙烯酸酯樹脂 11 2-2 光聚合機制 12 2-2-1自由基鏈成長聚合反應 12 2-2-2 光聚合反應 15 2-2-2-1 光聚合反應簡介 15 2-2-2-2 光起始劑 15 2-2-2-3 氧氣對光聚合之影響 17 2-3 互穿型高分子網狀結構體 18 2-4 溶膠-凝膠法 20 2-4-1 溶膠-凝膠法簡介 20 2-4-2 水解與縮合反應 21 2-4-3 矽氧烷化物改質玻璃 23 第三章 實驗方法與原理 24 3-1 實驗藥品 24 3-2 實驗設備 27 3-3 實驗流程與步驟 29 3-3-1 實驗總流程 29 3-3-2 紫外光可硬化樹脂代號 30 3-3-3 紫外光可硬化樹脂製備 31 3-3-3-1 同分子量雙官能基聚胺酯丙烯酸樹脂 32 3-3-3-2 semi-IPNs聚胺酯丙烯酸樹脂 32 3-3-3-3 聚合軟鏈段型聚胺酯丙烯酸樹脂 33 3-3-3-4 星狀結構聚胺酯丙烯酸樹脂 34 3-4 強化樹脂對玻璃之黏著力 36 3-4-1 聚丙烯酸丁酯之混摻 36 3-4-2 壓克力系矽烷氧化合物改質玻璃 37 3-5 紫外光聚合 38 3-5-1 塊材製作 38 3-5-2 紫外光可硬化樹脂塗佈與光聚合 39 3-6 實驗監測與材料性質分析 39 3-6-1 傅立葉轉換紅外線光譜分析 39 3-6-2 熱重分析儀 40 3-6-3 微差掃描卡計儀 41 3-6-4 紫外光-可見光光譜儀 41 3-6-5 動態機械分析儀 41 3-6-6 百格測試 42 3-6-7 應力-應變性質測試 44 3-6-8 耐撞擊測試 44 第四章 結果與討論 46 4-1 傅立葉轉換紅外線光譜之分析 46 4-1-1同分子量雙官能基聚胺酯丙烯酸樹脂之合成分析 46 4-1-2 semi-IPNs聚胺酯丙烯酸樹脂之合成分析 46 4-1-3聚合軟鏈段型聚胺酯丙烯酸樹脂之合成分析 47 4-1-4星狀結構聚胺酯丙烯酸樹脂之合成分析 48 4-2 熱性質分析 48 4-2-1熱穩定性分析 48 4-2-1-1 同分子量雙官能基聚胺酯丙烯酸樹脂之熱穩定性分析 48 4-2-1-2 semi-IPNs聚胺酯丙烯酸樹脂之熱穩定性分析 49 4-2-1-3聚合軟鏈段型聚胺酯丙烯酸樹脂之熱穩定性分析 49 4-2-1-4 星狀結構聚胺酯丙烯酸樹脂之熱穩定性分析 51 4-2-2 玻璃轉移溫度分析 52 4-2-2-1同分子量雙官能基聚胺酯丙烯酸樹脂之玻璃轉移溫度分析 52 4-2-2-2 semi-IPNs聚胺酯丙烯酸樹脂之玻璃轉移溫度分析 53 4-2-2-3聚合軟鏈段型聚胺酯丙烯酸樹脂之玻璃轉移溫度分析 53 4-2-2-4星狀結構聚胺酯丙烯酸樹脂之玻璃轉移溫度分析 55 4-3 黏著力強化之綜合分析 55 4-3-1 聚丙烯酸丁酯之混摻 56 4-3-2 丙烯酸矽氧烷聚合物改質玻璃 56 4-4 光學性質分析 58 4-4-1 聚胺酯丙烯酸樹脂之可見光穿透度分析 58 4-4-2 MSMA改質玻璃對可見光穿透度的影響 60 4-5 機械性質分析 60 4-5-1 應力-應變測試結果分析 61 4-5-1-1 同軟鏈段分子量聚胺酯丙烯酸樹脂之應力-應變測試分析 61 4-5-1-2 semi-IPNs聚胺酯丙烯酸樹脂之應力-應變測試分析 62 4-5-1-3聚合軟鏈段型聚胺酯丙烯酸樹脂之應力-應變測試分析 63 4-5-1-4星狀結構聚胺酯丙烯酸樹脂之應力-應變測試分析 64 4-5-2 耐撞擊測試結果分析 64 第五章 結論 68 參考文獻 70 | |
dc.language.iso | zh-TW | |
dc.title | 紫外光可硬化聚胺酯丙烯酸樹脂之製備與其應用於高透明度防破裂玻璃保護膜之研究 | zh_TW |
dc.title | Synthesis of UV-Curable Urethane Acrylates and Their Application for High Transparency and Blast-resistence Glass Protective Coating | en |
dc.type | Thesis | |
dc.date.schoolyear | 97-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 韓錦鈴,邱文英,王怡仁 | |
dc.subject.keyword | 紫外光可硬化,聚胺酯丙烯酸樹脂,高透光度,半網狀互穿高分子結構,玻璃塗膜,黏著力,溶膠-凝膠法, | zh_TW |
dc.subject.keyword | UV-curable,Urethane acrylate,High Transparency,Semi-interpenetrating Polymer Networks,Glass Coating,Adhesion,Sol-Gel Process, | en |
dc.relation.page | 109 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2009-08-17 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
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