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請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/43359
完整後設資料紀錄
DC 欄位值語言
dc.contributor.advisor陳永芳(Yang-Fang Chen)
dc.contributor.authorChung-Liang Chengen
dc.contributor.author程仲良zh_TW
dc.date.accessioned2021-06-15T01:51:48Z-
dc.date.available2011-07-21
dc.date.copyright2009-07-21
dc.date.issued2009
dc.date.submitted2009-07-02
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dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/43359-
dc.description.abstract本論文研究主要目的在於了解一維二六族半導體奈米材料的成長機制進而控制其製造與形成。特別地,本論文還檢測了二六族半導體材料的一維結構和不同形貌在奈米尺度下所導致之新奇特性。
我們還試著了解巨觀的實驗裝置改變如何影響奈米材料在微觀上的變化,更近一步了解與控制一維奈米材料的成長,可以使我們能更容易控制奈米材料的結構與形貌,並更容易操作使其成為有用的奈米元件。
本論文涵蓋了下列材料的合成與特性分析: (1)氧化鋅奈米樹枝與奈米塔 (2)硒化鋅奈米線 (3)氧化鋅奈米瓶與奈米針尖複合物 (4)金屬鋅和錫的奈米管與金屬銅和銀的奈米管/奈米線之接合 (5)氧化鋅奈米管。
zh_TW
dc.description.abstractMotivated by a desire to understand the basic concepts of one-dimensional nanostructure growth, the research described in this thesis aims at understanding the basic mechanisms controlling the synthesis and formation of a specific group of II-VI semiconducting nanostructures. In particular, this thesis examines one-dimensional nanostructures and different morphologies of semiconductors that lead to the novel properties of the materials at the nanoscale.
In order to understand how to manipulate the properties of the grown nanostructures, this thesis focuses on having an understanding of the growth mechanism that dictates the morphology and structure. In addition, we also try to understand the impact changes on the nanoscopic scale of the nanomaterials due to the macroscopic setup in the experiment. Having a better understanding and exerting more precise control over the growth of nanomaterials will allow a higher level of selectivity, more control over dimensionality and the type of morphology, easier manipulation, and the simpler incorporation of these structures into a nanotechnological device.
In general, this thesis covers the synthesis and characterization of the following nanomaterials: (1) ZnO nanodendrites and nanotowers, (2) ZnSe nanowires, (3) ZnO nanobottles decorated with ZnO nanotips, (4) metal (Zn, Sn) nanotubes and metal (Cu, Ag) nanotube/nanowire junctions, and (5) ZnO nanotubes. Efforts have been made to pinpoint the underlying science and to exploit their possible engineering applications.
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Previous issue date: 2009
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dc.description.tableofcontentsContents
1 Introduction……………………………………….………....01
1.1 Nanotechnology………………………………………..……..…….01
1.2 Nanostructures.……………………………………………..……....03
1.3 Scope and Aim of the Thesis…………………………...….…...…..04
Reference of Chapter 1 ……………………………………………..06
2 Background Knowledge of Experimental Techniques….....08
2.1 Growth Mechanism of Nanostructures…………..…………….....08
2.1.1 Vapor-Liquid-Solid Growth Mechanism….…………………...…08
2.1.2 Vapor-Solid Growth Mechanism…..……………………………..09
2.1.3 Solution-Liquid-Solid Growth Mechanism…………….…….......11
2.1.4 Oxide-Assisted Growth Mechanism..……………………………12
Reference of Section 2.1 .....………………………………………....14
2.2 Formation Mechanism of Anodic Aluminum Oxide…….…….....16
Reference of Section 2.2 …………………………………………….18
2.3 Basic Concepts of Electrodeposition………………..……...……...19
3 Techniques of Measurement…………………………….…..22
3.1 Transmission Electron Microscope Observation………….….…..22
3.2 Scanning Electron Microscope Observation………………….......22
3.3 Energy Dispersive Spectrometer Analysis…………………….......23
3.4 Cathodoluminescence Measurement…….……………………......23
3.5 X-rays Diffractometry ………………………………………..........24
3.6 Raman Scattering Measurement………..……………………........25
3.7 Field Emission Measurement…….…………..………………........26
Reference of Chapter 3 …………………………………………..…28
4 Patterned Growth of ZnO Nanostructures Based on the Templation of Plant Cell Walls……………………………..29
4.1 Introduction………………………………………………………...29
4.2 Experimental Details……….……………………………………....30
4.3 Results and Discussion……………………………………………..32
4.4 Summary…………………………………………………………....44
Reference of Chapter 4 ……………………………………………....45
5 Low Temperature Synthesis of ZnSe Nanowires by Self-Catalytic Liquid-Solid Growth………….……….……48
5.1 Introduction…………………………………………………...……48
5.2 Experiment Details………...……………………………………….49
5.3 Results and Discussion…………………………………………......50
5.4 Summary………………………………………………………...….56
Reference of chapter 5 ……………………………………………….58
6 Enhancement of Field Emission in Nanotip-Decorated ZnO Nanobottles………………………………………………….60
6.1 Introduction………………………………………………...………60
6.2 Experimental Details…………………………………………….....61
6.3 Results and Discussion……………………………………………..62
6.4 Summary…………………………………………………………....68
Reference of chapter 6 ……………………………………………..…69
7 Fabrication and Growth Mechanism of Metal (Zn, Sn) Nanotube Arrays and Metal (Cu, Ag) Nanotube/Nanowire Junction Arrays……..............................................................71
7.1 Introduction………………………………………………………...71
7.2 Experimental Details……………………………………………….72
7.3 Results and Discussion……………………………………..………73
7.4 Summary……………………………………………………………80
Reference of Chapter 7 …………………………………………........81
8 A Simple Approach for the Growth of Highly Ordered ZnO Nanotube Arrays…………………………….……………...83
8.1 Introduction………………………………………………………...83
8.2 Experimental Details……………………………………………….85
8.3 Results and Discussion…………………………………………..…86
8.4 Summary…………………………………………………………....94
Reference of Chapter 8 ……………………………………………....96
9 Conclusion…………………………………………………..100
dc.language.isoen
dc.subject電鍍zh_TW
dc.subject氧化鋅zh_TW
dc.subject硒化鋅zh_TW
dc.subject奈米結構zh_TW
dc.subject陽極氧化鋁zh_TW
dc.subjectZnSeen
dc.subjectelectrodepositionen
dc.subjectZnOen
dc.subjectanodic aluminum oxideen
dc.subjectnanostructuresen
dc.title一維二六族半導體奈米結構之製造與特性分析zh_TW
dc.titleFabrication and Characterization of One-Dimensional II-VI Semiconducting Nanostructuresen
dc.typeThesis
dc.date.schoolyear97-2
dc.description.degree博士
dc.contributor.oralexamcommittee黃鶯聲,張顏暉,林泰源,沈志霖
dc.subject.keyword氧化鋅,硒化鋅,奈米結構,陽極氧化鋁,電鍍,zh_TW
dc.subject.keywordZnO,ZnSe,nanostructures,anodic aluminum oxide,electrodeposition,en
dc.relation.page103
dc.rights.note有償授權
dc.date.accepted2009-07-03
dc.contributor.author-college理學院zh_TW
dc.contributor.author-dept物理研究所zh_TW
顯示於系所單位:物理學系

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