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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/42957| Title: | 以CTV為基礎之籠狀分子與銨鹽的錯合研究 The Complexation of a CTV-Based Molecular Container to Tetra-alkyl Ammonium Salts |
| Authors: | Tzu-Huan Wong 翁梓桓 |
| Advisor: | 邱勝賢(Sheng-Hsien Chiu) |
| Keyword: | 超分子化學,環三聚藜烴,分子容器, Supramolecular Chemistry,cyclotirveratrylene,Molecular Container, |
| Publication Year : | 2009 |
| Degree: | 碩士 |
| Abstract: | 運用實驗室先前發展出來之ＣＴＶ為基礎的分子容器合成策略，合成以dibenzo-30-crown-10為架構之ＣＴＶ分子容器。將分子容器與適當之客體分子做錯合的研究，從NMR氫譜上可以看到明顯之化學位移改變，可推測我們的分子容器對此客體分子有錯合之作用。 We have synthesized the cyclotirveratrylene molecular container based on dibenzo-30-crown-10 using the method we developed before. We studied the complex character between the molecular container and appropriate guest molecule. It showed that the chemical shift of the 1H-NMR spectra moved obviously. We supposed there were some interaction between our molecular container and the guest molecule. |
| URI: | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/42957 |
| Fulltext Rights: | 有償授權 |
| Appears in Collections: | 化學系 |
Files in This Item:
| File | Size | Format | |
|---|---|---|---|
| ntu-98-1.pdf Restricted Access | 3.73 MB | Adobe PDF |
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