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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 黃孝平(Hsiao-Ping Huang) | |
| dc.contributor.author | Jui-Hung Ho | en |
| dc.contributor.author | 何瑞鴻 | zh_TW |
| dc.date.accessioned | 2021-06-15T01:24:56Z | - |
| dc.date.available | 2009-07-29 | |
| dc.date.copyright | 2009-07-29 | |
| dc.date.issued | 2009 | |
| dc.date.submitted | 2009-07-22 | |
| dc.identifier.citation | [中文]
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Ind. Eng. Chem. Res. 2009 (submitted) | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/42826 | - |
| dc.description.abstract | 反應性分隔內壁蒸餾塔為一項新式整合技術，將具有兩根塔以上之反應蒸餾系統，以分隔內壁觀念整合之，無論在設備成本與操作成本上，反應性分隔內壁蒸餾塔均有相當大的優勢。本文考慮可逆放熱反應A+B<=>C+D之四成份理想系統，並在Tung與Yu及Lin等人針對各種相對揮發度排序下之反應蒸餾系統設計中，採用其中6個雙塔架構，探討其在反應性分隔內壁蒸餾塔上之設計及特性。
本研究除了進行反應性分隔內壁蒸餾塔設計之模擬外，亦提出一項簡易且有效率的方法，在原有的反應蒸餾系統之最佳化條件下，預測出反應性分隔內壁蒸餾塔之節能效益，在理想系統之雙塔及三塔架構上驗證此方法之準確性，均顯示出相當好的結果。 | zh_TW |
| dc.description.abstract | Reactive dividing wall column (RDWC) is a novel thermal coupling technique in chemical engineering industry. For the reactive distillation system (RD system), which contains at least one reactive distillation column (RD) and one distillation column (DC), capital cost and energy consumption could be reduced by integrating the RD system to a RDWC.
In this thesis, a reversible reaction ( ) was considered. For this reaction, Tung and Yu[47] and Lin et al.[31] proposed a series of RD system designs for different relative volatility rankings. Thus, we chose 6 two-column cases in these designs to discuss the characteristics of the RDWC. Besides the simulation work of the RDWC, we proposed a simple but powerful method to estimate the energy consumption of the RDWC by the results of the optimal RD system. In this work, two-column cases and three-column cases were taken to test the precision of this method. The calculation results demonstrated that the accuracy of this method is promising. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T01:24:56Z (GMT). No. of bitstreams: 1 ntu-98-R96524052-1.pdf: 2692492 bytes, checksum: a49b22ad8876d5bc3b5d933ec466af58 (MD5) Previous issue date: 2009 | en |
| dc.description.tableofcontents | 致謝 I
摘要 III Abstract V 目錄 VII 圖索引 IX 表索引 XIII 1 緒論 1 1.1 前言 1 1.2 文獻回顧 7 1.3 研究動機與目的 9 1.4 組織章節 11 2 模擬系統分類及模擬程序 13 2.1 理想系統分類 13 2.2 理想系統之熱力學與動力學模式 14 2.2.1 熱力學模式 14 2.2.2 反應動力學模式 15 2.3 雙塔RD system架構 16 2.4 程序模式假設與規格限制 18 2.5 程序最適化方法：模擬退火法 19 3 穩態設計 23 3.1 前言 23 3.2 雙塔RD system穩態設計 23 3.2.1 Neat IR 24 3.2.2 Neat IIP 26 3.2.3 Neat IIR 29 3.2.4 Excess IP 32 3.2.5 Excess IIIP 35 3.2.6 Excess IIIR 38 3.2.7 RD system穩態設計結果 42 3.3 RDWC穩態設計 44 3.3.1 Neat IR 44 3.3.2 Neat IIP 47 3.3.3 Neat IIR 50 3.3.4 Excess IP 53 3.3.5 Excess IIIP 56 3.3.6 Excess IIIR 59 3.3.7 RDWC穩態設計結果 63 3.4 穩態設計結果之比較與討論 65 3.5 結論 69 4 RDWC之特性探討 71 4.1 前言 71 4.2 塔板數對RDWC影響之探討 71 4.3 反應速率對RDWC影響之探討 75 4.4 結論 77 5 由RD system結果估計RDWC 79 5.1 前言 79 5.2 Underwood’s method 79 5.3 將Underwood’s method應用於RDWC 81 5.3.1 直接序列式部份熱整合RDWC 81 5.3.2 間接序列式部份熱整合RDWC 82 5.4 雙塔架構之計算方式 83 5.4.1 直接序列式 85 5.4.2 間接序列式 90 5.5 結果比較與討論 93 5.6 應用於三塔反應蒸餾系統 96 5.6.1 三塔架構計算方式：PTC_PTC 99 5.6.2 三塔架構計算方式：PTC_FTC 101 5.6.3 結果比較與討論 104 5.7 結論 106 6結論 107 參考文獻 109 附錄A 年總成本計算公式 117 附錄B 符號說明 119 | |
| dc.language.iso | zh-TW | |
| dc.title | 理想系統之反應性分隔內壁蒸餾塔設計與節能研究 | zh_TW |
| dc.title | Design and Energy Saving of Reactive Dividing Wall Column for an ideal System | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 97-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 陳誠亮(Cheng-Liang Chen),黃琦聰(Chi-Tsung Huang),王聖潔(San-Jang Wang) | |
| dc.subject.keyword | 反應性蒸餾,分隔內壁,熱整合,節能效益, | zh_TW |
| dc.subject.keyword | reactive distillation,dividing wall,thermal coupling,energy saving, | en |
| dc.relation.page | 121 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2009-07-23 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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