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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 徐治平 | |
| dc.contributor.author | Wei-Lun Hsu | en |
| dc.contributor.author | 徐偉倫 | zh_TW |
| dc.date.accessioned | 2021-06-15T01:20:45Z | - |
| dc.date.available | 2010-07-28 | |
| dc.date.copyright | 2009-07-28 | |
| dc.date.issued | 2009 | |
| dc.date.submitted | 2009-07-25 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/42718 | - |
| dc.description.abstract | 本論文利用有限元素法探討邊界效應對球形膠體粒子的擴散泳行為的影響。所考慮的系統包括單顆硬球在球形孔洞中任意位置的泳動、單顆軟球在球形孔洞中任意位置的泳動以及單顆硬球沿一長圓管軸心的泳動。吾人深入討論了擴散泳極化效應的情形，定義出兩種不同方向的極化電場，使擴散泳行為得以合理被解釋。並探討電解質溶液中離子與帶電粒子的靜電交互作用力對擴散泳行為的影響。
數值模擬的結果顯示粒子的特性、邊界的幾何形狀、粒子與邊界的距離、粒子表面電位、電雙層厚度及離子的擴散係數大小對擴散泳速度有顯著的影響。在不同的條件下，粒子會往不同方向移動，本論文所獲結果提供擴散泳設計與操作的參考資訊。 | zh_TW |
| dc.description.abstract | The boundary effect on the diffusiophoretic behavior of a particle is analyzed theoretically by considering the diffusiophoresis of a charged sphere under arbitrary surface potential and double-layer thickness at an arbitrary position in an uncharged spherical cavity or along the axis of a cylindrical pore. We show that the factors key to the present problem include two types of double-layer polarization, the repulsion between the particle and the coions accumulated immediately outside the double layer, the difference in ionic diffusivities, and the osmotic flow of solvent. The presence of a boundary can have a profound influence on the behavior of a particle. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T01:20:45Z (GMT). No. of bitstreams: 1 ntu-98-R96524068-1.pdf: 3557069 bytes, checksum: 1cb92bda983998d8b2b4c51e6021d1c8 (MD5) Previous issue date: 2009 | en |
| dc.description.tableofcontents | CONTENTS
CHINESE ABSTRACT I ENGLISH ABSTRACT II CONTENTS III LIST OF FIGURES IV CHAPTER 1 Diffusiophoresis of a Rigid Sphere in a Cavity 1 CHAPTER 2 Diffusiophoresis of a Soft Sphere in a Cavity 55 CHAPTER 3 Diffusiophoresis of a Sphere along the Axis of a Cylindrical Pore 104 CHAPTER 4 Diffusiophoresis of a Charge-Regulated Sphere along the Axis of a Cylindrical Pore 146 CHAPTER 5 Conclusions 193 REFERENCES 199 APPENDIX 206 | |
| dc.language.iso | en | |
| dc.subject | 電雙層 | zh_TW |
| dc.subject | 擴散泳 | zh_TW |
| dc.subject | 極化效應 | zh_TW |
| dc.subject | 邊界效應 | zh_TW |
| dc.subject | 生物膠體粒子 | zh_TW |
| dc.subject | double-layer polarization | en |
| dc.subject | boundary effect | en |
| dc.subject | diffusiophoresis | en |
| dc.subject | cylindrical pore | en |
| dc.subject | spherical cavity | en |
| dc.subject | colloid particle | en |
| dc.title | 邊界效應對擴散泳行為的影響：
球形粒子在球形或圓柱形孔洞中 | zh_TW |
| dc.title | Boundary Effect on Diffusiophoresis：
Sphere in a Spherical Cavity or a Cylindrical Pore | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 97-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 曾秀瑱,張有義,劉博滔,林松華 | |
| dc.subject.keyword | 擴散泳,電雙層,極化效應,邊界效應,生物膠體粒子, | zh_TW |
| dc.subject.keyword | diffusiophoresis,boundary effect,double-layer polarization,colloid particle,spherical cavity,cylindrical pore, | en |
| dc.relation.page | 207 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2009-07-27 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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