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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 黃孝平(Hsiao-Ping Huang) | |
dc.contributor.author | Zi-Liang Kuo | en |
dc.contributor.author | 郭子良 | zh_TW |
dc.date.accessioned | 2021-06-15T01:14:49Z | - |
dc.date.available | 2009-08-06 | |
dc.date.copyright | 2009-08-06 | |
dc.date.issued | 2009 | |
dc.date.submitted | 2009-07-28 | |
dc.identifier.citation | [中 文]
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(Available electronically at http://support.aspentech.com) [9] ASTM D6584-07, “Standard Test Method for Determination of Free and Total Glycerin in B-100 Biodiesel Methyl Esters By Gas Chromatography”, ASTM International, 2007. (Available electronically at http://www.astm.org) [10] Bailey, A. E.; Shahidi, F., “Bailey's Industrial Oil and Fat Products, Volume 2, Edible Oil and Fat Products: Edible Oils, Part 1, 6th Edition”, Wiley-Interscience, 2005. [11] Bambase, M. E.; Nakamura, N.; Tanaka, J.; Matsumura, M., “Kinetics of hydroxide-catalyzed methanolysis of crude sunflower oil for the production of fuel-grade methyl esters”, JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 82 (3): 273-280, Mar 2007. [12] Berrios, M., J. Siles, et al., 'A kinetic study of the esterification of free fatty acids (FFA) in sunflower oil.' Fuel 86(15): 2383-2388., 2005. [13] Bournay, L., D. 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L., “Variables affecting the yields of fatty esters from transesterified vegetable-oils”, JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 61 (10): 1638-1643, 1984. [19] Freedman, B.; Butterfield, R. O.; Pryde, E. H., “Transesterification Kinetics of Soybean Oil”, JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 63 (10): 1375-1380, Oct 1986. [20] Haas, M. J.; McAloon, A. J.; Yee, W. C.; Foglia, T. A., “A process model to estimate biodiesel production costs”, BIORESOURCE TECHNOLOGY, 97 (4): 671-678, Mar 2006. [21] Kiss, A. A.; Omota, F.; Dimian, A. C.;Rothenberg, G., “The heterogeneous advantage: biodiesel by catalytic reactive distillation”, TOPICS IN CATALYSIS, 40 (1-4): 141-150, Nov 2006. [22] Kiss, A. A.; Dimian, A. C.; Rothenberg, G., “Biodiesel Production by Integrated Reactive-Separation Design”, 17th European Symposium on Computer Aided Process Engineering, 2007. [23] Luyben, W. L.; Tyréus, B. D.; Luyben, M. L., “Plantwide Process Control”, McGraw-Hill, New York, USA, 1999. [24] Ma, F. R.; Hanna, M. A., “Biodiesel production: a review”, BIORESOURCE TECHNOLOGY, 70 (1): 1-15, Oct 1999. [25] Mo, X. H., E. Lotero, et al., 'A novel sulfonated carbon composite solid acid catalyst for biodiesel synthesis.' Catalysis Letters 123(1-2): 1-6.2008. [26] NIST Chemistry WebBook, “NIST Standard Reference Database Number 69, June 2005 Release”, National Institute of Standards and Technology (NIST). (Available electronically at http://webbook.nist.gov/chemistry/). [27] Noureddini, H.; Zhu, D., “Kinetics of transesterification of soybean oil”, JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 74 (11): 1457-1463, Nov 1997. [28] O’Brien, R. D.; Farr, W. E.; Wan, P. J., “Introduction to Fats and Oils Technology, 2nd Edition”, Champaign, Illinois, American Oil Chemists' Society, 2000. [29] Omota, F.; Dimian, A. C.; Bliek, A., “Fatty acid esterification by reactive distillation. Part 1: equilibrium-based design”, CHEMICAL ENGINEERING SCIENCE, 58 (14): 3159-3174, Jul 2003a. [30] Omota, F.; Dimian, A. C.; Bliek, A., “Fatty acid esterification by reactive distillation: Part 2 - kinetics-based design for sulphated zirconia catalysts”, CHEMICAL ENGINEERING SCIENCE, 58 (14): 3175-3185, Jul 2003b. [31] Sheehan, J.; Camobreco, V.; Duffield, J.; Graboski, M.; Shapouri, H., “An Overview of Biodiesel and Petroleum Diesel Life Cycles”, NREL/TP-580-24772, National Renewable Energy Laboratory, May 1998. (Available electronically at http://www.doe.gov/bridge). [32] Van Gerpen, J.; Shanks, B.; Pruszko, R.; Clements, D.; Knothe, G., “Biodiesel Production Technology”, NREL/SR-510-36244, National Renewable Energy Laboratory, Jul 2004. (Available electronically at http://www.osti.gov/bridge). [36] Vicente, G.; Martinez, M.; Aracil, J.;, Esteban, A., “Kinetics of sunflower oil methanolysis”, INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 44 (15): 5447-5454, Jul 2005. [34] Weber, W.; Petkov, S.; Brunner, G., “Vapour-liquid-equilibria and calculations using the Redlich-Kwong-Aspen-equation of state for tristearin, tripalmitin, and triolein in CO2 and propane”, FLUID PHASE EQUILIBRIA, 158: 695-706, Jun 1999. [35] Zhang, Y.; Dube, M. A.; McLean, D. D.; Kates, M., “Biodiesel production from waste cooking oil: 1. Process design and technological assessment”, BIORESOURCE TECHNOLOGY, 89 (1): 1-16, Aug 2003a. [36] Zhang, Y.; Dube, M. A.; McLean, D. D.; Kates, M., “Biodiesel production from waste cooking oil: 2. Economic assessment and sensitivity analysis“, BIORESOURCE TECHNOLOGY, 90 (3): 229-240, Dec 2003b. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/42494 | - |
dc.description.abstract | 本研究探討利用非均勻相固體酸觸媒催化製造生質柴油的程序設計。熱力學模式方面,液相與氣相分別採用UNIQUAC活性係數公式以及Redlich-Kwong狀態方程式加以計算液液以及氣液平衡。動力式方面,由於此製程為非均勻相催化故採用Eley-Rideal模式並加以推導其轉酯化與酯化的反應動力式,而後將實驗數據代入回歸出兩組動力式。利用反應之產物會分成有機與甘油兩相,在反應系統內架設分相槽使產物分離並將富含甲醇的甘油相回流至反應器再利用,期能降低反應物甲醇與油料之莫耳比(FR)。藉由反應器之設計方程式(Design Equations)的計算,確立此設計可以有效降低甲醇與油料之莫耳比(FR)與反應所需之觸媒量。
完成五個不同架構之反應系統討論後,再接續藉由整廠程序的設計與年總成本的計算找出其相對應的最適化設計。結論是具有內部回流反應系統的整廠架構由於其後續回收系統能耗較低,使得其年總成本比傳統架構降低了約12%。並以此架構完成同時進行酯化與轉酯化反應之整廠程序的最適化設計。 | zh_TW |
dc.description.abstract | Based-on rigorous thermodynamics and kinetics data, this work utilize UNIQUAC-RK activity coefficient equation and Eley-Rideal kinetics model to calculate the thermodynamic equilibrium and reactions rate more precisely.
Verify the possibility of decreasing the molar ratio of methanol to oil (FR) as well as the amount of catalyst needed by designing the reaction system with internal recycle of glycerol phase then. The results show that FR lowers down more than 20% when reaction systems designed properly, and it corresponds to lower amount of catalyst needed as well. The last section is to compare the conventional and the proposed systems, including the process which allows esterification and transesterification to be carried out simultaneously. The simulation results show that 12% saving of total annual cost (TAC ) by designing the systems with internal recycle of glycerol phase. And the design of simultaneous esterification and transesterification reactions is feasible. Moreover, with cheaper resource of oil utilized, the minimum TAC is expected. | en |
dc.description.provenance | Made available in DSpace on 2021-06-15T01:14:49Z (GMT). No. of bitstreams: 1 ntu-98-R96524048-1.pdf: 2404821 bytes, checksum: 72233e7d82c61c56e1daac94b2f61ceb (MD5) Previous issue date: 2009 | en |
dc.description.tableofcontents | 目錄
致謝 I 摘要 III Abstract V 目錄 VII 圖索引 IX 表索引 XI 1 緒論 1 1.1 前言 1 1.2 文獻回顧 2 1.3 研究動機與目的 4 1.4 組織章節 5 2熱力學與動力學分析 7 2.1 前言 7 2.2 代表性物質之選擇 7 2.3 熱力學模式 10 2.4 熱力學模式預測之驗證 11 2.5 動力學分析 13 2.5.1文獻回顧 13 2.5.2固體酸觸媒轉酯化動力式之分析 17 2.5.3固體酸觸媒酯化動力式之分析 23 3 轉酯化反應系統之設計 25 3.1 前言與文獻回顧 25 3.2 單一反應器 27 3.3 雙重反應器 31 3.3.1雙重反應器串聯 31 3.3.2雙重反應器並輔以分相槽移除甘油相產物 34 3.4 具有內部回流之反應系統 39 3.4.1單一反應器甘油相回流 39 3.4.2具有內部甘油相回流之雙重反應器架構 41 4 生質柴油製程整廠程序設計 45 4.1前言 45 4.2具有內部回流之反應系統之整廠程序設計 46 4.2.1進料設定與產物規範 46 4.2.2使用內部回流反應系統之整廠程序描述 47 4.2.3使用內部回流反應系統之整廠程序描述之最適化探討 51 4.2.4轉酯化反應整廠程序之最適化設計結果討論 56 4.3傳統反應系統之整廠程序設計 66 4.3.1使用傳統反應系統之整廠程序描述 66 4.3.2使用傳統反應系統之整廠最適化設計步驟 73 4.3.3傳統反應系統之整廠程序之最適化設計結果 74 4.4不同反應系統設計之整廠程序比較 80 4.5含游離脂肪酸之進料同時行酯化與轉酯化反應之整廠程序設計結果與討論 81 4.5.1使用內部回流反應系統同時行酯化與轉酯化反應之整廠程序描述 81 4.5.2使用內部回流反應系統同時行酯化與轉酯化反應之整廠程序最適化結果 85 5結論 91 附錄A 油酯之脂肪酸組成 98 附錄B CSTR反應器設計方程式 100 附錄C 年總成本計算公式 102 | |
dc.language.iso | zh-TW | |
dc.title | 利用固體酸觸媒同時進行酯化與轉酯化反應製造生質柴油之整廠程序設計 | zh_TW |
dc.title | Plantwide Design of Biodiesel Production by Simultaneous Esterification and Transesterification over Solid Acid Catalyst | en |
dc.type | Thesis | |
dc.date.schoolyear | 97-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 陳誠亮(Cheng-Liang Chen),吳哲夫(Jeffrey Ward),李明哲(Ming-Jer Lee),汪上曉(David Shan Hill Wong) | |
dc.subject.keyword | 固體酸觸媒催化,生質柴油製程,反應器設計,程序設計, | zh_TW |
dc.subject.keyword | Heterogeneous biodiesel production,Reactor design,Process design, | en |
dc.relation.page | 104 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2009-07-29 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
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