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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/42467完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 吳忠幟 | |
| dc.contributor.author | Chang Chin-Wei | en |
| dc.contributor.author | 張晉瑋 | zh_TW |
| dc.date.accessioned | 2021-06-15T01:14:16Z | - |
| dc.date.available | 2014-07-29 | |
| dc.date.copyright | 2009-07-29 | |
| dc.date.issued | 2009 | |
| dc.date.submitted | 2009-07-28 | |
| dc.identifier.citation | [1] :A. Martin et al., Res. Appl., 16, 435 (2008)
[2] : M. Gratzel et al., Nature, 353, 737－739 (1991) [3] : M. Gratzel et al., J. Am. Chem. Soc., 127, 16852－16847 (2005) [4] : J. Halme et al., Sol. Energy Mater. Sol. Cells, 90, 872－886 (2006) [5] : M. Gratzel, Chem., 44, 6841 (2005) [6] : A. B. F. Martinson et al., Chem. Eur. J., 14, 4458 (2008) [7] : T. W. Hamann et al., Energy Environ. Sci., 1, 66 (2008) [8] : N. Papageorgiou, Coord. Chem. Rev., 248, 1421 (2004) [9] : M. P. Lanurence, Phys. Chem. Chem. Phys., 9, 2630 (2007) [10]: J. Hamle et al., Sol. Energy Mater. Sol. Cells, 90, 872–886 (2006) [11]: M. Gratzel, Nature, 414, 338 (2001) [12]: Takeshi Yamaguchi, Nobuyuki Tobe, Daisuke Matsumoto and Hironori Arakawa, Chem. Commun., 2007, 4767–4769 [13]: Yum Jun-Ho et al., Energy Environ. Sci., 2, 100–102 (2009) [14]: http://www.solaronix.com/products/iodideelectrolytes/iodolyter50/ [15]: T. Watanabe et al., Sol. Energy Mater. Sol. Cells, 90, 640–648 (2006) [16]: H. Lindstrom, J. Photochem. Photobiol. A Chem., 145, 107–112 (2001) [17]: D. Zhang et al., J. Photochem. Photobiol. A Chem., 164,159–166 (2004) [18]: L. N. Lewis et al., Sol. Energy Mater. Sol. Cells, 90, 1041–1051 (2006) [19]: J. N. Hart et al.., Sol. Energy Mater. Sol. Cells, 91, 6–16 (2007) [20]: S. Yanagida et al., Material Research Bulletin, 40, 1335–1344 (2005) [21]: T. N. Murakami et al., J. Photochem. Photobiol. A Chem., 164, 187–191 (2004) | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/42467 | - |
| dc.description.abstract | 我們以商用漿料(Ti-Nanoxide T20-LALT, Solaronix)、(Ti-Nanoxide D20-LALT, Solaronix)製作多孔隙的二氧化鈦電極，以研製低溫製程染料敏化太陽能電池(dye-sensitized solar cells, DSSC)。藉由改變二氧化鈦電極厚度、設計光陷結構、製作堆疊式染料結構及電解液的選擇，以掃描式電子顯微鏡(SEM)、觸針式表面型態分析(Surface Profiling)、電流電壓特性(current-voltage characteristics)、頻譜響應(Spectrum response)等分析方式，探討上述不同的變因對於DSSC之影響，並提升DSSC的光電轉換效率。
在100 mW/cm2 (AM1.5)的模擬太陽光源下，以T20-LALT 為基礎的單層結構，效率可達5.8%。以T20-LALT及D20-LALT 為基礎的雙層結構，效率可達6.2%。以 T20-LALT及D20-LALT 為基礎的三層結構，最高效率可達6.8%，其中開路電壓(open circuit voltage)為0.67V，短路電流密度(short circuit current density)可達15.2mA/cm2，填充因子(fill factor)為0.66。 | zh_TW |
| dc.description.abstract | We used water-based solutions of commercially available gels (Ti-Nanoxide T20-LALT and Ti-Nanoxide D20-LALT) to prepare a porous photoelectrodes for the fabrication of low-temperature-processed dye-sensitized solar cells (DSSC). By varying the thickness and light-trapping structure of the titanium oxide electrodes, the tandem-like double-dye-layer structure and the composition of the electrolytes, we studied their influences on DSSC performances, by analyzing SEM, surface profiling, current-voltage characteristics and spectrum response.
In the single-layer photoelectrode structure, the light-to-electric-energy conversion efficiency of solar cells based on T20-LALT is up to 5.8% at 1 sun illumination (AM1.5, 100 mW/cm2). In the double-layer photoeletrode structure, the light-to-electric-energy conversion efficiency of solar cells based on T20-LALT and D20-LALT is up to 6.2% at 1 sun illumination (AM1.5, 100 mW/cm2). In the triple-layer photoeletrode structure, the light-to-electric-energy conversion efficiency of solar cells based on T20-LALT and D20-LALT is up to 6.8% (Voc= 0.67 V, Jsc =15.2 mA/cm2, FF=0.66) at 1 sun illumination (AM1.5, 100 mW/cm2) . | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T01:14:16Z (GMT). No. of bitstreams: 1 ntu-98-R96941021-1.pdf: 1154257 bytes, checksum: 37de1252c8838f944818a6a3ff837ed4 (MD5) Previous issue date: 2009 | en |
| dc.description.tableofcontents | 口試委員審定書…………………………………………………………………… i
目錄………………………………………………………………………………… ii 誌謝………………………………………………………………………………… iii 中文摘要…………………………………………………………………………… iv 英文摘要…………………………………………………………………………… v 第一章 序論 1.1 太陽能電池發展、現況與應用………………………………………… 1 1.2 染料敏化太陽能電池之介紹…………………………………………… 2 1.3 論文動機與架構 ……………………………………………………… 5 第二章 實驗方法 2.1 染料敏化太陽能電池之製作…………………………………………… 11 2.2 量測方法………………………………………………………………… 13 第三章 結果與討論 3.1 二氧化鈦電極之分析 3.1.1 單層結構………………………………………………………… 19 3.1.2 雙層結構………………………………………………………… 20 3.1.3 三層結構………………………………………………………… 21 3.2 堆疊式染料分析………………………………………………………… 22 3.3 電解液之分析…………………………………………………………… 23 第四章 結論………………………………………………………………………… 38 參考文獻 …………………………………………………………………………… 39 | |
| dc.language.iso | zh-TW | |
| dc.subject | 三層結構 | zh_TW |
| dc.subject | 染料敏化太陽能電池 | zh_TW |
| dc.subject | 二氧化鈦 | zh_TW |
| dc.subject | 雙層結構 | zh_TW |
| dc.subject | double-layer structure | en |
| dc.subject | triple-layer structure | en |
| dc.subject | dye-sensitized solar cell | en |
| dc.subject | Tio2 | en |
| dc.title | 低溫製程染料敏化太陽能電池之研究 | zh_TW |
| dc.title | Studies of Low-Temperature-Processed Dye Sensitized Solar Cells | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 97-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 汪根欉,林建村 | |
| dc.subject.keyword | 染料敏化太陽能電池,二氧化鈦,雙層結構,三層結構, | zh_TW |
| dc.subject.keyword | dye-sensitized solar cell,Tio2,double-layer structure,triple-layer structure, | en |
| dc.relation.page | 39 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2009-07-29 | |
| dc.contributor.author-college | 電機資訊學院 | zh_TW |
| dc.contributor.author-dept | 光電工程學研究所 | zh_TW |
| 顯示於系所單位： | 光電工程學研究所 | |
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