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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/41520完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 蘇國棟(Guo-Dong Su) | |
| dc.contributor.author | Si-Han Zeng | en |
| dc.contributor.author | 曾思翰 | zh_TW |
| dc.date.accessioned | 2021-06-15T00:21:33Z | - |
| dc.date.available | 2014-08-22 | |
| dc.date.copyright | 2011-08-22 | |
| dc.date.issued | 2011 | |
| dc.date.submitted | 2011-08-15 | |
| dc.identifier.citation | [1] 邱國斌、蔡定平 , 金屬表面電漿簡介 物理雙月刊（廿八卷二期） 2006
[2] 吳民耀、劉威志 表面電漿子理論與模擬 物理雙月刊（廿八卷二期）2006 [3] http://www.timkelf.com/Research/ResearchSurfacePlasmons.html [4] J. Ouyang, C.-W. Chu, F.-C. Chen, Q. Xu, Y. Yang High-Conductivity Poly(3,4-ethylenedioxythiophene):Poly(styrene sulfonate) Film and Its Application in Polymer Optoelectronic Devices , Advanced Functional Materials Volume 15, Issue 2, pages 203–208, February, 2005 [5] G. Greczynski, , Th. Kugler and W. R. Salaneck , Characterization of the PEDOT-PSS system by means of X-ray and ultraviolet photoelectron spectroscopy , Thin Solid Films 354 (1999) [6] 罗 洁 ，唐文军, 不同电导率的PEDOT对聚合物光电池性能的影响, Journal of Guangdong University of Technology Vo1．25 No．3 pp. 6-9 September 2008. [7] Nurdan D. Sankir, Selective deposition of PEDOT/PSS on to flexible substrates and tailoring the electrical resistivity by post treatment, Circuit World Volume 34 • Number 4 • 2008 • [8] J. Ouyang, C.-W. Chu, F.-C. Chen, Q. Xu, Y. Yang ,High-conductivity poly (3, 4-ethylenedioxythiophene): poly (styrene sulfonate) film and its application in polymer optoelectronic devices, Advanced Functional Materials Volume 15, Issue 2, pages 203–208, February, 2005 32–37. [9] 柯寶燦 (Bao-Tsan Ko)工業技術研究院 ,材化所 有機固態太陽光電技術研究開發 Development of Organic Solid State Photovoltaics [10] Barry C. Thompson and Jean M. J. Frechet* , Organic Photovoltaics: Polymer–Fullerene Composite Solar Cells Angew. Chem. Int. Ed. 2008, 47, 58 – 77 [11] http://spie.org/Images/Graphics/Newsroom/Imported/0756/0756_fig1.jpg [12] Yang Yang et al. Nature Mater. 2005, 4, 864. [13] http://en.wikipedia.org/wiki/Portal:Electronics/Selected_design [14] Draine, B.T., & Flatau, P.J., 'Discrete dipole approximation for scattering calculations', J. Opt. Soc. Am. A, 11, 1491-1499 (1994) [15] Draine, B.T., & Flatau, P.J., 'User Guide to the Discrete Dipole Approximation Code DDSCAT 7.1', http://arXiv.org/abs/1002.1505v1 (2010) [16] http://www.indium.com/_dynamo/download.php?docid=516 [17] http://www.sigmaaldrich.com/ [18] S.Link and A.El-Sayed, “Size and Temerature Dependence of the Plasmon Absorption of Colloidal Gold Nano -particles”, Phys.Chem. B, 103, 4212 -4217, 1999. | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/41520 | - |
| dc.description.abstract | 在這個研究中，我們發現PEODT:PSS薄膜的電阻會因為加入奈米金粒子而下降，而因為當外加偏壓為零時電流密度也是零，所以我們確定這不是光電流所造成的效應，而是真的電阻下降。為了驗證這個效應，我們使用DDSCAT作為模擬軟體，模擬奈米金粒子在可見光波段的吸收頻譜。利用這個模擬來對照PEDOT:PSS薄膜的電阻對不同入射光波長的變化。因為實驗結果與模擬結果非常的相近，讓我們相信電阻下降的現象是由於奈米金粒子所產生的侷限性表面電漿效應所產生的。
另外，我們利用有機太陽能電池來驗證侷限性表面電漿效應對電阻的改變在有機太陽能電池效率上的影響。首先我們利用NI Multism 來模擬電阻因為表面電漿效應而下降的有機太陽能電池的I-V curve。在實際上作出參雜奈米金粒子的有機太陽能電池，將實驗結果與模擬結果相互映證。由於實驗結果與模擬結果十分相近，我們完成了整個LSPR(Socalized Surface Plasmon Resonance) 對有機導電高分子以及太陽能電池影響的理論。 | zh_TW |
| dc.description.abstract | In this research, the resistance of PEDOT:PSS film is reduced by the LSPR effect that is generated by gold nanoparticles. Because the current density of device is zero wthout applying bias voltage, the decrease of resistance is not caused by photocurrents. From the simulation result of DDSCAT, we can observe that there are a peak on the curve of the absorption factor of gold nanoparticles versus the wavelength. According to this result, we consider that the decrease of resistance relate to the LSPR effect. To further confirm the relationship between resistance and LSPR. Device 2 would be expose to visible light irradiation the wavelength from 350nm-750nm, and measured the current density with bias voltage, it can be observed that the shape of those curve are very consistent with the simulation result. The fact that the resistance of sample would be decreased by LSPR was confirmed again.
To confirm the relationship between resistance ,organic solar cells and LSPR, we use NI multisim to construct the equivalent circuit of organic solar cell and simulate the I-V curve of those organic solar cells with and without gold nanoparticles, and comparing the simulation with the experiment result. Because of the consistence of the simulation and the experiment result, the theoretical framework was complete. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-15T00:21:33Z (GMT). No. of bitstreams: 1 ntu-100-R98941035-1.pdf: 2565089 bytes, checksum: 91b6ecf6156cafbae4dc2f5d302f45be (MD5) Previous issue date: 2011 | en |
| dc.description.tableofcontents | 口試委員會審定書 #
誌謝 i 中文摘要 ii ABSTRACT iii CONTENTS iv LIST OF FIGURES vi LIST OF TABLES ix Chapter 1 Introduction 1 1.1 Motivation 1 1.2 Surface Plasmon 2 1.2.1 Surface plasmon on metal plane 3 1.2.2 Surface plasmon resonance on metal nanoparticles 5 1.3 PEDOT:PSS 8 1.4 Organic Solar Cell 10 1.4.1 BHJ organic solar cell working principles 11 1.4.2 The electrical analysis of BHJ organic solar cells 15 1.4.3 The equivalent circuit of organic solar cell 18 Chapter 2 Simulation 20 2.1 DDSCAT 20 2.1.1 Refractive index 20 2.1.2 Simulation parameter 24 2.1.3 Simulation result 25 2.2 NI Multisim 11 26 Chapter 3 Fabrication 29 3.1 Materials 29 3.2 Structure and Materials preparations 32 3.2.1 Materials preparations 32 3.2.2 Structure 33 3.2.3 Schematic diagram of the whole process 35 Chapter 4 Experiment result and Discussion 37 4.1 The resistance analysis of PEDOT:PSS and organic solar cells 37 4.1.1 Keithley instrument setup 37 4.1.2 Choosing the type of PEDOT:PSS 38 4.1.3 The effects on PEDOT:PSS (Baytron P VP Al 4083) that caused by gold nanoparticles 41 4.1.4 The Influence of Organic Solar Cells by using Gold Nanoparticles 43 4.2 The spectrum analysis of PEDOT:PSS and organic solar cells 50 Chapter 5 Conclusion 55 Chapter 6 Future work 57 REFERENCE 58 Appendix A Optical constants of Gold 60 Appendix B DDSCAT optical constant file 63 | |
| dc.language.iso | en | |
| dc.subject | 聚(3 | zh_TW |
| dc.subject | 侷限性表面電漿 | zh_TW |
| dc.subject | 吩)-聚(苯乙烯磺酸) | zh_TW |
| dc.subject | 4-亞乙二氧基噻 | zh_TW |
| dc.subject | 有機太陽能電池 | zh_TW |
| dc.subject | PEDOT:PSS | en |
| dc.subject | LSPR | en |
| dc.subject | organic solar cell | en |
| dc.title | 參雜奈米金粒子之PEDOT:PSS在有機太陽能與光感測器之應用 | zh_TW |
| dc.title | The application of PEDOT:PSS doped with gold nanoparticles in organic solar and optical sensor | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 99-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 黃鼎偉(Ding-Wei Huang),林致廷(Chih-Ting Lin) | |
| dc.subject.keyword | 聚(3,4-亞乙二氧基噻,吩)-聚(苯乙烯磺酸),侷限性表面電漿,有機太陽能電池, | zh_TW |
| dc.subject.keyword | PEDOT:PSS,LSPR,organic solar cell, | en |
| dc.relation.page | 64 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2011-08-15 | |
| dc.contributor.author-college | 電機資訊學院 | zh_TW |
| dc.contributor.author-dept | 光電工程學研究所 | zh_TW |
| 顯示於系所單位： | 光電工程學研究所 | |
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