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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 戴子安 | |
| dc.contributor.author | Shih-Hau Huang | en |
| dc.contributor.author | 黃世豪 | zh_TW |
| dc.date.accessioned | 2021-06-14T17:08:13Z | - |
| dc.date.available | 2010-07-30 | |
| dc.date.copyright | 2008-07-30 | |
| dc.date.issued | 2008 | |
| dc.date.submitted | 2008-07-27 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/40947 | - |
| dc.description.abstract | Recently, the self-assembling behavior of rod-coil block copolymers has been rapidly explored. In the thesis, an aldehyde-terminated poly(phenylene vinylene) (PPV) was
synthesized by Siegrist polycondensation method, and the polymer had a number average molecular weight of 5000g/mol with narrow polydispersity. In addition, a monodispersed homopolymer living anion of poly(2-vinyl pyridine) (P2VP) was synthesized via anionic polymerization using sec-butyllithium as an initiator. Block copolymers of PPV-b-P2VP were synthesized by a nucleophilic addition reaction between P2VP living anion and aldehyde-terminated PPV. Five PPV-b-P2VP block copolymers with different PPV/P2VP molar ratio were successfully synthesized with high yield (>90%). The synthesized PPV-b-P2VPs were characterized by using various techniques including gel permeation chromatography (GPC), UV-VIS, photoluminescence (PL), TGA (thermogravimetric analysis) and differential scanning calorimetry (DSC). Furthermore, the self-assembling behavior of block copolymers was investigated by using TEM. Different microphase structures, e.g. lamellae, cylinders, and spheres were observed for different compositions of the copolymers. In the end, we used the wide angle X-ray scattering technique to study the crystalline structure of PPV in the PPV-P2VP nanostructure. It was found that the crystallinity of PPV decreases with increasing P2VP molecular weight. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-14T17:08:13Z (GMT). No. of bitstreams: 1 ntu-97-R95549022-1.pdf: 6977088 bytes, checksum: 32d2404a5e24438ade7c6f75fd29e0e1 (MD5) Previous issue date: 2008 | en |
| dc.description.tableofcontents | 摘要.....................................................I
ABSTRACT................................................II 目錄...................................................III 圖目錄...................................................V 表目錄................................................VIII 第一章 緒論..............................................1 第二章 文獻回顧..........................................3 2.1 塊狀共聚高分子.......................................3 2.1.1 介紹...............................................3 2.1.2 硬桿-柔曲塊狀共聚高分子及其合成方法................5 2.2 Poly(p-phenylene vinylene)s （PPVs）................10 2.2.1 合成方法..........................................10 2.2.2 光學性質..........................................22 2.3 陰離子聚合..........................................24 2.3.1 陰離子起始劑 ......................................24 2.3.2 陰離子聚合之單體與反應機制........................24 2.3.3 特殊尾端官能基之陰離子聚合........................26 2.4 含DEH-PPV系列之塊狀共聚高分子及其自組裝行為.........28 第三章 實驗.............................................30 3.1 實驗藥品............................................30 3.2 儀器設備............................................32 3.3 實驗步驟............................................33 3.3.1 合成DEH-PPV.......................................33 3.3.2 陰離子聚合........................................37 3.3.3 合成塊狀共聚高分子 DEH-PPV-b-P2VP.................43 第四章 結果與討論.......................................45 4.1 DEH-PPV及其單體合成之鑑定...........................45 4.1.1 單體合成之鑑定....................................45 4.1.2 DEH-PPV合成鑑定...................................46 4.2 P2VP 合成之鑑定.....................................48 4.3 塊狀共聚高分子DEH-PPV-b-P2VP合成之鑑定..............49 4.4光學性質分析.........................................50 4.4.1 UV / Vis光譜分析..................................50 4.4.2 PL光譜分析........................................50 4.5熱性質分析...........................................51 4.5.1 TGA ...............................................51 4.5.2 DSC ...............................................51 4.6 DEH-PPV-b-P2VP之微結構分析..........................52 4.6.1 TEM影像分析.......................................52 4.6.2 WAXS圖譜分析......................................52 第五章 結論.............................................55 參考文獻................................................57 附錄....................................................60 | |
| dc.language.iso | zh-TW | |
| dc.subject | 自組裝行為 | zh_TW |
| dc.subject | 硬桿-柔曲塊狀共聚高分子 | zh_TW |
| dc.subject | 聚對苯乙烯 | zh_TW |
| dc.subject | 聚2 乙烯 | zh_TW |
| dc.subject | 陰離子聚合 | zh_TW |
| dc.subject | 尾端偶合反應 | zh_TW |
| dc.subject | self-assembling behavior | en |
| dc.subject | rod-coil block copolymer | en |
| dc.subject | poly(phenylene vinylene) | en |
| dc.subject | poly(2-vinyl pyridine) | en |
| dc.subject | anionic polymerization | en |
| dc.subject | end-coupling reaction | en |
| dc.title | 利用偶合反應法合成聚對苯乙烯-聚2 乙烯之
硬桿-柔曲塊狀共聚高分子及其自組裝特性研究 | zh_TW |
| dc.title | End-Coupling Synthesis of Poly (phenylene vinylene)-b-Poly
(2-vinyl pyridine) Rod-Coil Block Copolymers and Their Self-Assembling Behavior | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 96-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 邱文英,王立義,芮祥鵬,程耀毅 | |
| dc.subject.keyword | 硬桿-柔曲塊狀共聚高分子,聚對苯乙烯,聚2 乙烯,陰離子聚合,尾端偶合反應,自組裝行為, | zh_TW |
| dc.subject.keyword | rod-coil block copolymer,poly(phenylene vinylene),poly(2-vinyl pyridine),anionic polymerization,end-coupling reaction,self-assembling behavior, | en |
| dc.relation.page | 83 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2008-07-29 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
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