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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 蔡蘊明 | |
| dc.contributor.author | Tzu-Chiun Lin | en |
| dc.contributor.author | 林子群 | zh_TW |
| dc.date.accessioned | 2021-06-14T17:04:07Z | - |
| dc.date.available | 2013-08-05 | |
| dc.date.copyright | 2008-08-05 | |
| dc.date.issued | 2008 | |
| dc.date.submitted | 2008-07-29 | |
| dc.identifier.citation | 1.(a) Nicolaou, K. C.; Vourloumis, D.; Winssinger, N.; Baran, P. S. Angew. Chem. Int. Ed. 2000, 39, 44–122.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/40865 | - |
| dc.description.abstract | 我們合成了一個含有胍基(Guanidinium)的客體分子，並發現其可與適當的大環分子在低極性溶液中形成穩定的錯合物。為證明此一錯合物主要是以準車輪烷形式存在溶液中，我們以「穿透後封鎖法」合成出一個同時具有胍基和吡啶(Pyridinium)二個辨識中心的車輪烷分子並成功地藉著改變溶劑極性及加入/移除鹵素離子或醋酸根離子來加以控制大環分子和胍基分子間的錯合與解離，進而操作分子開關的移動異構化（translational isomerization）。 | zh_TW |
| dc.description.abstract | We have demonstrated that guanidinium ions can thread through the cavity of BPX26C6 to form [2]pseudorotaxane-like complexes in low-polarity solvents. A [2]rotaxane derived from this new recognition system functions as a molecular switch, in which translational movement of macrocyclic component can be controlled two ways: through changes in solovent polarity and through exchanges of the counter anions. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-14T17:04:07Z (GMT). No. of bitstreams: 1 ntu-97-R95223045-1.pdf: 1771597 bytes, checksum: 4fb1f891aff3330223cf2a04b05c86ce (MD5) Previous issue date: 2008 | en |
| dc.description.tableofcontents | 摘要 ... I
目次 ... III 式子 ... IV 圖表 ... V 流程 ... VII 表 格... VIII 壹、導論 ... 1 1.1 前言 ... 1 1.2 超分子化學 ... 2 1.3 內鎖型分子—車輪烷及環連體 ... 7 1.4 分子開關 ...11 1.5 以陰離子控制之分子開關.... 15 貳、結果與討論 ... 20 2.1 研究動機 ... 20 2.2 車輪烷分子的設計與合成...21 2.3 分子開關的改良與研究 ... 30 參、結論 ...40 肆、實驗部份 ...41 伍、參考文獻 ...60 附錄 2D-NMR、1H-NMR與 13C-NMR 核磁共振光譜 ...65 | |
| dc.language.iso | zh-TW | |
| dc.subject | 陰離子 | zh_TW |
| dc.subject | 分子開關 | zh_TW |
| dc.subject | anion | en |
| dc.subject | Molecular switch | en |
| dc.title | 以胍基為基礎的分子開關之合成研究 | zh_TW |
| dc.title | A Guanidinium Ion-Based Anion Controllable Molecular Switch | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 96-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.coadvisor | 邱勝賢 | |
| dc.contributor.oralexamcommittee | 徐秀福,賴建成 | |
| dc.subject.keyword | 分子開關,陰離子, | zh_TW |
| dc.subject.keyword | Molecular switch,anion, | en |
| dc.relation.page | 65 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2008-07-29 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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