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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 柯淳涵(Chun-Han Ko) | |
dc.contributor.author | Szu-Hsien Wu | en |
dc.contributor.author | 吳思嫻 | zh_TW |
dc.date.accessioned | 2021-06-14T16:58:30Z | - |
dc.date.available | 2018-07-28 | |
dc.date.copyright | 2008-08-05 | |
dc.date.issued | 2008 | |
dc.date.submitted | 2008-07-30 | |
dc.identifier.citation | Atlow, S. C., L. Bonadonna-Aparo, A. M. Klibanov (1984) Dephenolization of industrial waste waters catalyzed by polyphenol oxidase. Biotechnologyl Bioengineering 26:599-603.
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/40746 | - |
dc.description.abstract | 製漿造紙業為主要民生工業之一,然而所產生的廢水有機物中木質素基團含量豐富,不易以傳統方式完全去除。漆酶為一種蛋白質,其中心結構含有銅原子,以形成自由基之方式促成酚類物質的高分子化,可使廢水中之酚類物質聚合。薄膜處理程序是以壓力驅動方式,使溶液通過孔徑大小不同之薄膜,而分離水中的物質。薄膜以孔徑大小及其所能阻隔之分子量,可區分為:微過濾(MF)、超過濾(UF)、奈濾(NF)以及逆滲透(RO)等四種方式。
本研究選用Guaiacol、Catechol與Cresol三種酚類物質與漿紙廠中原廢水、一級放流水以及二級放流水。以漆酶活性 2.98 IU/L,在常溫下與酚類和廢水作用,再使用凝膠色譜分析(GPC) 檢測其分子量變化。經過一小時後,Guaiacol 分子量可聚合至9600,Cresol分子量聚合至5400,Catechol則聚合至8350。原廢水、一級放流水與二級放流水可分別自平均分子量540.81、310.53與225.78聚合至4624.08、986.02與487.76。無論是不同酚類或各種廢水,一小時後分子量並無明顯增加。 本研究將三種酚類與廢水分別與活性 2.98 IU/L漆酶作用,再以分子量阻隔(MWCO)為54,000 Da、30,000 Da、10,000 Da、5,000 Da與300 Da之超過濾/納濾薄膜進行掃流式過濾,並同時觀查流速變化。因酚類與廢水之聚合物在薄膜上形成膠層而使流速降低。流速減緩情形,依據不同薄膜孔徑大小亦有所不同。未經反應之Guaiacol 的去除率為36%至48%,經過漆酶聚合180 分鐘後,去除率達54%至68%;Catechol的化學需氧量去除率由32%至48%提升至50%至65%;Cresol的化學需氧量去除率由21%至35%提升至48%至62%。 製漿造紙廢水方面,漆酶聚合處理可將原廢水的化學需氧量去除率,由40%至50%提升至53%至63%;一級放流水的化學需氧量去除率由34%至47%提升至52%至68%;二級放流水的化學需氧量去除率由34%至45%提升至52%至68%。薄膜孔徑越小,則漆酶提升製漿造紙廢水化學需氧量去除率的效應越佳。 | zh_TW |
dc.description.abstract | The pulp and paper industry is one of the prime consumer product industries. However, organics in its wastewater, containing lignin-related functional groups, is difficult to be completely removed by conventional methods. Laccase is a copper-centered protein. It could polymerize phenols by free radical formation. It could also promote polymerization of phenols in wastewater. Membrane treatment processes are pressure-driven. It could drive solution through membranes with different pore sizes and separate solutes in water. Membrane processes are categorized by their pore sizes and molecular cutoffs as the following: microfiltration (MF), ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO).
This research employed three kinds of phenols (Guaiacol, Catechol and Cresol) as well as pulp and paper raw, primary and secondary wastewaters. Under room temperature, phenol solutions and wastewaters reacted with 2.98IU/L laccase. Then gel permeation chromatography (GPC) was then employed to analyze the changes of molecular weights. After an hour, molecular weights of guaiacol, cresol and catechol solutions were increased to 9600, 5400 and 8350. Averaged molecular weights of raw, primary and secondary wastewaters were polymerized from 540.81, 310.53 and 225.78 to 4624.08, 986.02 and 487.76, respectively. After more than an hour, the molecular weights of phenol solutions and wastewaters did not exhibit significant increases. At this study, phenols and wastewater, after reacted with 2.98 IU/L laccase, were cross-flow filtered by MWCO 54,000 Da, 30,000 Da, 10,000 Da, 5,000 Da and 300 Da UF/NF membranes. Flux variations were monitored simultaneously. The fluxes decreased due to gel layer formation by polymerized products. Extents of flux decline depended on the pore sizes of membranes. Without polymerization, the removals of guaiacol has been from 36% to 48%, after laccase polymerization for 180 min, the removals were increased from 54%~68%. The removals of catechol were increased from 32%~48% to 50%~65%; the removals of cresol were increased from 21%~35% to 48%~62%. As for pulp and paper wastewaters polymerized by laccase, the removals COD in raw wastewater were improved from 40% ~50% to 53%~63%; from 34%~47% to 52%~68% for primary wastewater; from 34%~45% to 52%~68% for secondary wastewater. The results demonstrated that the less the molecular weight cutoff pore sizes led the more significant enhancement for pulp and paper wastewater COD removal by laccase polymerization. | en |
dc.description.provenance | Made available in DSpace on 2021-06-14T16:58:30Z (GMT). No. of bitstreams: 1 ntu-97-R93625009-1.pdf: 861429 bytes, checksum: 8830990070e5d3e0da475f6ce7f708e4 (MD5) Previous issue date: 2008 | en |
dc.description.tableofcontents | Index
口試委員審定書 I 謝誌 II 摘要 III Abstract V Index VII Figure index X Table index XII I Introduction 1 II Literature reviews 4 2.1 Membrane technology 4 2.1.1 The Kinds of the membrane 5 2.1.2 The process of the membrane 6 2.1.2.1 Microfiltration 6 2.1.2.2 Ultrafiltration 7 2.1.2.3 Nanofiltration 7 2.1.2.4 Reverse Osmosis 8 2.1.3 Membrane operation process 11 2.1.4 The advantage of membrane process 13 2.1.5 The limits of membranes 13 2.1.6 Flux models 16 III Materials and methods 17 3.1 The process of this study 17 3.2 Model phenols 17 3.3 Laccase and its assay 18 3.4 Membrane separation 18 3.5 Gel permeation chromatography 19 3.6 Analysis of wastewater 20 IV Results and discussion 21 4.1 GPC 21 4.1.1 Phenols 21 4.1.2 Wastewater 23 4.2 Flux reduction-phenols 25 4.2.1 Guaiacols 25 4.2.2 Catechol 27 4.2.3 Cresol 29 4.3 Flux reduction- wastewater 31 4.3.1 Raw wastewater 31 4.3.2 Primary wastewater 33 4.3.3 Secondary wastewater 35 4.4 COD reduction- phenols 37 4.4.1 Guaiacols 37 4.4.2 Catechol 39 4.4.3 Cresol 41 4.5 COD reduction- wastewater 43 4.5.1 Raw wastewater 43 4.5.2 Primary wastewater 45 4.5.3 Secondary wastewater 47 4.6 Membrane resistance-in-series-models 49 4.6.1 Phenols 49 4.6.2 Wastewater 50 V Conclusions 51 VI References 53 Appendix 59 Figure Index Fig. 2.1 Membrane separation capabilities for different materials 9 Fig. 2.2 Schematics of cross-flow filtration (A) and dead-end filtration (B) 11 Fig. 2.3 Membrane fouling mechanisms 15 Fig. 3.1 Phenol model compounds: 1.guaiacol, 2. catechol, 3. cresol 17 Fig. 3.2 The schematic diagram of membrane filtration 19 Fig. 4.1.1 Molecular weight changes for (a) guaiacol (b) catechol and (c) cresol with laccase 21 Fig. 4.1.2 Molecular weight changes for (a) raw wastewater (b) primary wastewater and (c) secondary wastewater with laccase 23 Fig. 4.2.1 Flux reduction of guaiacol for (a) 54,000 Da (b) 30,000 Da (c) 10,000 Da (d) 5,000 Da and (e) 300 Da MWCO membranes 25 Fig. 4.2.2 Flux reduction of catechol for (a) 54,000 Da (b) 30,000 Da (c) 10,000 Da (d) 5,000 Da and (e) 300 Da MWCO membranes 27 Fig. 4.2.3 Flux reduction of cresol for (a) 54,000 Da (b) 30,000 Da (c) 10,000 Da (d) 5,000 Da and (e) 300 Da MWCO membranes 29 Fig. 4.3.1 Flux reduction of raw wastewater for (a) 54,000 Da (b) 30,000 Da (c) 10,000 Da (d) 5,000 Da and (e) 300 Da MWCO membranes 31 Fig. 4.3.2 Flux reduction of primary wastewater for (a) 54,000 Da (b) 30,000 Da (c) 10,000 Da (d) 5,000 Da and (e) 300 Da MWCO membranes 33 Fig. 4.3.3 Flux reduction of secondary wastewater for (a) 54,000 Da (b) 30,000 Da (c) 10,000 Da (d) 5,000 Da and (e) 300 Da MWCO membranes 35 Fig.4.4.1 COD reduction of guaiacol for (a) 54,000 Da (b) 30,000 Da (c) 10,000 Da (d) 5,000 Da and (e) 300 Da MWCO membranes 37 Fig.4.4.2 COD reduction of guaiacol for (a) 54,000 Da (b) 30,000 Da (c) 10,000 Da (d) 5,000 Da and (e) 300 Da MWCO membranes 39 Fig.4.4.3 COD reduction of guaiacol for (a) 54,000 Da (b) 30,000 Da (c) 10,000 Da (d) 5,000 Da and (e) 300 MWCO Da MWCO membranes 41 Fig.4.5.1 COD reduction of raw wastewater for (a) 54,000 Da (b) 30,000 Da (c) 10,000 Da (d) 5,000 Da and (e) 300 MWCO Da MWCO membranes 43 Fig.4.5.2 COD reduction of primary wastewater for (a) 54,000 Da (b) 30,000 Da (c) 10,000 Da (d) 5,000 Da and (e) 300 Da MWCO membranes 45 Fig.4.5.3 COD reduction of secondary wastewater for (a) 54,000 Da (b) 30,000 Da (c) 10,000 Da (d) 5,000 Da and (e) 300 Da MWCO membranes 47 Table Index Table 2-1 Overview of the membrane process 10 Table 3-1Characteristics of membranes used in this study 18 Table 4-1Resistance in series for guaiacol 49 Table 4-2 Resistance in series for catechol 49 Table 4-3 Resistance in series for cresol 49 Table 4-4 Resistance in series for raw wastewater 50 Table 4-5 Resistance in series for primary wastewater 50 Table 4-6 Resistance in series for secondary wastewater 50 | |
dc.language.iso | zh-TW | |
dc.title | 使用超過濾及漆酶聚合淨化酚類及漿紙廠廢水 | zh_TW |
dc.title | Enhanced Removal of Phenols and Pulp and Paper Wastewater by Ultrafiltration and Laccase Polymerization | en |
dc.type | Thesis | |
dc.date.schoolyear | 96-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 蕭英倫,林奇剛,陳孝行,張上鎮 | |
dc.subject.keyword | 漆酶,薄膜處理程序,製漿造紙廢水,酚類,凝膠色譜分析, | zh_TW |
dc.subject.keyword | laccase,membrane treatment process,pulp and paper wastewater,phenols,gel permeation chromatography, | en |
dc.relation.page | 72 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2008-07-30 | |
dc.contributor.author-college | 生物資源暨農學院 | zh_TW |
dc.contributor.author-dept | 森林環境暨資源學研究所 | zh_TW |
顯示於系所單位: | 森林環境暨資源學系 |
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