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  1. NTU Theses and Dissertations Repository
  2. 生物資源暨農學院
  3. 森林環境暨資源學系
請用此 Handle URI 來引用此文件: http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/40432
完整後設資料紀錄
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dc.contributor.advisor張上鎮(Shang-Tzen Chang)
dc.contributor.authorChun-Ya Linen
dc.contributor.author林群雅zh_TW
dc.date.accessioned2021-06-14T16:47:29Z-
dc.date.available2010-08-06
dc.date.copyright2008-08-06
dc.date.issued2008
dc.date.submitted2008-07-29
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Hsu, F. L., H. T. Chang and S. T. Chang (2007) Evaluation of antifungal properties of octyl gallate and its synergy with cinnamaldehyde. Bioresource Technology 98: 734-738.
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Lόpez, P., C. Sánchez, R. Batlle and C. Nerín (2007) Vapor-phase activities of cinnamon, thyme, and oregano essential oils and key constituents against foodborne microorganisms. Journal of Agricultural and Food Chemistry 55: 4348-4356.
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Singh, G. and P. Marimuthu (2006) Antioxidant and biocidal activities of carum nigrum (Seed) essential oil, oleoresin, and their selected components. Journal of Agricultural and Food Chemistry 54: 174-181.
Singh, G., S. Maurya, M. P. deLampasosna and C. A. N. Catalan (2007) A comparison of chemical, antioxidant and antimicrobial studies of cinnamon leaf and bark volatile oils, oleoresins and their constituents. Food and Chemical Toxicology 45: 1650-1661.
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Tucker, E. J. B., A. Bruce and H. J. Staines (1997) Application of modified international wood preservative chemical testing standards for assessment of biocontrol treatments. International Biodeterioration and Biodegradation 39: 189-197.
Tunc, S., E. Chollet, P. Chalier, L. Preziosi-Belly and N. Gontard (2007) Combined effect of volatile antimicrobial agents on the growth of Penicillium notatum. International Journal of Food Microbiology 113: 263-270.
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Yen, T. B. and S. T. Chang (2008) Synergistic effects of cinnamaldehyde in combination with eugenol against wood decay fungi. Bioresource Technology 99: 232-236.
Yildiz, U. C., A. Temiz, E. D. Gezer and S. Yildiz (2004) Effects of the wood preservatives on mechanical properties of yellow pine (Pinus sylvestris L.) wood. Building and Environment 39: 1071-1075.
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dc.identifier.urihttp://tdr.lib.ntu.edu.tw/jspui/handle/123456789/40432-
dc.description.abstract防腐藥劑處理可有效地延長木材的使用年限,傳統的CCA(Chromated copper arsenate)木材防腐藥劑雖有很好的效果,但對人類及環境有毒性而逐漸被禁止使用,因此,尋找新的、有效的及安全的木材防腐藥劑便成為十分重要的議題。有鑑於此,本研究探討土肉桂(Cinnamomum osmophloeum)葉子精油中之主成分-桂皮醛抑制木材腐朽菌生長之機制,並進行桂皮醛處理材之木塊耐腐朽及耐白蟻試驗,同時測試桂皮醛處理材耐腐朽及耐白蟻之長效性;此外,亦評估桂皮醛在不同環境因子中之安定性。
由木塊耐腐朽及耐白蟻試驗結果得知,桂皮醛處理材經Lenzites betulina白腐菌、Laetiporus sulphureus褐腐菌腐朽及家白蟻(Coptotermes formosanus)啃食後之重量損失率皆顯著地小於未處理材之重量損失率,證實木材以桂皮醛含浸處理後能有效地減少腐朽菌及白蟻的危害,同時亦證明桂皮醛處理材長時間放置於常溫環境中,其耐腐朽及耐白蟻效果至少可維持一年。又由2種抗菌試驗方法(瓊脂稀釋法及紙片倒置法)及抗白蟻試驗得知,空間中桂皮醛含量愈高,抑制腐朽菌生長和白蟻忌避之活性愈佳,試驗結果證明桂皮醛抑制木材腐朽菌生長及白蟻之機制主要係由揮發性所造成。此外,根據桂皮醛安定性之評估結果得知,桂皮醛放置於常溫或不同酸鹼值環境中安定性良好。綜合上述試驗結果證明桂皮醛深具潛力應用為天然木材防腐藥劑。
zh_TW
dc.description.abstractTo prolong the service life of wood effectively, treating wood with appropriate preservatives is necessary. Although traditional wood preservative, chromated copper arsenate (CCA), possessed strong antifungal property, it was phased out due to its toxicity to human being and environment. Therefore, it is imperative to find out a novel, effective, and safe wood preservative to replace conventional ones. Thus, in this study the major constituent of leaf essential oil from Cinnamomum osmophloeum, cinnamaldehyde, was used to explore its mechanisms of inhibiting the growth of wood-rot fungi. The fungi decay resistance, termite attack resistance and long-term effectiveness of cinnamaldehyde-treated wood were evaluated. In addition, the stability of cinnamaldehyde at different temperature and pH conditions was also investigated, respectively.
Results from 90-day fungi (white-rot fungus Lenzites betulina and brown-rot fungus Laetiporus sulphureus) decay test and 30-day anti-termite (Coptotermes formosanus) test showed that weight losses of cinnamaldehyde-treated specimens were significantly lower than non-treated ones, revealing that cinnamaldehyde can endow wood block with excellent fungi decay resistance and termite attack resistance. In addition, the long-term effectiveness with excellent performance of cinnamaldehyde-treated wood was proved to last for 1 year at least. Also, from two antifungal methods (agar dilution method and inverted paper disc method) and anti-termitic test showed that the strong antifungal and antitermitic activities were observed when cinnamaldehyde released more amounts into headspace, indicating that mechanism of cinnamaldehyde inhibited the growth of wood-rot fungi and repelled the
termites resulted from its volatility. Moreover, results from the evaluation of cinnamaldehyde stability revealed that cinnamaldehyde was stable at ambient temperature and various pH values. According to forgoing results, cinnamaldehyde possessed the great potential to be used as a natural wood preservative.
en
dc.description.provenanceMade available in DSpace on 2021-06-14T16:47:29Z (GMT). No. of bitstreams: 1
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Previous issue date: 2008
en
dc.description.tableofcontents目錄 I
表目錄 IV
圖目錄 VII
摘要 X
Abstract XI
壹、前言 1
貳、文獻回顧 3
一、木材保存藥劑 3
(一)傳統的木材保存藥劑 3
(二)新型之木材保存藥劑 5
1. 銅、烷基銨化合物 5
2. 銅、硼、唑化合物 6
3. Copper bis-(N-cyclohexyldiazeniumdioxy) 6
二、植物天然抽出物含浸於木材中之耐腐朽活性 7
三、桂皮醛之活性 14
(一)抗細菌活性 14
(二)抗植物病原菌活性 17
(三)抗白蟻活性 19
(四)抗木材腐朽菌活性 20
參、材料與方法 29
一、試驗材料 29
(一)柳杉 29
(二)桂皮醛處理材 29
(三)木材腐朽菌 30
(四)培養基 30
(五)白蟻 30
(六)藥品 30
1. 試藥 30
2. 標準品 31
二、試驗方法 31
(一)抗腐朽菌試驗 31
1. 瓊脂稀釋法 31
2. 紙片倒置法 32
(二)木材耐腐朽試驗 33
(三)抗白蟻試驗 33
(四)桂皮醛安定性試驗 34
1. 酸鹼安定性 34
2. 熱安定性 34
三、性質分析 35
(一)桂皮醛之分析與定量 35
(二)紫外光吸收光譜測定 37
(三)傅立葉轉換紅外線光譜分析 37
(四)統計分析 38
肆、結果與討論 39
一、桂皮醛對木材腐朽菌之抑菌機制 39
二、桂皮醛處理材之抗腐朽菌活性 45
(一)木材以桂皮醛含浸處理後之化學結構變化 45
(二)桂皮醛處理材之耐腐朽性 46
(三)傅立葉轉換紅外線光譜分析腐朽後木材的化學結構變化 48
(四)處理材耐腐朽之長效性 53
三、桂皮醛之抗白蟻活性 56
四、桂皮醛之安定性 58
(一)熱安定性 58
(二)酸鹼安定性 59
伍、結論 62
陸、參考文獻 64
dc.language.isozh-TW
dc.subject長效性zh_TW
dc.subject桂皮醛zh_TW
dc.subject耐腐朽性zh_TW
dc.subject天然木材防腐劑zh_TW
dc.subject安定性zh_TW
dc.subject耐白蟻性zh_TW
dc.subjectCinnamaldehydeen
dc.subjectTermite attack resistanceen
dc.subjectStabilityen
dc.subjectNatural wood preservativeen
dc.subjectLong-term effectivenessen
dc.subjectFungi decay resistanceen
dc.title桂皮醛應用為天然木材防腐劑之潛力評估zh_TW
dc.titlePotency Evaluation of Cinnamaldehyde as a Natural Wood Preservativeen
dc.typeThesis
dc.date.schoolyear96-2
dc.description.degree碩士
dc.contributor.oralexamcommittee李鴻麟(Hong-Lin Lee),蘇裕昌(Yu-Chang Su),王升陽(Sheng-Yang Wang),張惠婷(Hui-Ting Chang)
dc.subject.keyword桂皮醛,耐腐朽性,長效性,天然木材防腐劑,安定性,耐白蟻性,zh_TW
dc.subject.keywordCinnamaldehyde,Fungi decay resistance,Long-term effectiveness,Natural wood preservative,Stability,Termite attack resistance,en
dc.relation.page69
dc.rights.note有償授權
dc.date.accepted2008-07-31
dc.contributor.author-college生物資源暨農學院zh_TW
dc.contributor.author-dept森林環境暨資源學研究所zh_TW
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