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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 徐治平 | |
dc.contributor.author | Ming-Hong Ku | en |
dc.contributor.author | 古明弘 | zh_TW |
dc.date.accessioned | 2021-06-13T16:50:08Z | - |
dc.date.available | 2007-07-15 | |
dc.date.copyright | 2005-07-15 | |
dc.date.issued | 2005 | |
dc.date.submitted | 2005-06-23 | |
dc.identifier.citation | 第一章 緒論
[1] Hunter, R. J. Foundations of Colloid Science, Vol. 1; University Press: Oxford, 2001. [2] Masliyah, J. H. Electrokinetic Transport Phenomena; AOSTRA, Edmonton, Alberta: Canada, 1994. [3] O’Brien, R.W.; White, L. R. J. Chem. Soc. FaradayⅡ 1978, 74, 1607. [4] Bird, R. B.; Stewart, W. E.; Lightfoot, E. N. Transport phenomena, 2nd ed.; John Wiley & Sons Press: New York, 2002. 第二章 單顆球形粒子沿著圓柱形孔洞的軸心泳動 [1] Von Smoluchowski, M. Z. Phys. Chem. 1918, 92, 129. [2] Huckel, E. Phys. Z 1924, 25, 204. [3] Henry, D. C. Proc. R. Soc. London Ser. A 1931, 133, 106. [4] Booth, F. Proc. R. Soc. London Ser. A 1950, 203, 514. [5] Wiersema, P. H.; Loeb, A. L.; Overbeek, J. Th. G. J. Colloid Interface Sci. 1966, 22, 78. [6] O’Brien, R. W.; White, L. R. J. Chem. Soc. Faraday Trans. 2 1978, 74 1607. [7] O’Brien, R. W.; Hunter, R. J. Can. J. Chem. 1981, 59, 1878. [8] Ohshima, H.; Healy, T. W.; White, L. R. J. Chem. Soc. Faraday Trans. 2 1983, 79, 163. [9] Ohshima, H. J. Colloid Interface Sci. 1994, 168, 269. 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[24] Ennis, J.; Zhang, H.; Stevens, G.; Perera, J.; Scales, P.; Carnie, S. J. Membr. Sci. 1996, 119, 47. [25] Backstrom, G. Fluid Dynamics by Finite Element Analysis; Studentlitteratur: Sweden, 1999. [26] FlexPDE version 2.22, PDE Solutions Inc., USA. [27] Hsu, J. P.; Kao, C. Y. J. Phys. Chem. B 2002, 106, 10605. 第三章 單顆球形粒子朝向無窮大的圓盤或平板泳動 [1] Morrison, F. A.; Stukel, J. J. J. Colloid Interface Sci. 1970, 33, 88. [2] Keh, H. J.; Lien, L. C. J. Chin. Inst. Chem. Eng. 1989, 20 , 283. [3] Keh, H. J.; Anderson, J. L. J. Fluid Mech. 1985, 153, 417. [4] Keh, H. J.; Lien, L. C. J. Fluid Mech. 1991, 224, 305. [5] Feng, J. J.; Wu, W. Y. J. Fluid Mech. 1994, 264, 41. [6] Ennis, J.; Anderson, J. L. J. Colloid Interface Sci. 1997, 185, 497. [7] Teubner, M. J. Chem. Phys. 1982, 76, 11. [8] Shugai, A. A.; Carnie, S. L.; Chan, D. Y. C.; Anderson, J. L. J. Colloid Interface Sci. 1997, 191, 357. [9] Shugai, A. A.; Carnie, S. L. J. Colloid Interface Sci. 1999, 213, 298. [10] Tang,Y. P.; Chih, M. H.; Lee, E.; Hsu, J. P. J. Colloid Interface Sci. 2001, 242, 121. [11] Chih, M. H.; Lee, E.; Hsu, J. P. J. Colloid Interface Sci. 2002, 248, 383. [12] Ninham, B. W.; Parsegian,V. A. J. Theor. Biol. 1971, 31, 405. [13] Chan, D.; Perram, J. W.; White, L. R.; Healy, Y. W. J. Chem. Soc. Faraday Trans. I 1975, 71, 1046. [14] Chan, D.; Healy, Y. W.; White, L. R. J. Chem. Soc. Faraday Trans. I 1976, 72, 2844. [15] Krozel, J. W.; Saville, D. A. J. Colloid Interface Sci. 1992, 150, 365. [16] Carnie, S. L.; Chan, D. Y. C. J. Colloid Interface Sci. 1993, 155, 297. [17] Carnie, S. L.; Chan, D. Y. C. J. Colloid Interface Sci. 1993, 161, 260. [18] Carnie, S. L.; Chan, D. Y. C.; Gunning, J. S. Langmuir 1994, 10, 2993. [19] Carnie, S. L.; Chan, D. Y. C.; Stankovich, J. J. Colloid Interface Sci. 1994, 165, 116. [20] Hsu, J. P.; Lee, E.; Yen, F. Y. J. Chem. Phys. 2000, 112, 6404. [21] Henry, D. C. Proc. R. Soc. London Ser. A 1931, 133, 106. [22] Backstrom, G. Fluid Dynamics by Finite Element Analysis; Studentlitteratur: Sweden, 1999. [23] O’Brien, R. W.; White, L. R. J. Chem. Soc. Faraday Trans. 2 1978, 74, 1607. [24] Brenner, H. Chem. Eng. Sci. 1961, 16, 242. [25] Maude, A. D. Brit. J. Appl. Phys. 1961, 12, 293. [26] FlexPDE version 2.22, PDE Solutions Inc., USA. [27] Zydney, A. L. J. Colloid Interface Sci. 1995, 169, 476. [28] Liu, H.; Bau, H. H.; Hu, H. H. Langmuir 2004, 20, 2628. [29] Shu, J. P.; Ku, M. H.; Kao, C. Y. J. Colloid Interface Sci. 2004, 276, 248. [30] Loeb, A. L.; Wiersema, P. H.; Overbeek, J. Th. G. The Electric Double-Layer Around a Spherical Colloid Particle; MIT Press: Boston, 1961. 第四章 單顆圓柱形粒子沿著圓柱形孔洞的軸心泳動 [1] Keh, H. J.; Anderson, J. L. J. Fluid Mech. 1985, 153, 417. [2] Keh, H. J.; Chen, S. B. J. Fluid Mech. 1988, 194, 377. [3] Ennis J.; Anderson, J. L. J. Colloid Interface Sci. 1997, 185, 497. [4] Keh, H. J.; Lien, L. C. J. Chin. Inst. Chem. Eng. 1989, 20, 283. [5] Keh, H. J.; Jan, J. S. J. Colloid Interface Sci. 1996,183, 458. [6] Chih, M. H.; Lee, E.; Hsu J. P. J. Colloid Interface Sci. 2002, 248, 383. [7] Tang, Y. P.; Chih, M. H.; Lee E.; Hsu J. P. J. Colloid Interface Sci. 2001, 242, 121. [8] Keh, H. J.; Chiou, J. Y. AIChE J. 1996, 42, 1397. [9] Shugai, A. A.; Carnie, S. L. J. Colloid Interface Sci. 1999, 213, 298. [10] Zydney, A. L. J. Colloid Interface Sci. 1995, 169, 476. [11] Lee, E.; Chu, J. W.; Hsu, J. P. J. Colloid Interface Sci. 1997, 196, 316. [12] Lee, E.; Chu, J. W.; Hsu, J. P. J. Colloid Interface Sci. 1998, 205, 65. [13] Chu, J. W; Lin, W. H; Lee, E.; Hsu, J. P. J. Colloid Interface Sci. 2001, 17,6289. [14] Hsu, J. P.; Hung, S. H.; Kao, C. Y. Langmuir 2002, 18, 8897. [15] Ye, C.; Sinton, D.; Erickson, D.; Li, D. Langmuir 2002, 18, 9095. [16] Hsu, J. P.; Kao, C. Y. J. Phys. Chem. B 2002, 106, 10605. [17] Liu, H.; Bau, H. H.; Hu, H. H. Langmuir 2004, 20, 2628. [18] Henry, D. C. Proc. R. Soc. London Ser. A 1931, 133, 106. [19] Backstrom, G. Fluid Dynamics by Finite Element Analysis; Studentlitteratur: Sweden, 1999. [20] O’Brien, R. W.; White, L. R. J. Chem. Soc. Faraday Trans. 2 1978, 74, 1607. [21] FlexPDE version 2.22, PDE Solutions Inc., USA. [22] Happel, J.; Brenner, H. Low Reynolds Number Hydrodynamics; Martinus: Nijhoff, The Hague, 1983; Chapter 4. [23] Sherwood, J. D. J. Chem. Soc. Faraday Trans. 2 1982, 78, 1091. [24] Chen, S. B.; Koch, D. L. J. Colloid Interface Sci. 1996, 180, 466. 第五章 雙顆圓柱形粒子沿著圓柱形孔洞的軸心泳動 [1] Hsu, J. P.; Hung, S.H.; Kao, C. Y. Langmuir 2002, 18, 8897. [2] Keh, H. J.; Chen, S. B. J. Fluid Mech. 1988, 194, 377. [3] Keh, H. J.; Horng, K. D.; Kuo, J. J. Fluid Mech. 1991, 231, 211. [4] Zydney, A. L. J. Colloid Interface Sci. 1995, 169, 476. [5] Ennis, J.; Anderson, J. L. J. Colloid Interface Sci. 1997, 185, 497. [6] Shugai, A. A.; Carnie, S. L. J. Colloid Interface Sci. 1999, 213, 298. [7] Reed, L. D.; Morrison, F. A. J. Colloid Interface Sci. 1976, 54, 117. [8] Keh, H. J.; Chen, S. B. AIChE J. 1988, 34, 1075. [9] Keh, H. J.; Chen, S. B. J. Colloid Interface Sci. 1989, 130, 542. [10] Keh, H. J.; Chen, S. B. J. Colloid Interface Sci. 1989, 130, 556. [11] Keh, H. J.; Yang, F. R. J. Colloid Interface Sci. 1990, 139, 105. [12] Keh, H. J.; Yang, F. R. J. Colloid Interface Sci. 1991, 145, 362. [13] Chen, S. B.; Keh, H. J. J. Fluid Mech. 1992, 238, 251. [14] Keh, H. J.; Chen, J. B. J. Colloid Interface Sci. 1993, 158, 199. [15] Shugai, A. A.; Carnie S. L.; Chan, D. Y. C.; Anderson, J. L. J. Colloid Interface Sci. 1997, 191, 357. [16] Sherwood, J. D.; Stone, H. A. Phys. Fluid. 1995, 7, 697. [17] Henry, D. C. Proc. R. Soc. London Ser. A 1931, 133, 106. [18] Backstrom, G. Fluid Dynamics by Finite Element Analysis; Studentlitteratur: Sweden, 1999. [19] FlexPDE version 2.22, PDE Solutions Inc., USA. [20] Hsu, J. P.; Kao, C. Y. J. Phys. Chem. B 2002, 106, 10605. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/38872 | - |
dc.description.abstract | 本論文以有限元素法研究帶電邊界對膠體粒子電泳動的影響。文中探討的主題包含單顆球形粒子沿著圓柱形孔洞的軸心泳動、單顆球形粒子朝向無窮大的圓盤或平板泳動、以及單顆或雙顆圓柱形膠體粒子沿著圓柱形孔洞的軸心泳動,並測試了固定表面電位、固定表面電荷密度與電荷可調整三種表面荷電模式的影響。在低表面電位、弱外加電場與低雷諾數的假設下,吾人利用加疊原理求解相關電場與流場之線性化方程組,並獲得膠體粒子的電泳速度(或電泳遷移率)。
數值模擬的結果顯示,下列幾個因素對膠體粒子的電泳速度有顯著的影響:粒子與邊界的表面荷電模式、粒子與邊界的幾何形狀、粒子與邊界的距離或粒子間的距離、以及電雙層的厚度。其次,帶電邊界對膠體粒子泳動的影響是不可忽略的,因為它除了會有效增加或減少粒子的電泳速度外,在某些條件下,甚至會導致膠體粒子的電泳速度消失或產生一局部極大值。 | zh_TW |
dc.description.abstract | The electrophoretic behaviors of colloidal particles near a rigid, charged boundary are investigated through solving numerically the governing electrokinetic equations by a finite element method. Four types of system are considered: a sphere along the axis of a cylindrical pore, a sphere normal to a large disk/plane, and a short cylinder or two short cylinders along the axis of a cylindrical pore. Three kinds of charged conditions on particle surface are considered: constant surface potential, constant surface charge density, and charge-regulated model. Under the conditions of low surface potential and weak applied electric field, the electrophoretic mobility of a particle is evaluated by a superposition method.
The influences of the key parameters of the systems under consideration on the mobility of a particle are investigated through numerical simulation. These include the charged conditions on a particle and on a boundary, the geometries of a particle and a boundary, the separation distance between a particle and a boundary or between two particles, and the thickness of double layer. Several interesting results are observed which are of both fundamental and practical significance. For instance, we show that the presence of a charged boundary can increase, decrease, or even change the direction of the movement of a particle. Also, the mobility of a particle may exhibit a local maximum as the thickness of double layer varies. | en |
dc.description.provenance | Made available in DSpace on 2021-06-13T16:50:08Z (GMT). No. of bitstreams: 1 ntu-94-D89524010-1.pdf: 2627654 bytes, checksum: 2d6d219479620853d23e217508eebecc (MD5) Previous issue date: 2005 | en |
dc.description.tableofcontents | 中文摘要 I
英文摘要 II 目錄 Ⅲ 圖目錄 Ⅵ 第一章 緒論 1 1.1 膠體系統 1 1.2 膠體的穩定性與表面電荷 1 1.3 電雙層與zeta電位 3 1.4 電動力學現象 5 1.5 基本文獻回顧 6 1.6 電動力學方程式 8 1.7 本論文架構 13 第二章 單顆球形粒子沿著圓柱形孔洞的軸心泳動 18 2.1 簡介 19 2.2 理論分析 21 2.3 結果與討論 25 2.3.1 粒子表面攜帶正電荷但孔壁未攜帶電荷 25 2.3.2 粒子表面未攜帶電荷但孔壁攜帶正電荷 27 2.3.3 粒子表面與孔壁同時攜帶正電荷 29 2.4 總結 31 第三章 單顆球形粒子朝向無窮大的圓盤或平板泳動 40 3.1 簡介 41 3.2 理論分析 43 3.3 結果與討論 51 3.3.1 固定表面電位模式 52 3.3.2 表面電荷可調整模式 60 3.4 總結 72 第四章 單顆圓柱形粒子沿著圓柱形孔洞的軸心泳動 90 4.1 簡介 91 4.2 理論分析 93 4.3 結果與討論 98 4.3.1 粒子表面攜帶正電荷但孔壁未攜帶電荷 99 4.3.2 粒子表面未攜帶電荷但孔壁攜帶正電荷 103 4.4 總結 108 第五章 雙顆圓柱形粒子沿著圓柱形孔洞的軸心泳動 124 5.1 簡介 125 5.2 理論分析 128 5.3 結果與討論 133 5.4 總結 137 第六章 結論 149 附錄A 主控方程式之線性化近似 152 附錄B 力積分方程式 158 附錄C 流場之線性加疊 161 作者簡介 163 | |
dc.title | 帶電邊界對膠體粒子電泳的影響 | zh_TW |
dc.title | Effect of a charged boundary on the electrophoresis
of a colloidal particle | en |
dc.type | Thesis | |
dc.date.schoolyear | 93-2 | |
dc.description.degree | 博士 | |
dc.contributor.oralexamcommittee | 王大銘,李克強,楊台鴻,曾琇瑱 | |
dc.subject.keyword | 電泳,帶電邊界,滲透流,固定表面電位, | zh_TW |
dc.subject.keyword | electrophoresis,charged boundary,electroosmosis,constant surface potential, | en |
dc.relation.page | 163 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2005-06-24 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
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