請用此 Handle URI 來引用此文件:
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/38333
完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 吳乃立(Nae-Lih Wu) | |
dc.contributor.author | Chin-Cheng Hsu | en |
dc.contributor.author | 徐金正 | zh_TW |
dc.date.accessioned | 2021-06-13T16:30:42Z | - |
dc.date.available | 2006-07-20 | |
dc.date.copyright | 2005-07-20 | |
dc.date.issued | 2005 | |
dc.date.submitted | 2005-07-12 | |
dc.identifier.citation | [1] G. Redmond, D. Fitzmaurice, and M. Graetzel, “Effect of Surface Chelation on the Energy of An Intraband Surface-State of A Nanocrystalline TiO2 Film,” J. Phys. Chem.-US, 97 (1993) 6951-6954.
[2] R. Palmans, and A. J. Frank, “A Molecular Water-Reduction Catalyst – Surface Derivatization of TiO2 Colloids and Suspensions with A Platinum Complex,” J. Phys. Chem.-US, 95 (1991) 9438-9443. [3] P. Wu, and M. Iwamoto, “Metal-ion-planted MCM-41. Part 3. Incorporation of titanium species by atom-planting method,” J. Chem. Soc. Faraday T, 94 (1998) 2871-2875. [4] A. D. Paola, E. G.-Lopez, S. Ileda, G. Marci. B. Ohtani, and L. Palmisano, “Photocatalytic degradation of organic compounds in aqueous systems by transition metal doped polycrystalline TiO2,” Catal. Today, 75 (2002) 87-93. [5] S. Ikeda, N. Sugiyama, B. Pal, G. Marci, L. Palmisano, H. Noguchi, K. Uosaki, and B. Ohtani, “Photocatalytic activity of transition-metal-loaded titanium(IV) oxide powders suspended in aqueous solutions: Correlation with electron-hole recombination kinetics,” Phys. Chem. Chem. Phys., 3 (2001) 267-273. [6] H. Fujii, K. Inata, M. Ohtaki, K Eguchi, and H. Arai, “Synthesis of TiO2/CdS nanocomposite via TiO2 coating on CdS nanoparticles by compartmentalized hydrolysis of Ti alkoxide,” J. Mater. Sci., 36 (2001) 527-532. [7] H. Tada, A. Hattori, Y. Tokihisa, K. Imai, N. Tohge, and S. Ito, “A Patterned-TiO2/SnO2 Bilayer Type Photocatalyst”, J. Phys. Chem. B, 140 (2000) 4585-4587. [8] N. Serpone, and E. Pelizzetti, Photocatalysis: Fundamental and Applications, Wiley Interscience, 1989, pp. 136, 315. [9] M. Zhang, T. An, X. Hu, C. Wang, G. Sheng, and J. Fu, “Preparation and photocatalytic properties of a nanometer ZnO-SnO2 coupled oxide,” Appl. Catal., A 260 (2004) 215-222. [10] T. Tani, L. Madler, and S. E. Pratsinis, “Synthesis of α-Willemite Nanoparticles by Post-calcination of Flame-made Zinc Oxide/Silica Composites,” Part. Part. Syst. Charact., 19 (2002) 354-358. [11] K. R. Gopidas, M. Bohorquez, and P. V. Kamat, “Photophysical and Photochemical Aspects of Coupled Semiconductors. Charge-Transfer Processes In Colloidal CdS-TiO2 and CdS-AgI Systems,” J. Phys. Chem., 94 (1990) 6435-6440. [12] A. J. Nozik, “Photochemical Diodes,” Appl. Phys. Lett., 30 (1977) 567-569. [13] S. Okazaki, T. Okuyama, “Nb2O5 Supported on TiO2-Catalytic Activity For Reduction of NO with NH3,” B. Chem. Soc. Jpn., 56 (1983) 2159-2160. [14] D.C. Vermaire, P. C. Vanberge, “The Preparation of WO3/TiO2 and WO3/Al2O3 Characterization by Temperature-Programmed Reduction,” J. Catal., 116 (1989) 309-317. [15] A. L. Linsebigler, G. Lu, and J. T. Yates, Jr., “Photocatalysis on TiO2 surfaces: Principles, mechanisms, and selected results,” Chem. Rev., 95 (1995) 735-758. [16] A. J. Nozik, and R. Memming, “Physical Chemistry of Semiconductor/Liquid Interfaces,” J. Phys. Chem.-US, 100 (1996) 13061-13078. [17] N. G. Vannerbeng, Arkiv for Kemi, 14 (1959) 119. [18] S. Lindross, and M. Leskela, “Growth of zinc peroxide (ZnO2) and zinc oxide (ZnO) thin films by the successive ionic layer adsorption and reaction-SILAR-technique,” Inter. J. Inorg. Mater., 2 (2000) 197-201. [19] N. Uekawa, J. Kajiwara, N. Mochizuki, K. Kakegawa, and Y. Sasaki, “Synthesis of ZnO Nanoparticles by Decomposition of Zinc Peroxide,” Chem. Lett., (2001) 606-607. [20] D.C. Look, D. C. Reynolds, J. R. Sizelove, R. L. Jones, C. W. Litton, G. Cantwell, and W. C. Harsch, “Electrical properties of bulk ZnO,” Solid State Commun., 105 (1998) 399-401. [21] P. Fons, K. Iwata, S. Niki, A. Yamada, and K. Matsubara, “Growth of high-quality epitaxial ZnO films on alpha-Al2O3,” J. Cryst. Growth, 201 (1999) 627-632. [22] Y. Liu, C. R. Gorla, S. Liang, N. Emanetoglu, Y. Lu, H. Shen, and M. Wraback, “Ultraviolet detectors based on epitaxial ZnO films grown by MOCVD,” J. Electron. Mater., 29 (2000) 69-74. [23] D.C. Look, ”Recent advances in ZnO materials and devices,” Mater. Sci. Eng., B80 (2001) 383-387. [24] D. P. Norton, Y. W. Heo, M. P. Ivill, K. Ip, S. J. Pearton, M. F. Chisholm, and T. Steiner, “ZnO: growth, doping & processing,” Materialstoday (2004) 34-40. [25] Z. L. Wang, “Nanostructures of zinc oxide,” Materialstoday (2004) 26-33. [26] Y. N. Xu, and W. Y. Ching, “Electronic, optical, and structural properties of some wurtzite crystals,” Phys. Rev. B, 48 (1993) 4335-4351. [27] M. S. Tokumoto, S. H. Pulcinelli, Celso V. Santilli, and V. Briois, “Catalysis and Temperature Dependence on the Formation of ZnO Nanoparticles and of Zinc Acetate Derivatives Prepared by the Sol-Gel Route,” J. Phys. Chem. B, 107 (2003) 568-574. [28] L. Jing, Z. Xu, X. Sun, J. Shang, and W. Cai, “The surface properties and photocatalytic activities of ZnO ultrafine particles,” Appl. Surf. Sci., 180 (2001) 308-314. [29] H. Xu, H. Wang, Y. C. Zhang, S. Wang, M. K. Zhu, H. Yan, ”Asymmetric Twinning Crystals of Zinc Oxide Formed in a Hydrothermal Process,” Cryst. Res. Technol., 38 (2003) 429-432. [30] B. Liu, and H. C. Zeng, “Hydrothermal Synthesis of ZnO Nanorods in the Diameter Regime of 50 nm,” J. Am. Chem. Soc., 125 (2002) 4430-4431. [31] S. Music, S. Popovic, M. Maljkovic, and D. Dragcevic, “Influence of synthesis procedure of the formation and properties of zinc oxide,” J. All. Comp., 347 (2002) 324-332. [32] M. F. Ogawa, Y. Natsume, T. Hirayama, and H. Sakata, “Preparation and Electrical Properties of Undoped Zinc-Oxide Films by CVD,” J. Mater. Sci. Lett., 9 (1990) 1351-1353. [33] T. Sekiguchi, S. Miyashita, K. Obara, T. Shishido, and N. Sakagami, “Hydrothermal growth of ZnO single crystals and their optical characterization,” J. Cryst. Growth, 214 (2000) 72-76. [34] H. Y. Xu, H. Wang, Y. C. Zhang, W. L. He, M. K. Zhu, B. Wang, and H. Yan, “Hydrothermal synthesis of zinc oxide powders with controllable morphology,” Ceram. Int., 30 (2004) 93-97. [35] B. Cheng, and E. T. Samulski, “Hydrothermal synthesis of one-dimetional ZnO nanostructure with different aspect ration,” Chem. Comm., (2004) 986-987. [36] S. Lindross, M. Leskela, “Growth of zinc peroxide (ZnO2) and zinc oxide (ZnO) thin films by the successive ionic layer adsorption and reaction-SILAR-technique,” Inter. J. Inorg. Mater., 2 (2000) 197-201. [37] A. E. J.-Gonzailez, and P. K. Nair, “Photosensitive ZnO thin films prepared by the chemical deposition method SILAR,” Semicond. Sci. Technol., 10 (1995) 1277-1281. [38] J. J. Robbins, J. Esteban, C. Fry, and C. A. Wolden, “An Investigation of the Plasma Chemistry Involved in the Synthesis of ZnO by PECVD,” J. Electrochem. Soc., 150 (2003) C693-C698. [39] M. Ortega-Lopez, A. Avila-Garcia, M. L. Albor-Aguilera, and V. M. S. Resendiz, “Improved efficiency of the chemical bath deposition method during growth of ZnO thin films,” Mater. Res. Bull., 38 (2003) 1241-1248. [40] M. O.-Lopez, A. A.-Garcia, M. L. A.-Aguilera, and V. M. S. Resendiz, “Improved efficiency of the chemical bath deposition method during growth of ZnO thin films,” Mater. Res. Bull., 38 (2003) 1241-1248. [41] Y. Wu et al, “Inorganic semiconductor nanowires: rational growth, assembly, and novel properties,” Chem. Eur. J., 8 (2002) 1260-1268. [42] Z. W. Pan, Z. R. Dai, and Z. L. Wang, “Nanobelts of semiconducting oxides,” Science, 291 (2001) 1947-1949. [43] H. Kind, H. Yan, B. Messer, M. Law, and P. Yang, “Nanowire ultraviolet photodetectors and optical switches,” Adv. Mater., 14 (2002) 158-160. [44] Y. Wu, H. Yan, and P. Yang, “Semiconductor nanowire array: potential substrates for photocatalysis and photovoltaics,” Top. Catal., 19 (2002) 197-202. [45] B. Pal, and M. Sharon, “Enhanced photocatalytic activity of highly porous ZnO thin films prepared by sol-gel process,” Mater. Chem. Phys., 76 (2002) 82-87. [46] R. Comparelli, P. D. Cozzoli, M. L. Curri, A.Agostiano, G. Mascolo, and G. Lovecchio, “Photocatalytic degradation of methyl-red by immobilized nanoparticles of TiO2 and ZnO,” Water Sci. Technol., 49 (2004) 183-188. [47] P. M. Martin, M. S. Good, J. W. Johnston, L. J. Bond, and S. L Crawford., “Piezoelectric films for 100MHz ultrasonic transducers,” Thin Solid Films, 379 (2000) 253-258. [48] L. M. Leviinson, and H. R. Philipp, in: Buchanan, R. C. (Ed.), Ceramic Materials for Electronics, Marcel Dekker, New York, 1991, pp. 349-378. [49] C. H. Lin, B. S. Chiou, C. H. Chang, and J. D. Lin, ”Preparation and cathodoluminescence of ZnO phosphor,” Mater. Chem. Phys., 77 (2003) 647-654. [50] J. Q. Xu, Q. Y. Pan, Y. A. Shun, and Z. Z. Tian, ”Grain size control and gas properties of ZnO gas sensors,” Sensors Actuators B Chem., 66 (2000) 277-279. [51] G. Gordillo, “New materials used as optical window in thin film solar cells,” Surf. Rev. Lerr., 9 (2002) 1675-1680. [52] S. Muthukumar, C. R. Gorla, N. W. Emanetoglu, S. Liang, and Y. Lu, “Control of morphology and orientation of ZnO thin films on SiO2/Si substrates,” J. Cryst. Growth, 225 (2000) 197-201. [53] S. B. Zhang, S. H. Wei, and A. Zunger, “Intrinsic n-type versus p-type doping asymmetry and the defect physics of ZnO,” Phys. Rev. B, 63 (2001) 075205-1 - 075205-7. [54] Y. R. Ryu, T. S. Lee, and H. W. White, “Properties of arsenic-doped p-type ZnO grown by hybrid beam deposition,” Appl. Phys. Lett., 83 (2003) 87-89. [55] G. Wang, G. T. Kiehne, G. K. L. Wong, J. B. Ketterson, X. Liu, and R. P. H. Chang, “Large second harmonic response in ZnO thin films, ” Appl. Phys. Lett., 80 (2002) 401-403. [56] A. Fujishima, K. Honda, “Electrochemical Photolysis of Water at a Semiconductor Electrode,” Nature, 238 (1972) 37-38. [57] Z. Ding, G. Q. Lu, and P.F. Greenfield, “Role of the Crystallite Phase of TiO2 in Heterogeneous Photocatalysis for Phenol Oxidation,” J. Phys. Chem. B, 104 (2000) 4815-4820. [58] S. Nishimoto, B. Ohtani, H. Kajiwara, and T. Kagiya, “Correlation of the crystal structure of titanium dioxide prepared from titanium tetra-2-propoxide with the photocatalytic activity for redox reactions in aqueous propan-2-ol and silver salt solutions,” J. Chem. Soc. Faraday Trans. 1, 81 (1985) 61-68. [59] J. K. Burdett, T.Hughbanks, G. J. Miller, J. W. Richardson, and J. V. Smith, ” Structural Electronic Relationships in Inorganic Solids–Powder Neutron-Diffraction Studies of the Rutile and Anatase Polymorphs of Titanim-Dioxide at 15 and 295 K,” J. Am. Chem. Soc., 109 (1987) 3639-3646. [60] A. Fujishima, K. Hashimoto, and T. Watanabe, TiO2 Photocatalysis Fundamental and Application, BKC, Inc., 1999, pp. 125. [61] K. M. Glassford, and J. R. Chelikowsky, “Structrual and electronic properties of titanium dioxide,” Phys. Rev. B, 46 (1992) 1284-1298. [62] H. D. Nam, B. H. Lee, S. J. Kim, C. H. Jung, J. H. Lee, and S. Park, “Preparation of Ultrafine TiO2 Powders from Aqueous TiCl4 Solution by Precipitation,” J. Appl. Phys., 37 (1998) 4603-4608. [63] D. S. Seo, H. Kim, H. C. Jung, and J. K. Lee, “Synthesis and characterization of TiO2 nanocrystalline powder prepared by homogeneous precipitation using urea,” J. Mater. Res., 18 (2001) 571-577. [64] S. J. Kim, S. D. Park, Y. H. Jeong, and S. Park, “Homogeneous precipitation of TiO2 ultrafine powders from aqueous TiOCl2 solution,” J. Am. Ceram. Soc., 82 (1999) 927-932. [65] H. K. Park, D. K. Kim, and C. H. Kim, “Effect of Solvent on Titania Partical Formation and Morphology in Thermal Hydrolysis of TiCl4,” J. Am. Ceram. Soc., 80 (1997) 743-749. [66] J. L. Look, and C. F. Zukoski, “Colloidal Stability and Titania Precipitate Morphology–Influence of Short-Range Repulsions,” J. Am. Ceram. Soc., 78 (1995) 21-23. [67] D. Vorkapic and T. Matsoukas, “Effect of Temperature and Alcohols in the Preparation of Titania Nanoparticles from Alkoxides,” J. Am. Ceram. Soc., 81 (1998) 2815-2820. [68] B. Xia, H. Huang, and Y. Xie, “Heat treatment of TiO2 nanoparticles prpared by vapor-phase hydrolysis,” Mater. Sci. Eng. B, 57 (1999) 150-154. [69] Y. Takahashi, H. Suzuki, and M Nasu, “Rutile Growth at the Surface of TiO2 Films Deposited by vapor-phase Decomposition of Isopropyl Titanate,” J. Chem. Soc. Farad. T. 1, 81 (1985) 3117-3125. [70] Y. Suyama, A. Kato, “Effect of Additives on the Formatio of TiO2 Particles by Vapor-Phase Reaction,” J. Am. Ceram. Soc., 68 (1985) C154-C156. [71] T. Sreethawong, Y. Suzuki, and S. Yoshikawa, “Synthesis, characterization, and photocatalytic activity for hydrogen evolution of nanocrystalline mesoporous titania prepared by surfactant-assisted templating sol-gel process,” J. Solid State Chem., 178 (2005) 329-338. [72] B. L. Bischoff and M. A. Anderson, ”Peptization Process in the Sol-Gel Preparation of Porous Anatase (TiO2),” Chem. Mater., 7 (1995) 1772-1778. [73] I. Moriguchi, H. Maeda, Y. Teraoka and S. Kagawa, “Preparation of a TiO2 Nanoparticulate Film Using a Two-Dimensional Sol-Gel Process,” Chem. Mater., 7 (1997) 1050-1057. [74] Y. Murakami, T. Matsumoto and Y. Takasu, “Salt Catalysts Containing Basic Anions and Acidic Cations for the Sol-Gel Process of Titanium Alkoxide: Controlling the Kinetics and Dimentionality of the Resultant Titanium Oxide,” J. Phys. Chem. B, 103 (1999) 1836-1840. [75] S. Music, M. Gotic, M. Ivanda, S. Popovic, A. Turkovic, R. Trojko, A. Sekulic, and K. Furic, “Chemical and microstrucutre properties of TiO2 synthesized by sol-gel procedure,” Mater. Sci. Eng. B, 47 (1997) 33-40. [76] R. R. Bacsa, and M. Gratzel, “Rutile formation in hydrothermally crystallized nanosized titania,” J. Am. Ceram. Soc., 79 (1996) 2185-2188. [77] E. Hosono, S. Fujihara, K. Kakiuchi, and H. Imai,“Growth of Submicrometer-Scale Rectangular Parallelepiped Rutile TiO2 films in Aqueous TiCl3 Solutions under Hydrothermal Conditions,” J. Am. Ceram. Soc., 126 (2004) 7790-7791. [78] M. Andersson, L. Osterlund, S. Ljungstrom, and A. Palmqvist, ”Preparation of Nanosize Anatase and Rutile TiO2 by Hydrothermal Treatment of Microemulsions and Their Activity for Photocatalytic Wet Oxidation of Phenol,” J. Phys. Chem. B, 106 (2002) 10674-10679. [79] J. Yang, S. Mei and J. M. F. Ferreira,“Hydrothermal Synthesis of Nanosized Titania Powders: Influence of Peptization and Peptizing Agents on the Crystalline Phases and Phase Transitions,” J. Am. Ceram. Soc., 83 (2000) 1361-1368. [80] T. Noguchi, and A. Fujishima, “Photocatalytic Degradation of Gaseous Formaldehyde Using TiO2 Film,” Environ. Sci. Technol., 32 (1998) 3831-3833. [81] T. H. Lim, S. M. Jeong, S. D. Kim, and J. Gyenis, “Photocatalytic decomposition of NO by TiO2 particles”, J. Photochem. Photobio. A, 134 (2000) 209-217. [82] M. Anpo, Y. Ichihashi, M. Takeuchi, and H. Yamashita, “Design of Unique Titanium Oxide Photocatalysis by An Advanced Metal Ion-Implantation Method and Photocatalytic Reactions Under Visible Light Irradiation”, Res. Chem. Intermed., 24 (1998) 143-149. [83] H. Yamashita, Y. Ichihashi, S. G. Zhang, Y. Matsumura, Y. Souma, T. Tatsumi, and M. Anpo, “Photocatalytic decomposition of NO at 275 K on titanium oxide catalysts anchored within zeolite cavities and framework”, Applied Surface Science, 121/122 (1997) 305-309. [84] B. Kraeutler, and A. J. Bard, “Heterogeneous Photocatalytic Preparation of Supported Catalysts. Photodeposition of Platinum on TiO2 Powder and Other Substrates”, J. Am. Chem. Soc., (1978) 4317-4318. [85] H. Yoneyama and T. Torimoto, “Titanium dioxide/adsorbent hybrid photocatalysis for photodestruction of organic substances of dilute concentrations”, Catalysis Today, 58 (2000) 133-140. [86] G. N. Schrauzer and T. D. Guth, “Photolysis of Water and Photoreduction of Nitrogen on Titanium Dioxide”, J. Am. Chem. Soc., 99 (1977) 7189-7193. [87] S. N. Frank and A. J. Bard, “Heterogeneous Photocatalytic Ixidation of Cyanide Ion in Aqueous Solutions at TiO2 Powder”, J. Am. Chem. Soc., 99 (1977) 303-304. [88] H. Yamashita, Y. Fujii, Y. Ichihashi, S. G. Zhang, K. I., D. R. Park, K. Koyano, T. Tatsumi, and M. Anpo, “Selective formation of CH3OH in the photocatalytic reduction of CO2 with H2O on titanium oxides highly dispersed within zeolites and mesoporous molecular sieves”, Catalysis Today, 45 (1998) 221-227. [89] R. A. Evarestov, V. P. Smirnov, and D. E. Usvyat, “Local properties of the electronic structure of cubic SrTiO3, BaTiO3 and PbTiO3 crystals, analysed using Wannier-type atomic functions,” Solid State Commun., 127 (2003) 423-426. [90] K. Tsuda, and M. Tanaka, “Refinement of Crystal Structure Parameters using Convergent-Beam Electron Diffraction: the Low Phase of SrTiO3,” Acta Cryst., A51 (1995) 7-19. [91] M. Capizzi, A. Frova, “Optical Gap of Strontium Titanate (Deviation from Urbach Tail Behavior),” Phys. Rev. Lett., 25 (1970) 1298-1301. [92] Y. Suemune, “Thermal Conductivity of BaTiO3 and SrTiO3 from 4.5 Degrees to 300 Degrees K,” J. Phys. Soc. Jpn., 20 (1965) 174. [93] M. Wohlecke, V. Marrello, and A. Onton, “Refractive-Index of BaTiO3 and SrTiO3 Films,” J. Appl. Phys., 48 (1977) 1748-1750. [94] H. Tagawa, and K. Igarashi, “Reaction of Strontium Carbonate with Anatase and Rutile,” J. Am. Ceram. Soc., 69 (1986) 310-314. [95] G. J. McCatyhy, W. B. White, and R. Roy, “Phase Equilibria in 1375 Degrees C Isotherm of System Sr-Ti-O,” J. Am. Ceram. Soc., 52 (1969) 463-467. [96] R. E. Riman, R. R. Landham, and H. K. Bowen, “Synthesis of Uniform Titanium and 1-1 Strontium-Titanium Carboxyhydrosols by Controlled Hydrolysis of Alkoxymetal Carboxylate Precursors,” J. Am. Ceram. Soc., 72 (1989) 821-826. [97] W. Xuewen, Z. Zhiyong, and Z. Shuixian, “Preparation of nano-crystalline SrTiO3 powder in sol-gel process,” Mat. Sci. Eng. B-Solid, 86 (2001) 29-33. [98] S. Zhang, Y. Han, B. Chen, and X. Song., “The influence of TiO2•H2O gel on hydrothermal synthesis of SrTiO3 powders,” Matt. Lett., 51 (2001) 368-370. [99] D. Chen, X. Jiao, and M. Zhang, “Hydrothermal synthesis of strontium titanate powders with nanometer size derived from different precursors,” J. Eur. Ceram. Soc., 20 (2000) 1261-1265. [100] M. Fujimoto, and W. D. Kingery, “Microstructure of SrTiO3 Inernal Boundary-Layer Capacitors During and After Processing and Resultant Electrical-Properties,” J. Am. Ceram. Soc., 68 (1985) 169-173. [101] S. H. Kim, J. D. Byun, W. Park, Y. Kim, “ Effect of Na-diffution on the electrical properties of SrTiO3,” J. Matt. Sci., 34 (1999) 3057-3061. [102] J. Gerblinger, and H. Meixner, “Fast Oxygen Sensors Based on Sputtered Strontium-Titanate,” Sensors Actuat. B-Chem, 4 (1991) 99-102. [103] M. Kawai, S. Watanabe, and T. Hanada, “Molucular-Beam Epitaxy of Bi2Sr2CuOx and Bi2Sr2Ca0.85Sr0.15Cu2Ox Ultra Thin-Films at 300-Degrees-C,” J. Cryst. Growth, 112 (1991) 745-752. [104] K. Domen, A. Kudo, and T. Onishi, “Mechanism of Photocatalytic Decomposition of Water into H-2 and O-2 over Nio - SrTiO3,” J. Catal., 102 (1986) 92-98. [105] R. Konta, T. Ishii, H. Kato, and A. Kudo, “Photocatalytic Activities of Noble Metal Ion Doped SrTiO3 under Visible Light Irradiation,” J. Phys. Chem. B, 108 (2004) 8992-8995. [106] H. Kato, and A. Kudo, “Visible-Light-Response and Photocatalytic Activities of TiO2 and SrTiO3 Photocatalysts Codoped with Antimony and Chromium,” J. Phys. Chem. B, 106 (2002) 5029-5034. [107] W. Luo, W. Duan, S. G. Louie, and M. L. Cohen, “Structural and electronic properties of n-doped and p-doped SrTiO3,” Phys. Rev. B, 70 (2004) 1-8. [108] K. Byrappa, and M. Yoshimura, Handbook of Hydrothermal Technology: A Technology for Crystal Growth and Materials Processing, William Andrew Publishing, LLC Norwich, New York 2001. [109] W. J. Dawson, “Hydrothermal Synthesis of Advanced Ceramic Powders,”Am. Ceram. Soc. Bull., 67 (1988) 1673-1678. [110] www.chemat.com/html/solgel.html [111] S. Al-Qaradawi, and S. R. Salman, “Photocatalytic degradation of methyl orange as a model compound,” J. Photoch. Photobio. A, 148 (2002) 161-168. [112] M. Ortega-Lopez, A. Avila-Garcia, M. L. Albor-Aguilera, and V. M. S. Resendiz, “Improved efficiency of the chemical bath deposition method during growth of ZnO thin films,” Mater. Res. Bull., 38 (2003) 1241-1248. [113] S. Al-Qaradawi, and R. Salman, “Photocatalytic degradation of methyl orange as a model compound,” J. Photochem. and Photobio. A: Chem., 148 (2002) 161-168. [114] C. He, Y. Yu, X. Hu, and A. Larbot, “Influence of silver doping of the photocatalytic activity of titania films, ” Appl. Surf. Sci., 200 (2002) 239-247. [115] D. S. Hwang, Y. I. Cho, N. H. Lee, H. G. Lee, D. H. Cho, and S. J. Kim, “Effects of positive ionic radius on the phase transition of titania nano powders from aqueous TiOCl2 solutions,” Key. Eng. Mat., 264-268 (2004) 21-24, Part 1-3. [116] W. D. Kingery, H. K. Bowen, and D. R. Uhlmann, “Introduction to Ceramics,” 2nd ed., Wiley, New York (1976) 457. [117] C. F. Lin, and N. L. Wu, “Prparation and Photocatalysis of Nanocrystalline Titanium Oxide,” Master Thesis of Chemical Engineering, NTU (2001) 17-20. [118] M. Gartner, V. Dremov, P. Muller, and H. Kisch, “Bandgap Widening of Titania through Semiconductor Support Interactions,” Chem. Phys. Chem., 6 (2005) 714-718. [119] E. Pelizzetti, and M. Visca, Bifunctional redox catalysis: synthesis and operation in water-cleavage reactions, Energy Resources through Photochemistry and Catalysis, Academic Press, 1983, pp. 263. [120] C. J. Brinker, and G. W. Scherer, Sol-gel Science: the physics and chemistry of sol-gel processing, first ed., Academic Press, 1990. [121] J. F. Moulder, W. F. Stickle, P. E. Sobol, and K. D. Bomben, Handbook of X-ray Photoelectron Spectroscopy: A Reference Book of Standard Spectra for Identification and Interpretation of XPS Data, Physical Electronics, Inc., 1995. [122] M. R. Hoffmann, S. T. Martin, W. Choi, and D. W. Bahnemann, “Environmental Applications of Semiconductor Photocatalysis,” Chem. Rev., 95 (1995) 69-96. [123] A. Mills, J. Wang, “Photobleaching of methylene blue sensitized by TiO2 : an ambiguous system?,” J. Photochem. Photobio. A, 127 (1999) 123-134. [124] A. Houas, H. Lachheb, M. Ksibi, E. Elaloui, C. Guillard, and J.-M. Herrmann, “Photocatalytic degradation pathway of methylene blue in water,” Appl. Catal. B-Environ., 31 (2001) 145-157. [125] R. W. Matthews, “Photocatalytic Oxidation and Adsorption of Methylene-blue on Thin-films of Near-ultroviolet-illuminated TiO2”, J. Chem. Soc. Farad. T. 1, 85 (1989) 1291-1302. [126] S. Lakshmi, R. Renganathan, and S. Fujita, “Study on TiO2-mediated photocatalytic degradation of methylene blue,” J. Photoch. Photobio. A, 88 (1995) 163-167. [127] R. Wang, N. Sakai, A. Fujishima, T. Watanabe, and K. Hashimoto, “Studies of Surface Wettability Conversion on TiO2 Single-Crystal Surfaces,” J. Phys. Chem. B, 103 (1999) 2188-2194. [128] R. Asahi, T. Morikawa, T. Ohwaki, K. Aoki, and Y. Taga, “Visible-Light Photocatalysis in Nitrogen-Doped Titanium Oxides,” Science, 293 (2001) 269-271. [129] R. P. Vasquez, “X-ray Photoelectron-Spectroscopy Study of Sr and Ba Compounds,” J. Electron Spectrosc. Relat. Phemon., 56 (1991) 217-240. [130] M. Ueda, S. O. Y. Matsuo, “Preparation of tubular TiO2-SrTiO3-δ composite for photocatalytic electrode,” Sci.Technol. Adv. Mat., 5 (2004) 187-193. [131] Y. Zhang, H. Zhang, Y. Xu, and Y. Wang, “Significant effect of lanthanide doping on the texture and properties of nanocrystalline mesoporous TiO2,” J. Solid State Chem., 177 (2004) 3490-3498. [132] A. W. Xu, Y. Gao, and H. Q. Liu, “The Preparation, Characterization, and their Photocatalytic Activities of Rare-Earth-Doped TiO2 Nanoparticles,” J. Catal., 207 (2002) 151-157. [133] Z. Zhang, C. C. Wang, R. Zakaria, and J. Y. Ying, “Role of Particle Size in Nanocrystalline TiO2-Based Photocatalysis,” J. Phys. Chem. B, 102 (1998) 10871-10878. [134] S. Lakahmi, R. Renganathan, S. Fujita, “Study of TiO2-mediated photocatalytic degradation of methylene blue,” J. Photoch. Photobio. A, 88 (1995) 163-167. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/38333 | - |
dc.description.abstract | 利用水熱法製程在120 ~ 180 ℃的溫度範圍之間以過氧化鋅為前驅物來製備氧化鋅/過氧化鋅的複合材料。氧化鋅/過氧化鋅複合材料所呈現出的形態為在稜柱形氧化鋅結晶體的表面上有小顆粒狀的過氧化鋅「融合」在其上。此外,以溶膠-凝膠法以及初濕含浸法,利用二氧化鈦作為母相,並在不同鍛燒溫度下來製備鈦酸鍶/二氧化鈦之複合材料。另一方面,在光觸媒活性分析上,以波長300 nm的光源照射甲基橙以及亞甲基藍溶液以進行降解反應,發現氧化鋅/過氧化鋅與鈦酸鍶/二氧化鈦複合材料有最佳的光反應活性。如此反應活性的提高是由於在組成複合材料的兩相在表面存在著緊密鍵結的異相結構鍵結且兩種不同相的氧化物之間其結構上以及其能帶上的差異,因而有助於光激發電子電洞對的分離。
本研究同時也提出一種製備緊密接合雙成份半導體光觸媒組合物的製程,該製程是以該組合物內之其中一成份半導體光觸媒相為起始相,經由一個以上的化學反應將此起始相部份轉化合成出具不同化學組成之另一成份半導體光觸媒相,以形成最終之雙成份組合物物件以該製程所獲得之雙成份半導體光觸媒呈現較其任一組成的單一相材料有著更佳的光觸媒活性。 | zh_TW |
dc.description.abstract | ZnO/ZnO2 composite photocatalysts were synthesized by hydrothermal treatment at 120 ~ 180 ℃ of ZnO2, which in turn was obtained from an aqueous solution of ZnSO4 and H2O2. The composite particles showed morphology of ZnO prismatic crystallites with small ZnO2 granules “fused” at surface. Besides, SrTiO3/TiO2 composite photocatalysts were prepared by sol-gel and incipient wetness impregnation method and proceeded to calcine at high temperature, with TiO2 as the main phase of the composite.
Photocatalytic activity was characterized based on photocatalytic degradation of methyl orange and methylene blue under UV-light (300 nm) illumination, and the maximum activity was both observed for the composite photocatalysts synthesized based on pre-formed main phase, ZnO/ZnO2 and SrTiO3/TiO2. The enhanced activity has been attributed to the presence of the intimate hetero-structure on the surface of composites and the effective way for the separation of excitons. This study also points out a new approach to synthesize a coupled composite photocatalyst containing strongly coupled constituents by phase transformation among the constituents through one or more than one chemical reaction(s). | en |
dc.description.provenance | Made available in DSpace on 2021-06-13T16:30:42Z (GMT). No. of bitstreams: 1 ntu-94-R92524087-1.pdf: 1496274 bytes, checksum: c7b79d4ddc936fbfea2e42882ab0d384 (MD5) Previous issue date: 2005 | en |
dc.description.tableofcontents | Table of Contents
摘要 I Abstract II List of Figures VI List of Tables XI Introduction 1 Chapter 1 Background 3 1-1 Composite photocatalysts 3 1-2 ZnO2 8 1-3 ZnO 8 1-3-1 Properties and synthetic methods of ZnO 9 1-3-2 Applications of ZnO 12 1-4 TiO2 14 1-4-1 Properties and synthetic methods of TiO2 14 1-4-2 Applications of TiO2 24 1-5 SrTiO3 25 1-5-1 Properties and synthetic methods of SrTiO3 26 1-5-2 Applications of SrTiO3 28 1-6 Synthetic methods 29 1-6-1 Hydrothermal process 29 1-6-2 Sol-gel process 30 Chapter 2 Experimental 35 2-1 Synthesis of composite photocatalyst 35 2-1-1 ZnO/ZnO2 composite photocatalyst 35 2-1-2 SrTiO3/TiO2 composite photocatalyst 38 2-2 Experimental Instruments and Chemical Reagents 41 2-2-1 Experimental Instruments 41 2-2-2 Chemical Reagents 42 2-3 Analyses 42 2-3-1 X-ray Diffraction 42 2-3-2 UV-Vis spectrum 44 2-3-3 Scanning Electron Microscopy 45 2-3-4 Brunauer-Emmett-Teller (BET) surface area 47 2-3-5 X-ray Photoelectron Spectroscopy 48 2-4 Kinetic analyses 50 Chapter 3 Result and Discussion 55 3-1 ZnO/ZnO2 composite photocatalyst 55 3-1-1 XRD analyses 55 3-1-2 UV-vis spectrum analyses 59 3-1-3 SEM analyses 63 3-1-4 BET surface area analyses 68 3-1-5 Kinetic analyses 69 3-2 SrTiO3/TiO2 composite photocatalyst 76 3-2-1 SrTiO3/TiO2 with molar ratio Sr/Ti=0.1 calcined at different temperatures 76 3-2-1-1 XRD analyses 76 3-2-1-2 UV-vis spectra analyses 83 3-2-1-3 BET surface area analyses 87 3-2-1-4 XPS analyses 89 3-2-1-5 Kinetic analyses 94 3-2-2 SrTiO3/TiO2 calcined at 600 and 700 ℃ with different molar ratios 114 3-2-2-1 XRD analyses 114 3-2-2-2 Kinetic analyses 117 3-2-3 Effect of amount of composite photocatalyst 122 Chapter 4 Conclusions 126 References 128 | |
dc.language.iso | en | |
dc.title | 複合式光觸媒之製備與分析 | zh_TW |
dc.title | Synthesis and Characterization of Composite Photocatalyst | en |
dc.type | Thesis | |
dc.date.schoolyear | 93-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 吳紀聖(Chi-Sheng Wu),黃淑娟(Shu-Jiuan Huang) | |
dc.subject.keyword | 光觸媒,複合材料,氧化鋅,過氧化鋅,二氧化鈦,鈦酸鍶, | zh_TW |
dc.subject.keyword | Photocatalyst,Composite,ZnO,ZnO2,TiO2,SrTiO3, | en |
dc.relation.page | 145 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2005-07-12 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
文件中的檔案:
檔案 | 大小 | 格式 | |
---|---|---|---|
ntu-94-1.pdf 目前未授權公開取用 | 1.46 MB | Adobe PDF |
系統中的文件,除了特別指名其著作權條款之外,均受到著作權保護,並且保留所有的權利。