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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 林正芳(Cheng-Fang Lin) | |
| dc.contributor.author | Jia-Hong Tsai | en |
| dc.contributor.author | 蔡家弘 | zh_TW |
| dc.date.accessioned | 2021-06-13T15:38:21Z | - |
| dc.date.available | 2013-07-16 | |
| dc.date.copyright | 2008-07-16 | |
| dc.date.issued | 2008 | |
| dc.date.submitted | 2008-07-09 | |
| dc.identifier.citation | 3M Company (1999). The science of organic fluorochemistry., U.S. EPA docket EPA-HQ-OPPT-2002-0043-0006
3M Company (2001). Environmental monitoring-multi-city study., 3M Envrionmental Laboratory, U.S. EPA Administrative Record AR226-1030A Abdellatif, A.G., Preat, V., Taper, H.S., and Roberfroid, M. (1991). The modulation of rat liver carcinogenesis by perfluorooctanoic acid, a peroxisome proliferator., Toxicol. Appl. Pharmacol., 111, 530-537 Adinehzadeh, M., Reo, N.V., Jarnot, B.M., Taylor, C.A., and Mattie, D.R. (1999). Dose-response hepatotoxicity of the peroxisome proliferator, perfluorodecanoic acid and the relationship to phospholipid metabolism in rats., Toxicology, 134(2-3), 179-195 Allsopp, M., Santillo, D., Walters, A., and Johnston, P. (2005). Perfluorinated chemicals An emerging concern., Greenpeace Research Laboratories Technical Note 04/2005 Andreozzi, R., Caprio, V., Insola, A., and Marotta, R. (1999). Advanced oxidation processes (AOP) for water purification and recovery., Catalysis Today, 53(1), 51-59 Apelberg, B.J., Witter, F.R., Herbstman, J.B., Calafat, A.M., Halden, R.U., Needham, L.L., and Goldman, L.R. (2007). Cord serum concentrations of perfluorooctane sulfonate (PFOS) and perfluorooctanoate (PFOA) in relation to weight and size at birth., Environmental Health Perspectives, 115(11), 1670-1676 Boulanger, B., Vargo, J.D., Schnoor, J.L., and Hornbuckle, K.C. (2005). Evaluation of perfluorooctane surfactants in a wastewater treatment system and in a commercial surface protection product., Environ. Sci. & Technol., 39(15), 5524-5530 Brus, L. (1984). Electron-electron and electron-hole interactions in small semiconductor crystallites：The size dependence of the lowest excited electronic state., J. of Physical Chemistry, 80(9), 4403-4409 Chen, J., Zhang, P.Y., and Liu, J. (2007). Photodegradation of perfluorooctanoic acid by 185nm vacuum ultraviolet light., J. of Environ. Sci., 19(4), 387-390 Chen, J., Zhang, P.Y., and Zhang, L. (2006). Photocatalytic decomposition of environmentally persistent perfluorooctanoic acid., Chemistry Letters, 35(2), 230-231 Chen, Y.C., Vorontsov, A.V., and Smirniotis, P.G. (2003). Enhanced photocatalytic degradation of dimethyl methylphosphonate in the presence of low-frequency ultrasound., Photochem. Photobiol. Sci., 2, 694-698 Diebold, U. (2003). The surface science of titanium dioxide., Surface Science Reports, 48(5-8), 53-229 Dillert, R., Bahnemann, D., and Hidaka, H. (2007). Light induced degradation of perfluorocarboxylic acids in the presence of titanium dioxide., Chemosphere, 67(4), 785-792 Dinglasan, M.J., Ye, Y., Edwards, E.A., and Mabury, S.A. (2004). Fluorotelomer alcohol biodegradation yields poly- and perfluorinated acids., Environ. Sci. & Technol., 38(10), 2857-2864 European Chemicals Bureau (ECB) (2003). Technical Guidance Document in support of Commission Directive 93/67/EEC on risk assessment for new notified substances, Commission Regulation (EC) No 1488/94 on risk assessment for existing substances and Directive 98/8/EC of the European Parliament and of the Council concerning the placing of biocidal products on the market Giesy, J.P., and Kannan, K. (2001). Global distribution of perfluorooctane sulfonate in wildlife., Environ. Sci. & Technol., 35(7), 1339-1342 Giesy, J.P., and Kannan, K. (2002). Perfluorochemical surfactants in the environment., Environ. Sci. & Technol., 36(7), 147-152 Gratzel, M. (1989). Heterogeneous photochemical electron transfer., CRC Press Boca Raton, Fla. Hench, L.L, and West, J.K. (1989). The sol-gel process., Chem. Rev., 90, 33-72 Herrmann, J.M. (1999). Heterogeneous photocatalysis：Fundamentals and applications to the removal of various types of aqueous pollutants., Catalysis Today, 53(1), 115-129 Higgins, C.P., and Luthy, R.G. (2006). Sorption of perfluorinated surfactants on sediments., Environ. Sci. & Technol., 40(23), 7251-7256 Higgins, C.P., Field, J.A., Criddle, C.S., and Luthy, R.G. (2005). Quantitative determination of perfluorochemicals in sediments and domestic sludge., Environ. Sci. & Technol., 39(11), 3946-3956 Hori, H., Hayakawa, E., Einaga, H., Kutsuna, S., Koike, K., Ibusuki, T., Kiatagawa, H., and Arakawa, R. (2004). Decomposition of environmentally persistent perfluorooctanoic acid in water by photochemical approaches., Environ. Sci. & Technol.,38(22), 6118-6124 Hori, H., Yamamoto, A., Koike, K., Kutsuna, S., Murayama, M., Yoshimoto, A., and Arakawa, R. (2008). Photocatalytic decomposition of a perfluoroether carboxylic acid by tungstic heteropolyacids in water., Applied Catalysis, 82(1-2), 58-66 Hori, H., Yamamoto, A., Koike, K., Kutsuna, S., Osaka, I., and Arakawa, R. (2007). Photochemical decomposition of environmentally persistent short-chain perfluorocarboxylic acids in water mediated by iron(II)/(III) redox reactions., Chemosphere, 68(3), 572-578 Kim, M.S., Ryu, C.S., and Kim, B.W. (2005). Effect of ferric ion added on phtotdegradation of alachlor in the presence of TiO2 and UV radiation., Water Research, 39(4), 525-532 Lampert, D.J., Frisch, M.A., Speitel Jr., G.E., and McKetta, J.J. (2007). Removal of perfluorooctanoic acid and perfluorooctane sulfonate from wastewater by ion exchange., Practice Periodical of Hazardous, Toxic, and Radioactive Waste Management, 11(1), 60-68 Legan, R.W. (1982). Ultraviolet light take on CPI roles., Chemical Engineering, 89(22), 95-100 Li, G.H., Ciston, S., Saponjic, Z.V., Chen, L., Dimitrijevic, N.M., Rajh, T., and Gray, K.A. (2008). Synthesizing mixed-phase TiO2 nanocomposites using a hydrothermal method for photo-oxidation and photoreduction applications., Journal of Catalysis, 253(1), 105-110 Li, Y.J., Li, X.D., Li, J.W., and Yin, J. (2004). Photocatalytic properties of TiO2 bonded active carbon composites prepared by SOL-GEL., Trans. Nonferrous Met. Soc., 14(6), 1232-1237 Linsebigler, A.L., Lu, G., and Yates Jr., J.T. (1995). Photocatalysis on TiO2 surfaces Principles, mechanisms, and selected results., Chem. Rev., 95, 738-758 Liu, Z.Q., Zhou, Y.P., Li, Z.H., Wang, Y.C., and Ge, C.C. (2007). Preparation and characterization of (metal, nitrogen)-codoped TiO2 by TiCl4 sol-gel auto-igniting synthesis., Rare Metals, 26(3), 263-270 Maezawa, A., Nakadoi, H., Suzuki, K., Furusawa, T., Suzuki, Y., and Uchida, S. (2007). Treatment of dye wastewater by using photo-catalytic oxidation with sonication., Ultrasonics Sonochemistry, 14(5), 615-620 Mason, T.J., and Lorimer, J.P. (2002). Applied Sonochemistry：The uses of power ultrasound in chemistry and processing., Wiley-VCH Verlag GmbH, Wernhiem Matos, J., Laine, J., and Herrmann, J.M. (1998). Synergy effect in the photocatalytic degradation of phenol on a suspended mixture of titania and activated carbon., Applied Catalysis, 18(3-4), 281-191 Minnesota Department of Health (MDH) (2007). Environmental health information – Perfluorochemicals and health., Minnesota, U.S. Mo, S.D., and Ching, W.Y. (1995). Electronic and optical properties of three phases of titanium dioxide：Rutile, anatase, and brookite., Physical Review B, 51(19), 23-32 Moody, C.A., Martin, J.W., Kwan, W.C., Muir, D.C.G., and Mabury, S.A. (2002). Monitoring perfluorinated surfactants in biota and surface water samples following an accidental release of fire-fighting foam into Etobicoke creek., Environ. Sci. & Technol., 36(4), 545-551 Moriwaka, A., Kamer, N., Harada, K., Inoue, K., Yoshinaga, T., Saito, N., and Koizumi, A. (2006). The bioconcentration factor of perfluorooctane sulfonate is significantly larger than that of perfluorooctanoate in wild turtles., Ecotoxicology and Environ Safty, 65(1), 14-21 Moriwaki, H., Takagi, Y., Tanaka, M., Tsuruho, K., Okitsu, K., and Maeda, Y. (2005). Sonochemical decomposition of perfluorooctane sulfonate and perfluorooctanoic acid., Environ. Sci. & Technol., 39(9), 3388-3392 Mrowetz, M., Pirola, C., and Selli, E. (2003). Degradation of organic water pollutants through sonophotocatalysis in the presence of TiO2., Ultrasonics Sonochemistry, 10(4-5), 247-254 New Jersey Department of Environmental Protection (NJDEP) (2007). Guidance for PFOA in drinking water at Pennsqrove water supply company., New Jersey, U.S. Nguyen, P.H.L. (2007). Study on distribution and behavior of PFOS (Perfluorooctane sulfonate) and PFOA (Perfluorooctanoate) in water environment., Ph.D. thesis, University of Tyoto, Japan North California Division of Water Quality (NCDWQ) (2006). Recommended interim maximum allowable concentration for perfluorooctanoic acid., North California, U.S. Nozoe, M., Fujii, S., Tanaka, S., Tamaka, H., and Yamashita, N. (2006). Investigation of PFOS and PFOA in a wastewater treatment plant., Environmental Engineering Research, 43, 105-111 O'Shea, K.E., Pernas, E., and Saiers, J. (1999). The influence of mineralization products on the coagulation of TiO2 photocatalyst., Langmuir, 15(6), 2071-2076 Peller, J., Wiest, O., and Kamat, P.V. (2003). Synergy of combining sonolysis and photocatalysis in the degradation and mineralization of chlorinated aromatic compounds., Environ. Sci. & Technol., 37(9), 1926-1932 Prevedouros, K., Cousins, I.T., Buck, R.C., and Korzeniowski, S.H. (2006). Sources, fate and transport of perfluorocarboxylates., Environ. Sci. & Technol., 40(1), 32-44 Qiu, Y. (2007). Study on treatment technologies for perfluorochemicals in wastewater., Ph.D. thesis, University of Tyoto, Japan Richardson S.D. (2003). Water analysis：Emerging contaminants and current issues., Anal. Chem., 75(12), 2831-2857 Riesz, P., Berdahl, D., and Christman, C.L. (1985). Free radical generation by ultrasound in aqueous and nonaqueous solutions., Environmental Health Perspectives, 64, 233-252 Sakai, H., Kawahara, H., Shimazaki, M., and Abe, M. (1998). Preparation of ultrafine titanium dioxide particles using hydrolysis and condensation reactions in the inner aqueous phase of reversed micelles：Effect of alcohol addition., Langmuir, 14(8), 2208-2212 Sato, C., and Yao, J. (2006). Simultaneous and sequential photosonolysis of TCE and PCE., J. of Environmental Engineering, 132(1), 32-41 Schröder, H.Fr., and Meesters, R.J.W. (2005). Stability of fluorinated surfactants in advanced oxidation processes - A follow up of degradation products using flow injection - mass spectrometry, liquid chromatography - mass spectrometry and liquid chromatography - multiple stage mass spectrometry., J. of Chromatography, 1082(1), 110-119 Schultz, M.M., Barofsky, D.F., and Field, J.A. (2006). Quantitative determination of fluorinated alkyl substances by large-volume-injection liquid chromatography tandem mass spectrometry - Characterization of municipal wastewaters., Environ. Sci. & Technol., 40(1), 289-295 Schultz, M.M., Higgins, C.P., Huset, C.A., Luthy, R.G., Barofsky, D.F., and Field, J.A. (2006). Fluorochemical mass flows in a municipal wastewater treatment facility., Environ. Sci. & Technol., 40(23), 7350-7357 Selli, E., Bianchi, C.L., Pirola, C., and Bertelli, M. (2005). Degradation of methyl tert-butyl ether in water：effects of the combined use of sonolysis and photocatalysis., Ultrasonics Sonochemistry, 12(5), 395-400 Serpone, N., Maruthamuthu, P., Pichat, P., Pelizzetti, E., and Hidaka, H. (1995). Exploiting the interparticle electron transfer process in the photocatalysed oxidation of phenol, 2-chlorophenol and pentachlorophenol：Chemical evidence for electron and hole transfer between coupled semiconductors., J. of Photochem.& Photobio., A：Chem., 85(3), 247-255 Stock, N.L., Peller, J., Vinodgopal, K., and Kamat, P.V. (2000). Combinative sonolysis and photocatalysis for textile dye degradation., Environ. Sci. & Technol., 34(9), 1747-1750 Su, C., Hong, B.Y., and Tseng, C.M. (2004). Sol-gel preparation and photocatalysis of titanium dioxide., Catalysis Today, 96(3), 119-126 Tang, C.Y., Fu, Q.S., Criddle, C.S., and Leckie, J.O. (2007). Effect of flux (Transmembrane pressure) and membrane properties on fouling and rejection of reverse osmosis and nanofiltration membranes treating perfluorooctane sulfonate containing wastewater., Environ. Sci. & Technol., 41(6), 2008-2014 Tang, C.Y., Fu, Q.S., Robertson, A.P., Criddle, C.S., and Leckie, J.Q. (2006). Use of reverse osmosis membranes to remove perfluorooctane sulfonate (PFOS) from semiconductor wastewater., Environ. Sci. & Technol., 40(23), 7343-7349 Tryba, B., Morawski, A.W., and Inagaki, M. (2003). Application of TiO2-mounted activated carbon to the removal of phenol from water., Applied Catalysis, 41(4), 427-433 Tuulmets, A. (1997). Ultrasound and polar homogeneous reactions., Ultrasonics Sonochemistry, 4(2), 189-193 U.S. EPA (2002). Revised draft hazard assessment of perfluorooctanoic acid and its salts., Office of Pollution Prevention and Toxics Risk Assessment Division, U.S. U.S. EPA (2006). SAB review of EPA's draft risk assessment of potential human health effects associated with PFOA and its salts., Office of The Administration Science Advisory Board, U.S. Wallington, T.J., Hurley, M.D., Xia, J., Wuebbles, D.J., Sillman, S., Ito, A., Penner, J.E., Ellis, D.A., Martin, J., Mabury, S.A., Nielsen, O.J., and Anderson, M.P.S. (2006). Formation of C7F15COOH (PFOA) and other perfluorocarboxylic acids during the atmospheric oxidation of 8:2 fluorinated alcohol., Environ. Sci. & Technol., 40(3), 924-930 Wang, Y., Zhang, P., Pan, G., and Chen, H. (2008). Ferric ion mediated photochemical decomposition of perfluorooctanoic acid (PFOA) by 254nm UV light., J. of Hazardous Materials, doi:10.1016/j.jhazmat.2008.02.105 Wang, Y.P., Peng, P.Y., Ding, H.Y., and Wu, Y. (2005). Preparation and catalytic activity of active-carbon-supported TiO2., Acta Scientiae Circumstantiae, 25(5), 611-617 Yamamoto, T., Noma, Y., Sakai, S.-I., and Shibata, Y. (2007). Photodegradation of perfluorooctane sulfonate by UV irradiation in water and alkaline 2-propanol., Environ. Sci. & Technol., 41(16), 5660-5665 Yamashita, N., Kannan, K., Taniyasu, S., Horii, Y., Petrick, G., and Gamo, T. (2005). A global survey of perfluorinated acids in oceans., Marine Pollution Bulletin, 51(8-12), 658-668 Zhang, C., Zhou, Q., Chen, L., Yuan, Y., and Zhang, Q. (2006). Photochemical decomposition of environmentally persistent perfluorooctanoic acid in water., Water practice & Technology, 1(3), WPT. 2006061 Zhu, Y.F., Zhang, L., Gao, C., and Cao, L.L. (2000). The synthesis of nanosized TiO2 powder using a sol-gel method with TiCl4 as a precursor., J. of Materials Science, 35(16), 4049-4054 李安成、林榮顯、黃建程、吳宗翰 (2006)，以活性碳為載體之光觸媒的製備與特性研究，工程科技與教育學刊，3(1)，69-75。 林郁真 (2007)，論環境中之新興污染物，環境工程會刊，18(1)，39-55。 林郁真 (2007)，新興污染物對環境之污染現況及研究進展，國立臺灣大學工程學刊，96，73-82。 林尚賢 (2007)，超音波輔助超濾膜清洗程序，碩士論文，國立台灣大學環境工程學研究所，台北。 侯文哲 (2002)，結合半導體催化劑光催化降解水溶液中4-氯酚，碩士論文，國立台灣大學環境工程學研究所，台北。 高濂、鄭珊、張青紅 (2004)，奈米光觸媒，五南圖書出版股份有限公司，台北。 陳志賢 (2003)，奈米可見光V/TiO2觸媒之合成與物性分析，碩士論文，國立台灣大學化學工程學研究所，台北。 張青紅，高濂、郭景坤 (2000)，四氯化鈦水解法製備奈米氧化鈦超細粉體，無機材料學報，15(1)，21-25。 曾巧立 (2004)，以液相層析質譜儀檢測水樣與生物檢體中全氟界面活性劑之濃度，碩士論文，國立中央大學化學研究所，桃園。 歐信宏 (2003)，光觸媒間電子傳遞效應催化降解4-CP及4-NP，碩士論文，國立台灣大學環境工程學研究所，台北。 謝秉勳 (2002)，奈米級光觸媒之製備及光催化活性測定，碩士論文，國立台灣大學環境工程學研究所，台北。 | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/37680 | - |
| dc.description.abstract | 本研究利用結合超音波與UV/TiO2光觸媒光催化氧化法(sonophotocatalysis)降解全氟辛酸(PFOA)，分為串聯(sequential)與同時(simultaneous)操作，以探討PFOA的去除效率。
自行合成的Sol-gel TiO2經BET分析得比表面積為38.54 m2/g，TEM圖顯示粒徑約為30至50 nm，XRD分析礦物晶型為Anatase與Rutile共存的結構，能隙為3.03 eV。 僅用光催化法之PFOA去除效率為22%，零階速率常數為0.0292 (hr-1)，當結合超音波與光催化系統於同時操作時，超音波震盪可使TiO2保持均勻分散，減少發生凝聚現象(agglomerate)，並使表面反應位置更新(refreshed)，以增加TiO2與反應物的質量傳輸效率，產生協同效應(synergistic effect)有效使PFOA去除效率提升至49%，擬一階速率常數為0.0866 (hr-1)，串聯操作則無提升效率，而將TiO2改為Sol-gel TiO2後，去除效率更提升至64%，擬一階速率常數為0.1309 (hr-1)。在不同pH環境時，去除效率為：鹼性(pH=10) > 酸性(pH=4) > 中性(pH=7)，因鹼性環境下有較多高反應性氫氧自由基(．OH)與PFOA進行降解反應。 PFOA可有效被降解成毒性較低的全氟庚酸(PFHpA)、全氟己酸(PFHxA)與氟離子之中間產物，減少PFOA在環境中的危害性。 | zh_TW |
| dc.description.abstract | The objective is to utilize ultrasonic irradiation assisted photo-catalysis which divided into sequential operation and simultaneous operation for perfluorooctanoic acid (PFOA) removal in this study. The process is called “sonophotocatalysis.”
The specific surface area of synthesized sol-gel TiO2 was 38.54 (m2/g) by BET analysis and the particle diameter was about 30 to 50 nm by TEM. Its crystal structure was a mixture of anatase and rutile showed by XRD analysis. Also, it had 3.03 eV for energy band gap. The removal efficiency of PFOA was 22% and rate constant of zero-order equation, k, was 0.0292 (hr-1) for only photo-catalysis. It was increased to 49% and 0.0866 (hr-1) of pseudo first-order rate constant, k, due to the synergistic effect in simultaneous operation. Because ultrasonic irradiation can disperse TiO2 more evenly, prevent the agglomerate of TiO2, and keep the reactive surface of TiO2 being refreshed to increase mass transfer between TiO2 and reactant. However, the removal efficiency of PFOA was increased to 64% and 0.1309 (hr-1) of k by using sol-gel TiO2. But sequential operation was useless. In addition, the removal efficiency was better at pH=10 > pH=4 > pH=7 because there are much hydroxide radicals (．OH) to react with PFOA at pH=10. PFOA was also efficient to degrade to intermediates, such as PFHpA, PFHxA and fluoride ion to be harmfulless. | en |
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| dc.description.tableofcontents | 誌謝 I
中文摘要 II ABSTRACT III 目錄 IV 圖目錄 VII 表目錄 IX 第一章 緒論 1 1-1 前言 1 1-2 研究動機與假設 2 1-3 研究目標與內容 3 1-3-1 研究目標 3 1-3-2 研究內容 3 1-4 工作項目 4 第二章 文獻回顧 5 2-1 全氟辛酸 5 2-1-1 物理化學性質 6 2-1-2 來源及使用 7 2-1-3 環境暴露途徑 8 2-1-4 環境宿命 9 2-1-5 人體健康之影響 11 2-1-6 全氟辛酸相關之中間產物簡介 11 2-2 光催化法之介紹 12 2-2-1 光觸媒 12 2-2-1-1 半導體特性介紹 12 2-2-1-2 能隙 14 2-2-1-3 二氧化鈦 15 2-2-1-4 溶膠凝膠法 16 2-2-2 光催化反應機制與原理 18 2-2-2-1 異相光催化反應 20 2-2-2-2 反應動力學 22 2-2-3 提升光催化活性之方法 22 2-3 超音波反應機制與原理 23 2-4 去除全氟辛酸之相關研究文獻 25 第三章 實驗方法與材料 26 3-1 實驗內容與項目 26 3-1-1 光觸媒之物理化學特性分析 28 3-1-2 光催化之污染物濃度分析 29 3-1-3 控制因子與操作因子 30 3-2 光觸媒之製備 31 3-2-1 實驗原理 31 3-2-2 實驗步驟 32 3-2-3 實驗材料 34 3-2-3-1 藥品 34 3-2-3-2 儀器器材 34 3-2-4 分析儀器與方法 34 3-2-4-1 紫外光/可見光光譜儀 35 3-2-4-2 比表面積與孔洞分析儀 36 3-2-4-3 X光粉末繞射儀 37 3-2-4-4 穿透式電子顯微鏡 37 3-3 光催化反應實驗 37 3-3-1 實驗內容 37 3-3-2 實驗步驟 39 3-3-3 實驗材料 40 3-3-3-1 藥品 40 3-3-3-2 儀器器材 41 3-3-4 實驗設備 42 3-3-5 分析儀器與方法 44 3-3-5-1 高效能液相層析串聯質譜儀 44 3-3-5-2 離子層析儀 48 第四章 結果與討論 49 4-1 光觸媒特性分析 49 4-1-1 比表面積大小 49 4-1-2 礦物晶型結構 50 4-1-3 能隙大小分析 52 4-1-4 表面型態觀察 54 4-2 背景實驗 56 4-2-1 揮發實驗 56 4-2-2 吸附實驗 57 4-2-3 直接光解實驗 58 4-3 光催化反應實驗 60 4-3-1 最佳UV光瓦數與最佳光觸媒添加量 60 4-3-2 外加超音波場源之光催化反應 64 4-3-3 自行合成TiO2光觸媒於超音波結合光催化反應 67 4-3-4 中間產物與反應機制 70 4-3-5 不同pH值對於光催化去除PFOA之影響 73 第五章 結論與建議 79 5-1 結論 79 5-2 建議 81 參考文獻 82 附錄 94 | |
| dc.language.iso | zh-TW | |
| dc.subject | 全氟辛酸 | zh_TW |
| dc.subject | 協同效應 | zh_TW |
| dc.subject | 結合超音波與光催化反應系統 | zh_TW |
| dc.subject | Perfluorooctanoic acid (PFOA) | en |
| dc.subject | Sonophotocatalysis | en |
| dc.subject | Synergistic effect | en |
| dc.title | 超音波促進光催化氧化法去除水中全氟辛酸 | zh_TW |
| dc.title | Perfluorooctanoic Acid (PFOA) Removal by Sonication Assisted Photo-Catalytic Oxidation | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 96-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 林郁真(Angela Yu-Chen Lin),郝晶瑾,康佩群 | |
| dc.subject.keyword | 全氟辛酸,結合超音波與光催化反應系統,協同效應, | zh_TW |
| dc.subject.keyword | Perfluorooctanoic acid (PFOA),Sonophotocatalysis,Synergistic effect, | en |
| dc.relation.page | 99 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2008-07-09 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 環境工程學研究所 | zh_TW |
| 顯示於系所單位： | 環境工程學研究所 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-97-1.pdf 未授權公開取用 | 2.2 MB | Adobe PDF |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。