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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 梁文傑(Man-kit Leung) | |
| dc.contributor.author | You-Shiang Lin | en |
| dc.contributor.author | 林佑祥 | zh_TW |
| dc.date.accessioned | 2021-06-13T06:47:55Z | - |
| dc.date.available | 2013-07-29 | |
| dc.date.copyright | 2011-07-29 | |
| dc.date.issued | 2011 | |
| dc.date.submitted | 2011-07-22 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/35318 | - |
| dc.description.abstract | 利用醯胺鍵生成，合成出以三苯胺為主體的風扇狀三苯胺樹枝狀分子G0 與G1 以及運用Knoevenagel Reaction 合成出以氰基二乙烯苯為主體的三苯胺樹枝狀分子C0 與C1。並利用熱分析，光譜分析，顯微鏡與電化學方法來探討各別分子的熱性質，光物理，奈米結構與電化學特性。
而所有的分子都具有很特別的誘導聚集放光(aggregation-induced emission，AIE)或著是聚集誘導增強放光(aggregation-induced enhance emission，AIEE)等固相放光的特性是藉著分子內轉動限制(restriction of intramolecular rotation，RIR)或在固態時分子的排列模式所誘導。 而在不同的分子引入三苯胺基團都可利用電化學方式誘導分子聚合成高分子，以及所形成的高分子薄膜在氧化還原過程中具有電致變色特性的功能，最特別的是可以藉著電化學的氧化還原來控制固相螢光的開關行為。 我們發展出了一個簡單利用電化學方式來控制固相螢光特性的方法，可以應用到不同的光電元件上。 | zh_TW |
| dc.description.abstract | We used amide bond formation and Knoevenagel Reaction to synthesize propeller-shaped triphenylamine-based dendrimers G0, G1 and the others C0, C1 which utilize cyanostilbene as core unit.
By using thermal analysis, spectroscopy, microscopy, electrochemical method, we could observe their thermal, photophysical, nanostructure and electrochemical properties. All the aggregation-induced emission (AIE) or aggregation-induced enhance emission (AIEE) character of them, by restriction of intramolecular rotation (RIR) mechanism or through molecular structure packing arrangement in the solid-state. The triphenylamine group can be polymerized by electrochemistry and the polymer film have electrochromic character. The most special thing that we can control the switching behavior of the solid state emission by electrochemistry. The property can be applied in various electronic devices. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-13T06:47:55Z (GMT). No. of bitstreams: 1 ntu-100-R98223109-1.pdf: 11351520 bytes, checksum: d401b4ec75c0d190a49b85a3581345eb (MD5) Previous issue date: 2011 | en |
| dc.description.tableofcontents | 目錄 i
中文摘要 iii Abstract iv 圖目錄 v 表目 xii 流程目錄 xiii 化合物結構式與編號 xiv 一、緒論 1 1-1 物質吸光與放光 1 1-2 固相螢光簡介 2 1-3 三芳香胺簡介 7 1-4 三苯胺電化學 8 1-5 電致變色簡介 13 1-6 電致變色材料分類 14 1-7 電致變色元件之應用 16 1-8 研究動機19 二、風扇結構三苯胺樹枝狀分子應用於固態螢光與電致變色21 2-1 分子設計21 2-2 目標分子逆合成分析與步驟 23 2-3 結果與討論 29 2-3-1 1H-NMR 光譜分析 29 2-3-2 熱性質探討 32 2-3-3 光學行為探討 33 2-3-4 顯微鏡分析探討 40 2-3-5 電化學行為探討 42 2-3-6 薄膜光譜電化學與電致變色實驗 49 2-3-7 螢光開關行為 54 2-3-8 奈米粒子的電化學行為 57 2-4 結論 62 三、氰基二苯乙烯為核心三苯胺樹枝狀分子應用於固態螢光開關 65 3-1 分子設計65 3-2 目標分子逆合成分析與步驟 66 3-3 結果與討論 69 3-3-1 光學行為探討 69 3-3-2 電化學行為探討 74 3-3-3 薄膜光譜電化學 80 3-3-4 螢光開關行為 86 3-4 結論 90 四、總結92 五、實驗步驟94 5-1 實驗儀器與試劑 94 5-2 合成步驟 97 六、參考文獻 113 七、附錄 118 | |
| dc.language.iso | zh-TW | |
| dc.subject | 螢光開關 | zh_TW |
| dc.subject | 三苯胺 | zh_TW |
| dc.subject | 固態螢光 | zh_TW |
| dc.subject | 電致變色 | zh_TW |
| dc.subject | electrochromism | en |
| dc.subject | flourescence switch | en |
| dc.subject | solid state emission | en |
| dc.subject | Triphenylamine | en |
| dc.title | 三苯胺樹枝狀分子應用於固態螢光、電致變色與螢光開關 | zh_TW |
| dc.title | Triphenylamine-based dendrimer application in solid state emission, electrochromism and fluorescence switch | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 99-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 何國川(Kuo-Chuan Ho),林建村(Jiann-Tsuen Lin) | |
| dc.subject.keyword | 三苯胺,固態螢光,電致變色,螢光開關, | zh_TW |
| dc.subject.keyword | Triphenylamine,electrochromism,solid state emission,flourescence switch, | en |
| dc.relation.page | 154 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2011-07-25 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
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