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???org.dspace.app.webui.jsptag.ItemTag.dcfield??? | Value | Language |
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dc.contributor.advisor | 周必泰 | |
dc.contributor.author | Kung-Shih Chen | en |
dc.contributor.author | 陳恭世 | zh_TW |
dc.date.accessioned | 2021-06-13T06:44:34Z | - |
dc.date.available | 2005-08-01 | |
dc.date.copyright | 2005-08-01 | |
dc.date.issued | 2005 | |
dc.date.submitted | 2005-07-29 | |
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J.; Arendse, F.; Comte, P.; Jirousek, M.; Lenzmann, F.; Shklover, V.; Gratzel, M. 1997, 80, 3157. 38. Kim, S.; Fisher, B.; Eisler, H. J.; Bawendi, M. G. J. Am. Chem. Soc. 2003, 125, 11466. 39. Mikhailova, M. P.; Titkov, A. N. Semicond. Sci. Technol. 1994, 9, 1279. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/35222 | - |
dc.description.abstract | 在染料敏化太陽能電池的架構中,陽極是在導電玻璃片上沈積中孔洞的二氧化鈦薄膜層組成的光電轉換工作電極。二氧化鈦的顆粒的表面吸附上染料,周圍則充滿了適當的氧化還原對電解質溶液。陰極則是另一片表面鍍上了催化用的白金顆粒的導電玻璃。利用半導體(如CdS, CdSe, CdTe等)奈米粒子作為染料比起有機的染料分子可能有著一些優勢:半導體材料比起有機分子通常含蓋更多波長的吸收範圍,同時也可能有較好的光穩定性。
我們使用了三種方法以達到以奈米粒子敏化二氧化鈦電極的目的:1. 先合成適當大小的半導體奈米粒子,再藉吸附的方式將使奈米粒子附著在二氧化鈦電極表面。2. 直接沈積在二氧電極表面就地沈積出半導體奈米粒子。3. 將合成的半導體奈米粒子與二氧化鈦粉末均勻混合後以高壓壓製出電極。以上各種方法所得的電極的皆在模擬太陽光下測試其光化學效應。 | zh_TW |
dc.description.abstract | The dye-sensitized TiO2 cell consists of a light-converting anode comprising a thin film of sintered mesoporous TiO2 deposited on electrically conducting glass. The TiO2 particles are covered with sensitizing dye and surrounded by an electrolyte containing a suitable redox couple. A second piece of conducting glass coated with a catalytic amount of platinum forms the cathode. Using inorganic nanoparticles (such as CdS, CdSe, CdTe, etc.) as sensitizers implies several advantages as compared to organic dyes: Inorganic nanoparticles usually have broader absorption spectral region for light harvesting, and usually were more stable against photo-degradation.
Three different approaches were used for nanoparticle sensitizing: 1. Nanoparticles were first synthesized separately with the desired size and then subsequently adsorbed them onto the TiO2 photoanode surface. 2. Nanoparticles were prepared and deposited in situ on the TiO2 photoanode in a single step. 3. Nanoparticles were first synthesized and mixed with dispersed nanocrytalline TiO2 particles, then the photoanode were fabricated using the “hydraulic pressing route”. The photoelectrochemical behaviors of these photoanodes were measured under simulated sunlight. | en |
dc.description.provenance | Made available in DSpace on 2021-06-13T06:44:34Z (GMT). No. of bitstreams: 1 ntu-94-R92223070-1.pdf: 3307915 bytes, checksum: 493a614e501783bff7848bc756d746e5 (MD5) Previous issue date: 2005 | en |
dc.description.tableofcontents | 目錄p.I
圖目錄p.IV 表目錄VII 中文摘要p.VIII 英文摘要p.IX 緒論p.1 第一章 太陽能電池簡介p.2 1.1研究背景p.2 1.2太陽能電池的簡介p.5 1.2.1 半導體簡介p.6 1.2.2 不同世代的太陽能電池p.8 1.3太陽能電池的效能測定p.18 1.3.1 太陽能電池的光電反應p.18 1.3.2 太陽能電池的效率常數p.19 1.3.3 標準測試狀況p.22 第二章 染料敏化太陽能電池原理p.24 2.1 染料敏化太陽能電池的運作原理p.24 2.2. 二氧化鈦電極p.26 2.3染料p.30 2.4 導電玻璃p.31 2.5相對電極與電解質p.33 2.6染料電池的發展p.34 第三章 N3染料敏化電池p.37 3.1 N3染料敏化太陽能電池的動力學過程p.38 3.2 N3染料敏化太陽能電池的製作與檢測p.40 3.2.1 儀器與材料p.40 3.2.2電池的組裝p.46 3.2.3 檢測方法p.49 3.2.4結果與討論p.50 第四章 奈米晶體敏化電池p.55 4.1半導體奈米晶體之特性p.55 4.1.1 限量化效應p.55 4.2奈米晶體敏化太陽能電池簡介p.61 4.3半導體奈米晶粒的合成與鑑定p.63 4.3.1 La Mer高均勻度膠體粒子成長模型p.63 4.3.2 界面活性劑與表面鈍化p.66 4.3.4 有機相合成CdX (X = S, Se, Te)奈米粒子p.69 4.3.5奈米晶體的鑑定p.72 4.4 奈米晶體敏化太陽能電池製備p.74 4.4.1奈米晶體吸附敏化電池p.74 4.4.2表面修飾奈米晶體敏化電池效能p.77 4.4.3 In Situ Depositionp.81 4.4.4 高壓壓膜法p.84 4.5未來方向p.90 結論p.99 參考文獻p.101 | |
dc.language.iso | zh-TW | |
dc.title | 奈米顆粒敏化奈米晶體二氧化鈦之光電效應研究 | zh_TW |
dc.title | Photoelectrochemical Behavior of Nanocrystalline Titanium Oxide Sensitized with Nanoparticles | en |
dc.type | Thesis | |
dc.date.schoolyear | 93-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 汪根欉,季昀 | |
dc.subject.keyword | 染料敏化,半導體奈米顆粒,太陽能電池, | zh_TW |
dc.subject.keyword | dye-sensitized,semiconductor nanoparticles,solar cells, | en |
dc.relation.page | 105 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2005-07-29 | |
dc.contributor.author-college | 理學院 | zh_TW |
dc.contributor.author-dept | 化學研究所 | zh_TW |
Appears in Collections: | 化學系 |
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