請用此 Handle URI 來引用此文件：
http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/33666完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 劉國平(Kopin Liu) | |
| dc.contributor.author | Chih-Hsuan Chang | en |
| dc.contributor.author | 張志鉉 | zh_TW |
| dc.date.accessioned | 2021-06-13T05:44:21Z | - |
| dc.date.available | 2006-07-19 | |
| dc.date.copyright | 2006-07-19 | |
| dc.date.issued | 2006 | |
| dc.date.submitted | 2006-07-14 | |
| dc.identifier.citation | 參考文獻
Chapter 1 1. R. D. Levine, Molecular Reaction Dynamics (Cambridge University Press, Cambridge, 2005) 2. R. D. Levine and R. B. Berstein, Molecular Reaction Dynamics and Chemical Reactivity, Oxford University Press, 1987 3. Tomas Baer and W. L. Hase, Unimolecular Reaction Dynamics: Theory and Experiments, Oxford University Press, NY, 1996. 4. W. C. Wiley and I. H. McLaren, Rev. Sci. Instrum. 26, 1150(1955) 5. W. R. Simpson, A. J. Orr-Ewing, S. A. Kandel, T. P. Rakitzis, and R. N. Zare, J. Chem. Phys. 103, 7299(1995). 6. L. Schnieder, W. Meier, K. H. Welge, M. N. R. Ashfold, and C. M. Western, J. Chem. Phys. 92, 7027(1990) 7. A.T. J. P. Eppink and D. H. Parker, Rev. Sci. Instrum. 68, 3477(1997) 8. M. Laura Lipciuc, Joost B. Buijs, and Maurice H. M. Janssen, Phys. Chem. Chem. Phys. 8, 219(2006) 9. K. G. Spears and S. A. Rice, J. Chem. Phys. 55, 5561(1971) 10. I. Bar and S. Rosenwaks, Int. Rev. Phys. Chem. 20, 711(2001) 11. F. F. Crim, Ann. Rev. Phys. Chem. 44, 397(1993) 12. D. Bingemann, M. P. Gorman, A. M. King, and F. F. Crim, J. Chem. Phys. 107, 661(1997) 13. G. E. Hall, N. Sivakumar, D. Chawla, P. L. Houston, and I. Burak, J. Chem. Phys. 88, 3682(1988) 14. R. N. Dixon, J. Chem. Phys. 85, 1866(1986) 15. T. P. Rakitzis, S. A. Kandel, A. J. Alexander, Z. H. Kim, and R. N. Zare, Science. 281, 1346(1998) 16. B. J. Whitaker, Imaging in Molecular Dynamics (Cambridge University Press, Cambridge, 2003) 17. K. T. Lorenz, D. W. Chandler, J. W. Barr, W. Chen, G. L. Barnes, and J. I. Cline, Science. 293, 2063(2001) 18. R. N. Zare, Mol. Photochem. 4, 1(1972) 19. R. N. Zare and D. R. Herschback, Proc. I.E.E.E, 51, 173(1963) 20. R. J. Gordon and G. E. Hall, Adv. Chem. Phys. XCVI, 1(1996) 21.C. R. Gebhardt, T. P. Rakitzis, P. C. Samartzis,V. Ladopoulos, and T. N. Kitsopoulos, Rev. Sci. Instrum. 72, 3848(2001) chapter 2 1. D. W. Chandler and P. L. Houston, J. Chem. Phys. 87, 1445(1987) 2. A. T. J. P. Eppink and D. H. Parker, Rev. Sci. Instrum. 68, 3477(1997) 3. B. Y. Chang, R. C. Hoetzlein, J. A. Mueller, J. D. Geiser, and P. L. Houston, Rev. Sci. Instrun. 69, 1665(1998) 4. B. J. Whitaker, Image Reconstruction: The Abel Transform, ACS Symposium Series No. 68, edited by A. G. Suits, and R. E. Continetti (Oxford University Press, New York, 2000) 5. M. J. J. Vrakking, Rev. Sci. Instrum. 72, 4084(2001) 6. V. Dribinski, A. Ossadtchi, V. A. Mandelshtam, and H. Reisler, Rev. Sci. Instrum. 73, 2634(2004) 7. G. A. Garcia, L. Nahon, and I. Powis, Rev. Sci. Instrum. 75, 4989(2004) 8. C. R. Gebhardt, T. P. Rakitzis, P. C. Samartzis, V. Ladopoulos, and T. N. Kitsopoulos, Rev. Sci. Instrum. 72, 3848(2001) 9. J. J. Lin, J. Zhou, W. Shiu, and K. Liu, Rev. Sci. Instrum. 74, 2495(2003) 10. D. Townsend, M. P. Minitti, and A. G. Suits, Rev. Sci. Instrum. 74, 2530(2003) 11. D. H. Parker and A. T. J. B. Eppink, J. Chme. Phys. 107, 2357(1997) 12. D. H. Parker, R. F. Delmdahl, B. B. L. G. Bakker, and H. P. Loock, J. Chin. Chem. Soc. 48, 327(2001) 13. R. L. Toomes, P. C. Samartzis, T. P. Rakitzis, and T. N. Kitsopoulos, Chem. Phys. 301, 209(2004) 14. R. D. Levine and R. B. Berstein, Molecular Reaction Dynamics and Chemical Reactivity, Oxford University Press, 1987 15. U. Even, J. Jortner, D. Noy, N. Lavie, and C. Crossart-Magos, J. Chem. Phys. 112, 8068(2000) chapter 3 1. J. H. D. Eland, Int. J. Mass Spectrom. Ion. Phys. 12, 389(1974) 2. D. L. Judge and L. C. Lee, Int. J. Mass Spectrom. Ion. Phys.17, 389(1974) 3. C. R. Brundle and D. W. Turner, Int. J. Mass Spectrom. Ion. Phys. 2, 195(1974) 4. R. Frey, B. Gotchev, W. B. Peatman, H. Pollak, and E. W. Schlag, Int. J. Mass Spectrom. Ion. Phys. 26, 137(1978) 5. C. E. Strauss, G. C. McBane, P. L. Houston, I. Burak, and J. W. Hepburn, J. Chem. Phys. 95, 5364(1989) 6. T. P. Rakitzis, P. C. Samartzis, and T. N. Kitsopoulos, Phys. Rev. Lett. 87, 123001 (2001) 7. Y. Mo, H. Katayanagi, M. C. Heaven, and T. Suzuki, Phys. Rev. Lett. 77, 830 (1996) 8. T. Suzuki, H. Katayanagi, S. Nanbu, and T. Suzuki, J. Chem.Phys. 109, 5778 (1998) 9. I. Kopp, Can. J. Phys. 45, 4001(1967) 10. B. Yang, Yu-hui Chiu, Hunghsin Fu, and S. L. Anderson, J. Chem. Phys. 95, 3275, (1991) 11. B. Yang, Yu-hui Chiu, and S. L. Anderson, J. Chem. Phys. 94, 6459(1991) 12. R. Weinkauf and U. Boesl, J. Chem. Phys. 101, 8482(1994) 13. Ch. Cha, R. Weinkauf, and U.Boesl, J. Chem. Phys. 103, 5224(1995) 14. R. Weinkauf and U. Boesl, J. Chem. Phys. 98, 4459 (1993) 15. J. Ph. Berger, J. Baker, and S. Couris, J. Chem. Phys. 105, 6147(1996) 16. R. A. Morgan, M. A. Baldwin, D. Ascenz, A. J. Orr-Ewing, M. N. R. Ashfold, W. J. Buma, J. B. Milan, C. R. Scheper, and C. A. de. Lange, Int. J. Mass. Spec. and Ion process. 159, 1(1996) 17. R. A. Morgan, A, J, Orr-Ewing, D. Ascenzi, M. N. R. Ashfold, W. J. Buma, C. R. Scheper, and C. A. de Lange, J. Chem. Phys. 105, 2141(1996) 18. M. Ochsner, M. Tsuji, and J. P. Maier, Chem. Phys. Lett. 115, 373(1985) 19. R. Kakoschke, U. Boesl, J. Hermann, and E. W. Schlag, Chem. Phys. Lett. 119, 467(1985) 20. W. Chen, M. Hochlaf, P. Rosmus, G. Z. He and C. Y. Ng, J. Chem. Phys. 116, 5612(2002) 21. S. Stimson, M. Evans, C. Y. Ng, C. -W. Hsu, P. Heimann, C. Destandau, G. Chambaud, and P. Rosmus, J. Chem. Phys. 108, 6205(1998) 22. M. Sommavilla and F. Merkt, J. Phys. Chem. A 108, 9970(2004) 23. M. J. Hubin-Franskin, J. Delwiche, P. M. Guyon, M. Richard-Viard, M. Lavollée, O. Dutuit, J. M. Robbe, and J. P. Flament, Chem. Phys. 209, 143(1996) 24. S, Morse, M. Takahashi, J.H. D. Eland, and L. Karlsson, Int. J. Mass Spectrom. 184, 67(1999) 25. W. H. Press, B. P. Flannery, S. A. Teukolsky, and W. T. Vettering, Numerical Recipes in Fortran, 2nd ed.(Cambridge University Press, Cambridge, 1987). 26. Herzterg, G. Molecular Spectra and Molecular Structure III; Van Norstrand., Inc. Holland 1966 27. D. M. Hirst, Mol. Phys. 104, 55(2006) 28. G. E. Hall, N. Sivakumar, D. Chawla, P. L. Houston and I. Burak, J. Chem. Phys. 88, 3682(1988) 29. G. E. Busch and K. R. Wilson, J. Chem. Phys. 56, 3638(1972) chapter 4 1. D. G. Hopper, J. Am. Chem. Soc. 100, 1019(1978) 2. G. Chambaud, H. Gritli, P. Rosmus, H. J. Werner, and P. J. Knowles, Mol. Phys. 98, 1793(2000) 3. X. Li, Y.-H. Huang, G. D. Flesch, and C. Y. Ng, J. Chem. Phys. 106, 1373(1997) 4. J. H. Callomon and F. Creutzberg, Philos. Trans. R. Soc. London, A. 277, 157(1974) 5. J. F. M. Aarts and J. H. Callomon, Chem. Phys. Lett. 91, 419(1982) 6. J. F. M. Aarts and J. H. Callomon, Mol. Phys. 62, 637(1987) 7. M. Larzilliere and Ch. Jungen, Mol. Phys. 67, 807(1989) 8. S. Abed, M. Broyer, M. Carre, M. L. Gaillard, and M. Larzilliere, Phys. Rev. Lett. 49, 120(1982) 9. S. Abed, M. Broyer, M. Carre, M. L. Gaillard, and M. Larzilliere, Chem. Phys. 74, 97(1983) 10. M. Larzilliere, S. Abed, M. Carre, M. L. Garillard, J. Lerme, and M. Broyer, Chem. Phys. Lett, 119, 55(1985) 11. M. Larzilliere, K. Gragued, J. Lerme, and J. B. Koffend, Chem. Phys. Lett. 134, 467(1982) 12. H. Gritli, Z. B. Lakhdar, G. Chambaud, and P. Rosmus, Chem. Phys. 178, 223 (1993) 13. C. E. Fellows and M. Vervlot, Chem. Phys. 264, 203(2001) 14. W. Chen, J. Liu, and C. Y. Ng, J. Phys. Chem. A 107, 8086(2003) 15. H. Xu, Y. Guo, Q. Li, S. Lin, and X. Ma, J. Chem. Phys. 119, 11609 (2003) 16. D. Klapstein and J. P. Maier, Chem. Phys. Lett. 83, 590(1981) 17. J. Lerme, S. Abed, R. A. Holt, M. Larzilliere, and M. Carre, Chem. Phys. Lett. 96, 403(1983) 18. J. Lerme, S. Abed, M. Larzilliere, R. A. Holt, and M. Carre, J. Chem. Phys. 84, 2167(1986) 19. M. Richard-Virad, O. Atabek, O.Dutuit, and P. M. Guyon, J. Chem. Phys. 93, 8881 (1990) 20. H. Xu, Y. Guo, Q. Li, Y. Shi, S. Liu, and X. Ma, J. Chem. Phys. 121, 3069(2004) 21. J. Berkowitz and J. H. D. Eland, J. Chem. Phys. 67, 2740(1977) 22. T. Baer, P.-M. Guyon, I. Nerrer, A. Tabache-Fouhalle, R.Botter, L.F. A. Ferreria, and T. G. Govers, J. Chem. Phys. 70, 1585 (1979) 23. M. G. Szarak and S. C. Wallace, J. Chem. Phys. 95, 2336(1991) 24. E. Patsilinakou, R. T. Wiedmann, C. Fotakis, and E. R. Grant, J. Chem. Phys. 91, 3916(1989) 25. P. F. Bernath, M. Dulick, R. W. Field, and J. L. Hardwick, J. Mol. Spectrosc. 86, 275(1981) 26. H. T. Liou and K. L. Huang, Chem. Phys. 246, 391(1999) 27. H. Lefebvre-Brion and R. W. Field, The Spectra and Dynamics of Diatomic Molecules, Elsevier. Academic Press, 2004 28. R. N. Zare, Angular Momentum, Wiley-Interscience, New York, 1988 29. J. M. Brown and A. Carrington, Rotational Spectroscopy of Diatomic Molecules, Cambridge Molecular Science, 2003. 30. SpecView: Simulation and Fitting Of Rotational Structure Of Electronic And Vibronic Bands. V.L. Stakhursky, T.A. Miller, 56th Molecular Spectroscopy Symposium. 31. G. Herzberg, Electronic Spectra and Electronic Structure of Polyatomic Molecules, Van Nostrand, Princeton, NJ, 1991. 32. A. G. Adam and J. R. D. Peers, J. Mol. Spectrosc. 181, 24(1997) 33. M. Barnes, A. J. Merer, and G. F. Metha, J. Chem. Phys. 103, 8360(1995) 34. V. Dribinski, A. Ossadtchi, V. A. Mandelshtam, and H. Reisler, Rev. Sci. Instrum. 73, 2634 (2004) 35. P. M. Dehmer, L. J. Dehmer, and W. A. Chupka, J. Chem. Phys. 73, 126(1980) 36. D. G. Hopper, Chem. Phys. Lett. 31, 446(1975) 37. D .G. Hopper, J. Chem. Phys. 72, 3679(1980) 38. D. G. Hopper, J. Chem. Phys. 76, 1068(1982) 39. A. R. Gregory, Chem. Phys. 90, 63(1984) 40. A. R. Gregory, K. K. Sunil, and K. D. Jordan, Chem. Phys. Lett. 108, 439(1984) | |
| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/33666 | - |
| dc.description.abstract | 利用時間切片之離子影像技術研究OCS+(B2S+)與N2O+(A2S+)分子之振動與轉動光譜及分子預解離之動態學。我們也測試CO與CH3I分子之光電子影像，得到相當高品質之影像資料。
在OCS+系統中，利用2+1 REMPI 光譜技術，藉由F1D等Rydberg能態游離OCS分子，再激發至B2S+(u1,u2,u3)以觸發其預解離過程。分析振動能階得到三個振動頻率(n1=1891.2，n2=503.3與n3=826.7 cm-1)與相關非簡諧常數。我們的實驗確認B2S+能態之預解離產物為S+(2Du)+CO，並非Hubin-Franskin所提出的 S+(4Su)+CO 解離途徑。實驗上，首次解析出來自B2S+(0,0,0)能態解離的產物CO是高轉動激發(J=51)。經由產物 S+(2Du) 的速度分佈，我們提出兩解離途徑。在低振動(0,0,0)與(0,1,0)能階，主要是經由非放光過程到基態，進行單分子光解，產物CO有相當大的比例是在轉動激發。當振動能量高於 0.1 eV，另一途徑是透過B2S+與A2P能態之位能面交錯而轉移至A2P(2A'/2A')的高振動激發態，再由2D位能面解離，產物S+(2Du)+CO佔有較多之平動能(30-40 %)與CO之振動激發。兩位能面交錯估計約位於0.06-0.1 eV，比理論計算的0.2 eV略低。 對N2O+(A2S+)系統，利用3+1 REMPI 光譜技術產生N2O+(X2P,0,0,0)，藉由A2S+-X2P躍遷過程研究其預解離動態學。我們取得N2O+與同位素分子14N15NO+之轉動解析光譜，且分析其轉動結構以得到相關之光譜常數。對N2O+與14N15NO+，我們利用Dunham模型描述分子的振動結構以得到分子的振動頻率。對N2O+，分別為n1= 1348.00、n2= 616.64與n3= 2454.01 cm-1。對14N15NO+，為n1= 1346.61、n2= 600.82 與n3= 2401.21 cm-1。 N2O+分子之解離產物主要為NO++N(4Su)與NO++N(2Du)。NO++N(4Su)解離途徑主要經由跨自旋過程(ISC)到b4P(24A')位能面，再經a4S-(14A')位能面解離產生NO++N(4Su)，產物NO+ 之振動內能幾乎為單一振動激發(n=3,4,5)。NO++N(2Du)解離途徑之產物NO+為雙轉動激發。藉由14N15NO+之研究確認，經由基態解離之產物NO+，其轉動內能是分佈在低轉動。透過2D能態解離之NO+則是分佈在高轉動激發，此訊號與NO++N(4Su)解離途徑呈現互相競爭，且與對稱振動模式有相依。透過同位素分子14N15NO+，首次釐清scrambling機制是發生在X2A'位能面，主要是解離成14NO++15N(2Du)。實驗上，觀察到對稱振動激發有助於scrambling機制的生成。 | zh_TW |
| dc.description.provenance | Made available in DSpace on 2021-06-13T05:44:21Z (GMT). No. of bitstreams: 1 ntu-95-D90223014-1.pdf: 10378409 bytes, checksum: b98c8884c13d562aabb5a7fb0a9b60a6 (MD5) Previous issue date: 2006 | en |
| dc.description.tableofcontents | 內 容
第一章 序論 1 參考文獻 9 第二章 離子影像技術與實驗系統 11 2.1 影像技術之進展 11 2.2 切片影像之概念 13 2.3 離子透鏡組 13 2.4 二維偵測器 15 2.5 切片效果與速度校正 16 2.6 影像分析 21 2.7 實驗裝置與雷射系統 22 2.8 參考文獻 24 第三章 OCS+在 態之振動光譜與預解離動態學研究 25 3.1 前言 25 3.2 實驗系統 29 3.3 實驗結果 29 3.3.1 OCS之REMPI光譜 29 3.3.2 OCS+之光解裂片光譜 30 3.3.3 S+離子切片影像 35 3.4 分析與討論 44 3.5 結論 52 3.6 參考文獻 54 第四章 N2O+與同位素14N15NO+在 態之光譜與預解離動態學研究 57 4.1 前言 57 4.2 實驗系統 60 4.3 實驗結果 61 4.3.1 N2O與14N15NO之2+1/3+1 REMPI光譜 61 4.3.2 N2O+與14N15NO+之光解裂片光譜 63 4.3.3 NO+(X1S+,u)+N(4Su/2Du)解離途徑之 NO+ 切片影像 83 4.3.4 N2(X ,u)+O+(4Su) 解離途徑之O+切片影像 90 4.4 解離機制之討論 92 4.4.1 能態之預解離途徑 96 4.4.2 產物NO 之內能分析 102 4.4.3 Scrambling機制之討論 106 4.4.4 N2O+( 2S+)®N2(X ,u)+O+(4Su) 110 4.5 結論 111 4.6 參考文獻 113 附錄 A N2O+之振轉能階指派之整理 116 附錄 B 14N15NO+之振轉能階指派之整理 128 第五章 結論 137 | |
| dc.language.iso | zh-TW | |
| dc.subject | 預解離動態學 | zh_TW |
| dc.subject | 離子影像技術 | zh_TW |
| dc.subject | 速度成像技術 | zh_TW |
| dc.subject | time sliced imaging | en |
| dc.subject | predissociation | en |
| dc.subject | velocity mapping ion imaging | en |
| dc.title | 分子離子態預解離動態學之速度成像研究 | zh_TW |
| dc.title | Imaging the predissociation dynamics of molecular ions | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 94-2 | |
| dc.description.degree | 博士 | |
| dc.contributor.oralexamcommittee | 林志民(Jim Jr-Min Lin),倪其焜(Chi-Kung Ni),曾文碧(Wen-Bih Tzeng),許艷珠(Yen-Chu Hsu) | |
| dc.subject.keyword | 離子影像技術,速度成像技術,預解離動態學, | zh_TW |
| dc.subject.keyword | velocity mapping ion imaging,time sliced imaging,predissociation, | en |
| dc.relation.page | 138 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2006-07-17 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 化學研究所 | zh_TW |
| 顯示於系所單位： | 化學系 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-95-1.pdf 未授權公開取用 | 10.14 MB | Adobe PDF |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。