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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 謝國煌 | |
dc.contributor.author | Tsung-Hsun Li | en |
dc.contributor.author | 李宗勳 | zh_TW |
dc.date.accessioned | 2021-06-13T04:51:13Z | - |
dc.date.available | 2006-07-27 | |
dc.date.copyright | 2006-07-27 | |
dc.date.issued | 2006 | |
dc.date.submitted | 2006-07-14 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/33625 | - |
dc.description.abstract | 本研究成功地合成出光可聚合性藍色染料,並將此染料與壓克力樹脂、光起始劑、平坦劑與溶劑均勻混合後,可製備出藍色染料之光阻劑。
利用染料B35(1,4-Bis(butylamino)anthraquinone)上的二級胺(-NH)官能基與GMA(Glycidyl methacrylate)上的環氧基(-Epoxy)進行反應,可得光聚合性藍色染料。利用二異氰酸異佛爾酮(IPDI) 的異氰酸基(-NCO)與羥乙基丙稀酸酯(HEA)的羥基先行反應形成帶有一當量的異氰酸基前置物後,再將其與Epoxy acrylate側鏈上的羥基(-OH)反應,形成具有四個官能基之壓克力樹脂。 光聚合性藍色染料、壓克力官能基樹脂、平坦劑、溶劑和光起始劑,可組成藍色染料光阻劑,以微影製程在不同的光罩下,可得不同的圖案。在本研究中藉由改變藍色染料光阻劑的配方、比例以及曝後烤溫度…等,可以完整地探討對於光阻劑曝光後薄膜膜的色彩度、耐熱性、抗溶劑性以及耐酸鹼性的影響。 | zh_TW |
dc.description.abstract | In this study, the design and synthesis of novel photo-resist dye and color-filter material has been completely investigated. At first, the secondary amine group (-NH) of the blue dye B35 was reacted with the epoxy group of GMA to form the UV-curable blue dye. In the second part, the isocynate group of IPDI was reacted with the hydroxyl group of epoxy acrylate resin to form a prepolymer. After that, a UV-curable resin contained four vinyl groups can be obtained by reacting the surplus isocynate group of above mentioned prepolymer with the hydroxyl group of HEA.
The novel dye photo-resist can be obtained by blending with the UV-curable blue dye, multi-functional UV-curable resin, leveling agent, solvent and photo-initiator. By undergoing the lithography technology and utilizing different mask, variety line widths and patterns can be designed and developed. The chemical and physical properties were thoroughly investigated and discussed by adjusting different parameter and the post-baking temperature. It was found that the properties including the appearance color, thermal stability and resistance to acid or base of the color filter material changed dramatically and depended on different parameters greatly. | en |
dc.description.provenance | Made available in DSpace on 2021-06-13T04:51:13Z (GMT). No. of bitstreams: 1 ntu-95-R93549024-1.pdf: 1305341 bytes, checksum: 204dbb6993f32de21d8092785addece7 (MD5) Previous issue date: 2006 | en |
dc.description.tableofcontents | 中文摘要…………………………………………………………………I
英文摘要 ………………………………………………………………II 目錄……………………………………………………………………Ⅲ 表目錄…………………………………………………………………Ⅵ 圖目錄 …………………………………………………………………Ⅶ 第一章 緒論 ……………………………………………………………1 第二章 文獻回顧 ………………………………………………………3 2-1彩色濾光片原理……………………………………………3 2-2 染料改質…………………...…………………………………8 2-3 紫外光硬化(UV curable)簡介……………………………12 2-4 紫外光硬化樹脂之組成………………………………….…13 2-5 紫外光的作用及用途………………….……………………19 2-6 紫外光硬化反應機構…………………………………….…20 2-7 影響紫外光硬化之因素……………………………………23 2-8 紫外光硬化反應速率……………………………………..26 第三章 實驗方法………………………………………………………28 3-1實驗藥品……………………………………………………28 3-2 實驗儀器……………………………………………………35 3-3 實驗流程……………………………………………………38 3-3-1合成反應性染料流程圖………..………………………38 3-3-2 合成樹脂流程圖………………………………………39 3-3-3 光硬化膜流程圖………………………………………40 3-4 實驗步驟……………….……………………………………41 3-4-1合成反應性染料………………………………………41 3-4-2合成樹脂………………………………………………41 3-4-3 UV曝光……….……………………………………42 3-4-4 微影製程………………………………………………42 3-5 測試方法……………………………………………………43 3-5-1傅立葉紅外線光譜(FTIR)分析………………………43 3-5-2層析試驗………………………………..…………..…43 3-5-3凝膠滲透色層分析儀(GPC)分析……………………44 3-5-4 NMR分析……………………………….…………..…44 3-5-5 耐溶、耐酸、耐鹼性測試………………………………44 3-5-6 OM分析……………………….…………….…………44 3-5-7 TGA分析………………………….…………….……..45 3-5-8 DSC分析……………………………………………….45 第四章 結果討論………………………………………………………46 4-1 使用染料B35和GMA合成反應性染料…………………46 4-1-1染料B35和GMA的合成反應…………………………46 4-1-2 利用FTIR觀察反應情形……………..………………46 4-1-3 反應產物層析試驗……………………………………47 4-1-4 NMR分析……………………………………………...48 4-1-5 GPC分析……………………………….………………49 4-1-6 TGA分析………………………………………………49 4-1-7 UV分析………………………………………………...50 4-1-8 反應性染料之產率……………………………………50 4-2 使用Epoxy acrylate和IPDI和HEA合成樹脂……………51 4-2-1 Epoxy acrylate和IPDI和HEA合成樹脂………………51 4-2-2利用FTIR觀察其反應情形……………………………52 4-2-3 NMR分析……………………………………………...52 4-3含反應性染料光阻劑在光硬化成膜後的性質討論………..53 4-3-1 不同種類的oligomer對成膜性質的影響……….……53 4-3-2 測試各產物單純成膜的性質…………………………55 4-3-3 使用不同種類的光起始劑對成膜性質的影響………57 4-3-4 增加光起始劑的含量…………………………………58 4-3-5 不同曝光能量的比較…………………………………59 4-3-6 增加Doublemer 88對膜性質產生的影響……………61 4-3-7 改變不同溶劑對膜性質產生的影響…………………62 4-3-8 增加Solvent含量對成膜產生的影響………………...63 4-3-9 增加反應性染料的含量對成膜產生的影響…………64 4-3-10 改變不同曝後烤溫度對成膜性質產生的影響……..66 4-3-11 反應性染料光硬化膜微影實驗……………………..67 4-3-12 TGA分析……………………………………………68 4-3-13 DSC分析……………………………………………...69 4-3-14 UV分析…………………………………………….…69 第五章 結論……………………………………………………………70 第六章 參考文獻………………………………………………………73 | |
dc.language.iso | zh-TW | |
dc.title | 彩色濾光片之反應性藍色染料開發與研究 | zh_TW |
dc.title | Research and development of modified reactive blue dye for color filter | en |
dc.type | Thesis | |
dc.date.schoolyear | 94-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 韓錦鈴,邱文英,鄺東元 | |
dc.subject.keyword | 環氧基,異氰酸基,紫外光硬化, | zh_TW |
dc.subject.keyword | Epoxy,Isocyanate,UV curing, | en |
dc.relation.page | 110 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2006-07-17 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
顯示於系所單位: | 高分子科學與工程學研究所 |
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