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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 林嘉明(Jia-Ming Lin) | |
dc.contributor.author | Zong-Yi Yang | en |
dc.contributor.author | 楊宗逸 | zh_TW |
dc.date.accessioned | 2021-06-13T04:20:38Z | - |
dc.date.available | 2006-07-31 | |
dc.date.copyright | 2006-07-31 | |
dc.date.issued | 2006 | |
dc.date.submitted | 2006-07-23 | |
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dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/32973 | - |
dc.description.abstract | 二甲基硫(dimethyl sulfide, DMS)和二甲基二硫(dimethyl disulfide, DMDS)是具有臭味的揮發性硫化物,主要源自含硫有機物質厭氧分解。高濃度會刺激呼吸道、眼睛和皮膚,大量暴露可能導致意識喪失,並且為易燃性物質,曾為局限空間工作者致死之有毒氣體之一,因此倍受關心。本研究採用固相微萃取裝置(solid phase microextraction, SPME)搭配可攜式氣相層析儀,對於二甲基硫(dimethyl sulfide, DMS)和二甲基二硫(dimethyl disulfide, DMDS)進行採樣與分析之研究,以方便緊急時進行現場快速偵測。本研究使用Tedlar bag製備DMS和DMDS參考氣體,將袋中硫化物參考氣體濃度控制為三個等級(level),氣體相對濕度控制為六個等級,每個試驗進行三重複。選用纖維材質為75μm CarboxenTM-PDMS fiber,配合SPME裝置,進行裸露方式的採樣,採樣後之SPME纖維瞬即插入可攜式氣相層析儀之管柱(MXT-1)熱脫附分析,同時以檢知管法進行方法的比較。結果顯示兩種硫化物的採樣和分析可以在12分鐘內完成;裹覆厚度為75μm的CarboxenTM-PDMS fiber對於DMS的最大附載質量為27.57ng,而對DMDS的最大附載質量為5.12ng。當氣體相對濕度超過43.6%,採集質量會有較明顯的下降,而且相對濕度和硫化物濃度彼此也有交互作用。檢知管檢測DMS之準確度為1.5%∼133.9%,精密度為4.0%∼19.3%;而SPME/Portable GC/FPD檢測DMS之準確度則為1.8%∼52.2%,精密度為0.3%∼2.1%。 | zh_TW |
dc.description.provenance | Made available in DSpace on 2021-06-13T04:20:38Z (GMT). No. of bitstreams: 1 ntu-95-R93844012-1.pdf: 739015 bytes, checksum: 937b2d20feda56befda87c5c76278ecb (MD5) Previous issue date: 2006 | en |
dc.description.tableofcontents | 摘要 Ⅰ
Abstract Ⅱ 致謝 Ⅲ 目錄 Ⅳ 表目錄 Ⅶ 圖目錄 Ⅷ 第一章 緒論 1 1-1 前言 1 1-2 研究目的 2 1-3 研究架構 3 第二章 文獻探討 4 2-1 局限空間介紹 4 2-2 局限空間的危害 4 2-3 局限空間作業危害預防 7 2-4 硫化物介紹及其毒性資料 7 2-5 空氣中硫化物採樣分析方法 11 2-6 固相微萃取技術 16 2-7 可攜式氣相層析儀 22 2-8 固相微萃取技術與可攜式氣相層析儀的結合 24 2-9 火焰光度偵檢器與硫化物的檢測 25 2-10 實驗設計法 25 第三章 材料與方法 27 3-1 儀器設備與試藥 27 3-1-1 儀器設備與材料 27 3-1-2 試劑耗材 29 3-2 標準溶液的製備 29 3-3 檢量線的製作 30 3-4 樣品穩定性測試 31 3-5 參考氣體產生系統 31 3-5-1 稀釋空氣淨化裝置 32 3-5-2 稀釋空氣流量率控制裝置 32 3-5-3 濕度控制與量測 32 3-5-4 硫化物氣體濃度之控制 33 3-6 參考氣體產生系統驗證 34 3-6-1 浮子流量計之校準 34 3-6-2 相對濕度控制之驗證 34 3-7 SPME採樣分析硫化物之驗證 35 3-8 熱脫附效率測試 36 3-9 SPME採樣時間測試 36 3-10 不同硫化物濃度不同相對濕度下檢知管的採樣 37 第四章 結果 38 4-1 分析之品管 38 4-1-1 GC對硫化物的定性 38 4-1-2 DMS和DMDS檢量線 38 4-1-3 樣品穩定性測試 38 4-2 參考氣體產生系統品管 39 4-2-1 氣體流量率控制 39 4-2-2 相對濕度之控制 39 4-3 SPME採樣分析硫化物之驗證 39 4-3-1 熱脫附條件測試 39 4-3-2 SPME採樣時間測試 40 4-4 各控制變項對於SPME採樣表現的影響 41 4-5 各控制變項對於檢知管採樣表現的影響 42 第五章 討論和建議 44 5-1 SPME對於參考氣體採樣的探討 44 5-2 檢知管對於參考氣體採樣的探討 50 參考文獻 54 表目錄 表2-1 DMS的物理化學基本特性 60 表2-2 DMDS的物理化學基本特性 60 表2-3 現今空氣中DMS和DMDS分析方法整理 61 表2-4 現今SPME採樣分析DMS與DMDS之研究整理 62 表2-5 不同纖維材質的種類 64 表4-1 SPME採集DMS與DMDS熱脫附效率測試結果 64 表4-2 SPME對DMS之採集量與採樣時間的關係 65 表4-3 SPME對DMDS之採集量與採樣時間的關係 66 表4-4 SPME採集DMS質量與DMS濃度及相對濕度的關係 67 表4-5 DMS濃度和相對濕度影響SPME對DMS採集質量變異數分析 (Two way ANOVA)結果 68 表4-6 SPME採集DMDS質量與DMDS濃度及相對濕度的關係 69 表4-7 DMDS濃度和相對濕度影響SPME對DMDS採集質量變異數分析 (Two way ANOVA)結果 70 表4-8 不同DMS濃度不同相對濕度下檢知管的採樣分析結果 71 表4-9 SPME採集DMS採樣率與DMS濃度及相對濕度的關係 72 表4-10 不同DMS濃度不同相對濕度下SPME/GC的採樣分析結果 73 圖目錄 圖2-1 風箱式檢知器 75 圖2-2 膠球式檢知器 75 圖2-3 活塞式檢知器 75 圖2-4 單層式檢知管 76 圖2-5 多層式檢知管 76 圖2-6 雙生式檢知管 76 圖2-7 現今水中與空氣中揮發性硫化物之採樣分析流程 77 圖2-8 固相微萃取裝置 78 圖2-9 SPME纖維裸露採樣示意圖 78 圖3-1 參考氣體產生系統 79 圖3-2 氣體濕度與溫度量測控制系統 79 圖4-1 二甲基硫(DMS)在GC/FPD上的分析圖譜 80 圖4-2 二甲基二硫(DMDS)在GC/FPD上的分析圖譜 80 圖4-3 二甲基硫(DMS)之檢量線 81 圖4-4 二甲基二硫(DMDS)之檢量線 81 圖4-5 二甲基硫(DMS)樣品穩定性測試 82 圖4-6 二甲基二硫(DMDS)樣品穩定性測試 82 圖4-7 浮子流量計(FJS-110319-F, Taiwan)流量率之檢量線 83 圖4-8 注水量與袋中相對濕度的關係 83 圖4-9 用SPME (75μm CarboxenTM-PDMS fiber)採DMS之採集量 與採樣時間的關係 84 圖4-10 用SPME(75μm CarboxenTM-PDMS fiber)採DMDS之採集量 與採樣時間的關係 84 圖4-11 用SPME(75μm CarboxenTM-PDMS fiber)採DMS之採集量 與相對濕度及DMS濃度的關係 85 圖4-12 用SPME(75μm CarboxenTM-PDMS fiber)採DMDS之採集量 與相對濕度及DMDS濃度的關係 85 圖4-13 不同DMS濃度不同相對濕度下檢知管的採樣結果 86 圖4-14 不同DMS濃度不同相對濕度下SPME的採樣結果 86 圖4-15 SPME/GC檢出濃度與檢知管讀出濃度的關係 87 | |
dc.language.iso | zh-TW | |
dc.title | 以固相微萃取法結合可攜式氣相層析儀偵測二甲基硫和二甲基二硫之應用研究 | zh_TW |
dc.title | Determination of Dimethyl Sulfide and Dimethyl Disulfide by Solid Phase Microextraction Incorporated with Portable Gas Chromatograph | en |
dc.type | Thesis | |
dc.date.schoolyear | 94-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 蔡詩偉(Shih-Wei Tsai),洪益夫(I-Fu Hung) | |
dc.subject.keyword | 二甲基硫(dimethyl sulfide, DMS),二甲基二硫(dimethyl disulfide, DMDS),固相微萃取,CarboxenTM-PDMS fiber,可攜式氣相層析儀, | zh_TW |
dc.subject.keyword | dimethyl sulfide (DMS),dimethyl disulfide (DMDS),solid phase microextraction,CarboxenTM-PDMS fiber,portable gas chromatograph, | en |
dc.relation.page | 87 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2006-07-24 | |
dc.contributor.author-college | 公共衛生學院 | zh_TW |
dc.contributor.author-dept | 環境衛生研究所 | zh_TW |
顯示於系所單位: | 環境衛生研究所 |
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