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http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/32782完整後設資料紀錄
| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 林金福 | |
| dc.contributor.author | Chi-Wei Tu | en |
| dc.contributor.author | 杜其瑋 | zh_TW |
| dc.date.accessioned | 2021-06-13T04:15:28Z | - |
| dc.date.available | 2008-07-27 | |
| dc.date.copyright | 2006-07-27 | |
| dc.date.issued | 2006 | |
| dc.date.submitted | 2006-07-24 | |
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/32782 | - |
| dc.description.abstract | 本研究的目的主要是探討膠態電解質系統(Polymer/ACN/LiI/ I2/TBP) 對於染料敏化二氧化鈦太陽能電池效能的影響。藉由使用不同的高分子與高分子–蒙脫石複合材料之膠態電解質系統，來尋找能夠維持液態元件的高光電轉化效率，且能改善液態元件的封裝問題之最適合材料。
經由量測膠態電解質的導電度，以及對膠態系統元件作交流阻抗分析，可得知離子在電解質中的導電效果以及元件中的阻抗分布。測量的結果為PMA電解質系統 (PMA/ ACN/ LiI/ I2/ TBP) 有較高的導電度與較好的離子擴散速率，而PNIPAAm電解質系統 (PNIPAAm/ ACN/ LiI/ I2/ TBP )的導電度最差，離子擴散速率也不佳。但加了蒙脫石之後，PMA電解質系統的導電度及離子擴散速率皆下降，但PNIPAAm電解質系統卻上升了不少。而對於PVAc電解質系統 (PVAc/ ACN/ LiI/ I2/ TBP) 而言，加了蒙脫石之後導電度及離子擴散速率並無明顯的變動。 以元件的表現來看，液態乙腈電解質系統在入射光能量為100mW/cm2的光電轉換效率可達8.69%，電流值也可高達5.27mA。而膠態電解質系統中，以PMA電解質系統的表現最好，有高達7.17%的光電轉換效率。而PVAc與PNIPAAm系統則分別為5.62%與3.17%。加了蒙脫石的三個系統中，光電表現非常接近。PMA電解質系統的各項數據皆有些許的下降，但還是有5.84%的高效率。而PNIPAAm電解質系統在加了蒙脫石之後，效率大幅提升原來效率的70%。而PVAc電解質系統在加了蒙脫石之後，各項數據只有些微的下降，前後差異並不大，分別為5.62%與5.12%。 | zh_TW |
| dc.description.abstract | The objective of the research is to study the effects of the gel-type electrolyte systems (polymer/ACN/LiI/I2/ TBP) on the performance of dye-sensitized titanium oxide solar cells. By using different polymer and polymer-MMT nanocomposite electrolyte systems, we intended to find suitable materials for high performance and good sealing properties of the solar cell devices.
The performance of electrolyte for gel-type devices could be estimated by measuring conductivity and using EIS (Electrochemical Impedance Spectroscopy). The results was that the PMA electrolyte system (PMA/ACN/ LiI/I2/TBP) had higher conductivity and ionic diffusion rate. The PNIPAAm electrolyte system (PNIPAAm/ACN/LiI/ I2/TBP) had lowest conductivity and ionic diffusion rate. Addition of the montmorillonite (MMT) to gel-type electrolyte system, the conductivity and ionic diffusion rate of the PMA electrolyte system decreased, but the PNIPAAm electrolyte system increased. For the PVAc (PVAc/ACN/LiI/ I2/TBP) electrolyte system, the conductivity and ionic diffusion rate were not siginificantly changed with the addition of the MMT to the system. For the performance of the devices, the photon-to-electron power conversion efficiency of liquid ACN electrolyte system (ACN/LiI/I2/TBP) was 8.69% and the current was 5.27mA at an incident light intensity of 100mW/cm2. For gel-type electrolyte system, the PMA electrolyte system had best performance and its efficiency could reach as 7.17%. The efficiencies of PVAc and PNIPAAm system were 5.62% and 3.17%, respectively. For three systems with the MMT, the performances were very close. Although the data of PMA electrolyte system decreased after adding the MMT to the system, it still had high efficiency as 5.84%. The efficiency of the PNIPAAm system increased 70% after adding the MMT to the system. The PVAc and PVAc+MMT electrolyte systems with the efficiencies of 5.62% and 5.12%, respectively, were almost the same. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-13T04:15:28Z (GMT). No. of bitstreams: 1 ntu-95-R93549014-1.pdf: 4672926 bytes, checksum: afa9d31025846b479ccc4ea4f9f674de (MD5) Previous issue date: 2006 | en |
| dc.description.tableofcontents | 中文摘要…………………………………………………………………I
英文摘要………………………………………………………………III 目錄………………………………………………………………………V 圖目錄………………………………………………………………VIII 表目錄…………………………………………………………………XVI 第一章 緒論……………………………………………………………1 1-1 前言…………………………………………………………………1 1-2 太陽能電池簡介……………………………………………………4 1-2-1 半導體簡介…………………………………………………8 1-2-2 太陽能電池的工作原理…………………………………15 1-2-3 有機太陽能電池簡介……………………………………19 1-2-3-1 施受體型太陽能電池…………………………19 1-2-3-2 染料敏化太陽能電池…………………………26 1-3 交流阻抗分析原理………………………………………………30 1-4 電導值計算原理…………………………………………………37 1-5 文獻回顧…………………………………………………………39 1-5-1 染料敏化太陽能電池……………………………………39 1-5-2 固態染料敏化太陽能電池………………………………46 1-5-2-1 膠態高分子電解質……………………………48 1-5-3 蒙脫石……………………………………………………50 1-5-3-1 高分子/蒙脫石奈米複合物…………………52 1-6 研究動機與實驗架構……………………………………………55 第二章 實驗設備與方法………………………………………………57 2-1 儀器設備…………………………………………………………57 2-1-1 高溫爐……………………………………………………57 2-1-2 濺鍍儀……………………………………………………57 2-1-3 場發射鎗掃瞄式電子顯微鏡……………………………57 2-1-4 X光繞射分析儀……………………………………………57 2-1-5 光電測試與交流阻抗分析設備…………………………58 2-1-6 高壓釜……………………………………………………58 2-1-7 凝膠滲透層析儀…………………………………………58 2-1-8 電導度計…………………………………………………59 2-1-9 恆溫水槽…………………………………………………59 2-1-10 黏度計 …………………………………………………59 2-2 薄膜電極製備……………………………………………………60 2-2-1 二氧化鈦薄膜電極之製備………………………………60 2-2-2 白金電極之製備…………………………………………62 2-3 薄膜電極性質量測………………………………………………63 2-3-1 二氧化鈦薄膜電極X光繞射分析…………………………63 2-3-2 薄膜電極SEM表面分析……………………………………63 2-4電解質之製備………………………………………………………64 2-4-1 液態電解質之製備………………………………………64 2-4-2 膠態電解質之製備………………………………………64 2-4-2-1 高分子與高分子–蒙脫石複合材料之合成方法與 分子量分析……………………………………64 2-4-2-2 膠態電解質配製………………………………67 2-5 元件組裝…………………………………………………………70 2-6 太陽能電池光電化學測試………………………………………71 2-6-1實驗裝置……………………………………………………71 2-6-2 光電流–電壓特徵曲線…………………………………71 2-6-3 電解質導電度之量測……………………………………73 2-6-4 交流阻抗分析……………………………………………73 2-6-5 入射光子–電流轉換效率之量測………………………73 第三章 結果與討論……………………………………………………74 3-1 薄膜電極分析……………………………………………………74 3-1-1 X光繞射分析………………………………………………74 3-1-2 SEM表面分析………………………………………………78 3-2膠態高分子電解質導電度與黏度量測……………………………80 3-3交流阻抗分析染料敏化太陽能電池………………………………90 3-3-1 液態乙腈電解質系統…………………………………………90 3-3-2 膠態高分子電解質系統…………………………………92 3-4太陽能電池光電轉換效率之探討……………………………105 3-4-1 液態乙腈電解質系統……………………………………105 3-4-2 膠態高分子電解質系統…………………………………107 3-5 入射光子–電流轉換效率………………………………………118 3-6 長期穩定性測試…………………………………………………128 第四章 結論…………………………………………………………143 第五章 參考資料……………………………………………………145 | |
| dc.language.iso | zh-TW | |
| dc.title | 高分子及其蒙脫石奈米複合材料在膠態光敏型太陽能電池上的應用 | zh_TW |
| dc.title | Application of Polymers and Their Exfoliated MMT Nanocomposites on Gel-type Dye-sensitized Solar Cells | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 94-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 何國川,王立義 | |
| dc.subject.keyword | 染料敏化太陽能電池,高分子–蒙托石複合材料,膠態電解質系統,PMA,PVAc,PNIPAAm, | zh_TW |
| dc.subject.keyword | dye-sensitized solar cells,polymer-MMT composite,gel-type electrolyte system,PMA,PVAc,PNIPAAm, | en |
| dc.relation.page | 154 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2006-07-25 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 高分子科學與工程學研究所 | zh_TW |
| 顯示於系所單位： | 高分子科學與工程學研究所 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-95-1.pdf 目前未授權公開取用 | 4.56 MB | Adobe PDF |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。