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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 王珮玲 | |
| dc.contributor.author | Jia-Jing Wu | en |
| dc.contributor.author | 巫佳靜 | zh_TW |
| dc.date.accessioned | 2021-06-13T03:24:09Z | - |
| dc.date.available | 2007-07-31 | |
| dc.date.copyright | 2006-07-31 | |
| dc.date.issued | 2006 | |
| dc.date.submitted | 2006-07-27 | |
| dc.identifier.citation | 中文部分：
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/31909 | - |
| dc.description.abstract | 斷層活動和剪動帶形成的裂隙、裂面，被視為地殼中流體流動的主要通道，當環境條件適當時，原本充填流體的裂隙，開始沉澱結晶出適合生長的礦物而形成礦脈。礦脈帶有流體的同位素訊號，能反應生長條件，因此分析礦脈的同位素組成能瞭解流體的來源與破裂帶的特性。台灣地處活動造山帶，構造活動和礦脈的生成關係密不可分，本研究分析西部麓山帶地層中礦脈之碳氧同位素組成與地層變化和斷層活動間的關係，推測可能的碳源與流體來源，探討構造活動、流體作用與礦脈生長間的關係。
車籠埔斷層鑽井之A井岩心中出現的方解石脈、斷層擦痕充填物、生物碎屑及孔隙膠結物的碳氧同位素成分分析結果如下：方解石脈的 δ13CVPDB 值為 -14‰ 至 -2‰，δ18OVSMOW 值為 10‰ 至 24‰，斷層擦痕充填物的 δ13CVPDB 值為-10‰ 至 -2‰，δ18OVSMOW 值為14‰ 至 20‰，生物碎屑的 δ13CVPDB 值為 -10.0‰ 至 2‰，δ18OVSMOW值為12‰ 至 30‰，孔隙膠結物的 δ13CVPDB 值為 -11‰ 至 -3‰，δ18OVSMOW 值為16‰ 至 20‰。 比對礦脈之碳同位素組成隨深度的變化及岩心構造資料，推測影響碳酸鹽礦脈碳同位素組成的因素，可能與斷層構造活動及沉積岩層的改變有關。在岩心深度 400 至 1290 公尺出現的礦脈，碳同位素組成隨深度增加由 -10‰ 變重至 -2‰ ，顯示地下水中溶解的無機碳和海水碳酸鹽類為主要碳源的混合端成分。深度介於 1290 至 1710 公尺之礦脈的碳同位素組成，隨深度增加而由 -2‰ 變輕至 -12‰ ，由於此深度的岩心位於車籠埔斷層之下，所在地層由錦水頁岩轉變為桂竹林層，因此推論碳源的轉變應與斷層活動或岩層變化有關，而碳源的變化均受控於微生物作用。由礦脈氧同位素組成估算的流體氧同位素成分，其值隨著深度加深而變大，由 -14‰ 變重至 -4‰ ，推測流體的來源應為天水與海水或地層水之混合。 | zh_TW |
| dc.description.abstract | Faults and shear zones are generally thought to be major fluid conduits in crustal environment. Fluid circulation and migration may deposit or recrystallize carbonate minerals in fractures within the fault zone. Isotopic signatures of such crack-fill materials will serve as a good indicator of both sources of fluid and processes of fluid-rock interaction.
This study analyzed carbon and oxygen isotopic compositions of calcite veins, fillings of slickensides, cementations and fossils retrieved by Taiwan Chelungpu Drilling Program (TCDP) Hole-A Drill cores. The core penetrated the active Chelungpu fault zone at around 1100 m depth and was composed of the Cholan, Chinshui and Keichulin formation. The calcite veins mainly appeared in sandstone and siltstone with several mm in width. Calcite veins revealed variable δ18OVSMOW values ranging from 10 to 20‰, and δ13CVPDB values of -13 to -2‰. Filling of slickensides shown δ18OVSMOW values from 14 to 20‰ and δ13CVPDB values from -10 to -2‰. The δ18O VSMOW and δ13CVPDB values of cementation were between 16 to 20‰ and -11 to -3‰, respectively, and the valves for fossils varied from 12 to 30‰ in δ18O VSMOW values and -10 to 2‰ in δ13CVPDB values. The δ13CVPDB values of calcite veins and cementations generally increased with depth between 400 to 1290 m, then decreased with depth below 1290 m. A mixture of dissolved inorganic carbon in groundwater and marine carbonate was suggested to be the carbon sources for these carbonate precipitation from 400-1290 m interval. The carbon isotopic compositions of calcite veins from 1290-1710 m interval might be controlled by the fault events or the hosted formations. The composition reflected the microbial processes involved during fault activity or strata deposition. Calculated δ18O values of fluids in chemical equilibrium with calcite veins were ranging from -14 to -4‰, which were in between that of meteoric water and seawater. These results inferred that the calcite veins were formed from fluids originating from meteoric water mixed with seawater or formation water and carrying bicarbonate dissolved from fossil or diagenetic carbonate. | en |
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| dc.description.tableofcontents | 致謝 I
中文摘要 II 英文摘要 Ⅲ 目錄 IV 圖目錄 Ⅵ 表目錄 Ⅶ 附表目錄 Ⅷ 第一章：緒論 1 1.1前言 1 1.2研究動機 1 1.3研究目的 5 1.4地質背景 6 1.4.1 地層特徵 6 1.5相關前人研究 10 1.5.1台灣碳酸鹽類礦物之碳氧同位素研究 10 1.5.2沉積成岩作用之自生碳酸鹽類碳氧同位素組成 13 1.5.3構造活動帶中碳酸鹽礦脈之碳氧同位素研究 14 第二章：碳氧穩定同位素原理與應用 18 2.1 同位素基本原理 18 2.1.1 同位素之定義 18 2.1.2 同位素的種類 18 2.1.3 穩定同位素比值表示方法 18 2.1.4 穩定同位素分化 19 2.1.5 穩定同位素的標準品 21 2.2 碳氧同位素分析原理 22 2.3 碳氧穩定同位素組成在各儲庫的變化 22 第三章：研究方法 28 3.1 研究材料 28 3.1.1 岩心槪述 28 3.1.2 岩心構造特徵 28 3.1.3 樣品蒐集及分類 30 3.2 碳氧同位素分析 32 3.2.1 同位素分析前處理 32 3.2.2 碳氧同位素分析方法 32 3.3 碳酸鹽類礦物組成之X光繞射分析 35 第四章：分析結果 36 4.1 氧同位素分析結果 36 4.2 碳同位素分析結果 36 4.3 碳酸鹽類礦物組成之X光繞射分析結果 39 第五章：討論 40 5.1 碳酸鹽類礦物種類對碳氧同位素分析之影響 40 5.2 碳酸鹽礦脈之碳氧同位素組成變化原因探討 41 5.2.1 斷層活動與方解石脈出現頻率的影響 42 5.2.2 礦脈厚度變化的影響 44 5.2.3 破裂面種類的影響 46 5.2.4 沉積岩層變化的影響 46 5.3 碳酸鹽礦脈之碳氧同位素組成意義 48 5.3.1 碳酸鹽礦脈之無機碳來源 51 5.3.1.1 深度400公尺到1290公尺岩心礦脈之碳源 53 5.3.1.2 深度1290公尺到1710公尺岩心礦脈之碳源 53 5.3.2 碳酸鹽礦脈形成時之流體組成與來源 58 第六章：結論 66 參考文獻 67 圖目錄 圖1-1 台灣地質分區圖 3 圖1-2 車籠埔斷層鑽井區域之地質剖面圖 4 圖1-3 台灣中部地區之地質構造圖 7 圖1-4 海洋沉積盆地中自生碳酸鹽類礦物之碳氧同位素組成典型模式 12 圖1-5 斷層唧水模式 16 圖2-1 自然界中主要碳儲庫的碳同位素組成變化 24 圖2-2 自然界中各種岩石、流體與大氣中氧氣之氧同位素組成變化 27 圖3-1 岩心深度約1100公尺-車籠埔斷層破裂帶之岩心照片 29 圖3-2 碳酸鹽類礦物之分類與產狀 31 圖4-1 氧同位素成分隨深度變化圖 37 圖4-2 碳同位素成分隨深度變化圖 38 圖5-1 方解石脈隨深度的出現頻率變化圖 43 圖5-2 方解石脈及斷層擦痕充填物之厚度與其碳氧同位素組成關係圖 45 圖5-3 方解石脈及斷層擦痕充填物之碳氧同位素組成與其所在破裂面種類的關係圖 47 圖5-4 方解石脈及斷層擦痕充填物之碳氧同位素組成關係圖 49 圖5-5 不同深度範圍方解石脈及斷層擦痕充填物之碳氧同位素組成關係圖 50 圖5-6 方解石脈、斷層擦痕充填物及孔隙膠結物與自然界中主要碳儲庫的碳同位素組成之比較圖 52 圖5-7 各種生物殼體或骨骼之碳氧同位素組成與無機平衡條件下碳酸鈣之碳氧同位素組成差值 57 圖5-8 車籠埔斷層鑽井之 A 井井下深度900到1300公尺實測溫度資料 59 圖5-9 由方解石脈及斷層擦痕充填物之氧同位素組成所計算的流體氧同位素值隨深度變化圖 60 圖5-10 由方解石脈及斷層擦痕充填物之氧同位素組成所估算之流體氧同位素值與自然界流體氧同位素組成之比較 62 圖5-11 重新估算方解石脈氧同位素異常低值之平衡流體氧同位素組成隨深度變化圖 64 表目錄 表1-1 台灣西部麓山帶北部、中北部及中部地層比對表 9 表2-1 微生物作用分解有機物產生碳酸氫根之碳同位素組成 25 表3-1 標準樣品在不同質譜儀之碳氧同位素分析結果 34 表3-2 碳酸鹽類礦物之最強繞射角 35 表4-1 岩心中碳酸鹽類礦物之組成鑑定 39 表5-1 重新估算方解石脈氧同位素異常低值之平衡流體氧同位素組成結果 65 附表目錄 附表一 各種碳酸鈣樣品之碳氧同位素分析結果 72 附表二 與碳酸鈣礦脈平衡流體之氧同位素組成計算結果 79 | |
| dc.language.iso | zh-TW | |
| dc.subject | 碳氧同位素 | zh_TW |
| dc.subject | 車籠埔斷層鑽井 | zh_TW |
| dc.subject | 碳酸鹽類礦物 | zh_TW |
| dc.subject | TCDP | en |
| dc.subject | carbonate minerals | en |
| dc.subject | carbon and oxygen isotope | en |
| dc.title | 台灣車籠埔斷層鑽井A井岩心之碳酸鹽類礦物碳氧同位素研究 | zh_TW |
| dc.title | Oxygen and Carbon Isotopic Studies of Carbonate Minerals from TCDP Hole-A Drill Cores in Taiwan | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 94-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 林立虹,宋聖榮,俞震甫,陳于高 | |
| dc.subject.keyword | 車籠埔斷層鑽井,碳酸鹽類礦物,碳氧同位素, | zh_TW |
| dc.subject.keyword | TCDP,carbonate minerals,carbon and oxygen isotope, | en |
| dc.relation.page | 81 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2006-07-29 | |
| dc.contributor.author-college | 理學院 | zh_TW |
| dc.contributor.author-dept | 海洋研究所 | zh_TW |
| 顯示於系所單位： | 海洋研究所 | |
文件中的檔案：
| 檔案 | 大小 | 格式 | |
|---|---|---|---|
| ntu-95-1.pdf 未授權公開取用 | 2.46 MB | Adobe PDF |
系統中的文件，除了特別指名其著作權條款之外，均受到著作權保護，並且保留所有的權利。