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| DC 欄位 | 值 | 語言 |
|---|---|---|
| dc.contributor.advisor | 謝國煌(Kuo-Huang Hsieh) | |
| dc.contributor.author | Liang-Wei Chiang | en |
| dc.contributor.author | 江亮威 | zh_TW |
| dc.date.accessioned | 2021-06-13T03:14:41Z | - |
| dc.date.available | 2014-08-05 | |
| dc.date.copyright | 2011-08-05 | |
| dc.date.issued | 2011 | |
| dc.date.submitted | 2011-07-29 | |
| dc.identifier.citation | 1. WTRG Economics.
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| dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/31552 | - |
| dc.description.abstract | 本研旨在合成一系列之磺化聚醯亞胺/聚乙烯醇（SPI/PVAs）共混聚合物及磺化聚醯亞胺/聚乙烯醇半互穿型網狀（SIPN SPI/cPVA20-GAs）之質子交換膜。 其中SPI 的合成是使用高耐水解的1,4,5,8-萘四酸二酐（NTDA）為二酸酐、4,4’-二氨基二苯醚（ODA）為非磺化二胺單體與具有雙磺酸基之4,4-二（4-胺苯甲基）二苯（BAPBD）單體進行熱醯亞胺化；PVA 分別以5 phr、10 phr與20 phr 的比例混摻於SPI 中而製備出不同組成比例的共混聚合物；將SPI/PVA20 膜浸於30 ℃ 的1 vol% 的戊二醛（GA）水溶液（pH~1.4）中，使GA 對PVA 進行交聯反應，製備出不同交聯程度的半互穿型網狀結構；利用FTIR-ATR 鑑定SPI 的醯亞胺化以及PVA 和GA 的交聯反應特性。 最後利用熱性質分析、含水率、尺寸穩定性、氧化穩定性、質子傳導度、甲醇穿透度以及直接甲醇燃料電池（DMFC）發電效能來分析SPI/PVAs 共混聚合物和SIPN SPI/cPVA20-GAs 的質子交換膜特性。 | zh_TW |
| dc.description.abstract | In this study, a series of polyimide/poly(vinyl alcohol) (SPI/PVAs) polymer blend and semi-interpenetrating networks of sulfonated polyimide/poly(vinyl alcohol) polymer (SIPN SPI/cPVA20-GAs) proton exchange membranes were successfully synthesis. The linear polymer composes of sulfonated polyimide (SPI) derived from 1,4,5,8-naphthalenetetracarboxylic dianhydride (NTDA), sulfonated 4,4'-Bis(4-aminophenoxy)biphenyl (BDSA) and 4,4’-oxydianiline (ODA) were prepared by a thermal imidization reaction. SPI was blended with 5 phr, 10 phr and 20 phr PVA respectively to obtain SPI/PVAs polymer blend membranes. The networks structure of PVA was prepared by immersing SPI/PVA20 membrane in pH~1.4, 1vol% glutaraldehyde (GA) solution at 30℃. By controlling crosslinking time, different crosslinking degree of SIPN SPI/cPVA20-GAs membranes can be obtained. Fourier transform infrared spectroscopy (FTIR-ATR) were utilized to verify the synchronization of the imidization of sulfonated poly(amic acid) (SPAA) and the crosslinking reactions between PVA and GA. The structure-property relationship of proton exchange membranes are discussed in details according to the chemical structure of the various content and crosslinking degree of PVA in the SPI/PVAs polymer blend and SIPN SPI/cPVA20-GAs proton exchange membranes from the viewpoints of thermal stability, water uptake, dimension stability, proton conductivity, oxidation stability, methanol permeability, and direct methanol fuel cell (DMFC) performance. | en |
| dc.description.provenance | Made available in DSpace on 2021-06-13T03:14:41Z (GMT). No. of bitstreams: 1 ntu-100-R98524043-1.pdf: 2326421 bytes, checksum: e377c8fb3a52ae6a64586cd17bd66083 (MD5) Previous issue date: 2011 | en |
| dc.description.tableofcontents | 論文口試委員審定書 I
序言 II 中文摘要 III ABSTRACT IV 目錄 VI 圖目錄 X 表目錄 XIV 第一章 緒論 1 1-1 燃料電池基本原理 4 1-2 燃料電池種類 5 1-3 實驗目的 7 第二章 文獻回顧 8 2-1 直接甲醇燃料電池（DIRECT METHANOL FUEL CELL, DMFC）簡介 8 2-1.1 DMFC 工作原理 8 2-1.2 影響DMFC效能（Power density）的因素 10 2-2 直接甲醇燃料電池電解質膜 12 2-2.1 磺化聚芳烴高分子 14 2-2.2 質子在質子交換膜中的傳遞機制 15 2-3 磺化聚醯亞胺 （SULFONATED POLYIMIDE, SPI） 16 2-3.1 雙酐（dianhydrides） 17 2-3.2 二胺類單體 18 2-3.3 磺化二胺類單體對磺化聚醯亞胺（NTDA-based SPIs）的水解影響 18 2-4 SPI應用在氫燃料電池（PEMFC）的效能 20 2-5 共混聚合物 （POLYMER BLEND） 21 2-5.1 聚乙烯醇共混 （PVA Blend） 21 2-5.2 半互穿型網狀結構（Semi-interpenetrating Networks, SIPN）高分子 22 第三章 實驗設備與步驟 24 3-1 實驗材料與藥品 24 3-2 實驗設備 28 3-3 實驗步驟 30 3-3.1 磺化4，4-二（4-胺苯甲基）二胺（BAPBDS）單體合成 30 3-3.2 磺化聚醯亞胺 （SPI）合成 30 3-3.3 磺化聚醯亞胺/聚乙烯醇（SPI/PVAs）共混聚合物之質子交換膜製備 31 3-3.4 磺化聚醯亞胺/聚乙烯醇半互穿型網狀結構（SIPN SPI/cPVA20-GAs）之質子交換膜製備 31 3-3.5 Nafion117質子交換膜的前處理 32 3-3.6 膜電極組製備 32 3-4 質子交換膜之性能測試 33 3-4.1 離子交換容量（Ionic Exchange Capacity, IEC）測試 33 3-4.2 含水率（Water Uptake）測試 33 3-4.3 尺寸安定（Dimensional Change）測試 34 3-4.4 質子傳導度（Proton conductivity）測試 34 3-4.5 薄膜甲醇滲透率（Methanol permeability）測試 35 3-4.6 熱重損失分析儀分析（TGA）測試 38 3-4.7 示差掃瞄熱卡計(Differential Scanning Calorimeter, DSC) 38 3-4.8 氧化穩定性（Oxidation stability）測試： 38 3-4.9 拉力測試 39 3-4.10 場發射掃描式電子顯微鏡（FE-SEM）分析 39 3-4.11 DMFC放電效能測試 39 第四章 結果與討論 42 4-1 質子交換膜之合成鑑定 42 4-1.1 磺化4，4-二（4-胺苯甲基）二苯（BAPBDS）單體之合成鑑定 42 4-1.2 磺化聚醯亞胺（SPI）與磺化聚醯亞胺/聚乙烯醇（SPI/PVAs）共混聚合物之合成鑑定 43 4-1.3 磺化聚醯亞胺/聚乙烯醇半互穿型網狀結構（SIPN SPI/cPVA20-GAs）之合成鑑定 44 4-2 質子交換膜之熱性質分析 46 4-2.1 熱重分析（Thermogravimetric Analysis, TGA） 46 4-2.2 示差掃瞄熱卡計（Differential Scanning Calorimeter, DSC）分析 48 4-3 質子交換膜之物性分析 50 4-3.1 離子交換容量、含水率與尺寸安定性分析 50 4-3.2 質子傳導度（Proton conductivity） 51 4-3.3 甲醇滲透率（Methanol permeability） 53 4-3.4 氧化穩定性（Oxidation stability） 57 4-4 DMFC效能分析（SINGLE CELL PERFORMANCE） 59 4-4.1 質子交換膜在2 MMeOH(aq)下的DMFC 池效能探討 59 4-4.2 質子交換膜在4 MMeOH(aq)與6 MMeOH(aq)下的DMFC 效能探討 62 第五章 結論 65 參考文獻 66 附錄 71 附錄一 SEM觀察質子交換膜厚度與MEA剖面圖 71 附錄二 SPI與SPI/PVAS共混聚合物之DSC圖 73 附錄三 NAFION117、SPI、SPI/PVAS共混聚合物與SIPN SPI/CPVA20-GAS質子交換膜在不同甲醇濃度下的甲醇穿透率（WT.%/S） 75 附錄四 NAFION117、SPI/CPVA20-GA10MIN 與SPI/CPVA20-GA1HR 在2 MMEOH(AQ)、4 MMEOH(AQ) 與6 MMEOH(AQ) 下進行DMFC效能分析 84 | |
| dc.language.iso | zh-TW | |
| dc.subject | 聚乙烯醇 | zh_TW |
| dc.subject | 磺化聚醯亞胺 | zh_TW |
| dc.subject | 共混聚合物 | zh_TW |
| dc.subject | 半互穿型網狀 | zh_TW |
| dc.subject | 質子交換膜 | zh_TW |
| dc.subject | 戊二醛 | zh_TW |
| dc.subject | 直接甲醇燃料電池 | zh_TW |
| dc.subject | proton exchange membrane | en |
| dc.subject | DMFC | en |
| dc.subject | glutaraldehyde | en |
| dc.subject | poly(vinyl alcohol) | en |
| dc.subject | sulfonated polyimides | en |
| dc.subject | polymer blend | en |
| dc.subject | semi-interpenetrating | en |
| dc.title | 磺化聚醯亞胺/聚乙烯醇半互穿型網狀結構體作為燃料電池之質子交換膜的研發 | zh_TW |
| dc.title | Studies on Preparation of Semi-interpenetrating Networks of Sulfonated Polyimide/Poly(vinyl alcohol) as Proton Exchange Membranes for Fuel Cell Application | en |
| dc.type | Thesis | |
| dc.date.schoolyear | 99-2 | |
| dc.description.degree | 碩士 | |
| dc.contributor.oralexamcommittee | 王怡仁(Yen-Zen Wang),韓錦鈴(Jin-Lin Han),李其鴻(Chi-Hung Lee) | |
| dc.subject.keyword | 半互穿型網狀,共混聚合物,磺化聚醯亞胺,聚乙烯醇,戊二醛,質子交換膜,直接甲醇燃料電池, | zh_TW |
| dc.subject.keyword | semi-interpenetrating,polymer blend,sulfonated polyimides,poly(vinyl alcohol),glutaraldehyde,proton exchange membrane,DMFC, | en |
| dc.relation.page | 85 | |
| dc.rights.note | 有償授權 | |
| dc.date.accepted | 2011-08-01 | |
| dc.contributor.author-college | 工學院 | zh_TW |
| dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
| 顯示於系所單位： | 化學工程學系 | |
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