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完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.advisor | 呂宗昕 | |
dc.contributor.author | Bo-Jun Shen | en |
dc.contributor.author | 沈柏君 | zh_TW |
dc.date.accessioned | 2021-06-13T02:05:08Z | - |
dc.date.available | 2012-07-16 | |
dc.date.copyright | 2007-07-16 | |
dc.date.issued | 2007 | |
dc.date.submitted | 2007-07-02 | |
dc.identifier.citation | [1] J. M. Tarascon and M. Armand, Nature, 414 (2001) 359.
[2] M. K. Aydinol and G. J. Ceder, J. Electrochem. Soc., 144 (1997) 3832. [3] T. Nagaura and K. Tozawa, Prog. Batt. Solar Cells, 9 (1990) 209. [4] M. S. Whittingham, J. Electrochem. Soc. 123 (1975) 315. [5] D. W. Murphy, F.A. Trumbore, J. Cryst. Growth, 39 (1977) 185. [6] J. Broadhead, F.A. Trumbore, S. Basu, J. Electroanal. Chem. 118 (1981) 241. [7] B. V. Ratnakumar, C. L. Ni, S. DiStefano, R. B. Somoano, C. P. Bankston, in Primary and Secondary Ambient Temperature Lithium Batteries (Eds: J.-P. Gabano, Z. Takehara, P. Bro), Electrochemical Society, Pennington, NJ 1988, PV88-6, p. 565. [8] B. Vyas, in Proc. of the 33rd Int. Power Sources Symp., Electrochemical Society, Pennington, NJ 1988, p. 101. [9] F. A. Trumbore, J. Power Sources 26 (1989) 65,. [10] S. Basu, F. A. Trumbore, J. Electrochem. Soc. 139 (1992) 3379,. [11] W. Kronert, K. Plieth, Z. Anorg. Allg. Chem. 336 (1965) 207. [12] A. Meerschaut, J. Rouxel, J. Less-Common Met. 39 (1975) 197. [13] J. Broadhead, F.A. Trumbore, S. Basu, Prog. Electrochem. 15 (1981) 241. [14] M. S. Whittingham, Ann. Chim. Paris 7 (1982) 204. [15] G. Pistoia, L. Li, G. Wang, Electrochim. Acta, 37 (1992) 63. [16] J. A. Wilson, A. D. Yoffe, Adv. Phys. 18 (1969) 193. [17] B. G. Silbernagel, Solid State Commun. 17 (1975) 361. [18] M. S. Whittingham, F. R. Gamble, Mater. Res. Bull. 10 (1975) 363. [19] A. J. Jacobson, R. R. Chilannelli, M. S. Whittingham, J. Electrochem. Soc. 12(1979) 2277. [20] K. Kobayashi, K. Kosuge, S. Kachi, Mater. Res. Bull. 4 (1969) 95. [21] W. Rüdorf, H. Becker, Z. Naturforsch. 9 (1954) 614. [22] J. C. Anderson, M. Schieber, J. Phys. Chem. Solids 25 (1964) 961. [23] W. D. Johnston, R. R. Heikes, D. Sestrich, J. Phys. Chem. Solids, 7 (1954) 1. [24] J. B. Goodenough, D. G. Wickham, W. J. Croft, J. Appl. Phys. 29 (1958) 382. [25] J. B. Goodenough, D. G. Wickham, W. J. Croft, J. Phys. Chem. Solids 5 (1958) 107. [26] L. D. Dyer, B. S. Borie, Jr., G. P. Smith, J. Am. Chem. Soc. 76 (1954) 1433. [27] W. Y. Liang, in Intercalation in Layered Materials (Ed: M. S. resselhaus), NATO ASI Series B 1986, Vol. 148, p. 31. [28] J. P. Parant, R. Olazcuga, M. Devalette, C. Fouassier, P. Hagenmuller, J. Solid State Chem., 3 (1971) 1. [29] C. Fouassier, G. Matejka, J. M. Reau, P. Hagenmuller, J. Solid State Chem., 6 (1973) 532. [30] M. G. S. R. Thomas, P. G. Bruce, J. B. Goodenough, Solid State Ionics, 18-19 (1986) 794. [31] M. G. S. R. Thomas, P. G. Bruce, J. B. Goodenough, Solid State Ionics, 17 (1985) 13. [32] J. J. Auborn, Y. L. Barberio, J. Electrochem. Soc. 134 (1987) 638. [33] T. Ohzuku, A. Ueda, M. Nagayama, Y. Iwakoshi, H. Komori, Electrochim. Acta 38 (1993) 1159. [34] M. Broussely, F. Perton, P. Biensan, J. M. Bodet, J. Labat, A. Lecerf, C. Delmas, A. Rougier, J. P. Peres, J. Power Sources 54 (1995) 109. [35] P. G. Bruce, A. Lisowska-Oleksiak, M. Y. Saidi, C. A. Vincent, Solid State Ionics 57 (1992) 353. [36] J. R. Dahn, U. von Sacken, C. A. Michal, Solid State Ionics, 44 (1990) 87. [37] H. Hirano, R. Kanno, Y. Kawamato, Y. Takeda, K. Yamaura, M. Takano, K. Ohyama, M. Ohashi, Y. Yamaguchi, Solid State Ionics, 78 (1995) 123. [38] L. A. de Picotto, M. M. Thackeray, G. Pistoia, Solid State Ionics, 28-30 (1988) 1364. [39] R. Hoppe, G. Brachtel, M. Jansen, Z. Anorg. Allg. Chem. 417 (1975) 1. [40] T. Ohzuku, A. Ueda, T. Hirai, Chem. Express, 7 (1992) 193. [41] L. Chen, J. Schoonman, Solid State Ionics, 67 (1993) 17. [42] L. Chen, X. Huang, E. Kelder, J. Schoonman, Solid State Ionics, 76 (1995) 91. [43] J. Barker, R. Pynenburg, R. Koksbang, J. Power Sources, 52 (1994) 185. [44] J. Barker, R. Pynenburg, R. Koksbang, J. Power Sources 52, (1994) 185. [45] T. Ohzuku, Y. Makimura, Chem. Lett. (2001) 642. [46] T. Ohzuku, A. Ueda, M. Nagayama, Y. Iwakoshi, H. Komori, Electrochim. Acta 38 (1993) 1159. [47] M.K. Aydinol, A.F. Kohan, G. Ceder, K. Cho, J. Joannopoulos, Phys. Rev. B 56 (1997) 1354. [48] C. Wolverton, A. Zunger, Phys. Rev. B 57 (1998) 2242. [49] Y. Koyama, I. Tanaka, H. Adachi, Y. Makimura, T. Ohzuku, J. Power Source, 119-121,(2003) 644-648. [50] C.R. Strauss, Aust. J. Chem. 52 (1999) 83. [51] S. Caddick, Tetrahedron 51 (1995) 10403. [52] S.A. Galima, Chem. Soc. Rev. 26 (1997) 233. [53] T. Vidal, A. Petie, A. Loupy, R.N. Gedye, Tetrahedron 56 (2000) 5473. [54] M.S. Khajavi, F. Nikpour, M. Hajihadi, J. Chem. Res. (1996) 96. [55] M. Kidwai, R. Kumar, Gazz. Chim. Ital. 127 (1997) 263. [56] D. Guyomard, J.M. Tarascon, Solid State Ionics 69 (1994) 222. [57] J.M. Tarascon, M. Armand, Nature 414 (2001) 359 [58] C.H. Lu, H.C. Wang, J. Eur. Ceram. Soc. 23 (2003) 865. [59] C.H. Lu, H.C. Wang, J. Mater. Chem. 13 (2003) 428. [60] K. Kang, Y.S. Meng, J. Breger, C.P. Grey, G. Ceder, Science 311 (2006) 977. [61] J. Molenda, Material Science-Poland 24, 1 (2006) 61. [62] J. Lu, Z. Tang, Z. Zhang, W. Shen, The Electrochemical Society, 152, 7, (2005) A1441. [63] Z. Lu, D.D. MacNeil, J.R. Dahn, Elecrtrochem. Solid-State Lett. 4 (12) (2001) A200. [64] D.D. MacNeil, Z. Lu, J.R. Dahn, J. Electrochem. Soc. 149 (10) (2002) A1332. [65] T. Ohzuku and Y. Makimura, Chem. Lett., 2001 642. [66] K.M. Shaju, G.V. Subba Rao, B.V.R. Chowdari, Electrochim. Acta 48 (2002) 145. [67] C.H. Chen, C.J. Wang, B.J. Hwang, J. Power Sources 146 (2005) 626. [68] M.-H. Lee, Y.-J. Kang, S.-T. Myung, Y.-K. Sun, Electrochim. Acta 50, (2004) 939. [69] Y. Kim, H. S. Kim, S. W. Martin, Electrochim. Acta 52 (2006) 1316. [70] X. Jia, W. He, X. Zhang, H. Zhao, Z. Li, Y. Feng, Nanotechnology 18 (2007) 075602 [71] L. Ma, W.X. Chen, Y.F. Zheng, J. Zhao, Z.Xu, Matt. Lett. 61 (2007) 2765 [72] A.S. Shaporev, V.K. Ivanov, A.E. Baranchikov, Y.D. Tret’yakov, Inorganic Mater. 43 (2007) 35. [73] K.S. Park, M.H. Cho, S.J. Jin, K.S. Nahm, Electrochem. Solid-state Lett. 7 (2004) A239. [74] T. Ohuzuku, A. Ueda, M. Nagayama, J. Electrochem. Soc. 140 (1993) 1862 [75] P.Y. Liao, J.G. Duh, S.R. Sheen, J. Electrochem. Soc. 152 (2005) A1695. [76] P. Lidstrom, J. Tierney, B. Wathey, J. Westman, Tetrahedron 57 (2001) 9925. [77] T.H. Cho, S.M. Park, M. Yoshio, T. Hirai, Y. Hideshima, J. Power Sources 142 (2005) 306. [78] D. Li, T. Muta, L. Zhang, M. Yoshio, H. Noguchi, J. Power Sources 132 (2004) 150. [79] D.C. Li, T. Muta, L.Q. Zhang, M. Yoshio, H. Noguchi, J. Power Sources 132 (2004) 150 [80] C.H. Lu, H.C. Wang, J. Mater. Chem., 13 (2003) 428. [81] C.H. Lu, H.H. Chang, Y.K. Lin, Ceram. Int. 20 (2004) 1641. [82] C.H. Lu, S.W. Lin, J. Power Sources 97 (2001) 458. [83] A.S. Shaporev, V.K. Ivanov, A.E. Baranchikov, Y.D. Tret’yakov, Inorganic Mater. 43 (2007) 35. [84] S. Jouanneau, J. R. Dahn, Chem. Mater. 15 (2003) 495. [85] J. Guao, L. F. Jiao, H. T. Yuan, H. X. Li, M. Zhang, Y. M. Wang, Electrochimica Acta 51 (2006) 3731. [86] A. Rougier, P. Gravereau, C. Delmas, J. Electrochem. Soc. 143 (1996) 1168. [87] T. Ohzuku, A. Ueda, M. Nagayama, Y. Iwakoshi, H. Komori, Electrochem. Acta 38 (1993) 1159. [88] M. Kageyama, D. Li, K. Kobayakawa, Y. Sato, Y.S. Lee, J. Power Sources 157 (2006) 494. [89] P. Lidstrom, J. Tierney, B. Wathey, J. Westman, Tetrahedron 57 (2001) 9925. [89] Y.M. Todorov, K. Numata, Electrochim. Acta 50 (2004) 495. [90] J. Cho, B. Park, J. Power Source 92 (2001) 35. [91] C.H. Lu, S.K. Saha, Materials Science and Engineering B79 (2001) 247. [92] S.H. Park, H.S. Shin, S.T. Myung, C.S. Yoon, K. Amine, Y.K. Sun, Chem. Mater. 17 (2005) 6. [93] A.J. Bard, L.R. Faulkner, Electrochemical Methods, second ed., Wiley (2001) p384. [94] H. Liu, Q. Cao, L.J. Fu, C. Li, Y.P. Wu, H.Q. Wu, Electrochem. Commun. 8 (2006) 1553. [95] K.M. Shaju, G.V. Subbb Rao, B.V.R. Chowdari, J. Electrochem. Soc. 151 (2004) A1324. | |
dc.identifier.uri | http://tdr.lib.ntu.edu.tw/jspui/handle/123456789/30487 | - |
dc.description.abstract | 本研究成功利用微波水熱法合成層狀材料LiNi1/3Co1/3Mn1/3O2,在800oC溫度下可得良好結晶相之粉體。此法和目前最常用的共沉澱法互相比較,微波水熱法不僅僅節省了許多共沉澱法的複雜步驟和總反應時間,而且還有效地減少粉體的平均粒徑大小,電性的結果皆顯示利用微波水熱的合成粉體比共沉澱法還要優良。
而當進一步改變微波溫度以觀察其影響時,發現當微波反應溫度增加時,先驅物粉體的凝團程度減少,導致許多二次粒子皆轉變成粉體粒徑較小的一次粒子,此結果進而促使煆燒後層狀粉體的比表面積增加,亦增強許多粉體電化學特性上的表現。當微波溫度達到180oC時,其最後產物的粉體在0.1C-rate測試條件下達到約170 mAh/g的高電容量,10圈之後的保留值依然有98.5%,從EIS測試中,可以算出此粉體擁有高鋰離子擴散係數,此結果有助於高速充放電的特性測試。因此可以從結果中得到一個重要的結論:對於微波水熱系統來說,溫度是控制粉體的一個重要的參數,導致粉體表現出不同的電化學特性。 | zh_TW |
dc.description.abstract | LiNi1/3Co1/3Mn1/3O2 powders have been successfully synthesized through a developed microwave-hydrothermal (M-H) process. In comparison with the co-precipitation process having complicated steps, the microwave-hydrothermal process not only reduced the reaction time for preparing LiNi1/3Co1/3Mn1/3O2, but also effectively decreased the average particle size of powders. The results of electrochemical performance show that the sample prepared by the microwave hydrothermal process is superior to that by the co-precipitation method.
In order to study the influences of microwave-radiated temperatures on the morphology of particles, the temperature during the reaction was changed. When the microwave-radiated temperature increased from 100oC to 180oC, the particles exhibited a less agglomerated morphology and reduced particle size. Increasing the microwave-radiated temperatures of preparation for precursors not only increased the surface area of LiNi1/3Co1/3Mn1/3O2 powders but also enhanced the electrochemical performances. When the temperature of microwave-hydrothermal treatment was raised to 180oC, the final products of LiNi1/3Co1/3Mn1/3O2 exhibited significantly improved characteristics. It showed that the discharge capacity was approximately 170 mAh/g and the retention was 98.5% after 10 cycles. The prepared materials also exhibited high lithium ion diffusion coefficient and good rate capability in EIS tests. | en |
dc.description.provenance | Made available in DSpace on 2021-06-13T02:05:08Z (GMT). No. of bitstreams: 1 ntu-96-R94524086-1.pdf: 2650554 bytes, checksum: 7d4d71bbc953227833abb274c81828a2 (MD5) Previous issue date: 2007 | en |
dc.description.tableofcontents | 摘要
Abstract Table of contents………………………………………VI Lists of Figures……...………….… .………….VIII Lists of Tables………………………………………..X Chapter 1 Introduction and Background 1.1 Rechargeable Lithium Batteries………………………………....………....1 1.2 Cathode Materials…………………………………………………………..3 1.2.1 One-dimensional Hosts…..…………………………………..……….4 1.2.2 Two-dimensional Hosts……….…………………………………….. 6 1.2.2.1 Layered-Type Transition-Metal Dichalcogenides…..……… 6 1.2.2.2 Layered-Type Transition-Metal Dioxides…………………...8 1.2.3 Three-Dimensional Hosts…………....……………………………...12 1.2.4 LiNi1-x-yCoxMyO2………………………..…………………………..13 1.3 Synthesis methods………………………………………………………...16 1.3.1 Concept…………………..………………………………………….16 1.3.2 Rate enhancement..……………………….…………………………16 1.3.3 More Uniform and Unique…………………………..……………...17 1.3.4 Synthesis Mechanisms……………………………………………....18 1.4 Research Objectives….…………………………..…...…………………..19 Chapter 2 Preparation and Electrochemical Characteristics of LiCo1/3Ni1/3Mn1/3O2 via the Microwave-Hydrothermal Process 2.1 Introduction………………………………………………………………..29 2.2 Experimental………………………………………………………………32 2.3 Results and Discussion……….................................…………………….35 2.3.1 Microwave-hydrothermal method compared to co-precipitation method for preparing LiNi1/3Co1/3Mn1/3O2 powders……………….……………….….35 2.3.2 Preparing LiNi1/3Co1/3Mn1/3O2 powders at various microwave radiation temperature……………………………………………………...…...………..39 2.4 Summary……………………………………………………………….48 Chapter 3 Conclusion……..……………………………………………..72 References……………………………………..…………………………...74 | |
dc.language.iso | en | |
dc.title | 鋰離子二次電池多成份層狀陰極材料之製備與特性分析 | zh_TW |
dc.title | Preparation and Electrochemical Characterization of Multicomponent Layered Cathode Materials for Lithium Ion Secondary Batteries | en |
dc.type | Thesis | |
dc.date.schoolyear | 95-2 | |
dc.description.degree | 碩士 | |
dc.contributor.oralexamcommittee | 吳弘俊,蔡大翔 | |
dc.subject.keyword | 鋰離子二次電池,陰極材料,微波水熱,LiNi1/3Co1/3Mn1/3O2氧化物,微波輻射溫度, | zh_TW |
dc.subject.keyword | Lithium ion battery,cathode materials,microwave hydrothermal,LiNi1/3Co1/3Mn1/3O2 oxide,microwave radiation temperature, | en |
dc.relation.page | 77 | |
dc.rights.note | 有償授權 | |
dc.date.accepted | 2007-07-03 | |
dc.contributor.author-college | 工學院 | zh_TW |
dc.contributor.author-dept | 化學工程學研究所 | zh_TW |
顯示於系所單位: | 化學工程學系 |
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